共查询到19条相似文献,搜索用时 265 毫秒
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根据最新的Cs2分子中间态A1∑+u -b3Πu全局解微扰获得的能级数据, 归属了通过微扰增强红外-红外光学双共振中间态A1∑+u 到上态23△1g的140条碰撞线, 包含之前实验观测到的221条23△1g←A1∑+u← X1∑+g 双共振跃迁[J. Chem. Phys. 128, 204313 (2008)], 重新计算了23△1g态的分子常数和势能曲线(排除54个微扰能级). 本次拟合得到的离心畸变常数和从经验公式计算得到的值相符合. 在亚多普勒激发光谱中,没有分辨出23△1g态的超精细结构. 对23△1g态的超精细结构进行初步计算,比较实验结果给出解释和说明. 相似文献
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提出了解释掺杂离子局域结构畸变的配体平面移动模型,建立了此模型下晶体微观结构与自旋哈密顿参量之间的定量关系.在考虑自旋与自旋、自旋与另一电子轨道和轨道与轨道作用等微小磁相互作用的基础上,采用全组态完全对角化方法,对Al2O3晶体中V3+的局域结构和自旋哈密顿参量进行了系统的研究.结果表明,V3+掺入Al2O3晶体后,上下配体氧平面间距离增大了0.0060 nm.从而成功地解释了Al2O3:V3+晶体的自旋哈密顿参量.在此基础上,研究了三角晶场下3d2离子自旋哈密顿参量的微观起源.研究发现,自旋三重态对自旋哈密顿参量的贡献是主要的,微小磁相互作用对自旋哈密顿参量的贡献只与自旋三重态有关. 相似文献
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通过在碱液中共沉淀Mn2+、Ni2+和Fe2+后制备了棒状的前躯体,前躯体于不同温度煅烧后制得了MnxNi0:5-xZn0:5Fe2O4棒状体. 利用X射线衍射仪和透射电镜对棒状体的物相、形貌及粒径进行了表征,并利用振动样品磁强计对磁性能进行研究. 结果表明长径比大于15的棒状,随着x值的增加,MnxNi0:5-xZn0:5Fe2O4样品的直径增加,长度下降,长径比变小,当x=0.5时其直径在50 nm左右而长径比减小到7~8. 随着x值的增加,样品的矫顽力先增加后减少,x值达到0.4时样品的矫顽力再次增加,当煅烧温度为600 oC,x=0.5时样品的矫顽力最大为134.3 Oe. 饱和磁化强度随着x值的增加先增加后减少,当煅烧温度为800 oC和x=0.2时达到最大为68.5 Oe. 相似文献
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利用溶胶-凝胶法在Pt/Ti/SiO2/Si(100)衬底上制备了Nd掺杂Bi4Ti3O12(Bi4-xNdxTi3O12, x=0.00,0.30,0.45,0.75,0.85,1.00,1.50)铁电薄膜样品.研究了Nd掺杂对Bi4Ti3O12薄膜的微结构和铁电性能的影响.研究结果表明:Nd掺杂未改变Bi4Ti3O12薄膜的基本晶体结构.在掺杂量x<0.45时,Nd3+只取代类钙钛矿层中的A位Bi3+.当x=0.45时,样品剩余极化强度达最大值,在270kV·cm-1的电场下为32.7μC·cm-2.掺杂量进一步增加时,结构无序度开始明显增大,Nd3+开始进入(Bi2O2)2+层,削弱其绝缘层和空间电荷库的作用,导致材料剩余极化逐渐下降.当掺杂量x达到1.50时,掺杂离子最终破坏(Bi2O2)2+层的结构,材料发生铁电-顺电相变. 相似文献
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本文应用坩埚下降法技术在全密封铂金坩埚条件下生长了不同Pr3+离子掺杂浓度的高质量LiLuF4单晶. 测定了单晶体从420 nm至500 nm的激发光谱. 在446 nm光激发下,观察到单晶体480 nm(3P0→3H4)蓝色发射带、522 nm(3P1→3H5)绿色发射及605 nm(1D2→3H4)的红色发射,其对应的平均寿命分别为38.5、37.3和36.8 μs. 其荧光寿命明显大于Pr3+掺杂的氧化物单晶. 同时研究了激发波长和掺杂浓度对发射强度以及色度坐标的影响. 获得最佳的Pr3+浓度为∽0.5 mol%,并分析了环境温度从298 K 到443 K变化对荧光强度的影响. 结果表明随着温度的增加,荧光强度逐步变弱,其中3P0→3H4(480 nm)能级跃迁受温度影响最大,其次是3P1→3H5和1D2→3H4. 相似文献
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利用光参量放大过程输出的闲置光载波-包络相位(CEP)被动稳定的特点,搭建了三级光参量放大(OPA)系统,获得了CEP稳定的近红外高能量超短激光脉冲(1.4 mJ/40 fs/1 kHz @ 1.8 μm),其CEP抖动为516 mrad(rms).经空心光纤展宽光谱和块体材料补偿色散,激光脉宽最终可被压缩至小于两个光学周期(<12 fs),脉冲能量达到0.54 mJ.该系统为单个阿秒脉冲的产生和其他高次谐波实验提供了优质的光源.
