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1.
向勇  陈静  白满社  任杰  张晋宽 《应用光学》2014,35(3):500-504
 介绍了Li2O-Al2O3-SiO2微晶玻璃的加工特点。基于纳米划痕技术对Li2O-Al2O3-SiO2微晶玻璃进行了纳米划痕实验,测得微晶玻璃材料脆延转变临界切削深度和临界载荷的平均值分别为125.6 nm和29.78 mN。将实验所得临界切削深度值与基于压痕断裂力学模型建立的脆延转变临界切削深度计算值进行了对比,结果表明,T. G. Bifano基于显微压痕法给出的临界切削深度计算值与实验结果差别较大,结合实验结果对其公式进行了修正;基于压痕断裂力学模型建立的延性域磨削临界切削深度计算值与实验结果相差较小,并分析了产生差异的原因。  相似文献   

2.
纳米α-Al2O3磨料抛光单晶硅片光滑表面的形成机理   总被引:2,自引:0,他引:2  
"将纳米α-Al2O3粉体配制成抛光液并冷冻成冰结抛光垫对单晶硅片进行了抛光,用原子力显微镜观察了抛光表面的微观形貌并测量了其表面粗糙度,采用透射电镜观察了单晶硅片抛光后的断面形貌.为进一步分析抛光过程中的化学作用机理,采用X射线光电子能谱分析了单晶硅片抛光后表面的化学成分.利用纳米压痕仪的划痕附件对单晶硅片进行了划痕测试,研究了抛光过程中的机械作用机理.结果表明纳米α-Al2O3磨料冰冻抛光单晶硅片时,在1 mm£1 mm的范围内得到了微观表面粗糙度为0.367 nm的超光滑表面,亚表面没有任何损伤,材  相似文献   

3.
本文采用纳米压痕技术对固相烧结法制备的 MgB2 超导块材进行压入力学实验, 对不同压深的载荷-位移曲线和纳米压痕数据的再现性进行了分析, 实验数据使用 Oliver-Pharr 方法计算得出 MgB2 的硬度值, 借助经验方程拟合纳米压痕蠕变曲线求得蠕变速率敏感指数(m ) . 结果表明, 微观结构不均匀性会对材料在压头压入过程中抵抗外力作用时产生影响, 使压痕数据再现性变差; MgB2 的硬度表现出尺寸效应, 即随着压入深度的增加硬度逐渐下降;m 值随压入深度增加而增加是位错滑移速度加快的结果.  相似文献   

4.
在Li2O-Al2O3-SiO2系统玻璃中掺入少量晶核剂TiO2,ZrO2,P2O5,再掺入稀土离子和过渡金属离子作为着色剂,在高温下溶制得到彩色透明玻璃,对上述玻璃进行微晶化处理,用差热分析(DTA)确定其晶化温度,测定与讨论了所获彩色透明微晶玻璃在紫外波段至近红外波段的吸收光谱特性,研究结果表明,玻璃微晶化后,由于基质玻璃对光的微弱散射,引起吸收的增强,但不改变稀土离子和过渡金属离子的本征吸收峰位。  相似文献   

5.
PLD方法制备的超硬非晶碳薄膜研究   总被引:2,自引:3,他引:2       下载免费PDF全文
 用脉冲激光沉积在不同条件下制备非晶碳超硬薄膜,研究了非晶碳超硬薄膜的表面形貌、结构、应力、硬度以及能谱等。原子力显微镜和扫描电镜图像显示,薄膜表面平整、致密且光滑,均方根粗糙度最大为0.877 nm。在高激光重复频率、高激光通量条件下,薄膜有很大的应力,致使膜层褶皱甚至破裂,小角X射线衍射表明薄膜为非晶态且最大残余应力达30 GPa以上,但300 ℃温度的原位退火可以有效降低残余应力;纳米压痕测试表明薄膜硬度大于20 GPa,弹性模量大于200 GPa;X射线光电子能谱表明薄膜中sp3的含量在39%~53%之间变化,并且与激光通量成正比。  相似文献   

