Features of the kinetics of electrical damage of polymers

The kinetics of electrical damage (breakdown) of polymer films 20–50 μm thick in a constant-sign field of 0.5–0.6 GV/m at 77–300 K has been studied. At elevated temperatures (250–300 K), the exponential temperature dependence of the durability and the above-barrier thermal-fluctuation mechanism of electron emission from traps, i.e., space charge accumulation leading to breakdown, take place. At low temperatures (77–200 K), there are separate local decreases in the durability (minima) at the athermal durability level. The identity of the temperatures of durability minima and measured thermoluminescence maxima of polymers was found. A conclusion is made about the mechanism of thermally stimulated tunneling (subbarrier emission) of electrons from traps.     

Tunneling as a Classical Escape Rate Induced by the Vacuum Zero-point Radiation

We make a brief review of the Kramers escape rate theory for the probabilistic motion of a particle in a potential well U(x), and under the influence of classical fluctuation forces. The Kramers theory is extended in order to take into account the action of the thermal and zero-point random electromagnetic fields on a charged particle. The result is physically relevant because we get a non-null escape rate over the potential barrier at low temperatures (T → 0). It is found that, even if the mean energy is much smaller than the barrier height, the classical particle can escape from the potential well due to the action of the zero-point fluctuating fields. These stochastic effects can be used to give a classical interpretation to some quantum tunneling phenomena. Relevant experimental data are used to illustrate the theoretical results.     

Kinetic interpretation of the structural-time criterion for fracture

The incubation-period-based criterion for fracture is considered in terms of the Zhurkov kinetic model of fracture. Within the kinetic model, fracture is treated as a continuously developing process, which starts immediately after the application of a tensile load to a sample and consists in breaking of the interatomic bonds and gradual accumulation of broken bonds in the material in the course of a fracture test. For certain materials, the inclusion of the thermal-fluctuation mechanism for fracture in the incubation-period-based criterion significantly affects the position of the static branch of the time dependence of strength. Time dependences of strength are calculated for a number of materials. The experimental data are analyzed using the structural-time criterion for fracture, which allows one to obtain a unified time dependence of strength for quasi-static and high-rate short-term loadings. The temperature dependence of the incubation period (latent time) is calculated analytically, and a relation is found between the latent fracture time and the thermal vibration frequency of atoms.     

Quantum tunneling at zero temperature in the strong friction regime

In the large damping limit we derive a Fokker-Planck equation in configuration space (the so-called Smoluchowski equation) describing a Brownian particle immersed into a thermal environment and subjected to a nonlinear external force. We quantize this stochastic system and survey the problem of escape over a double-well potential barrier. Our finding is that the quantum Kramers rate does not depend on the friction coefficient at low temperatures; i.e., we predict a superfluidity phenomenon in overdamped open systems. Moreover, at zero temperature we show that the quantum escape rate does not vanish in the strong friction regime. This result, therefore, is in contrast with the work by Ankerhold et al. [Phys. Rev. Lett. 87, 086802 (2001)]] in which no quantum tunneling is predicted at zero temperature.     

Relaxation and resonance ultrasound attenuation by Jahn-Teller centers in a GaAs:Cu crystal

The interaction of ultrasound with Cu_Ga4As in a GaAs:Cu crystal has been experimentally studied. The temperature dependences of the attenuation of all normal ultrasonic modes propagating in the ??110?? direction both in doped copper and in nominally pure gallium arsenide crystals have been measured. In the GaAs:Cu crystal, the attenuation peak has been revealed for a transverse wave polarized along the ??110?? axis whose elastic shifts correspond to the symmetry of the tetragonal mode of the Jahn-Teller effect. The temperature dependence of the attenuation of this wave indicates that two types of attenuation??relaxation and resonance??occur. The constructed temperature dependence of the relaxation time indicates that tunneling through the potential barrier between the minima of the adiabatic potential energy is the main relaxation mechanism at temperatures below 10 K. Tunneling splitting estimated from experimental data is in good agreement with the theoretical estimate.     

