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1.
崔一平  罗宗南  钟嫄  杨正名  韦钰 《光学学报》1995,15(10):1342-1345
实验研究了聚合物Poly(2,5-thienylenevinylene)薄膜的超快共振光学克尔效应。获得了3×10-11esu的光学克尔极化率。一个双激发子弛豫机制被用来解释克尔信号动力学特性对入射光强度的依赖性。  相似文献   

2.
合成了一系列聚芳香杂环甲烯,包括聚吡咯甲烯和聚噻吩甲烯.采用四波混频法研究材料的共振三阶非线性光学效应(λ=532nm),其共振二阶超分子极化率γ三阶非线性光学系数分别达到10-30esu和10-8esu.选择具有良好溶解性、成膜性的聚吡咯对二甲氨基苯甲烯(PPDMAB),采用飞秒时间分辨光克尔效应方法研究材料的非共振三阶非线性光学效应(λ=790nm).实验表明,翠绿亚胺碱溶液的光克尔信号仅表现一超快响应的成分,归功于π电子云扭转产生的非共振激发.PPDMAB的非共振二阶超分子极化率γ三阶非线性光学系数分别达到γ=5.78×10-32esu和χ(3)=1.26×10-10esu.  相似文献   

3.
本文考察了不同的侧链长度对聚对苯乙炔(PPV)衍生物的光学性质等的影响,以及PPV/C60的组合薄膜中的激发传递和电荷转移过程,结果表明随着连接在PPV的侧链长度的增长,其π-π跃迁带隙变窄,使得吸收和发射峰的位置逐渐红移;同时观测到PPV/C60间存在着极有效的激发传递过程,从而使得PPV衍生物的荧光在很大程度上被C60分子所猝灭;MD-PPV/C60组合膜中观测了C60的吸收峰,这表明该体系存在着基态电荷转移过程,同时也表明PPV衍生物与C60分子间的相互作用和PPV的侧链长短密切相关。  相似文献   

4.
此文研究了三种不同分子结构的聚苯胺(本征态聚苯胺,间位聚苯胺和掺入有机玻璃的掺杂态聚苯胺)的飞秒非线性光学响应过程。用飞秒时间分辨吸收光谱技术测量了三种样品的激子和极化子的光激发和弛豫过程。从一个三能级模型出发,分析了上述过程的来源。最后讨论了存在于聚苯胺中的这种超快驰豫过程在光学双稳器件中的应用  相似文献   

5.
李宝铭  吴洪才  李晓奇  易文辉 《光子学报》2006,35(10):1522-1525
通过双醚化反应、氯甲基化反应以及在强碱性条件下进行的脱氯化氢反应制备聚(2-甲氧基-5-丁氧基)对苯乙炔(PMOBOPV)、聚(2-甲氧基-5-己氧基)对苯乙炔(PMOHOPV)、聚(2,5-二丁氧基)对苯乙炔(PDBOPV)和聚(2,5-二己氧基)对苯乙炔(PDHOPV)等四种可溶性聚对苯乙炔(PPV)衍生物,通过紫外-可见吸收光谱对产物分子结构进行表征.结果显示,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共轭π电子发生π → π* 跃迁的吸收峰分别位于491 nm、495nm、504nm和510nm处,相应的光学禁带宽度分别为2.23eV、2.18eV、2.12eV和2.07eV.利用简并四波混频技术测量PPV衍生物的三阶非线性光学性能,探讨了分子结构对PPV衍生物三阶非线性极化率(χ(3))的影响.研究发现,激发波长为532 nm时,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共振χ(3)值分别为3.45×10-10、5.13×10-10、7.15×10-10和9.61×10-10 esu;激发波长为1064 nm时,它们的非共振χ(3)值分别为1.09×10-11、1.42×10-11、1.62×10-11和2.14×10-11 esu.  相似文献   

6.
张绍银  艾树涛 《光学学报》2019,39(8):307-314
结合干涉光刻和磁控溅射制备了一维周期性起伏的磁性多层薄膜。利用扫描探针显微镜对样品的微结构进行表征,利用椭偏仪和磁光测量系统对样品的光学性能参数和磁光克尔效应进行测试和研究。实验结果发现,磁性多层薄膜磁光性能得到极大的提升,磁光增强的克尔谱峰值与条带的宽度、中间层二氧化铪层的厚度有关;利用介质层的厚度可调制复合薄膜的磁光特性。进一步研究发现横克尔效应的增强现象。理论计算的结果证实,磁光增强源于光学腔干涉共振和磁等离激元的耦合效应。  相似文献   