6.
纳米氧化铈的制备及其抛光性能的研究   总被引:9,自引:0,他引:9  
采用溶胶-凝胶法制备了纳米CeO2粉体,并采用XRD、TOF-SIMS对其进行了表征。结果表明平均晶粒度在13.3nm,粒度分布均匀。进而研究了纳米CeO2在玻璃基片抛光中的抛光性能。ZYGO形貌仪表明,抛光后其表面平均粗糙度值(Ra)可降低到0.6nm左右。原子力显微镜(AFM)在5μm×5μm范围内测得基片表面粗糙度Ra值为0.281nm,表面光滑,划痕等表面微观缺陷明显改善。  相似文献   

7.
介绍了用MPCVD方法制备纳米金刚石膜的工艺。用MPCVD方法实验研究了在光学玻璃上镀纳米金刚石膜:膜层厚度为0 4551μm,粒度小于200nm,表面粗糙度小于29 5nm,最大透过率为80%;平均显微硬度为34 9GPa,平均体弹性模量为238 9GPa,均接近天然金刚石的力学性能。与衬底材料表面应力-2 78GPa相比,具有较好的抗压和耐磨效果。  相似文献   

8.
张艳  王增梅  陈云飞  郭新立  孙伟  袁国亮  殷江  刘治国 《物理学报》2013,62(6):66802-066802
具有准同型相界组分的0.5Ba(Ti0.8Zr0.2)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-0.5BCT)陶瓷, 表现出优异的铁电、压电性能, 作为一种具有潜在应用前景的无铅压电材料得到广泛关注. 本文采用溶胶-凝胶方法在Si(100)基底上制备了BZT-0.5BCT压电薄膜. 使用原子力显微镜和扫描电子显微镜测量得到样品的形貌图, 形貌图表明该方法制备的无铅压电薄膜表面光滑, 晶粒大小均匀、呈半球形, 直径为80–100 nm, 厚度为1.7 μm, 膜的内部有气孔.摩擦力实验表明, 压电薄膜样品与硅针尖之间存在静电力的作用, 导致其摩擦力远大于硅针尖与SiO2之间的摩擦力, 但是两者的摩擦系数基本相同.划痕实验表明, BZT-0.5BC薄膜具有很强的法向承载能力, 但是切向抗磨损能力差, 样品的平均弹性模量为23.64 GPa± 5 GPa, 其硬度为2.7–4 GPa, 两者均略低于压电陶瓷Pb(Zr, Ti)O3材料的体态值. 关键词: BZT-BCT薄膜 纳米摩擦力 纳米压痕 纳米划痕  相似文献   

9.
K2O-ZnO-Al2O3-B2O3-SiO2系掺Cr3+透明莫来石微晶玻璃的研究   总被引:1,自引:0,他引:1  
采用了X射线衍射、透射电镜和吸收光谱及荧光光谱技术研究了K2O-ZnO-Al2O3-B2O3-SiO2系掺Cr^3 玻璃的析晶性能和光谱。研究结果表明:在K2O-Al2O3-B2O3-SiO2系掺Cr^3 玻璃的基础上引入ZnO后,析晶性能明显改善;析晶温度降低,析出的纳米莫来石微晶均匀、规则;微晶玻璃的发光强度明显增强。  相似文献   

10.
通过使用波长 800nm、重复频率 250kHz的飞秒激光脉冲聚焦进Li2O-Nb2O5-SiO2组分的玻璃内部,空间选择性诱导出铌酸锂微晶.为了进一步地研究辐照区域晶体的生长机制,使用显微拉曼光谱仪分析了玻璃样品辐照区域不同位置的结构变化.研究表明,在飞秒激光辐照一段时间后的聚焦区域,由于非线性效应和热累积效应形成了一个高温辐射梯度场,在激光辐照中心区域超过玻璃的析晶温度而促使玻璃熔融析晶.  相似文献   