Mechanisms of elementary events in the kinetics of electrical breakdown of polymer and ceramic dielectrics

The kinetics of electrical breakdown of thin (15–70 μm) layers of polymers and ceramics in a constant-sign field at 77–480 K has been investigated. The temperature dependences of the longevity (breakdown waiting time) of both dielectrics have been found to be similar to each other. At elevated temperatures, the longevity of the dielectrics varies exponentially with increasing temperature, and at reduced temperatures, it is temperature-independent (there is an athermal plateau). The mechanisms of elementary events controlling the process of preparation of the dielectrics for breakdown at elevated and reduced temperatures are the thermal-fluctuation over-barrier electron transition from trap to trap and the tunneling (under-barrier) transition, respectively. The hopping electron transport in the field direction gives rise to critical space charges causing breakdown of the dielectrics. The transition barrier heights (trap depths) have been determined. The low-temperature longevities of the polymer and the ceramic have been found to be similar, whereas the transition barrier for the ceramic is much higher than that for the polymer and the applied field in the former case is significantly (by a factor of tens) lower than that in the latter case. Electron traps in the polymer are adequately described by the Coulomb center model, whereas this is not the case for the ceramic.     

Shot-noise-driven escape in hysteretic Josephson junctions

We have measured the influence of shot noise on hysteretic Josephson junctions initially in the macroscopic quantum tunneling regime. The escape threshold current into the resistive state decreases monotonically with increasing average current through the scattering conductor, which is another tunnel junction. Escape is predominantly determined by excitation due to the wideband shot noise. This process is equivalent to thermal activation (TA) over the barrier at effective temperatures up to about 4 times the critical temperature of the superconductor. The presented TA model is in excellent agreement with the experimental results.     

Manifestation of disorder effects in the excess tunnel current of heavily doped silicon diodes

The temperature dependence of the forward current in heavily doped silicon p-n diodes has been measured at low temperatures, at which conduction occurs via tunneling. In the lowest temperature region, variable range hopping conduction was observed, whereas at higher temperatures the diode current exhibited a superexponential temperature dependence, which can be explained by thermotunneling through some random potential barriers.     

Strength and microplasticity of biocarbons prepared by carbonization in the presence of a catalyst

The microdeformation has been investigated under uniaxial compression of beech-derived biocarbons partially graphitized during carbonization in the presence of a Ni- or Fe-containing catalyst. The strength and ultimate fracture strain have been determined at different temperatures of carbonization of the samples in the absence or in the presence of a catalyst. It has been shown using high-precision interferometry that the deformation of biocarbon samples under uniaxial loading occurs through jumps (in magnitude and rate of deformation) with axial displacements in the nanometer and micrometer ranges. The use of a catalyst leads to a decrease in the size of nanometer-scale jumps and in the number of micrometer-scale jumps. The standard deviations of the strain rate on loading steps from the smooth average dependence of the strain rate on the displacement have been calculated for micrometer-scale jumps. A similar characteristic for nanometer- scale jumps has been determined from the distortion of the shape of beats in the primary interferogram. It has been shown that the variation in the standard deviation of the strain rate with a change in the carbonization temperature is similar to the corresponding dependence of the ultimate fracture strain.     

Quantum phase diffusion in a small underdamped Josephson junction

Quantum phase diffusion in a small underdamped Nb/AlO(x)/Nb junction (～0.4 μm(2)) is demonstrated in a wide temperature range of 25-140 mK where macroscopic quantum tunneling (MQT) is the dominant escape mechanism. We propose a two-step transition model to describe the switching process in which the escape rate out of the potential well and the transition rate from phase diffusion to the running state are considered. The transition rate extracted from the experimental switching current distribution follows the predicted Arrhenius law in the thermal regime but is greatly enhanced when MQT becomes dominant.     

Particle tunneling and scattering in a three-dimensional potential with a barrier

The particle tunneling through a 3-D rectangular potential barrier has been studied. The simplest model for multiple internal reflections has been assumed. The explicit expression for all the transmission and reflection probability amplitudes have been derived, as well as the tunneling and reflection phase times.      

