Surface-Enhanced Infrared Spectral Investigations of 2,3-Bis(chloromethyl)anthracene-1,4,9,10-tetraone on Copper Nanoparticles

ABSTRACT

Surface-enhanced infrared (IR) absorption spectroscopic technique has been employed to investigate the orientation of 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone (BCMAT) on copper nanoparticles (NPs). Copper NPs have been prepared by the chemical reduction method. The observed ring stretching modes show higher downshifts, broader bandwidths, and higher enhancement. The observed features in out-of-plane and in-plane CH deformation modes indicate that the BCMAT molecules may be adsorbed in a “flat-on” orientation on the copper NPs. The observed lower enhancement factor of the in-plane C?O deformation mode and C?O stretching mode and the higher enhancement factor of out-of-plane C?O deformation mode elucidate that the BCMAT molecules are adsorbed on the copper NPs in a “flat-on” orientation. All these observations show that BCMAT is adsorbed on copper NPs through the π-anthraquinone ring system in a “flat-on” orientation.     

Band gap behaviours of periodic magnetoelectroelastic composite structures with Kagome lattices

In this paper, the elastic wave propagation in periodic cylinder magnetoelectroelastic composite structures is studied using the plane wave expansion method. The band structure characteristics of magnetoelectroelastic rods embedded in polymer matrix and the reverse case are investigated taking the electric, magnetic and mechanical coupling effects into account. The generalised eigenvalue equation is derived to analyse the in-plane and out-of-plane modes, respectively. The numerical calculations for both the cases with Kagome lattices are performed. The relation between the gap widths and filling fractions are discussed in detail. The effects of the magnetoelectricity on the band structures and widths of band gaps are analysed. The band gap characteristics are illustrated further and the results will be helpful to design such kind of composite structures.     

Designing broad phononic band gaps for in-plane modes

Phononic crystals are known as artificial materials that can manipulate the propagation of elastic waves, and one essential feature of phononic crystals is the existence of forbidden frequency range of traveling waves called band gaps. In this paper, we have proposed an easy way to design phononic crystals with large in-plane band gaps. We demonstrated that the gap between two arbitrarily appointed bands of in-plane mode can be formed by employing a certain number of solid or hollow circular rods embedded in a matrix material. Topology optimization has been applied to find the best material distributions within the primitive unit cell with maximal band gap width. Our results reveal that the centroids of optimized rods coincide with the point positions generated by Lloyd's algorithm, which deepens our understandings on the formation mechanism of phononic in-plane band gaps.     

Flexural wave suppression by an acoustic metamaterial plate

A new acoustic metamaterial plate is presented for the purpose of suppressing flexural wave propagation. The metamaterial unit cell is made of a plate with a lateral local resonance (LLR) substructure which consists of a four-link mechanism, two lateral resonators and a vertical spring. The substructure presents negative Young’s modulus property in certain frequency range. We show theoretically and numerically that two large low-frequency band gaps are obtained with different formation mechanisms. The first band gap is due to the elastic connection with the foundation while the second is induced by the lateral resonances. Besides, four-link mechanisms can transform the flexural wave into the longitudinal vibration which stimulates the lateral resonators to vibrate and to generate inertial forces for absorbing the energy and thus preventing the wave propagation. Frequency response function shows that damping from the vertical spring has little influence on the band gaps, although the damping can smooth the variation of frequency response (see the dotted line in Figs. 10 and 11). Increasing the damping of the lateral resonators may broaden the second band gap but deactivate its effect. This study provides guidance for flexibly tailoring the band characteristics of the metamaterial plate in noise and vibration controls.     

Experimental and numerical investigations of resonant vibration characteristics for piezoceramic plates.

