SiO2分子的基态(X1A1)结构与分析势能函数

应用群论及原子分子反应静力学方法推导了SiO₂分子的电子态及其离解极限，采用B3P86方法，在6-311G^**水平上,优化出SiO₂基态分子稳定构型为单重态的C_2V构型，其平衡核间距R_e=R_Si—O=0.1587 nm,∠OSiO＝111.2°,能量为-440.4392 a.u..同时计算出基态的简正振动频率:对称伸缩振动频率ν(B₂)=945.4cm^-1，弯曲振动频率ν(A₁)=273.5 cm^-1和反对称伸缩振动频率ν(A₁)=1362.9cm^-1.在此基础上，使用多体项展式理论方法，导出了基态SiO₂分子的全空间解析势能函数，该势能函数准确再现了SiO₂(C_2V)平衡结构.     

质量数在160-180核区形变双奇核高自旋态实验研究

基于在160-180核区形变双奇核高自旋态研究中所取得的研究结果和最近几年陆续发表的双奇核高自旋态核谱学数据,系统地考察和研究了πh_11/2⊙νi_13/2强耦合带和πh_9/2⊙νi_13/2半退耦带旋称反转的特征和规律.指出^182,184Au核素的πh_13/2⊙νi_13/2半退耦带也可能出现旋称反转;有限的实验数据似乎支持这一观点.首次在双奇核^178,180Ir的πh_11/2⊙νi_13/2强耦合带中发现了低转频下的逐渐顺排现象;在¹⁷⁸Ir核中发现了回弯频率反常超前.这些反常现象可能与核形变(或中子对力)的组态依赖性有关.     

Ⅰ类和Ⅱ类准周期半导体超晶格的电子子带和波函数

本文将包迹函数近似推广用于计算有理数近似下,垂直于超晶格轴的波矢K_⊥不等于零时,准周期半导体超晶格(QSS)的电子子带和波函数,对K_⊥=0的情形,分别计算了Ⅰ类的GaAs/Al_xGa_1-xAs和Ⅱ类的InAs/GaSb QSS的电子子带和波函数,直至代序数m=9和6。对于价带对导带影响强的InAs/GaSb QSS,分别计算了m=5和6时电子子带随K_⊥的变化关系。并提出了利用本文结果计算Ⅰ类的GaAs/Al_xGa_1-xAs QSS带间集体激发的具体方法。     

光纤布喇格光栅器件应力疲劳评价理论研究

在10℃~230℃温差下,对大气相干长度r₀分别采用夏克-哈特曼的到达角起伏法、差分像运动法、波面法三种测量法和四象限探测器进行了测试和对比;对折射率结构常量C_n²及闪烁功率谱分别采用夏克-哈特曼和光电倍增管进行对比.实验结果表明:对于r₀,在强湍流时四象限探测器比夏克-哈特曼的稳定性明显降低,且对夏克-哈特曼三种方法,差分像运动法可克服设备抖动等问题,但引入了方向上不一致的问题,波面法可有效避免该问题;对于C_n²,夏克-哈特曼比光电倍增管测量更稳定,拟合相关系数高达0.96;对于闪烁功率谱,由于噪音影响,在200℃时夏克-哈特曼比光电倍增管测得的最大频率高15 Hz;最后,通过对夏克-哈特曼子孔径的闪烁功率谱分析得出,若同一子孔径入射光强不在CCD响应的线性区间时无法准确测量闪烁功率谱,否则可通过不同子孔径可完成湍流均匀性的测量.这将为湍流池提供最优的测试方法及理论依据.     

聚酰胺6的红外光谱

根据对聚酰胺类高聚物红外光谱的类比和对聚酰胺6试样进行氘化和碘处理后红外光谱的改变,以及根据对拉伸过的聚酰胺6薄膜试样的偏振红外光谱的观察,我们对聚酰胺6红外光谱中400cm^-1—1400cm^-1之间的主要吸收带,作了如下解释:1370cm^-1吸收带为ν_(cщN);1265cm^-1和1205cm^-1吸收带为δ_N-H+ν_(cщN)(酰胺Ⅲ);1170cm^-1吸收带为ν_(cN);730cm^-1吸收带为γ_(CH2)[当(CH₂)_n的n≥4时];690cm^-1吸收带为δ_N-H(面外);580cm^-1吸收带亦为δ_N-H(面外)。     

单光子波长调制吸收光谱用于1.5 μm激光器的波长锁定

提出了一种kHz调制频率量级的单光子调制技术,实现对激光器的实时锁定. 通过探测乙炔气体的单光子吸收光谱,对离散的单光子响应脉冲进行锁定放大, 获得激光器频率锁定的鉴频曲线.将1.5 μm分布反馈半导体激光器的输出频率稳定在乙炔气体 ν₁ + ν ₃带P5e支吸收峰上,在175 s内典型激光频率起伏小于25 MHz. 这种基于单光子波长高频调制吸收光谱的稳频技术消除了低频段较高背景的噪声, 可应用于单光子量级的量子保密通讯系统以及光学波分复用系统.     