Zener enhancement of quantum tunneling in a two-level superconducting circuit

We have investigated the macroscopic quantum tunneling (MQT) of the phase across a Josephson junction embedded in a superconducting circuit. This system is equivalent to a spin 1/2 particle in a potential energy well. The MQT escape rate of such a particle was recently predicted to be strongly modified when a crossing of its inner Zeeman levels occurs while tunneling. In this regime, we observe a significant enhancement of the MQT rate and compare it to theory.     

Tunneling characteristics of a double-barrier magnetic junction

The spin-polarized current through a planar double-barrier magnetic tunnel junction has been calculated using the quasi-classical model. The coefficients of electron transmission through the barriers have been calculated in terms of the quantum theory. The dependences of the transmission coefficients, spinpolarized currents, and tunneling magnetoresistance on the applied voltage under resonant conditions have been shown. Under non-resonant conditions, the tunneling magnetoresistance has been compared with the experimental data.     

Irradiation effect on the activation energy of thermal decomposition of polymers

The present work looks into the aspect of thermal modifications induced in polymers by proton irradiation. The kinetics of thermal decomposition of polymers is investigated by using the thermogravimetric (TG) technique. It has been observed that the degradation of polymers is a multi-step process that involves sequential and competing processes, and obeys the Arrhenius kinetics which allows us to connect the rate constant with the absolute temperature and the activation energy. The activation energy of thermal decomposition has been calculated from the TG curves, and its variation with different irradiation doses has been derived.     

Temperature dependence of the kinetics of irreversible escape of cesium atoms from a vapor phase into an antirelaxation coating

The kinetics of escape of cesium atoms into an antirelaxation coating is experimentally studied in the temperature range 298?C335 K in a cell with a lock when the working volume of the cell and a stem with the metal are subjected to individual thermostating. Under all experimental conditions, the kinetic curve is found to be well described by a two-exponential function with fast and slow components. This kinetics is shown not to obey the Arrhenius law for the temperature range of changing the working volume temperature at a constant temperature of the stem with the metal. During simultaneous but different changes in the working volume temperature and the temperature of the stem with the metal, the temperature dependences of the fast and slow components of the kinetics decomposes into segments where the Arrhenius law is obeyed. The separation point is likely to be the melting temperature of the coating material. At high temperatures, the activation energy of escape of cesium atoms into the coating is found to be higher than that at low temperatures by approximately an order of magnitude.     

量子遂穿在双阱异核分子形成过程中的作用(英文）

对于束缚在双阱中的两组分玻色－爱因斯坦凝聚体,本文研究了基于光缔合机制形成分子的过程中,量子隧穿所起的作用．该双阱外势可以在实验上利用磁场生成的谐振子势和由蓝失谐光或射频源生成的中心势垒来实现．在合适的光场中,我们分析了系统在不同初始状态下的短时极限量子动力学,同时对系统做了在平均场近似下的数值计算分析．我们发现无论是隧穿强度还是初始状态的制备都对系统的动力学有很大的影响．我们还计算了同核分子在这些情况下的结果,并和异核分子计算的结果作了比较．量子化的光缔合光场在分子形成过程的影响也在文章中给予了讨论．     

Influence of temperature on the ionization coefficient and ignition voltage of the Townsend discharge in an argon–mercury vapor mixture

The kinetics of main types of charged and excited particles present in a low-current discharge in an argon–mercury vapor mixture used in gas-discharge illuminating lamps has been investigated in a wide interval of the reduced electric field strength and temperature. Mechanisms behind the production and loss of ions and metastable atoms have been discovered, and the temperature dependences of their contributions to maintaining their balance have been determined. It has been shown that, when the discharge is initiated in the lamp and the mercury content in the mixture is low, the ionization coefficient exceeds that in pure argon, which is almost exclusively due to the Penning reaction. The influence of this reaction grows with a reduction of the electric field strength in the interelectrode gap. The dependences of the discharge ignition voltage on the interelectrode gap (Paschen curves) for different temperatures of the mixture have been calculated, and the nonmonotonicity of the temperature dependence of the ignition voltage has been explained.