7.
俞洋  张文杰  赵婉莹  林贤  金钻明  刘伟民  马国宏 《物理学报》2019,68(1):17201-017201
单层过渡金属硫化物由于其特有的激子效应以及强自旋-谷耦合性质,在光电子学及谷电子学等方面有着很广阔的应用前景.利用超快时间分辨光谱,本文系统地比较了两类钨基单层硫化物(WS_2和WSe_2)的A-激子动力学和谷自旋弛豫特性.实验结果表明, WS_2单层膜的A-激子弛豫表现为双指数过程,而对于WSe_2,其A-激子衰减表现为三指数过程,且激子的寿命远长于前者. WS_2谷自旋极化弛豫表现为单指数衰减,其寿命约0.35 ps,主要由电子-空穴交换作用所主导.而对于WSe_2,谷自旋弛豫表现出双指数弛豫特性:一个寿命为0.5 ps的快过程和一个寿命为28 ps的慢过程.快过程的弛豫来源于电子-空穴交换作用,而慢过程则由于自旋晶格散射形成暗激子的过程.通过调谐抽运光波长,进一步证实WSe_2较WS_2更容易形成暗激子.  相似文献   

8.
利用半经典理论研究了N-型四能级相干原子的瞬态光学特性。理论分析表明:当信号光开启的瞬间,介质对探针光的非线性吸收从接近于零的状态迅速增加,经过驰豫振荡过程,趋于稳定状态。本文的研究结果将为吸收型光子开关的设计提供理论依据和参考。  相似文献   

9.
水溶性CdTe量子点的三阶光学非线性极化特性   总被引:1,自引:0,他引:1       下载免费PDF全文
利用超短脉冲Z扫描技术和光学Kerr效应研究了以巯基丙酸为稳定剂的CdTe量子点水溶液的三阶光学非线性极化特性. 在532nm,30ps和800nm,130fs脉冲激光激发下, 发现分别具有正负相反取值的三阶光学非线性折射率,自由载流子吸收和双光子吸收分别是这两种脉冲激光激发下三阶光学非线性吸收的起因. 测量得到CdTe量子点的三阶光学非线性极化率约为CS2的32倍, 在520—700nm光谱区的CdTe量子点的光学响应时间小于400fs. 关键词: CdTe量子点(QDs) Z扫描 三阶光学非线性极化特性 双光子吸收  相似文献   

10.
研究了一阶厄米-高斯模TEM01模和TEM10模在光学参量放大器中的共振情况。针对非线性KTP晶体各向异性引入像散效应,导致TEM01模和TEM10模不能在光学参量放大器中同时共振,设计了一个对称补偿方案,使其可以在光学参量放大器中同时共振,并进行了实验验证,为超纠缠态的实验产生奠定了基础。  相似文献   

11.
Ultrafast third-order optical nonlinearities of the as-deposited and annealed Au:Bi2O3 nanocomposite films deposited by magnetron cosputtering are investigated by using femtosecond time-resolved optical Kerr effect (OKE) and pump probe techniques. The third-order optical nonlinear susceptibility is estimated to be 2.6Ф×10^- 10 esu and 1.8 × 10.9 esu at wavelength of 800nm, for the as-deposited and the annealed film, respectively. The OKE signal of the as-deposited film is nearly temporally symmetrical with a peak centred at zero delay time, which indicates the dominant contribution from intraband transition of conduction electrons. For the annealed film, the existence of a decay process in OKE signal implies the important contribution of hot electrons. These characteristics are in agreement with the hot electron dynamics observed in pump probe measurement.  相似文献   

12.
程萍  高峰  陈向东  杨继平 《物理学报》2010,59(4):2831-2835
为探讨洞悉电场对有机发光二极管电致荧光量子效率的影响,通过激发-探测超快光谱技术研究了激子在电场下的瞬态行为.与单重态激子相应的激发态在230 μJ/cm2激发强度下,显示了快慢两个弛豫过程. 快慢组分的权重因子及快组分弛豫时间常数是电场相关的, 在6.4×105 V/cm的电场下,与无偏置电场相比,激子的快组分弛豫时间加速,快组分的权重因子由22%增加为72%,约50%的初始激子又通过电场而离解. 慢组分是电场无关的,其弛豫时间常数为890 ps. 实验结果还揭示了由激发光所产生的长程声学声子,其声速为17 /ps. 关键词: 聚对苯乙烯 超快光谱 激子 有机发光二极管  相似文献   

13.
Optical Kerr nonlinearity (n2) in n-type indium tin oxide (ITO) films coated on glass substrates has been measured using Z-scans with 200-fs laser pulses at wavelengths ranging from 720 to 780 nm. The magnitudes of the measured nonlinearity in the ITO films were found to be dependent on the carrier concentration with a maximum n2-value of 4.1×10-5 cm2/GW at 720-nm wavelength and an electron density of Nd=5.8×1020 cm-3. The Kerr nonlinearity was also observed to be varied with the laser wavelength. By employing a femtosecond time-resolved optical Kerr effect (OKE) technique, the relaxation time of OKE in the ITO films is determined to be ∼1 ps. These findings suggest that the Kerr nonlinearity in ITO can be tailored by controlling the carrier concentration, which should be highly desirable in optoelectronic devices for ultrafast all-optical switching. PACS 42.65.An; 42.65.Hw; 78.40.Fy  相似文献   