11.
TiN/TiB2异结构纳米多层膜的共格生长与力学性能   总被引:1,自引:0,他引:1       下载免费PDF全文
魏仑  梅芳华  邵楠  董云杉  李戈扬 《物理学报》2005,54(10):4846-4851
采用多靶磁控溅射法制备了一系列具有不同TiB2调制层厚度的TiN/TiB2纳米多层膜.利用x射线衍射仪、高分辨电子显微镜和微力学探针研究了TiB2层厚变化对多层膜生长结构和力学性能的影响.结果表明,在fcc-TiN层(111)生长面的模板 作用下,原为非晶态的TiB2层在厚度小于2.9nm时形成hcp晶体态,并与fcc-TiN 形成共格外延生长;其界面共格关系为{111}TiN//{0001}TiB2,〈110〉TiN//〈1120〉TiB2.由于共格界面存在晶格失配 度,多层膜中形成拉、压交变的应力场,导致多层膜产生硬度和弹性模量升高的超硬效应, 最高硬度和弹性模量分别达到46.9GPa和465GPa.继续增加TiB2层的厚度,TiB2形成非晶态并破坏了与TiN层的共格外延生长,多层膜形成非晶TiN层和非晶TiB< sub>2层交替的调制结构,其硬度和弹性模量相应降低. 关键词: 2纳米多层膜')" href="#">TiN/TiB2纳米多层膜 共格生长 晶体化 力学性能  相似文献   

12.
Z.A.Umar  R.S.Rawat  R.Ahmad  A.K.Kumar  Y.Wang  T.Hussain  Z.Chen  L.Shen  Z.Zhang 《中国物理 B》2014,23(2):25204-025204
The Al/a-C nanocomposite thin films are synthesized on Si substrates using a dense plasma focus device with alu- minum fitted anode and operating with CH4/Ar admixture. X-ray diffractometer results confirm the formation of metallic crystalline Al phases using different numbers of focus shots. Raman analyses show the formation of D and G peaks for all thin film samples, confirming the presence of a-C in the nanocomposite thin films. The formation of Al/a-C nanocomposite thin films is further confirmed using X-ray photoelectron spectroscopy analysis. The scanning electron microscope results show that the deposited thin films consist of nanoparticles and their agglomerates. The sizes of th agglomerates increase with increasing numbers of focus deposition shots. The nanoindentation results show the variations in hardness and elastic modulus values of nanocomposite thin film with increasing the number of focus shots. Maximum values of hardness and elastic modulus of the composite thin film prepared using 20 focus shots are found to be about 10.7 GPa and 189.2 GPa, respectively.  相似文献   

13.
在服役环境中,超高声速飞行器表面与空气剧烈摩擦导致温度极高。超高温陶瓷相较于一般陶瓷而言具有高熔点和良好的抗氧化烧蚀性能,是目前极具前景的热防护材料之一。采用放电等离子两步烧结工艺将ZrB2纳米粉末和SiC粉末在1700℃下制备超高温陶瓷材料ZrB2-20%SiC,通过纳米压痕微观实验、三点弯实验研究其力学性能及其在高温环境下的氧化行为,着重分析1000、1200、1400和1600℃4种不同氧化温度下ZrB2-20%SiC超高温陶瓷的氧化表面、氧化截面和氧化层厚度。结果表明:ZrB2-20%SiC超高温陶瓷的硬度为18 GPa,弹性模量为541 GPa,断裂韧性为5.7 MPa·m1/2;当氧化温度为1600℃时,超高温陶瓷内部的SiC由被动氧化转变为主动氧化,并且随着氧化温度升高,超高温陶瓷氧化层厚度与氧化温度呈正相关。  相似文献   

