共查询到18条相似文献,搜索用时 453 毫秒
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本文建立了直接甲醇燃料电池的二维、单相数学模型来研究电池内各种场的分布情况.模型中考虑了与电化学反应相伴随的、与流体动力学相关的反应与物料传递的耦合过程以及甲醇串流对阴极反应的影响;对阳极和阴极催化层传质过程引入了团聚块模型进行修正.计算了电池内的反应组分浓度分布和局部电流分布以及催化层沿长度方向的局部过电势分布,分析丁催化层内反应的非均匀性.在此基础上考察了对电池流场板结构的改进方案:减小集流板肋条宽度以及在肋条过窄时引入金属泡沫代替电池流场板和扩散层对电池性能的影响,通过对比计算表明两种改进均可以使得催化层反应均匀化,使电池输出性能得到提高,后者效果更佳. 相似文献
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本文建立了直接甲醇燃料电池(DMFC)的二维两相模型,并重点研究阳极的两相流动和质量传递.模型考虑甲醇串流现象,定量计算了在不同电流密度下甲醇串流量的大小及其对电池工作性能的影响;模型中提出求解气、液单相流速的方法,并分别研究气、液流速对物质传递和电池性能的影响.定量分析发现:由甲醇串流产生的寄生电势导致实际开路电压值远低于理论值;在大电流密度下扩散层和催化层内的气相体积分数非常大,阻碍了液相燃料向催化层扩散,成为制约电池性能的关键因素;扩散层和催化层内存在气、液两相的反向流动,且气、液相速度分别有利于排出生成气体并推动液体燃料到达催化层;减小多孔介质的扩散率将削弱对流,恶化电池性能. 相似文献
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本文建立了一个两相流、非等温、三维模型来研究PEM燃料电池内的传递过程,讨论了其内部水分布和温度分布特性。模拟结果表明水分布和温度分布都不均匀。沿着流动方向阳极侧水浓度逐渐降低,而阴极侧水浓度却不断升高,导致阴极容易形成液态水;在垂直流动方向上,脊下水的浓度和液态水饱和度都高于流道下;不同放电电压下阴极GDL中液态水分布趋势不同。沿流动方向温度逐渐降低,反应气体不足时降低梯度更大;脊下膜电极中温度低于流道下;垂直膜电极方向上最高温度在阴极催化层,放电电压越低,温度梯度越大;相同放电电压下质子交换膜越厚,各处的温度越低,温度梯度也越小。 相似文献
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质子交换膜燃料电池(PEMFC)气体扩散层(GDL)具有各向异性属性,常规数值模拟对GDL采取均匀模型,忽略了各向异性传递过程对PEMFC性能的影响。本文发展了一个三维非等温单相模型,在GDL平面内和GDL厚度方向采用不同的传递系数,模拟了各向异性传递系数对PEMFC整体和局部性能的影响。在本文计算条件下,GDL各向异性和均匀模型模拟得到的电池极化曲线几乎完全相同,但电池电流密度分布和温度分布等局部特性存在很大差异。该结果进一步证明了不能单独用极化曲线来验证电池数学模型的正确性。 相似文献
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气体相与颗粒相混合流场的声速研究, 由于具有重要的基础理论价值与广泛的工程应用背景, 逐渐受到人们重视. 针对稠密可压缩气粒两相流动, 综合考虑颗粒相所占空间体积以及颗粒间相互作用, 推导给出了新的等熵声速计算公式; 新公式包含了已有的纯气体、稀疏气粒两相流情形的计算公式作为其特例, 一方面验证了公式推导的正确性, 另一方面说明新公式更具有通用性; 分析了不同颗粒质量分数条件下的声速变化规律, 相应结果与普朗特的理论分析符合, 特别对于稠密气粒两相流动工况得到了一些新的物理认识; 开展了颗粒间相互作用建模参数的物理分析, 揭示了其对气粒两相流动声速的影响机理. 本文取得的成果为稠密可压缩气粒两相流动研究以及相关工程应用提供理论支撑. 相似文献
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零净液流量两相流持液率与阻力特性研究 总被引:1,自引:0,他引:1
分别以牛顿流体和非牛顿流体为液相,研究了垂直管中零净液流量气液两相流的流动特性。提出了零净液流量气液两相流动模型,应用这一模型计算了零净液流量气液两相流的持液率和压力降,模型计算结果与试验结果相符。研究结果表明,零净液流量气液两相流与常规气液两相流相比具有特殊性,表现为其持液率仅由质量平衡方程控制,其摩擦阻力压力降为负值。 相似文献
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In this paper, the results of an experimental investigation of the distribution of local coefficients of mass transfer on
a pipe wall for a flow of a two-phase gas-liquid mixture with a turn of 90° are presented. The mass transfer coefficients
were measured by using an electrodiffusion method. It has been shown that the distribution of local mass transfer coefficients
on the inner surface of a curvilinear channel is nonuniform both in length and along the perimeter and depends on the content
of gas in the two-phase flow. 相似文献
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A mathematical model was developed to simulate two-phase gas-dispersed flow moving through a pipe with axisymmetric sudden
expansion. In the model, the two-fluid Euler approach was used. The model is based on solving Reynolds-averaged Navier — Stokes
