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1.
M. D. Volnyanskii S. N. Plyaka M. P. Trubitsyn Yahia A. H. Obaidat 《Physics of the Solid State》2012,54(3):499-503
The electrical properties of a lithium heptagermanate (Li2Ge7O15) crystal have been studied in DC and AC measuring fields at temperatures from 500 to 700 K. In a DC field, a substantial
decrease of electrical conductivity σ with time has been detected. On the basis of kinetic dependences σ(t), estimates of the charge carrier diffusion coefficient D have been obtained. In the frequency range 101–105 Hz, the spectra of complex impedance ρ*(f) have been measured. The analysis of diagrams in the complex plane (ρ″–ρ′) has been performed within the equivalent circuit
approach. It has been shown that, in the considered temperature and frequency intervals, the electrical properties of Li2Ge7O15 crystals have been determined by the hopping conduction of interstitial lithium ions A
Li and accumulation of charge carriers near the blocking Pt electrodes. 相似文献
2.
The Ac electrical conductivity and the dielectric relaxation properties of the [(C3H7)4N]2Cd2Cl6 polycrystalline sample have been investigated by means of impedance spectroscopy measurements over a wide range of frequencies
and temperatures, 209 Hz–5 MHz and 361–418 K, respectively. The purpose is to make a difference between the electrical and
dielectric properties of the polycrystalline sample and single crystal. Besides, a detailed analysis of the impedance spectrum
suggests that the electrical properties of the material are strongly temperature-dependent. Plots of (Z" versus Z') are well
fitted to an equivalent circuit model consisting of a series combination of grains and grains boundary elements. Moreover,
the temperature dependence of the electrical conductivity in the different phases follows the Arrhenius law and the frequency
dependence of σ (ω) follows the Jonscher’s universal dynamic law. Furthermore, the modulus plots can be characterized by full
width at half height or in terms of a nonexperiential decay function φ(t) = exp(t/t)β. Finally, the imaginary part of the permittivity constant is analyzed with the Cole–Cole formalism. 相似文献
3.
Manganese-doped ZnSiAs<Subscript>2</Subscript> chalcopyrite: A new advanced material for spintronics
L.?I.?Koroleva D.?M.?Zashchirinski? T.?M.?Khapaeva S.?F.?Marenkin I.?V.?Fedorchenko R.?Szymczak B.?Krzumanska V.?Dobrovol’ski? L.?Kilanski? 《Physics of the Solid State》2009,51(2):303-308
A new spintronics material with the Curie temperature above room temperature, the ZnSiAs2 chalcopyrite doped with 1 and 2 wt % Mn, is synthesized. The magnetization, electrical resistivity, magnetoresistance, and
the Hall effect of these compositions are studied. The temperature dependence of the electrical resistivity follows a semiconducting
pattern with an activation energy of 0.12–0.38 eV (in the temperature range 124 K ≤ T ≤ 263 K for both compositions). The hole mobility and concentration are 1.33, 2.13 cm2/V s and 2.2 × 1016, 8 × 1016 cm−3 at T = 293 K for the 1 and 2 wt % Mn compositions, respectively. The magnetoresistance of both compositions, including the region
of the Curie point, does not exceed 0.4%. The temperature dependence of the magnetization M(T) of both compositions exhibits a complicated character; indeed, for T ≤ 15 K, it is characteristic of superparamagnets, while for T > 15 K, spontaneous magnetization appears which correspond to a decreased magnetic moment per formula unit as compared to
that which would be observed upon complete ferromagnetic ordering of Mn2+ spins or antiferromagnetic ordering of spins of the Mn2+ and Mn3+ ions. Thus, for T > 15 K, it is a frustrated ferro- or ferrimagnet. It is found that, unlike the conventional superparamagnets, the cluster
moment μ
c
in these compositions depends on the magnetic field: ∼12000–20000μB for H = 0.1 kOe, ∼52–55μB for H = 11 kOe, and ∼8.6–11.0μB at H = 50 kOe for the compositions with 1 and 2 wt % Mn, respectively. The specific features of the magnetic properties are explained
by the competition between the carrier-mediated exchange and superexchange interactions. 相似文献
4.