关键词:
光参量放大
周期量级近红外激光脉冲
载波-包络相位稳定 相似文献
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Pulses with a spectral width of 450 nm at a wavelength of 2.2 μm are generated in a parametric amplifier based on a type-I BBO crystal pumped by the second harmonic (620 nm) of a Cr:forsterite laser. Such a broadband radiation is obtained in a specific regime of the group velocity matching near the vertical region of the tuning curve. The generated pulses can be compressed to a duration of about 2.5 optical cycles (34 fs) in a medium with positive group-velocity dispersion. 相似文献
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Comparative investigation of long-wave infrared generation based on ZnGeP2 and CdSe optical parametric oscillators 下载免费PDF全文
Long-wave infrared(IR) generation based on type-II(o→e+o) phase matching ZnGeP 2(ZGP) and CdSe optical parametric oscillators(OPOs) pumped by a 2.05 μm Tm,Ho:GdVO 4 laser is reported.The comparisons of the birefringent walk-off effect and the oscillation threshold between ZGP and CdSe OPOs are performed theoretically and experimentally.For the ZGP OPO,up to 419 mW output at 8.04 μm is obtained at the 8 kHz pump pulse repetition frequency(PRF) with a slope efficiency of 7.6%.This ZGP OPO can be continuously tuned from 7.8 to 8.5 μm.For the CdSe OPO,we demonstrate a 64 mW output at 8.9 μm with a single crystal 28 mm in length. 相似文献
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Comparative investigation of long-wave infrared generation based on ZnGeP2 and CdSe optical parametric oscillators 下载免费PDF全文
Long-wave infrared (IR) generation based on type-II (o→e+o) phase matching ZnGeP2 (ZGP) and CdSe optical parametric oscillators (OPOs) pumped by a 2.05 μm Tm,Ho:GdVO4 laser is reported. The comparisons of the birefringent walk-off effect and the oscillation threshold between ZGP and CdSe OPOs are performed theoretically and experimentally. For the ZGP OPO, up to 419 mW output at 8.04 μm is obtained at the 8 kHz pump pulse repetition frequency (PRF) with a slope efficiency of 7.6%. This ZGP OPO can be continuously tuned from 7.8 to 8.5 μm. For the CdSe OPO, we demonstrate a 64 mW output at 8.9 μm with a single crystal 28 mm in length. 相似文献
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We report efficient generation of picosecond pulses in the near- and mid-IR in the new nonlinear material CdSiP(2) pumped at 1.064 μm by an amplified mode-locked Nd:YVO(4) laser at a 100 kHz repetition rate. By using single-pass optical parametric generation in 8-mm-long crystal cut for type I(e→oo) noncritical phase matching, an average idler power of 154 mW at 6.204 μm together with 1.16 W of signal at 1.282 μm has been obtained for 6.1 W of pump at photon conversion efficiencies of 15% and 23%, respectively. Signal pulse durations of 6.36 ps are measured for 9 ps pump pulses. 相似文献
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Second harmonic generation was observed in ammonium tartrate single crystals by a phase matching technique at the fundamental wavelength 1.153 μm. The nonlinear coefficients were found to be comparable in magnitude to those of KDP. The optical transmission and the refractive indices were also measured. 相似文献
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基于能量守恒和三波耦合波方程,建立了超短脉冲在参变过程中二次谐波产生时的I类和II类相位匹配条件、基波与谐波之间的群速延迟时间、以及群速失配对晶体长度限制的理论基础。以负单轴非线性光学晶体CsLiB6O10为例,分析和数值计算了超短脉冲宽度为100fs时,谐波的群速匹配长度随基波波长变化的规律。研究结果表明在I类相位匹配条件下,基波波长为642nm时,群速延迟最小,相应的群速匹配晶体长度最长为19.1mm;在II类相位匹配条件下,基波波长为767nm,群速延迟最小,群速匹配长度最长为0.89mm。 相似文献
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Investigation results on linear and non-linear optical properties, damage threshold and potential efficiencies of biaxial negative LiInS2 crystal are represented. It shows that the crystal has phase-matching and group-velocity matching in wide spectral range for second harmonic, sum- and difference-frequency generation of visible, near and middle IR lasers. The possibilities of designing middle IR optical parametric oscillator (OPO) pumped by Nd:YAG and dye lasers and specially possibility of frequency conversion with 3 um range femtosecond erbium lasers are given. 相似文献