射频电感耦合夹层等离子体中的模式转换

本文利用微波相位法和光谱诊断法, 研究了ICP放电等离子体在圆台状夹层等离子体中E模和H模相互转换的物理现象. E模和H模的之间转换过程是一个瞬间突变的, 转换点的输入功率随真空室压强的变化而变化. H模向E模转换的阈值功率低于E模向H模转换的值, 等离子体参数随输入功率变化曲线类似于铁磁物质中的磁滞回线. Ar II 408.2 nm谱线的强度的变化规律和电子密度随功率变化的规律基本一致. 通过本实验可以获得一种电子密度范围为3.85×10¹¹ cm^-3 < n_e < 4.68× 10¹¹ cm^-3, 外表面积为0.3 m², 厚度为2 cm稳定工作的等离子体源.     

双奇核中π1/2－[541]⊙νi13/2带的系统学特征

通过束流能量为97MeV的¹⁵²Sm(¹⁹F,5n)¹⁶⁶Lu熔合蒸发反应,用在束γ(谱学方法研究了¹⁶⁶的高自旋态,建立了5条转动带,其中3条带是本实验中首次确定的.发现了π1/2^－[541]⊙ν5/2⁺[642]带的低自旋旋称反转现象,该带的反转点自旋值17.5h同A=170区奇奇核的π1/2^－[541]⊙νi_13/2带的反转点变化趋势非常相符.     

PT-PEK-c电光聚合物薄膜的厚度和介电性质

研制了新的PT-PEK-c电光聚合物薄膜材料,用准波导耦合m线方法测量了PT-PEK-c电光聚合物薄膜的厚度,并测量了该聚合物薄膜在1×10²Hz到1×10⁷Hz频率范围内的室温介电常数.测量结果为:厚度d=2.328±0.315μm,在10KHz下,介电常数ε_r＝4023±0.063,介电损耗tanδ＝0.003.     

169Re的转动带结构组态相关性研究

研究了¹⁶⁹Re的高自旋态能级结构,建立了组态为π9/2^－[514]的强耦合带和组态为π1/2^－[541]的退耦合带,推转壳模型(Cranked shell model)计算结果表明组态相关的不同形变能够解释这些转动带的不同带交叉频率,在已知的奇ARe核中,¹⁶⁹Re的9/2^－[514]转动带在低自旋时具有最大的能量旋称劈裂,当一对i_13/2中子顺排后,旋称劈裂发生了反转,并且劈裂的幅度非常显著地减少了,另外,还观测到了一个三准粒子激发带,并指定了它的最可能组态为π9/2^－[514]⊙νAE。     

Performance Evaluation and Effectiveness of the Reverberation Room

This research presents a thorough evaluation of the reverberation room at Acoustics Laboratory in National Institute of Standards (NIS) according to the related international standards. The evaluation aims at examining the room performance and exploring its effectiveness in the frequency range from 125 Hz to 10000 Hz according to the international standard requirements. The room, which was designed and built several years ago, is an irregular rectangular shape free from diffusers. Its volume is about 158.84 m³, which meets the requirement of the ISO 354 standard L_max < 1.9V^1/3. Cut-off frequencies of one and one-third octave are 63 Hz and 100 Hz respectively; however Schroder frequency is 400 Hz. Calculations of cut-off frequency and modal density showed adequate modes that give acceptable uniformity starting comfortably from frequency of 125 Hz. The room has a reverberation time that is suitable for its size over the frequency range of interest. The room sound absorption surface area and its sound absorption coefficient satisfy the criteria given in ISO 3741 and ISO 354. There is an accepted diffuse sound field inside the room due to the standard deviation of measured sound level, which is less than 1.5 dB over all the frequency range. The only exception was 125 Hz which may be due to a lack of diffusivity of the sound field at this frequency. The evaluation proves that the NIS reverberation room is in full agreement with the international standards, which in turns qualifies the room to host measurements inside without concerns.     