The [N(CH3)4][N(C2H5)4]ZnCl4 compound has been synthesized by a solution-based chemical method. The X-ray diffraction study at room temperature revealed
an orthorhombic system with P21212 space group. The complex impedance has been investigated in the temperature and frequency ranges 420–520 K and 200 Hz–5 MHz,
respectively. The grain interior and grain boundary contribution to the electrical response in the material have been identified.
Dielectric data were analyzed using the complex electrical modulus M
* for the sample at various temperature. The modulus plots can be characterized by full width at half height or in terms of
a non-exponential decay function ϕ(t) = exp[(−t/τ)
β
]. The detailed conductivity study indicated that the electrical conduction in the material is a thermally activated process.
The variation of the AC conductivity with frequency at different temperatures obeys the Almond and West universal law. 相似文献
5.
The AC conductivity of the LiCaPO4 compound has been measured in the temperature range 634–755 K and the frequency range 300 Hz–5 MHz. The impedance data were
fitted to an equivalent circuit consisting of series combination of grains, grains boundary, and electrode elements. Dielectric
data were analyzed using complex electrical modulus M* at various temperatures. The modulus plots are characterized by the presence of two relaxation peaks thermally activated.
The activation energies obtained from the analysis of M″ (0.90 eV) and conductivity data (0.94 eV) are very close, revealing an ionic hopping mechanism. 相似文献
6.
The temperature dependence of the electrical conductivity of the compound 2,4,4-trimethyl-4,5-dihydro-3H-benzo[b] [1,4] diazepin-1-ium tetrachlorocadmiate in the different phases follows the Arrhenius law. The imaginary part of
the permittivity constant is analyzed with the Cole–Cole formalism. In the temperature range 348–394 K, the activation energy
of conductivity obtained from complex permittivity in regions I and II are, respectively, 1.03 and 0.33 eV, and E
m (in regions I and II are, respectively, 0.97 and 0.36 eV) obtained from the modulus spectra is close, suggesting that the
ion transport is probably due to a hopping mechanism. The Kohlrausch–Williams–Watts function,
j(t) = exp( - ( \fractt\textKWW )b ) \varphi (t) = \exp \left( { - {{\left( {\frac{t}{{{\tau_{\text{KWW}}}}}} \right)}^\beta }} \right) , and the coupling model are utilized for analyzing electric modulus at various temperatures. The decreasing of β at 373 K is due to approaching the temperatures of change in the conduction mechanism of the sample. 相似文献
7.
V. V. Popov P. P. Konstantinov Yu. V. Rud’ 《Journal of Experimental and Theoretical Physics》2011,113(4):683-691
Electrical resistivity ρ and Hal coefficient R are measured as a function of the temperature (T = 1.7−310 K) and the magnetic field (up to H = 28 kOe) in zero-gap semiconductor CuFeS2 samples subjected to hydrostatic compression and under various heat-treatment conditions. At low temperatures, anomalies
are observed in the kinetic effects related to the presence of ferromagnetic clusters: the magnetoresistance at T = 4.2 K and T = 20.4 K acquires a hysteretic character and thermopower α changes its sign at T < 15 K. The temperature dependence of conduction-electron concentration n in CuFeS2 has a power form in the temperature range T = 14−300 K, which is characteristic of the intrinsic conductivity in zero-gap semiconductors. In CuFeS2, we have n(T) ∝ T
1.2; in isoelectron compound Cu1.13Fe1.22Te2, we have n(T) ∝ T
1.93. Heat treatment is found to affect the intrinsic conductivity of CuFeS2, as the action of hydrostatic compression (carrier concentration changes); that is, the carrier concentration changes. However,
a power form of the n(T) and ρ(T) dependences is retained. 相似文献
8.