Electronic speckle pattern interferometry (ESPI) is a full field, non-contact technique for measuring the surface displacement of a structure subjected to static loading or, especially, to dynamic vibration. In this article we employ an optical system called the amplitude-fluctuation ESPI with out-of-plane and in-plane measurements to investigate the vibration characteristics of piezoceramic plates. Two different configurations of piezoceramic plates, namely the rectangular and the circular plates, are discussed in detail. As compared with the film recording and optical reconstruction procedures used for holographic interferometry, the interferometric fringes of AF-ESPI are produced instantly by a video recording system. Because the clear fringe patterns will be shown only at resonant frequencies, both the resonant frequencies and the corresponding mode shapes are obtained experimentally at the same time by the proposed AF-ESPI method. Excellent quality of the interferometric fringe patterns for both the in-plane and out-of-plane vibration mode shapes is demonstrated. The resonant frequencies of the piezoceramic plates are also measured by the conventional impedance analysis. From experimental results, we find that the out-of-plane vibration modes (type A) with lower resonant frequencies cannot be measured by the impedance analysis and only the in-plane vibration modes (type B) will be shown. However, both the out-of-plane (bending) and in-plane (extensional) vibration modes of piezoceramic plates are obtained by the AF-ESPI method. Finally, the numerical finite element calculations are also performed, and the results are compared with the experimental measurements. It is shown that the numerical calculations and the experimental results agree fairly well for both the resonant frequencies and the mode shapes.     

Tunable band gaps in an inertant metamaterial plate with two-degree-of-freedom local resonance

This article presents an inertant metamaterial plate with two-degree-of-freedom (TDOF) local resonance. It is theoretically investigated with dispersion relation, effective density, and group velocity, and phase velocity to show the unique acoustic performance. Results show that the metamaterial plate can generate two tunable band gaps with a single mass attached by tuning the distance of springs to the centroid of mass due to the extra rotation of the mass. Simultaneously, the band gaps can also be tuned to the lower frequency range by exploiting the inerter. Effective mass density shows negative within the band gaps, and is also tuned by the attached spring-mass and inerter. Finally, within specific frequency ranges, the group velocity is negative which manifests the metamaterial plate behaves abnormal dispersion.     

可用于隔声和带隙调控的五模式超材料

为了利用在声学领域极具应用前景的双锥型五模式超材料进行隔声降噪,提出一种双锥宽直径不全同型五模式超材料.利用有限元方法分析了其声子能带结构、各波模相速度、品质因数随结构与材料参数的变化关系,在实用性和稳定性上与窄直径不同型五模式超材料作了比较.宽直径不全同型五模式超材料在保持原始五模式结构单模传输能带的前提下,还产生了更低频、宽带的三维完全带隙,且结构更稳定,重量更轻。双锥型五模式超材料在特定宽直径不同时具有三维完全带隙,品质因数主要由结构参数决定,各材料参数只是不同程度地影响带隙的绝对宽度和位置.研究结果表明双锥宽直径不全同型五模式超材料有望用于带隙调控和隔声。      

Metamaterial-embedded dual wideband microstrip antenna for 2.4 GHz WLAN and 8.2 GHz ITU band applications

ABSTRACT

A compact dual-band antenna designed for operating in IEEE 802.11b/g WLAN (2.4–2.484?GHz) and ITU frequency bands (8.01–8.5?GHz) is presented in this communication. The antenna has two distinct resonant modes generated with the help of three U-shaped transmission lines and a modified ground plane. A periodic repeating pattern of metamaterial unit cells integrated on the same plane of the substrate has enhanced the antenna performances using improved loading method. The measured bandwidth of the metamaterial-embedded antenna is increased by 16% in the lower operating band and 6% in the upper operating band. The compact proposed antenna provides wide measured bandwidths of about 40% (2–3?GHz) in the lower and 16% (8.19–9.63?GHz) in the upper frequency spectra. The maximum measured gain of the proposed antenna is increased around 3.63?dB at 2.36?GHz and 1?dB at 8.45?GHz. The proposed antenna radiator is about 89.6% compact with respect to a conventional antenna. An excellent agreement of the simulation with the benchmark results validates the design of the proposed structure.     

