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 共查询到17条相似文献,搜索用时 140 毫秒
1.
路海  李若平  孙彩霞  黄明举 《光学学报》2007,27(9):1675-1681
研究了光致聚合物的光化学反应理论模型及其动力学参量。合成了染料藻红B和亚甲基蓝作为联合光敏剂共同敏化的全息光存储光致聚合物材料。对材料测试分别得到在曝光波长为633 nm与曝光强度为65 mW/cm2时,透射率随曝光条件的变化关系以及材料各光化学参量。结果表明,随着曝光波长与曝光强度的增加,光致聚合物的光化漂白速率常数k与量子产率Φ增大,当曝光强度为65 mW/cm2时透射率在短波长下出现了下降,光化漂白速率常数k出现负值,而摩尔吸收系数ε在条件不同时则表现了不同的变化趋势。  相似文献   

2.
陈珂  成建群  肖勇  唐道广  黄明举 《物理学报》2009,58(2):1007-1013
研究了光致聚合物的光化学反应和单体扩散反应的理论模型及动力学参数. 合成了以聚乙烯醇为粘结剂,三乙醇胺为引发剂,藻红B敏化的丙烯酰胺基光致聚合物全息存储材料,通过对测定的透过率和衍射效率进行曲线拟合,分析了染料浓度对光致聚合物的摩尔吸收系数ε、量子产率Φ和光化漂白速率常数k等光化动力学参数的影响规律,以及曝光强度对聚合反应速率k0、扩散时间常数τD和最大折射率调制度Δn等扩散动力 关键词: 光致聚合物 透过率 衍射效率 动力学参数  相似文献   

3.
根据光致聚合物中光栅形成机制,应用数学模型与实验相结合的方法,研究了一种新型光致聚合物在全息记录中的暗增长现象.研究表明,应用不同写入光强使衍射效率达到相同的饱和程度后,前期的写入光较弱则对应后期的暗增长程度较强.为了利用暗增长过程提高衍射效率,设计并实施了非连续曝光实验,使曝光与暗增长过程交替进行.并且通过暗增长过程的实验数据拟合出该材料的扩散时间常量为21 s,据此设定非连续曝光的周期.结果表明,相同记录条件下,非连续曝光比连续曝光可以获得更高的衍射效率.  相似文献   

4.
孙彩霞  李若平  路海  翟凤潇  肖勇  黄明举 《光子学报》2007,36(11):1998-2002
制备了一种三乙醇胺与N-苯基苷氨酸为共同引发剂的丙烯酰胺基光致聚合物全息存储材料,并用He-Ne 激光器633 nm波长的光对样品进行曝光测试.实验表明,与单引发剂的光致聚合物相比,薄膜的质量有一定的提高,在曝光灵敏度变化不大的情况下,衍射效率有很大提高.优化两种引发剂浓度后,此种共同引发的光致聚合物材料呈现的衍射效率达到54%,曝光灵敏度为1.85×10-2cm2/mJ.还研究了此种光致聚合物的透过率随曝光时间和曝光强度的变化,说明此种光致聚合物材料内部均匀性好,对光的散射小.  相似文献   

5.
马晨  张保民  张立  马玉峰  赵维富 《物理学报》2010,59(9):6266-6272
本文研究了全息存储实验中以波长532 nm的半导体激光器作为记录和读出光源,碱性品红作为光敏剂的丙烯酰胺基光致聚合物薄膜的光致光衍射现 象.它可以考虑为透过全息干涉条纹的原始入射光和反射光,与来自光聚物中未曝光的不均匀表面和内部的散射光四波混频的结果.根据简并四波混频理论中的位相匹配条件对双光束全息写入时产生的衍射光锥,以及单光束辐照复现时产生的衍射光锥现象分别做出了理论解释;并且利用全息散射理论结合三角学知识对入射光的入射角与衍射光锥的锥角的依赖关系进行了深入讨论. 关键词: 全息 光致聚合物 衍射光锥 碱性品红  相似文献   