Solid polymer electrolytes (SPE) based on poly-(vinyl alcohol) (PVA)0.7 and sodium iodide (NaI)0.3 complexed with sulfuric acid (SA) at different concentrations were prepared using solution casting technique. The structural
properties of these electrolyte films were examined by X-ray diffraction (XRD) studies. The XRD data revealed that sulfuric
acid disrupt the semi-crystalline nature of (PVA)0.7(NaI)0.3 and convert it into an amorphous phase. The proton conductivity and impedance of the electrolyte were studied with changing
sulfuric acid concentration from 0 to 5.1 mol/liter (M). The highest conductivity of (PVA)0.7(NaI)0.3 matrix at room temperature was 10−5 S cm−1 and this increased to 10−3 S cm−1 with doping by 5.1 M sulfuric acid. The electrical conductivity (σ) and dielectric permittivity (ε′) of the solid polymer electrolyte in frequency range (500 Hz–1 MHz) and temperature range (300–400) K were carried out.
The electrolyte with the highest electrical conductivity was used in the fabrication of a sodium battery with the configuration
Na/SPE/MnO2. The fabricated cells give open circuit voltage of 3.34 V and have an internal resistance of 4.5 kΩ. 相似文献
9.
A. U. Sheleg V. G. Hurtavy S. N. Mustafaeva E. M. Kerimova 《Physics of the Solid State》2011,53(3):472-475
The temperature dependences of the electrical conductivity and the permittivity of TlInSe2 and TlGaTe2 crystals unirradiated and irradiated with 4-MeV electrons at a doze of 1016 cm−2 have been investigated. It has been established that electron irradiation leads to a decrease in the electrical conductivity
σ and the permittivity ɛ over the entire temperature range under study (90–320 K). It has been revealed that the TlInSe2 and TlGaTe2 single crystals undergo a sequence of phase transitions characteristic of crystals of this type, which manifest themselves
as anomalies in the temperature dependences σ = f(T) and ɛ = f(T). Electron irradiation at a doze of 1016 cm−2 does not affect the phase transition temperatures of the crystals under investigation. 相似文献
10.
Karen B. Paul 《Central European Journal of Physics》2005,3(1):115-126
A monocrystal ofFe
3
O
4 is characterized by resistance, magnetoresistance and magnetic measurements in a temperature range from 4.2 K to 350 K and
magnetic field-cycling from −9 T to 9 T. The resistance measurements revealed a metal-insulator Verwey transition (VT) atT
v
=123.76 K with activation energy E=92.5 meV at T >T
v
and temperature-substitute for the activation energy below the VT,T
0=E/k
B
≈3800 K within 70 K–110K. The magnetotransport results independently verified the VT at 123.70 K, with discontinuous change
in the magnetic moment ΔM≈0.21 ΔM≈0.21μ
B
and resistance hysteresis, dependent on the magnetic field in a narrow temperature range of 0.4° around theT
v
. The magnetic characterization established self consistentlyT
v
as ≈123.67 K, the jump in the magnetization at the VT≈0.25μ
B
and confirmed, that the magnetocrystalline anisotropy is the main microscopic mechanism responsible for the magnetization
of the monocrystal (88%) with additional natural and imposed defects contributing as 12%. 相似文献
11.
The electrical conductivity, magnetization, and magnetoresistance of manganites La1 − x
Ag
x
MnO3 have been investigated in the temperature range 78–300 K. The samples have been synthesized by the sol-gel method. At room
temperature, the magnetic field of 0.6 T has no effect on the electrical conductivity. As the temperature decreases, an abrupt
jump is observed in the magnetization curve due to the semiconductor-metal phase transition. This transition hardly affects
the temperature dependence of the resistance. 相似文献
12.