Band structure of collective modes and effective properties of binary magnonic crystals

In this paper a theoretical study of the band structure of collective modes of binary ferromagnetic systems formed by a submicrometric periodic array of cylindrical cobalt nanodots partially or completely embedded into a permalloy ferromagnetic film is performed. The binary ferromagnetic systems studied are two-dimensional periodic, but they can be regarded as three-dimensional, since the magnetization is non uniform also along the z direction due to the contrast between the saturation magnetizations of the two ferromagnetic materials along the thickness. The dynamical matrix method, a finite-difference micromagnetic approach, formulated for studying the dynamics in one-component periodic ferromagnetic systems is generalized to ferromagnetic systems composed by F ferromagnetic materials. It is then applied to investigate the spin dynamics in four periodic binary ferromagnetic systems differing each other for the volume of cobalt dots and for the relative position of cobalt dots within the primitive cell. The dispersion curves of the most representative frequency modes are calculated for each system for an in-plane applied magnetic field perpendicular to the Bloch wave vector. The dependence of the dispersion curves on the cobalt quantity and position is discussed in terms of distribution of effective “surface magnetic charges” at the interface between the two ferromagnetic materials. The metamaterial properties in the propagative regime are also studied (1) by introducing an effective magnetization and effective “surface magnetic charges” (2) by describing the metamaterial wave dispersion of the most representative mode in each system within an effective medium approximation and in the dipole-exchange regime. It is also shown that the interchange between cobalt and permalloy does not necessarily lead to an interchange of the corresponding mode dispersion. Analogously to the case of electromagnetic waves in two-dimensional photonic crystals, the degree of localization of the localized collective modes is expressed in terms of an energy concentration factor.     

Flexural vibration band gaps in thin plates with two-dimensional binary locally resonant structures

The complete flexural vibration band gaps are studied in the thin plates with two-dimensional binary locally resonant structures, i.e. the composite plate consisting of soft rubber cylindrical inclusions periodically placed in a host material. Numerical simulations show that the low-frequency gaps of flexural wave exist in the thin plates. The width of the first gap decreases monotonically as the matrix density increases. The frequency response of the finite periodic thin plates is simulated by the finite element method, which provides attenuations of over 20dB in the frequency range of the band gaps. The findings will be significant in the application of phononic crystals.     

Transmission loss of periodically stiffened laminate composite panels: shear deformation and in-plane interaction effects

This paper investigates the transmission loss of symmetric and asymmetric laminate composite panels periodically reinforced by composite stiffeners. A comprehensive model based on periodic structure theory is developed. First order shear deformation theory is used and the coupling of the in-plane motion of the panel with its out-of-plane motion is taken into account. Stiffeners interact with the panel through three forces (two in-plane, one out-of-plane) and a torsion moment. Three types of cross sections are investigated for the composite stiffeners: I-shaped, C-shaped, and omega-shaped cross-sections. The model is validated numerically by comparison with the finite element/boundary element method. Experimental validations are also conducted. In both cases, excellent agreement is obtained. Numerical results show that the in-plane coupling effect is increased by increasing the panel thickness and the stiffener's eccentricity. The in-plane coupling effect is also found to increase with frequency.     

Localisation of elastic waves in two-dimensional randomly disordered solid phononic crystals

Combined with the supercell technique, the plane wave expansion method is used to calculate the band structures of the two-dimensional solid–solid phononic crystals with the random disorders in either radius or location of the scatterers. Phononic systems with plumbum scatterers embedded in an epoxy matrix are calculated in detail. The influences of the disorder degree on the band structures for both anti-plane and in-plane wave modes are investigated. It is found that, with increase of the disorder degree, the band gaps become narrower with more flat bands appearing in the gaps. Both displacement distribution and response spectra show that at the flat bands, elastic waves are localised due to the presence of the disorder. Wave localisation is more pronounced at the flat bands near the lower/upper edge for the radius/location disorder. Wave propagation and localisation in a randomly disordered system with a point defect is also studied. The influence of the disorder on the point-defect state is discussed. The results show that the disorder can tune the frequencies of the defect states. It is particularly noticed that the double degenerate mode appearing within the gap of the mixed in-plane waves is split up into two separated ones when the random disorder is introduced into the system. Generally, the influence of the disorder is more pronounced for the mixed in-plane modes than the anti-plane modes. The analysis of this paper is relevant to the assessment of the influences of manufacture errors on wave behaviours in phononic crystals as well as the possible control of wave propagation by intentionally introducing disorders into periodic systems.     