Effect of the internal rotation of the CHD2 group on the CH stretching infrared and Raman spectra of toluene C6D5CHD2 and nitromethane NO2CHD2 in vapor phase

Gas-phase infrared and Raman spectra of toluene C₆D₅CHD₂ and nitromethane NO₂CHD₂ were recorded in the CH stretching region. They are all characterized by a strong band with a weaker one at lower frequency. These bands have simple Raman profiles and their infrared contours are respectively of A and C type. A quantum theory of these spectra is put forward, assuming an anharmonic coupling of the νCH mode with the internal rotation of the CHD₂ group in the adiabatic approximation. Theoretical calculations based on this model give a good fit of the experimental Raman bandshapes and a good picture of the observed infrared spectra. Thus each of the observed bands can be characterized. The frequency of the intense band is the average of that of the νCH mode during the almost free internal rotation of the CHD₂ group, while the frequency of the weaker band is approximately equal to the minimal νCH frequency. This last one corresponds to the position of the CH bond in a plane perpendicular to that of the molecule (ν_⊥CH). The frequency difference between ν_∥CH (the CH bond being in the plane of the molecule) and ν_⊥CH is found to be 42 cm^?1 for the two compounds.     

Transverse momentum of hadrons produced in ν and ν interactions on an isoscalar target in BEBC

The average transverse momentum squared, 〈p_⊥²〉, of hadrons is studied as a function of W² and of Q² for ν and $\text{ν}$ interactions on an isoscalar target. An increase of 〈p_⊥²〉 with W² is observed for the hadrons emitted forward in the hadronic c.m.s. The p_⊥ dependence of the fragmentation function is found to factorise from the structure function at fixed W, but does not factorise at fixed Q². Unlike the case of forward-going particles, the 〈p_⊥²〉 of hadrons going backward in the c.m.s. shows no strong dependence on W².     

变压器典型工作环境对声功率测量结果的影响

变压器两侧常建有高大的防火墙,其从声学角度可视为刚性反射壁面,会改变变压器的辐射声场,进而影响变压器声功率测量结果。本文利用有限元、边界元等数值计算方法建立了变压器声辐射的仿真模型用以分析反射壁面对变压器声功率测量结果的影响,并通过实际测量验证了仿真计算所得结论。结果表明,反射壁面对变压器声功率测量结果的影响程度随反射壁面到变压器箱体距离增加而减弱,且当反射壁面距变压器箱体5 m以上时,其对变压器声功率基频及各谐波成份测量结果的影响均在2 dB以内。另外反射壁面对变压器噪声高频成份声功率测量结果的影响较大,而对100 Hz、200 Hz等低频成份测量结果影响较小,基本低于3 dB。     

Frequencies Rotation at High Sound Pressure Levels Toward Low Frequencies

Today, analyzing of sound pressure level and frequency is considered as an important index in human society. Sound experts believe that analyzing of these parameters can help us to better understanding of work environments. Sound measurements and frequency analysis did to fix the harmful frequency in all sections in Shiraz gas power plant with sound analyzer model BSWA 308. The sound pressure levels (L_P) and the one and one-third octave band were continuously measured in A and C weighting networks and slow mode for time response. Excel 2013 and Minitab 18.1 software used for statistical calculations. Results analyzed by Minitab 18.1 software. The highest harmful frequency in Shiraz Gas Power Plant (SGPP) was 50 Hz with 115 dB. The sound pressure level (SPL) ranged from 45 dB to 120 dB in one-third octave band and weighting network C. The maximum sound pressure level was in Craft electricity generator with 105.3 dB and 67 Hz. Sound pressure level in surrounded environment was 120 dB. According to the results, in this industry the sound pressure level exceeded the Occupational Exposure Level of Iran (OEL). The value of sound pressure level were higher than the Standard of occupational health. SGPP consumes 47000 cubic meters of natural gas per hour to produce 100 MW (Mega Watt) of electricity. It is very high and it is not economical and cost effective. These numbers indicate that the power plant’s efficiency is low. It could be concluded that the noise pollution is an important issue in these industries. Moreover, SGPP produce noise with loss energy. Frequencies rotation at high sound pressure levels toward low frequencies were happened.     

Adjustment on subjective annoyance of low frequency noise by adding additional sound

Structure-borne noise originating from a heat pump unit was selected to study the influence on subjective annoyance of low frequency noise (LFN) combined with additional sound. Paired comparison test was used for evaluating the subjective annoyance of LFN combined with different sound pressure levels (SPL) of pink noise, frequency-modulated pure tones (FM pure tones) and natural sounds. The results showed that, with pink noise of 250-1000 Hz combined with the original LFN, the subjective annoyance value (SAV) first dropped then rose with increasing SPL. When SPL of the pink noise was 15-25 dB, SAV was lower than that of the original LFN. With pink noise of frequency 250-20,000 Hz added to LFN, SAV increased linearly with increasing SPL. SAV and the psychoacoustic annoyance value (PAV) obtained by semi-theoretical formulas were well correlated. The determination coefficient (R²) was 0.966 and 0.881, respectively, when the frequency range of the pink noise was 250-1000 and 250-20,000 Hz. When FM pure tones with central frequencies of 500, 2000 and 8000 Hz, or natural sounds (including the sound of singing birds, flowing water, wind or ticking clock) were, respectively, added to the original sound, the SAV increased as the SPL of the added sound increased. However, when a FM pure tone of 15 dB with a central frequency of 2000 Hz and a modulation frequency of 10 Hz was added, the SAV was lower than that of the original LFN. With SPL and central frequency held invariable, the SAV declined primarily when modulation frequency increased. With SPL and modulation frequency held invariable, the SAV became lowest when the central frequency was 2000 Hz. This showed a preferable correlation between SAV and fluctuation extent of FM pure tones.     