14.
丁迎春  陈敏  高秀英  蒋孟衡 《中国物理 B》2012,21(6):67101-067101
According to the density functional theory we systematically study the electronic structure, the mechanical prop- erties and the intrinsic hardness of Si2N2O polymorphs using the first-principles method. The elastic constants of four Si2N2O structures are obtained using the stress-strain method. The mechanical moduli (bulk modulus, Young’s mod- ulus, and shear modulus) are evaluated using the Voigt-Reuss-Hill approach. It is found that the tetragonal Si2N2O exhibits a larger mechanical modulus than the other phases. Some empirical methods are used to calculate the Vickers hardnesses of the Si2N2O structures. We further estimate the Vickers hardnesses of the four Si2N2O crystal structures, suggesting all Si2N2O phases are not the superhard compounds. The results imply that the tetragonal Si2N2O is the hardest phase. The hardness of tetragonal Si2N2O is 31.52 GPa which is close to values of β-Si3N4 and γ-Si3N4.  相似文献   

15.
The objective of this article is to provide an experimental test and evaluation on mechanical characteristics of the W/Cr interface. The elastic modulus and hardness of the sample are measured by a nanoindentation tester. The test results show that the elastic modulus and hardness of the sample are nonlinear with respect to the depth h of the interface structure, unlike the usual approximate horizontal linear relationship as expected. To understand the bonding characteristics between W and Cr in nanoscale, the nano-scratch test is conducted considering the influence of thermal cycling load on the sample. The test results show that interfacial bonding strengths are different between samples under different thermal cycling loading conditions. It implies that the thermal loading has the potential probability to reduce the bonding reliability of the W/Cr interface. It builds a basis for future work of further investigations on mechanical properties of W/Cr interface structure.  相似文献   

16.
The nanoindentation characterizations and mechanical properties of fluorine-doped tin oxide (SnO2:F) films deposited on glass substrates, using chemical vapor deposition (CVD) method, were studied, which included the effects of the indentation loads, the loading time and the hold time on the thin film. The surface roughness, fractal dimension and frictional coefficient were also studied by varying the freon flow rates. X-ray diffraction (XRD), atomic force microscopy (AFM) and frictional force microscopy (FFM) were used to analyze the morphology of the microstructure. The results showed that crystalline structure of the film had a high intensity (1 1 0) peak orientation, especially at a low freon flow rate. According to the nanoindentation records, the Young's modulus ranged from 62.4 to 75.1 GPa and the hardness ranged from 5.1 to 9.9 GPa at a freon flow rate of 8000 sccm. The changes in measured properties were due to changing loading rate.  相似文献   

17.
The elastic modulus of Fe72.5Ga27.5 magnetostrictive alloy is determined by testing ac impedance resonance frequency and first-principle calculations. The observed elastic modulus is 90.2 GPa for a directionally solidified sample and 103.4 GPa for a water-quenched sample tested in a dc magnetic field of 32. 7mT without compressive pre-stress. The bulk modulus by first-principles calculation is 179.3GPa which is basically consistent with the experimental result. The elastic modulus first increases and then decreases with increasing dc magnetic field, attributed to magnetostriction occurrence in the Fe72.5Ga27.5 alloy. The elastic modulus increases with increasing compressive pre-stress, resulting from the initial magnetic states change under the applied compressive pre-stress. The elastic modulus increases match well with the improved magnetostriction after quenching.  相似文献   

18.
The elasticity and nanomechanical response of Aspergillus niger spores determined using atomic force microscopy (AFM) and nanoindentation are discussed. The force-displacement curve of the spore surfaces shows that the average surface roughness of spores was approximately 33 nm and that the adhesion force ranged from 9 to 28 nN. The Young's modulus of the A. niger spores ranged from 0.1 to 21.4 GPa and the hardness ranged from 0.01 to 0.17 GPa. The critical buckling load of the spore membrane is 290 μN.  相似文献   

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