Wideband magneto-optic modulation in a bismuth-substituted yttrium iron garnet waveguide

We present a tunable wideband bismuth-substituted yttrium iron garnet (Bi-YIG) waveguide magneto-optic (MO) modulator. High-speed current transients are used to switch the in-plane magnetization of the film, which modulates an 800 nm optical beam. Large bandwidth optical modulation is achieved by driving the device in a non-resonant mode that is well below the ferromagnetic resonance frequency of the film. The MO modulator has the potential of operating at bandwidths higher than 1 GHz by tuning the applied static magnetic field.     

The influence of pore shapes on the band structures in phononic crystals with periodic distributed void pores

The influence of the pore shapes on the band structures in phononic crystals with periodic distributed void pores are investigated in this paper. By using finite difference time domain (FDTD) scheme, the dispersion properties of the in-plane x-y mode waves in the materials with triangular, circular or square pores are discussed respectively. The influence of the pore shapes and the porosity on the band gap structures is analyzed. The results show that for x-y mode waves, the stop bands are easily formed in the materials with triangular pores, but hard for square ones. Moreover, a critical porosity exists for the formation of the absolute band gaps. Along with the increase of the porosity, the width of the absolute band gap is increased, but the centre frequency is dropped.     

Transmission control by asymmetric electromagnetically induced transparency-like metamaterials in transverse electromagnetic waveguide

We numerically and experimentally present passive and active electromagnetically induced transparency-like metamaterials in a TEM waveguide under normal excitation. Asymmetry of the metamaterial unit cell leads to the splitting of the radiative resonance. Surface current distributions are analyzed to account for each resonance. Moreover, by implementing a varactor diode to one of the gaps of the double-split ring resonator, electromagnetically induced transmission-like band is shifted in frequency and the corresponding bandwidth is modulated. A modulation ratio of 29.5 dB in transmission is experimentally demonstrated by only increasing the bias voltage 4 volts.     

A simple design of ultra-broadband and polarization insensitive terahertz metamaterial absorber

Ultra-broadband metamaterial absorbers have attracted considerable attention due to their great prospect for practical applications. These absorbers are usually stacked by many (no. <20) different shaped or sized subunits in a unit cell, making it quite troublesome to be fabricated. Simple design for ultra-broadband absorber is urgently necessary. Herein, we propose a simple design of ultra-broadband and polarization insensitive terahertz metamaterial absorber based on a double-layered composite structure on a metallic board, and each layer consists of two sets of different sized square metallic plates. Greater than 90 % absorption is obtained across a frequency range of 0.85 THz with the central frequency around 1.60 THz. The relative absorption bandwidth of the device is greatly improved to 53.3 %, which is much larger than previous results. The mechanism of the ultra-broadband absorber is attributed to the overlapping of four closely resonance frequencies. The proposed metamaterial absorber has potential applications in detection, imaging and stealth technology.     

含螺旋单元频率选择表面的宽频带强吸收复合吸波体

设计和制备了含螺旋单元频率选择表面吸波片的三层复合吸波体,上层和下层均为磁性吸波片,中间层为带缺口的螺旋单元频率选择表面.复合吸波体在总厚度分别为1.4,1.7和2.0 mm时,其反射率在-10d B以下的频带宽度分别达到了9.29,6.69和7.11 GHz,与不含有频率选择表面的吸波体相比较(其他参数相同),-10d B以下反射率带宽分别提高了159.5%,69.3%和129.4%,复合吸波体在总厚度低于吸波体时,也取得了更好的反射效果.带缺口圆螺旋单元的频率选择表面嵌入吸波体中,引入了额外的吸收频带,拓宽了吸波体的反射率频带宽度.仿真分析表明嵌入频率选择表面能够改善吸波体的阻抗匹配性,进而影响其反射率.     