6.
吡咯俘精酸酐的光致各向异性研究   总被引:3,自引:1,他引:2  
将有机光致变色化合物—吡咯取代俘精酸酐掺杂于PMMA中形成薄膜.在紫外光照射下,薄膜由无色态转换为呈色态.用650 nm线偏振激光照射薄膜,在由呈色态转变为无色态时产生光致各向异性.对633 nm的探测光具有正单轴晶体特性,光轴方向平行于激发光振动方向,光致二向色性率(D-D)可达0.2,光致双折射率(n-n)可达2×10-3.实验还测量了光致各向异性与曝光量的特性曲线,发现最佳曝光量为13~20 J/cm2;理论分析了其原因.这些结果为俘精酸酐材料在光信息处理方面的应用提供了实验数据.  相似文献   

7.
作为光存储材料的有机光致聚合物材料研究进展   总被引:13,自引:0,他引:13  
本综述了光致聚合物的光化学反应和动力学基本原理,讨论了影响光聚物光存储性能的各个因素,对近几年光致聚合物材料的发展状况和光聚物在光全息存储方面所具有的巨大潜力进行了论述。  相似文献   

8.
新型绿光敏感光致聚合物高密度全息存储特性   总被引:9,自引:0,他引:9       下载免费PDF全文
用实验方法研究了一种新合成的绿光敏感光致聚合物的高密度全息存储性质.结果表明该种光致聚合物具有较高的衍射效率、大的动态范围和折射率调制度,适合做高密度数字全息存储的记录材料,但材料的灵敏度需要提高,同时读出过程必须考虑曝光过程所导致的布拉格偏移;利用角度复用技术在样品的同一位置记录了20个数字化数据信息页,存储密度达到0.125GBcm3,平均误码率达到5.15×10 关键词: 光致聚合物 高密度数字全息存储 布拉格偏移  相似文献   

9.
本文综述了光致聚合物的光化学反应和动力学基本原理 ,讨论了影响光聚物光存储性能的各个因素 ,对近几年光致聚合物材料的发展状况和光聚物在光全息存储方面所具有的巨大潜力进行了论述  相似文献   

10.
本文从原子核的α集团独立粒子模型出发,在平面波冲量近似下讨论了质子在12C,16O等轻核上引起的(p,pα)准自由散射。α集团的独立粒子波函数表示成谐振子波函数的叠加,其中的参数用拟合高能电子散射实验测定的核电荷密度分布的数据来确定。结果表明,用这样确定的波函数能给出比较符合实验结果的准自由散射的理论截面。  相似文献   

11.
陈珂  成建群  王艳  黄明举 《中国物理 B》2010,19(1):14204-014204
A dynamic theoretical model of photochemistry and hologram formation in holographic photopolymer is established, and the dynamic development process of holographic gratings in the photopolymer is discussed with the model. A novel multi-wavelength visible light sensitive photopolymer for holographic storage is prepared. The influence of exposure wavelength on holographic storage characteristics is analysed. By fitting the experimental data of transmittance and diffraction efficiency to a function of time with different exposure intensities and wavelengths, the variations of dynamic parameters of photochemistry and photopolymerization diffusion are presented.  相似文献   

12.
The photochemical kinetics of phenanthrenequinone (PQ) doped poly (methyl methacrylate) photopolymer in holographic recording was studied theoretically and experimentally. The diffusion of PQ molecules during holographic recording was negligible because of its small diffusion coefficient at room temperature. A photochemical reaction kinetics model of PQ/PMMA was established. The analytical expressions for the temporal variations of transmittance and diffraction efficiency were derived. By fitting the experimental curves, some parameters related with the polymer components were obtained by the proposed model, which can be used to analyze the photochemical process and will be helpful to the optimization of material preparation.  相似文献   

