热不敏感腔的解与特征

本文发展了变换圆图解处理方法,并运用它求得了热不敏感腔的一般解:σ₁圆与π_f圆相切,清晰地阐明了它的主要特征;同时,澄清了有关它的特证的若干不确切的看法,进而,还求得了最佳热不敏感腔的特别解:g₁^*g₂^*=1/2;L₂=0或L₂=R₂。 关键词：     

多棒串接固体激光器谐振腔的研究

运用矩阵光学的方法对多棒串接固体激光器的谐振腔参数及其在平平腔时的热稳条件进行了研究，并计算了六棒串接平平腔固体激光器的稳定区.结果证明：多棒串接固体激光器的稳定区和非稳区相互间隔，在平平腔总腔长、激光棒数量n和棒间距L一定的条件下，当采用对称结构时(L₁=L₂)，则谐振腔的每段稳定区均达到最大；且只要 平平腔满足L₁=L₂=L/2以及热焦距f在大于某个下限值f_m时，稳定性条件01< 关键词： 多棒串接固体激光器 稳定区 热稳条件     

低热敏激光谐振腔理论和实验

本文介绍一种内含热聚焦元件的热不敏感谐振腔理论,给出新的严格的解析解法,分析了腔参数变化的影响,得到一些重要结论。用本方法设计了单模Nd:YAG激光器,并取得实验与理论分析相一致的结果。实验发现了两个不同阈值的热稳区,发现在一个合理设计的腔中,其热稳工作状态可对应于最大的TEM_(∞)模输出。 关键词：     

磁性物质交换Hamiltonian中两项的竞争

对于一个N电子体系, 正确的交换Hamilton应该由两项组成，为H_ex=-2A1ii·s_j-2A₂ii·sj，而不是以往的铁磁学理论使用的H_ex=-2Aii ·s_j （其中A为A₁与A₂的代数和， A₁>0, A₂<0）, 以往的理论使用了一个不合理的交换Hamiltonian量.-2A₁ii·s_j与-2A₂ii< /sub>·s_j在数学上是同类项，但是在物理上不是 同类项，它们有不同的本征态和本征值.根据量子力学中的态叠加原理，这个电子系统的本 征态矢为X〉=1A²₁+A²₂(A₁ 1〉+A₂‖2〉),其中Dirac符号1〉表示系统所有电子 的自旋平行排列时的态（简称平行自旋态）矢量，2〉表示系统所有电子或最近邻电子的自 旋反平行排列时的态（简称反平行自旋态）矢量，H_ex的本征值（即系统的 交换能） 为E=-Nz（A₁-A₂）-2NzA₂²A₁ +A₂=-Nz（A₂-A₁）-2NzA²₁A< sub>1+A₂,其中z为最近邻电子数.当A₂=0时，X〉=1〉，E =-A₁, 系统具有Wei ss 铁磁性；当A₁ =0 时，X〉=2〉，E =-A₂，系统具有Neel 反铁磁性；当A₁ =A₂（即A=0）时，X〉=12 (1〉+2〉)，E=-A₁，系统处于自旋玻璃（spin glass）态；当A₁>A ₂时，X〉=1A²₁+A²₂［(A₁-A₂)1〉+A₂(1〉+2〉)］,平行自旋态与自旋 玻璃态共存；当A₁2时，X〉=1A²₁+A2₂［(A₂-A₁)2〉+A₁( 1〉+2〉)］，反平行自旋态与自旋玻 璃态共存.与原来理论中的Weiss铁磁态或Neel反铁磁态相比，平行自旋态与自旋玻璃态共存 或反平行自旋态与自旋玻璃态共存使系统的交换能降低.自旋玻璃态中电子自旋之间取向的 随机性或无序性是由交换Hamiltonian中-2A₁iis_j与-2A₂ii·s_j之间的竞争引起的，不是热运 动引起的. 关键词： 交换哈密顿量 铁磁态 反铁磁态 自旋玻璃态     

用Monte-Carlo方法计算L12结构的有序度

本文应用Monte-Carlo统计物理计算方法,计算了L1₂结构有序度随温度的变化。计算中考虑了最近邻有序相互作用J₁和次近邻有序相互作用J₂=0,-0.3J₁,0.3J₁三种情况。计算结果显示存在有序无序一级相变,临界温度T_c与准化学方法等理论结果相符,同时发现次近邻有序相互作用J₂敏感地影响到有序无序转变温度T_c,为间隙原子对L1₂结构金属间化合物塑性的作用提供了一种可能的解释。 关键词：     

RbIO3-HIO3和CsIO3-HIO3两个赝二元系的研究

用X射线衍射及差热分析法研究了两系统的相平衡。确定了RbH₂(IO₃)₃的结构(三斜晶系,点阵常数:a=8.338?,b=8.244?,c=8.254?,α=60.66°,β=85.58°,γ=66.01°,z=2)。密度D_m=4.61g/cm³。CsIO₃-HIO₃系中有两个化合物:CsH(IO₃)₂(为质子导体)和3CsIO₃·17HIO₂。 关键词：     