Pulsed Rayleigh wave scattered at a surface crack

This paper investigates Rayleigh wave interaction with machined slots on flat aluminium blocks to simulate surface breaking cracks. Using a finite element method, Rayleigh wave scattering by narrow slots of varied depth ranging from 0.5 mm to 20 mm is calculated. Pulsed wideband Rayleigh waves with a centre frequency of 590 kHz and -6 dB bandwidth of 520 kHz is considered. Reflection and transmission coefficients are calculated and compare well with the published literature. We and other workers have reported enhancement of the measured amplitude or particle velocity of an apparent Rayleigh wave close to a surface defect. In this paper, it is found that the predicted enhancement of in-plane components of particle velocities close to a crack is significantly higher than that of the out-of-plane components of particle velocities which appears to be mainly due to the mode-converted surface skimming longitudinal wave from the crack that has mainly in-plane components near the sample surface. The enhancement of the in-plane particle velocity will be observed regardless of the type of in-plane sensitive ultrasonic detector used. The explanation of the discrepancy of the reflection and transmission coefficients obtained by pulsed and narrow band or pseudo continuous Rayleigh waves is discussed. The later-arriving Rayleigh waves from reverberation along the inside of the crack surface are observed, as has been previously reported by other workers, and this may also be used to gauge slot depth.     

局域共振复合单元声子晶体结构的低频带隙特性研究

本文提出了一种新型局域共振复合单元声子晶体结构, 并结合有限元方法对结构的带隙机理及低频共振带隙特性进行了分析和研究. 共振带隙产生的频率位置由所对应的局域共振模态的固有频率决定, 并且带隙宽度与局域共振模态的品质因子及其与基体之间的耦合作用强度有关. 采用局域共振复合单元结构可以实现声子晶体的多重共振, 在低频范围能打开多条共振带隙, 但受到共振单元排列方式的的影响. 由于纵向和横向局域共振模态的简并, 复合单元结构能在200 Hz以下的低频范围打开超过60%宽度的共振带隙, 最低带隙频率低至18 Hz. 这为声子晶体结构获得低频、超低频带隙提供了一种有效的方法. 关键词： 局域共振 低频带隙 复合单元 声子晶体     

Semi-analytic solutions for the free in-plane vibrations of confocal annular elliptic plates with elastically restrained edges

A two-dimensional analytical model is developed to describe the free extensional vibrations of thin elastic plates of elliptical planform with or without a confocal cutout under general elastically restrained edge conditions, based on the Navier displacement equation of motion for a state of plane stress. The model has been simplified by invoking the Helmholtz decomposition theorem, and the method of separation of variables in elliptic coordinates is used to solve the resulting uncoupled governing equations in terms of products of (even and odd) angular and radial Mathieu functions. Extensive numerical results are presented in an orderly fashion for the first three anti-symmetric/symmetric natural frequencies of elliptical plates of selected geometries under different combinations of classical (clamped and free) and flexible boundary conditions. Also, the occurrences of “frequency veering” between various modes of the same symmetry group and interchange of the associated mode shapes in the veering region are noted and discussed. Moreover, selected 2D deformed mode shapes are presented in vivid graphical form. The accuracy of solutions is checked through appropriate convergence studies, and the validity of results is established with the aid of a commercial finite element package as well as by comparison with the data in the existing literature. The set of data reported herein is believed to be the first rigorous attempt to obtain the in-plane vibration frequencies of solid and annular thin elastic elliptical plates for a wide range of plate eccentricities.