The electrical and galvanomagnetic properties of high-porosity biocarbon preforms prepared from white pine wood by pyrolysis
at carbonization temperatures T
carb = 1000 and 2400°C have been studied. Measurements have been made of the behavior with temperature of the electrical resistivity,
as well as of magnetoresistance and the Hall coefficient in the 1.8–300-K temperature interval and magnetic fields of up to
28 kOe. It has been shown that samples of both types (with T
carb = 1000 and 2400°C) are characterized by high carrier (hole) concentrations of 6.3 × 1020 and 3.6 × 1020 cm−3, respectively. While these figures approach the metallic concentration, the electrical resistivity of the biocarbon materials
studied, unlike that of normal metals, grows with decreasing temperature. Increasing T
carb brings about a decrease in electrical resistivity by a factor 1.5–2 within the 1.8–300-K temperature range. The magnetoresistance
also follows a qualitatively different pattern at low (1.8–4.2 K) temperatures: it is negative for T
carb = 2400°C and positive for T
carb = 1000°C. An analysis of experimental data has revealed that the specific features in the conductivity and magnetoresistance
of these samples are described by quantum corrections associated inherently with structural characteristics of the biocarbon
samples studied, more specifically with the difference between the fractions of the quasi-amorphous and nanocrystalline phases,
as well as with the fine structure of the latter phase forming at the two different T
carb. 相似文献
13.
Monika Aggarwal M. Husain Samina Khan Zishan H. Khan 《Journal of nanoparticle research》2007,9(6):1047-1055
Carbon nanotubes (CNTs) are synthesized by the catalytic decomposition of acetylene using low pressure chemical vapour deposition
method (LPCVD) at 800 °C and at a chamber pressure of 10 Torr over a supported catalyst film of Fe70Pd30. Morphology of these CNTs is studied using Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM) and
High Resolution Transmission Electron Microscopy (HRTEM). From HRTEM image of these multi-walled carbon nanotubes (MWNTs),
it is clear that these MWNTs do not possess a co-axial cylindrical structure, but are composed of imperfect and broken graphite
cylinders of different sizes. The average diameter and length of the nanotubes varies between 20–70 nm and 5–60 μm respectively.
Electrical transport measurements of these MWNTs are studied over a temperature range of 298–4.2 K. The results have been
interpreted in terms of variable-range hopping (VRH) over the entire temperature range of 298–4.2 K. Three-dimensional variable-range
hopping (VRH) is suggested for the temperature range (298–125 K), while two-dimensional VRH is observed for the temperature
range (125–4.2 K). 相似文献
14.
The photoelectric characteristics of Pb0.975Sn0.025Se solid solution films prepared by the hydrochemical codeposition of PbSe and SnSe with the subsequent heat treatment in
air at 573–700 K have been investigated. The thermal and optical band gaps, the temperature coefficient of the optical band
gap, the dark resistance, the volt-watt sensitivity, and the range of spectral sensitivity have been determined in the temperature
range of 220–300 K. It has been found that, after heat treatment below 573 K, the films of the Pb0.975Sn0.025Se solid solutions possess metallic conductivity, while being heat treated at elevated temperatures, they become semiconductors
with p-type conductivity. The composition of the solid solution is independent of the heat treatment temperature; it is formed during
deposition. 相似文献
15.
S. Kabi A. Ghosh 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,79(4):377-381
Electrical complex ac conductivity of the compound
Li0.9[Ni1/3Mn1/3Co1/3]O1.95 has been studied in the
frequency range 10 Hz–2 MHz and in the temperature range 93–373 K. It
has been observed that the frequency dependence of the ac conductivity obeys
a power law and the temperature dependence of the ac conductivity is quite
weak. The experimental data have been analyzed in the framework of several
theoretical models based on quantum mechanical tunneling and classical
hopping over barriers. It has been observed that the electron tunneling is
dominant in the temperature range from 93 K to 193 K. A crossover of
relaxation mechanism from electron tunneling to polaron tunneling is
observed at 193 K. Out of the several models discussed, the electron
tunneling and the polaron tunneling models are quite consistent with the
experimental data for the complex ac conductivity. The various parameters
obtained from the fits of the experimental results for the real and
imaginary parts of the conductivity to the predictions of these models are
quite reasonable. 相似文献
16.