13.
The enhancement of photochemical response is investigated in Zinc methylacrylate organometallic compound and phenathrenequinone doped poly(methyl methacrylate) photopolymer experimentally and theoretically. In experiments, the improvement in photosensitivity due to ZnMA compound is presented quantitatively. The dynamics parameters, quantum yield and initiation rate of PQ molecules, are determined by nonlinear fitting the experimental curves. The theoretical model with nonlocal effect is proposed to explain the contribution of actual chemical process to the enhancement of photochemical response. The comparison of theoretical and experimental results is finally described. Two significant roles of ZnMA compound, as a catalyst to accelerate the photochemical reaction and as a reactant to participate in the photoattachment with PQ molecules, are demonstrated quantitatively. The time constant of grating formation 20.9 s and the photosensitivity 2.3×10−5 cm2/J are experimentally obtained in an optimized 0.1 wt% ZnMA doped PQ-PMMA sample. This study contributes the physical mechanism for improvement of photosensitivity and provides significant theoretical foundation for advance the properties of materials in holographic memory.  相似文献   

14.
 An experimental method to study the photochemical reaction in solid-state dichromated gelatin during exposure is proposed, in which two laser sources with different wavelengths are used to induce photoreaction and to excite photoacoustic signal, respectively. This method is to obtain the real-time characteristics during the formation of the photoreaction product. The curve is fitted using the Rosencwaig-Gersho (R-G) theory and chemical kinetics. The reaction order and the rate of reaction may be obtained by fitting the parameters. The results show that photochemical reaction in dichromated gelatin conforms to the mechanism suggested by Watanable-Westheimer, and the photosensitivity of the samples, prepared under different conditions, is dependent on the initial concentration of photoactive ions. Received: 18 April 1995/Revised version: 3 May 1996  相似文献   

15.
通过实验研究了光聚合物材料聚甲基丙烯酸肉桂酰氧基乙酯(CEMC)的光化学反应过程, 以及对液晶材料LC-6710A 的取向能力. 通过原子力显微镜(AFM)观察了取向层表面在光化学反应前后的变化, 测量了光控取向膜液晶盒中液晶分子的预倾角及单面光控取向扭曲向列液晶显示器(TNLCD)的电光特性和时间响应特性曲线, 研究了液晶分子排列取向的机理.  相似文献   

16.
Recently, extensive studies have been carried out on the time varying absorption effects, which occur in photopolymer materials, during holographic exposure. The theoretical analysis presented in these studies, assumed that three primary mechanisms determined the dye kinetic behaviour. These mechanisms are: (i) photon absorption, (ii) the regeneration or recovery of absorptive photosensitiser, and (iii) photosensitiser bleaching. Based on this analysis, the generation of primary radicals were then described. In this article, we significantly extend these theoretical analyses. A detailed examination of the photochemical reactions, which take place during the photo-initiation mechanisms, is presented. Then a more accurate representation of the initiation mechanisms is developed. This enables more exact expressions for both the temporal and spatial variations of the photosensitiser and primary radical concentrations, to be generated.  相似文献   

17.
微细光束固化的蒙特卡罗建模   总被引:1,自引:0,他引:1  
王翔  裴香涛  邵鹏  黄文浩 《光学学报》2008,28(12):2388-2393
光固化是光束与光敏树脂之间的光化学反应,其作用过程对光固化加工分辨率有着直接影响.基于光子输运理论,利用蒙特卡罗方法追踪光子往树脂中的运动轨迹,对曝光光束人射、传输过程进行抽样,建立了微细光束固化模型;利用遗传算法并结合光同化实验重构获得了树脂材料的光学参数;利用该崮化模型,模拟计算了微细会聚紫外光束(λ=365 nm)单点曝光同化过程和固化单元点的形状和大小,分析了不同曝光最对固化结果的影响规律,计算结果与实验结果一致.研究表明,该模型可以有效地对微细光束与光敏树脂作用的复杂过程进行仿真,并能对不同入射光和曝光工艺条件下的固化物进行模拟计算,为微细光固化机理的研究和工艺优化提供了基础.  相似文献   

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