equations for a two-phase stream. In calculating the fluctuating characteristics of the dispersed phase, equations borrowed
from the models by Simonin (1991), Zaichik et al. (1994), and Derevich (2002) were used. Results of a comparative analysis
with previously reported experimental and numerical data on two-phase flows with separation past sudden expansion in a plane
channel and in a pipe are given.
This work was supported by the President of the Russian Federation through the Foundation for Young Candidates of Sciences
under Grant MK-186.2007.8 and by the Russian Foundation for Basic Research (Grants Nos. 05-08-33586 and 06-08-00967). 相似文献
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一种新的气液两相流体流量计-三通管型分流分相式两相流体流量计 总被引:2,自引:2,他引:0
利用三通管的相分离特性,从被测气液两相流体中分流分离出一部分单相气体,通过测量这部分单相气体的流量计算被测气液两相流体的流量或干度.文中给出了这种分流分相式气液两相流体流量计的组成原理,分流系数特性及实验结果. 相似文献
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A subgrid scale two-phase second-order-moment (SGS-SOM) model based on the two-fluid continuum approach is presented for the analysis of the instantaneous flow structures of swirling and non-swirling coaxial-jet particle-laden turbulence flows. Since the interaction between the two-phase subgrid scale stresses and the anisotropy of two-phase subgrid scale stresses is fully considered, it is superior to the conventional subgrid scale model on the basis of single gas phase or together with their similar forms for the particle phase for not taken these characters thoroughly into account. The swirling numbers s=0.47 and s=0 of coaxial-jet particle-laden turbulence flows (measured by M. Sommerfeld, H.H. Qiu, Detailed measurements in a swirling particulate two-phase flow by a phase Doppler anemometer, Int. J. Heat Fluid Flow 12 (1991) 20-28) are numerically simulated by large eddy simulation using this model, together with a Reynolds-averaged Navier-Stokes model using the unified second-order-moment two-phase turbulence model (RANS-USM). The instantaneous results show that the multiple recirculating gas flow structure is similar to that of single-phase swirling flows; but the particle flow structure contains less vortices. Both SGS-SOM and RANS-USM predicted that the two-phase time-averaged velocities and the root-mean-square fluctuation velocities are validated and are in good agreement with the experimental results. It is seen that for the two-phase time-averaged velocities both the models give almost the same results, hence the RANS-USM modeling is validated by large eddy simulation. For the two-phase root-mean-square fluctuation velocities the SGS-SOM results are obviously better than the RANS-USM results. 相似文献
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叶片式混输泵内气液两相流的数值计算 总被引:1,自引:0,他引:1
气液两相流的数值模拟是多相混输技术研究中的一个难点.本文假定混输泵叶轮内为泡状流动,基于雷诺时均N-S方程和气液两相双流体模型,采用SIMPLEC算法,对叶片式混输泵叶轮内部两相三维紊流流场进行了数值计算,分析了水气混合工况下的流场分布特点.对含气率GVF=15%工况下的扬程特性进行了预测并与试验结果进行对比.数值计算结果表明,混输泵叶轮流道采用较小的径向尺寸差能较好地避免离心力所引起的气液分离,防止气堵现象的发生;叶轮进口部分存在的低压旋涡区容易使气体积聚,因此有必要进一步改进叶轮进口区的水力设计. 相似文献