We have synthesized nanosized La0.67Ca0.33MnO3 by a simple low-cost novel synthesis route without calcination at high temperature. The study of these nanoparticles indicates
excellent properties similar to colossal magnetoresistance (CMR) materials sintered at ∼1600°C for 20 h. The resulting particle
size is in the range of 50–160 nm as determined by scanning electron microscopy. Resistivity measurement has been carried
out down to 12 K. The sample shows metal-to-insulator (M–I) transition at 205 K.
相似文献
17.
V. A. Kulbachinskii V. G. Kytin P. M. Tarasov N. A. Yuzeeva 《Physics of the Solid State》2010,52(9):1830-1835
The effect of Ga doping on the temperature dependences (5 K ≤ T ≤ 300 K) of the Seebeck coefficient α, electrical conductivity σ, thermal conductivity coefficient κ, and thermoelectric
figure of merit Z of p-(Bi0.5Sb0.5)2Te3 single crystals has been investigated. It has been shown that, upon Ga doping, the hole concentration decreases, the Seebeck
coefficient increases, the electrical conductivity decreases, and the thermoelectric figure of merit increases. The observed
variations in the Seebeck coefficient cannot be completely explained by the decrease in the hole concentration and indicate
a noticeable variation in the density of states due to the Ga doping. 相似文献
18.
L. S. Ewe I. Hamadneh H. Salama N. A. Hamid S. A. Halim R. Abd-Shukor 《Applied Physics A: Materials Science & Processing》2009,95(2):457-463
The magnetotransport and magnetoresistive (MR) properties of manganese-based La0.67Ca0.33MnO3 perovskite with different grain sizes are reported. The electrical resistivity was measured as a function of temperature
in magnetic fields of 0.5 and 1 T. The insulator–metal transition temperature, T
IM, shifted to a higher temperature with the application of the magnetic field. In zero field, T
IM is almost constant (∼271 K) for all samples except for the sample with the largest grain size, where T
IM=265 K. The temperature dependence of resistivity was fitted with several equations in the metallic (ferromagnetic) region
and the insulating (paramagnetic) region. The density of states at the Fermi level, N(E
F), and the activation energy of electron hopping were estimated by fitting the resistivity versus temperature curves. The
ρ–T
2 curves are nearly linear in the metallic regime, but the ρ–T
2.5 curves exhibit a deviation from linearity. The variable range hopping model and small polaron hopping model fit the data
well in the high-temperature region, indicating the existence of the Jahn–Teller distortion that localizes the charge carriers.
MR was found to increase with an increase in the magnetic field, an effect which is attributed to the intergrain spin tunneling
effect. 相似文献
19.
Sh. M. Ismailov N. L. Kramynina N. V. Lugueva 《Bulletin of the Russian Academy of Sciences: Physics》2009,73(8):1169-1171
The effect of temperature and pressure on heat conductivity of ternary compounds TiSbC
2VI (C
VI → S, Se, Te) in the solid and liquid states in a temperature range of 300–800 K, as well as under the pressure up to 0.35
GPa in a temperature range of 275–450 K, is studied. The dependence of heat conductivity on average atomic weight under the
S → Se → Te transition is found. Analysis of the experimental data makes it possible to attribute TlSbS2 to the class of substances exhibiting semiconductor-semiconductor melting behavior. 相似文献
20.
K. P. Andryushin A. A. Pavelko I. A. Verbenko O. N. Razumovskaya L. A. Shilkina V. A. Aleshin L. A. Reznichenko 《Bulletin of the Russian Academy of Sciences: Physics》2011,75(8):1082-1084
Ceramic samples of bismuth ferrite and solid solutions of Bi1 − x
A
x
FeO3 type (where A = Lu, Yb, Tm, Er, Ho, Dy, Tb, Gb, Eu, Sm, Nd, Pr, La; 0.05 ≤ x ≤ 0.20; Δx = 0.05) were prepared. Spectra of the real part of electrical conductivity were studied within the range 10−4–10−6 Hz. The dependence of the samples’ thermal stability and electrical conductivity on the size of the substituting ions was
established. 相似文献