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1.
根据塞曼效应理论和浙江磁共振(LMR)光谱原理,本文建立一了套用于标识激光磁共振光谱的模型方法,并成功地对CF X^2П(ν=1)远红外及NO X^2П(ν←0)中红外激光磁共振光谱进行了标识。为新自由基分子的激光磁共振光谱提供了快速而准确的方法。  相似文献   

2.
2001年总目次     
第 1期金属酞菁配合物结构研究的一些谱学方法黄金陵 彭亦如 陈耐生 (1)………………………………………………………结构稳定的高质量荧光材料CaAl4 O7:Tb3 + ,Ce3 + 贾冬冬 吴伯群 朱 静 刘玉龙 (7)………………………………………CFX2 Π(υ=1)远红外及NOX2 Π(υ =1← 0 )中红外激光磁共振光谱的标识   郭远清 刘红平 林洁丽 刘效庸 黄光明 李奉延 李津蕊 刘煜炎 (11)……………………………………………银纳米粒子与R6G分子间的电荷转移郭立俊 张兴堂 杜祖亮 黄亚彬 莫育俊 (16 )……………………  相似文献   

3.
根据塞曼效应理论和激光磁共振光谱技术(LMR)的基本原理,讨论了双原子分子2П态的塞曼效应特性并导出了解释分子塞曼跃迁的简明代数拟合方程,用这些方程对14N16O(X2Π1/2,3/2)及15N16O(X2Π3/2) (υ=1←0)的LMR谱线进行数据拟合,得到塞曼跃迁上、下子能级的gJ因子值和二级塞曼效应因子k2.将按Hund耦合情形(a)及过渡情形(ab)的理论和拟合方程计算出的磁场位置分别与实验结果相比较,结果表明对NO分子而言,过渡情形(ab)能较真实反映它的耦合情况,且在较高强度磁场下,必须计及二级塞曼修正.验证了采用上述代数拟合方程实现新分子LMR谱线标识和指认的可靠性,并提供了系统的处理方法.  相似文献   

4.
以Nd∶YAG激光器抽运光学参变振荡器 /光学参变放大器做为激发源 ,得到了NO分子在 2 2 0~ 35 0nm波长范围内的双光子激光诱导荧光光谱 ,并将其归属于A2 Σ(ν′ =0 )→X2 Π(ν″ =1~ 8)跃迁 ,用最小二乘法拟合获得NO分子X2 Π态振动常量″ωe =(190 4 .7± 7.3)cm-1,″ωe ″xe =(14 .2± 1.2 )cm-1,″ωe″ye=- (0 .0 2 18± 0 .0 0 91)cm-1,及平衡位置的力常量k =(1.5 99± 0 .0 12 )× 10 3 N·m-1。计算了所得跃迁谱带的弗兰克康登因子及相对荧光强度 ,结果与实验观测值相符。这可为用激光诱导荧光光谱技术探测大气污染物NO分子提供理论及实验参考  相似文献   

5.
以皮秒Nd∶YAG激光器抽运光学参变发生 /放大器做激发源 ,得到了NO分子在 4 90~ 5 80nm波长范围内通过C2 Π态共振增强的多光子离化谱 ,离化谱由有规则的谱线序列组成。将理论计算的峰值位置与实验结果进行比较 ,确定了离化通道为 :NO(X2 Π) 3hνNO(C2 Π) 2hν(orhν) NO+ +e ,离化信号强度随激光强度的近五次方变化关系进一步验证了此结论。分析讨论了谱线强度的分布不符合夫兰克康登原理的可能原因。根据谱线峰值位置 ,利用最小二乘法拟合获得NO分子C2 Π态振动常数′ωe=(2 35 4 .9± 6 .4 )cm-1,′ωe ′χe=(14 .7± 2 .5 )cm-1及平衡位置的力常数k=(2 .4 4± 0 .0 8)× 10 3 N·m-1。结果可为用激光离化光谱技术探测大气污染物NO分子提供参考。  相似文献   