Development of a hand-held sensor probe for detection of sound components radiated from a specific device using surface intensity measurements

In this paper, a hand-held sensor probe is developed for surface intensity measurements. The sensor probe is composed of a 1/2-in. condenser microphone and a lightweight accelerometer of 1 g (=10⁻³ kg) which are connected with a vibration damper made of silicon rubber. The reliable measurement range of the sensor probe is examined and shown to be 100 Hz to7 kHz for sound and vibration. The precision of intensity measurements is confirmed by experiments in noisy environment. The precision is shown to be less than 3 dB for a random noise environment when the S/N is greater than −10 dB and for pure tone environment when the S/N is greater than −5 dB. The sensor probe is applied to determine the sound power level of a hard disc drive unit of a personal computer in an office setting. Good agreement is obtained for A-weighted sound power levels determined by the ISO method.     

薄膜型声学超材料对低频振动的隔声特性分析*

高效共振混合机工作频率为60 Hz,且系统处于共振,产生较大低频噪声。针对振动机械产生的有害噪声,分析了高效共振混合机低频高加速度共振混合过程的特点,得到了60 Hz低频声波穿透力强特点,相比传统的以吸声材料构建的50~100 mm厚度、隔声效果小于10 dB的隔声罩,分析了薄膜型声学超材料在低频减振降噪中的隔声特性。通过多物理场仿真分析,60 Hz时隔声量为31.4 dB,确定了硅橡胶弹性薄膜的预应力和质量块的面密度;采用3D打印机快速成型技术,构建了隔声实验装置,分析了独立隔声单元、面密度、薄膜尺寸等隔声特性规律。基于人耳在实际环境中感受到的噪声强度,提出了噪声衰减量和插入损失的分析方法,在距离声源380 mm和1000 mm的位置,60 Hz时隔声量分别为27 dB和38 dB。研究成果丰富了低频隔声特性理论,为薄膜型声学超材料的工程设计和优化提供了技术支撑。     

Dispersion of dielectric constants in bismuth strontium ferrite (Bi,Sr)FeO<Subscript>3 − <Emphasis Type="Italic">x</Emphasis></Subscript>—Variable-valence perovskite-structure solid solution

The reflection spectrum R(ν) and transmission spectrum Tr(ν) of polycrystalline solid solutions Bi_0.5Sr_0.5FeO_2.75 are studied for the first time using submillimeter and IR spectroscopy in the frequency range 7 < ν < 4000 cm^?1 at temperatures of 10–300 K. A large difference is found between the magnitudes of the dielectric susceptibility measured by contact (at a frequency of 10³ Hz) and noncontact (THz range) methods. It is suggested that powerful relaxation excitations exist at frequencies below 100 cm^?1 (“subphonon” region). The possible origin of the excitations is discussed.     

Raman-Nath acoustooptical diffraction in antiferromagnet α-Fe2O3 induced by modulation of the polarizations of optical normal modes

Raman-Nath acoustooptical diffraction was experimentally revealed in easy-plane antiferromagnet α-Fe₂O₃. The diffraction is due to linear modulation of the polarizations of the optical normal modes propagating along trigonal axis C₃ of the crystal due to oscillations of the antiferromagnetism vector L caused by magnetoelastic interaction. The dependence of the diffraction parameters on a dc magnetic field H _⊥ applied in the basal plane was studied. The dependence obtained is in good agreement with the field dependence of the exchange enhancement coefficient of magnetoelastic coupling in fields higher than that at which hematite transforms to a single-domain state (H _D ～ 1.8 kOe). for a sound flux power of about 1 W/cm² in a sample, the maximum intensity of the diffracted wave at H _⊥ = H _D is about 0.9% of the input light intensity and its polarization is perpendicular to that of the incoming linearly polarized wave. The results obtained agree qualitatively with the theory of acoustooptical diffraction in antiferromagnets and confirm the antiferromagnetic mechanism of diffraction in the experimental geometry under study.