钩吻素溴氢酸盐的晶体结构及其分子的绝对构型

利用Patterson和Fourier法测定了生物碱钩吻素溴氢酸盐(C₂₀H₂₂N₂O·HBr)的晶体结构,经全矩阵最小二乘法修正,偏离因子R=0.067,晶体属正交晶系;晶胞参数为α=14.307?,b=12.053?,c=9.862?;晶胞中分子数z=4;空间群为D₂⁴-P2₁ 2₁ 2₁,在非氢原子的坐标和各向异性热运动参数的 关键词：     

Bi2Pb2V2O10的晶体结构

使用X射线单晶衍射法测定了Bi₂Pb₂V₂O₁₀的结构。该晶体属三斜晶系,空间群为C₁¹-P1,单位晶胞内化学式数Z=1,晶胞参数为:a=7.084(4)?,b=7.278(3)?,c=5.587(3)?,α=111.91(5)°,β=95.01(6)°,γ=108.86(4)°,V=245.70?³,D_x=7.35g/cm³,μ(MoK_α)=678,94cm^-1,F(000)=456。用Patterson函数分析及Forier技术测定了结构,对原子坐标、各向同性及各向异性热参数进行了最小二乘方修正,R=0.079。结构分析表明,Bi₂Pb₂V₂O₁₀的Pb原子与O原子形成八角十二面体,Bi原子与O原子形成六角多面体。两个共棱的Pb—O多面体与两个共棱的Bi—O多面体相连,并沿bc平面无限延伸。讨论了吸收的影响。最后,将Bi₂Pb₂VO₁₀的结构与Pb₂SO₅的结构进行了比较。 关键词：     

管径及气体性质对爆轰极限的影响实验研究

本文在大尺度(D=50.3 mm,63.5 mm)光滑管道内对四种预混气(2H₂+O₂+50%Ar,C₂H₂+2.5O₂+70%Ar,C₂H₂+2.5O₂+85%Ar,CH₄+2O₂)进行了爆轰实验研究;获得了爆轰极限p_c和胞格尺寸λ,分析了四种气体的不稳定性,计算了边界层位移厚度δ^*和诱导长度?_i,深入研究了管径和气体性质对爆轰极限的影响。实验结果表明：随着初始压力和管径的减小,边界层位移厚度增大,边界效应加强,热损失增多,爆轰临界压力变大;大尺度管道内,不稳定性对极限的影响占据主导,因此极限情况下不稳定气(CH₄+2O₂)符合判据λ=πD,稳定气(2H₂+O₂+50%Ar,C₂H_2<...     

Mo-SiO2-C3H6催化反应体系的ESR动态表征

文章考察了Mo-SiO₂催化剂体系在丙烯歧化反应过程中的动态ESR波谱,发现在催化歧化反应过程中有两种Mo⁵⁺顺磁中心,一种为扰动八面体配位,g_||=1.89,g_⊥=1.94;另一种为扰动四棱锥配位,g_||=1.86,g_⊥=1.95。测得同位素^95,97Mo⁵⁺的各向异性超精细耦合常数A_||=90.3×10^-4cm^-1,A_⊥=44.8×10^-4cm^-1;观测到反应产生的积炭信号,g≈2.0O₂;氧阴离子自由基信号g₁=2.018,g₂=2.011,g₃=2.005。用LCAO-MO理论对上述Mo⁵⁺的ESR波谱进行计算,求得分子轨道系数,发现并总结出△g_||/△g_⊥与△g成直线关系,并建议用△g_||/△g_⊥=4(△E(B₂→E))/(△E(B₂→B₁)(β₁/ε)²之比值作为衡量C_4v扰动程度的尺度。     

An alternative method to specify the degree of resonator stability

We present an alternative method to specify the stability of real stable resonators. We introduce the degree of optical stability or the S parameter, which specify the stability of resonators in a numerical scale ranging from 0 to 100%. The value of zero corresponds to marginally stable resonator and S < 0 corresponds to unstable resonator. Also, three definitions of the S parameter are provided: in terms of A&D, B&Z _Ro and g ₁ g ₂. It may be noticed from the present formalism that the maximum degree of stability with S = 1 automatically corresponds to g ₁ g ₂ = 1/2. We also describe the method to measure the S parameter from the output beam characteristics and B parameter. A possible correlation between the S parameter and the misalignment tolerance is also discussed.      

Indirect measurements of the Jahn-Teller quenched spin-orbit splitting in the 5T2g-state of KMgF3:Fe2+

The energy separation of the first excited spin-orbit States Γ_3g, Γ_4g from the Γ_5g ground state, in the orbital ⁵T_2g triplet state of Fe²⁺ in KMgF₃, has been estimated from temperature dependence measurements on the 7860 cm^-1 zero-phonon-line (ZPL) transition from Γ_5g to the orbital ⁵E_g doublet state. Using a simplified crystal field energy level model, we find the Γ_5g Γ_3g, Γ_4g separation to be ～30 cm^-1, indicating that the vibronic Jahn-Teller coupling is considerably stronger in KMgF₃:Fe²⁺ than in MgO:Fe²⁺. Far infrared absorption data on KMgF₃:Fe²⁺ in magnetic fields up to 6T, are found to be consistent with this interpretation.     