6.
通过微量CH3CN(36Pa)与He(660Pa)混合气体交流Penning辉光放电获得CN自由基分子,采用光外差-磁旋转-浓度调制光谱技术,在可见光波段16850~17480cm^-1进行了转动分辨光谱测量,分别标识了CN分子红带A^2Πi-X^2Σ^ (6,1)和(7,2)138条和118条的转动光谱(其余光谱为C2自由基及CN红带(8,3)带光谱)。理论拟合分子常数时考虑电子态间的微扰作用,采用有效哈密顿量矩阵对角化获得了A^2Πi(v=6,7)态更精确的分子常数及电子态A^2Πi(v=7)与X^2Σ^ (v=11)之间的微扰常数ξ,η,总体拟合方差均小于实验误差0.007cm^-1,表明拟合结果是非常精确的。  相似文献   

7.
Na2 2 3 Πg 和 33 Πg 态在 3486 0cm-1(相对基态Te)和 3s+3d解离限之间的Ω =0 ,1,2能级进行了脉冲激光微扰增强双共振探测 .观测到两个态之间强烈的相互微扰 .给出忽略微扰情况下Ω =0能级的Tv 和Bv.  相似文献   

8.
采用激光诱导荧光技术对 In Cl分子 A3 Π0 → X1Σ 荧光光谱进行了分析和归属 ,并对A3 Π0 (ν′=1)→ X1Σ (ν"=1,2 ,3,4 ,5)的时间分辨谱进行了观测 ,得到 In Cl分子 A3 Π0 态无碰撞辐射寿命τ0 ≈ 370 ns,无碰撞弛豫速率常数 k Q ≈ 9.87× 10 -11cm3 molec-1s-1。  相似文献   

9.
以Nd :YAG脉冲激光器泵浦的光学参量发生器 放大器 (OPG OPA)作激发光源 ,获得了 4 2 0~ 4 72nm波长范围内NO分子的双光子激光荧光激发谱 ,并利用此技术对NO分子的能级结构进行了实验研究 ,将所得谱线峰归属为NO(A2 Σ←X2 Π)的跃迁 ,荧光强度随激光强度的二次方变化关系表明此过程是一双光子激发过程。利用实验所得峰值波长计算了NO(A2 Σ)态的基振动频率ωe 和平衡位置的力常数k。通过对NO分子A2 Σ→X2 Π跃迁的荧光时间分辨光谱进行实验研究 ,得到 2 6 6Pa气压下A2 Σ(v′ =0 )态的能级寿命τ=5 3 76ns。测量荧光寿命随气压的变化 ,利用曲线拟合得到NOA2 Σ(v′=0 ,1) 两振动态的自发辐射寿命和无辐射跃迁驰豫速率常数  相似文献   

10.
采用高灵敏度,高分辨率激光磁共振光谱(LMR)方法在6μm谱段测量了自由基分子NH_2v_2带的σ谱(△M_1=±1)。重复了前人已测过的谱,结果与之较好符合。并观测到了新谱,在14支激光谱线下共获得约115支塞曼(Zeeman)跃迁谱线,其中在6支激光谱线下新测得的谱线91支。  相似文献   

11.
本文叙述了采用CO激光磁共振方法对NO_2分子作定量测量,给出了激光磁共振信号幅度的数学表达式以及信号与分子浓度、激光功率等实验参数之间的依赖关系,实验结果与理论分析一致。  相似文献   