14.
Matsuo S  Yan L  Si J  Tomita T  Hashimoto S 《Optics letters》2012,37(10):1646-1648
An all-optical stabilization method of laser pulse energy is proposed using the optical Kerr effect (OKE). The method uses the OKE induced by a portion of the laser pulse as a power controller. The decrease (increase) in the throughput of the optical setup for OKE compensates for the increase (decrease) in pulse energy, thereby stabilizing the pulse-to-pulse fluctuation in pulse energy. The validity of this principle was proven by experiments with a femtosecond laser.  相似文献   

15.
Size-dependence of optical properties and energy relaxation in CdSe/ZnS quantum dots (QDs) were investigated by two-colour femtosecond (fs) pump-probe (400/800 nm) and picosecond time-resolved photoluminescence (ps TRPL) experiments. Pump-probe measurement results show that there are two components for the excited carriers relaxation, the fast one with a time constant of several ps arises from the Auger-type recombination, which shows almost particle sizeindependence. The slow relaxation component with a time constant of several decades of ns can be clearly determined with ps TRPL spectroscopy in which the slow relaxation process shows strong particle size-dependence. The decay time constants increase from 21 to 34 ns with the decrease of particle size from 3.2 to 2.1 nm. The room-temperature decay lifetime is due to the thermal mixing of bright and dark excitons, and the size-dependence of slow relaxation process can be explained very well in terms of simple three-level model.  相似文献   

16.
Optical, structural and morphological properties of thin films of polyparaphenylenevinylene (PPV) formed by an alkyl sulfinyl precursor route have been studied. Thin films were fabricated on an optical glass and on quartz glass either by spin-coating of the precursor solution or by layer-by-layer deposition using Langmuir–Blodgett technique. PPV precursor films were also spin-coated on gold-coated glass in order to study thin-film optical parameters by surface plasmon spectroscopy. We have been successful in forming about 40 precursor mono layers on quartz glass by Langmuir–Blodgett technique using optimized surface pressure and dipping conditions. After thermal conversion of the precursor layers good quality fluorescent PPV films of yellow colour have been obtained. Optical characterization of the films was carried out by linear absorption and emission spectroscopy, ellipsometry, and surface plasmon spectroscopy. Structural and morphological studies on the thin films were carried out by using X-ray scattering and atomic force microscopy. Wave-guided travelling-wave laser action has been achieved in a PPV film on quartz glass. The sample was transversally pumped with picosecond laser pulses (wavelength 347.15 nm, duration 35 ps). Laser emission occurred at 550 nm for pump pulse energy densities above .  相似文献   

17.
The wave-guided travelling-wave laser action (amplified spontaneous emission) of a neat film of poly(p-phenylenevinylene) (PPV) on a quartz glass substrate prepared by a sulfinyl precursor technique is studied. The samples are transversally pumped with picosecond excitation pulses (wavelength 347.15 nm, duration 35 ps). Lasing occurs at 550 nm. The optical constants of the neat films are determined by transmittance measurements exploiting the multiple beam interference in the transparency region. A fluorescence spectroscopic characterisation is carried out determining the fluorescence quantum distribution, fluorescence quantum yield, degree of fluorescence polarisation, and fluorescence lifetime. The emitting chromophore size (emitting singlet exciton extension) is determined by the ratio of exciton radiative lifetime to repeat-unit based radiative lifetime. The obtained size of about two repeat units is discussed in a disordered solid-state polymer model.  相似文献   

18.
翠绿亚胺碱的超快光克尔和光致吸收效应   总被引:4,自引:0,他引:4       下载免费PDF全文
报道了在飞秒染料激光脉冲作用下对翠绿亚胺碱(EB)的二甲基甲酰胺溶液的瞬态共振光克尔和光致吸收效应的研究.时间分辨的光克尔实验表明,翠绿亚胺碱溶液的光克尔信号仅表现一超快响应的成分,可归结为其基态和由于单光子共振吸收和双光子吸收产生的激发态的各振动能级与转动能级之间的弛豫过程.同时通过拟合计算分别给出了翠绿亚胺碱溶液的弛豫时间和三阶非线性极化率.抽运探测实验结果表明,翠绿亚胺碱分子的超快响应的光致吸收效应,主要来自于导致该分子中苯环结构π—π*跃迁的双光子吸收的贡献. 关键词:  相似文献   

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