基于补偿型微带谐振单元的一维光子带隙结构

提出了一种具有光子带隙(PBG)性能的补偿型微带谐振单元(C-CMRC)，通过并联两个开路微带线来补偿CMRC结构在低频通带内因为阻抗不平衡而引起的回波损耗，从而减小插入损耗，并且该C-CMRC谐振结构具有更强的慢波效应和更大的禁带宽度.利用该结构谐振单元的慢波效应，设计具有一维PBG性能的低通滤波器，重复周期仅为0.15λ_g.与普通的0.5λ_g周期的PBG结构相比，大大减小了电路面积.实际设计、制作和测试了CMRC和C-CMRC两种结构，通过两种结构的测试结果 关键词： 补偿型微带谐振单元 慢波 禁带 光子带隙     

Two and three pion-cut contributions to nucleon-nucleon scattering

Examining information from NN forward scattering in terms of discrepancy functions, we show that the 2π cut contributions as calculated via dispersion methods from πN scattering are in perfect agreement with NN scattering. Furthermore, we demonstrate the need for 3π cut contributions which are quantitatively well described by a nucleon exchange model. Finally, in addition to the 2π and 3π cut contributions, we determine the coupling constants of the ω and A₁ to be: g_Vω²/4π = 8.1 ± 1.5, g_Tω/g_Vω = 0.14 ± 0.20 and g_A1²/4π = 7.3 ± 3.0. The coupling of the η turns out to be zero.     

Optical absorption and EPR studies on enargite

The behaviour of transition metal ions in enargite has been studied by electron paramagnetic resonance and absorption spectroscopy in the UV–VIS and near-IR regions. The ground state of Cu(II) ions in enargite is confirmed as ²B_1g since g₁₁>g_⊥ (2.54>2.11). Three characteristic bands observed in the optical absorption spectra at 8275, 13105 and 18420 cm^?1 are assigned to the transitions, ²B_1g→²A_1g, ²B_1g→²B₂ and ²B_1g→²E_g, respectively, of Cu(II) ion in the tetragonal field. The presence of Fe(II) bands is an evidence for iron impurities in the mineral.     

Gauge boson/Higgs boson unification: The Higgs bosons as superpartners of massive gauge bosons

The N = 4 supergravity theories with local SO(4) invariance are formulated in superspace. The gauged SO(4) theory with two coupling constants (g₁, g₂) is shown to reduce to three inequivalent models: g₁ = g₂ with negative cosmological constant, g₁ = ?g₂ with positive cosmological constant, and g₁ = 0, g₂ ≠ 0 which is a particular case of the Freedman-Schwarz gauged SU(2) ? SU(2) model. The Higgs effect in the vector-scalar sector of the gauged N = 5 supergravity is analyzed.     

Laser excited Raman spectra of Gr. VI semiconducting compounds

Raman spectra of hexagonal layer compounds MoS₂, MoSe₂ and MoTe₂ were excited by a HeNe laser (6328Å). All the Raman active long-wave-length phonon frequencies were determined. These are A_1g, E¹_2g, E_1g and E²_g. The frequencies decrease as we pass from sulphur to tellurium and the quasiacoustical mode E²_2g has the lowest frequency. A comparison of the results with infrared spectra shows that the i.r. active mode for E ⊥ C is degenerate with one of the Raman active modes in the basal plane for all the compounds.     

ZnO based planar and micropillar resonators

In this paper we report on planar and microscopic cylindrical resonators with ZnO as the cavity and active medium surrounded with ZrO₂/MgO Bragg reflectors. We have observed resonator behaviour of these structures and, for the planar resonators, exciton–polariton coupling with a mode splitting of about 50 meV.     

Raman scattering study of IrxRu1−xO2 mixed metal oxide nanowires (0 ≤ x ≤ 1)

Recent interests in mixed metal oxide nanostructured materials especially Ir_xRu_1−xO₂ compounds have been mainly driven by the technological application as electrocatalyst and electrode materials. We present room temperature Raman scattering results of single crystalline Ir_xRu_1−xO₂ (0 ≤ x ≤ 1) nanowires grown by atmospheric pressure chemical vapor deposition. We observed that the E_g, the A_1g, and the B_2g phonon modes of a single Ir_xRu_1−xO₂ nanowire are blue-shifted linearly with respect to the Ir contents from which we could get stoichiometry information. We also observed that the asymmetric lineshape and the broadening of the full width at half maximum of the E_g mode that involves the out-of-plane oxygen vibration. The unusual asymmetric broadening of the E_g phonon can be explained by the activation of the non-zone-center phonons due to substitutional disorder present in the system. We also found that there is a mixed mode of the A_1g and the B_2g phonons due to the substitutional disorder, in the range of 630–750 cm⁻¹.