12.
Bending vibration-rotation transitions between the (010) μ(2)Sigma(-) and (000) (2)Pi(r) vibronic states of the CCN radical in its ground electronic state have been observed using far-infrared laser magnetic resonance (FIR LMR) spectroscopy. Thirteen FIR laser lines were used to record 769 resonances. The LMR data, combined with previous data, were used to determine vibrational, Renner-Teller, fine-structure, rotational, hyperfine, and molecular g-factor parameters using a least-squares fitting routine. The model used was an N(2) effective Hamiltonian modified to include the Renner-Teller effect explicitly in a (2)Pi electronic state. The band origin for the (010) μ(2)Sigma(-) <-- (000) &Xtilde;(2)Pi(r) transition was determined to be 179.598176 +/- 0.000067 cm(-1). The spin-orbit splitting in the ground state was refined and the complete set of (14)N-hyperfine parameters determined for the first time.  相似文献   

13.
采用内腔CO激光磁共振光谱方法和微机数据采样系统,观测到了NO,NO_2分子的超精细激光磁共振(LMR)谱,简述了测量原理,给出了实验结果。  相似文献   

14.
Observations of the rotational spectrum of BrO have been extended to include vibrational levels up to v = 8 in the X(1)(2)Pi(3/2) and v = 7 in the X(2)(2)Pi(1/2) states. The rotational spectra of isotopically enriched Br(18)O, X(1), v = 0, 1 and X(2), v = 0 have been observed as well. The spectra of all four isotopic species have been fit to a Hamiltonian in which the parameters have fixed isotopic ratios. An extensive set of isotopically independent parameters has been determined. Interatomic potentials have been derived for both the X(1) and X(2) states. The hyperfine constants and their vibrational dependencies have been determined more precisely and several of them have been determined for the first time. These are interpreted in terms of the electronic structure of the molecule. The isotope relations among the constants have provided a means of decorrelating the electron spin-rotation constant gamma from the fine-structure centrifugal distortion constant, A(D), and have allowed the first determination of an effective value for gamma. Copyright 2001 Academic Press.  相似文献   

15.
NO,NO2超精细LMR谱的观测   总被引:1,自引:1,他引:0  
龚本智  何勇 《波谱学杂志》1993,10(3):323-328
采用内腔CO激光磁共振光谱方法和微机数据采样系统,观测到了NO,NO2分子的超精细激光磁共振(LMR)谱,简述了测量原理,给出了实验结果。  相似文献   

16.
The v3 = 1 ← 0 (out-of-phase stretching vibration) transition wavenumbers of gas-phase NCO have been measured, in many cases with sub-Doppler resolution, by mid-infrared laser magnetic resonance (LMR) spectroscopy. In addition to the fundamental transition from the 2Π ground vibronic state, hot bands from the v2 = 1 2Σ and 2Δ and from the v2 = 2 2Φ vibronic states were detected and analyzed. The 2Σ vibronic level, with a spin-orbit coupling only partly quenched by the Renner-Teller effect, is characterised by complex and rapid tuning of energies in the magnetic field. This is the first successful analysis of magnetic resonance spectra for non-unique Renner-Teller vibronic states. The new LMR transitions were combined with data from previous studies and analysed, using an effective Hamiltonian in a 40-parameter fit to 660 transitions and combination differences. Several new coupling parameters are required, having magnitudes generally consistent with predictions from standard vibration-rotation theory.  相似文献   

17.
NO2ν2振动带的CO2激光磁共振垂直谱的观测   总被引:5,自引:5,他引:0  
采用高灵敏度、高分辨率激光磁共振光谱(LMR)方法,使用CO2激光器测量了分子NO2v2振动带的垂直谱(△MJ=±1).观测到了前人没有测过的新谱,在22支激光谱线下新获得100支塞曼(Zeeman)跃迁谱线。  相似文献   

18.
19.
本文采用法拉弟效应的激光磁共振光谱技术,研究了一氧化氮分子^14N^16OX^2П3/2R(1.5)v=0→1和同位素分子^15^16OX^2П3/2Q(1.5)v=0→跃迁的FLMR光谱,实验给出了样品浓度和信号强度之间的关系及调制磁场强度与FLMR信号强度之间的关系 。  相似文献   

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