High-temperature study of SrFe<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Mo<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>3−<Emphasis Type="Italic">z</Emphasis></Subscript> perovskites

The structure of high-temperature SrFe_{1 − x} Mo _x O_{3 − z} (0 ≤ x ≤ 0.5) phases was studied. Such studies are necessary to understand the mechanism of oxygen transport in membrane materials used for high-temperature oxygen separation.     

Magnetostriction of Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>S (<Emphasis Type="Italic">x</Emphasis> = 0.27) crystals

The magnetostriction of Fe _x Mn_{1 − x} S (x = 0.27) single crystals in strong magnetic fields up to 120 kOe has been investigated. It has been found that the magnetostriction reaches colossal values (±3 × 10⁻⁴) atypical of compounds of 3d elements. It has been found that the magnetostriction changes sign when varying temperature and magnetic field; this behavior indicates an important role of the spin-phonon interactions in the formation of the magnetic order in solid solutions of iron-manganese sulfides.     

Electronic structure and ground state parameters of Ru<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript><Emphasis Type="Italic">Me</Emphasis><Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Al refractory alloys

The electronic structure and ground state parameters of B2 RuAl-based refractory alloys have been investigated in the framework of the density functional theory using the exact muffin-tin orbital method in combination with the coherent potential approximation. It has been demonstrated that the number of states at the Fermi level for the Ru_{1 − x} Me _x Al alloys as a function of the alloying metal content has a minimum, which indicates a change in the Fermi surface topology and the presence of specific features in the behavior of elastic constants. It has been concluded that the electronic structure of the alloys can be described in terms of the rigid band model. The nonlinear variations of the lattice parameters of the alloys has been explained.     

Metallic-like conductivity of asymmetric <Emphasis Type="Italic">p</Emphasis>-In<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Ga<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>As quantum wells

The temperature dependence of the conductivity of the two-dimensional hole gas in an asymmetric GaAs/In _x Ga_{1 ? x} As/GaAs quantum well has been investigated. It is shown that fast spin relaxation leads to metallic-like behavior of the temperature dependence of the conductivity.     

Magnetocapacitance effect in Gd<Subscript> <Emphasis Type="Italic">x</Emphasis> </Subscript>Mn<Subscript>1–<Emphasis Type="Italic">x</Emphasis> </Subscript>S

The capacitance and dielectric loss tangent of Gd_xMn_1–xS (x ≤ 0.2) solid solutions have been measured at a frequency of 10 kHz without magnetic field and in a magnetic field of 8 kOe in the temperature range of 90–450 K. An increase in the permittivity and a dielectric loss maximum have been detected in the low-temperature region. It has been found that the temperature of the maximum of the imaginary part of the permittivity shifts to higher temperatures with increasing concentration. The magnetocapacitance effect has been revealed for two compositions. The dielectric loss has been described in the Debye model with “freezing” dipole moments and in the orbital-charge ordering model.     

Charge density of Ga<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Al<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Sb

Charge density calculations and electronic band structures for Ga _x Al_{1 − x} Sb with x = 1.0, 0.5 and 0.0 are presented in this work. The calculations are performed using the empirical pseudopotential method. The charge density is computed for a number of planes, i.e. z = 0.0, 0.125 and 0.25 A ₀ by generating the potential through a number of potential parameters available in the literature. The virtual crystal approximation was applied for the semiconducting alloy. The characteristics of the band structure and charge density are observed to be affected by the potential parameters. Calculated band gaps and the nature of gaps are in good agreement with the experimental data reported. The ionicity is also reasonably in good agreement with other scales proposed in the literature; however the formulation needs to be improved. The present work also demands indirect experimental band gap for the alloy.      

Metal-insulator transition in Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>S crystals

Results of an experimental study of MnS, FeS, and Fe _x Mn_1?x S single crystals are presented. The phase composition, the lattice parameters, and the state of paramagnetic ions in Fe _x Mn_1?x S have been determined by x-ray diffraction analysis and Mössbauer spectroscopy. A sequence of transitions have been found in iron manganese sulfide with x = 0.29 at temperatures T ₁ ≈ 25–50 K, T ₂ ≈ 125 K, and T ₃ ≈ 190 K with a change in kinetic properties and the formation of a metallic state at low temperatures T ≈ 2 K. The possibility of a Mott-Hubbard transition in Fe _x Mn_1?x S sulfides with variation of the composition and the temperature is discussed.     

Physical properties of Fe<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Dy<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Si crystals

The results of experimental investigation of magnetic and electric properties of Fe_1?x Dy _x Si crystals are reported. It is shown that the magnitude and position of the anomaly observed in the temperature dependences of magnetization are controlled to a considerable extent by the external magnetic field. It is found that the introduction of Dy ions leads to a weak magnetoresistive effect.     

Higher <Emphasis Type="Italic">η</Emphasis><Subscript>c</Subscript>(<Emphasis Type="Italic">nS</Emphasis>) and <Emphasis Type="Italic">η</Emphasis><Subscript>b</Subscript>(<Emphasis Type="Italic">nS</Emphasis>) mesons

The hyperfine splittings in heavy quarkonia are studied in a model-independent way using experimental data on dielectron widths. Relativistic correlations are taken into account together with the smearing of spin-spin interaction. The radius of smearing is fixed by known G/ψ−η _c(1S), ψ(2S)−η _c′(2S) splittings, which appears to be small, r _ss ≅ 0.06 fm. Nevertheless, even with such a small radius, substantial suppression of hyperfine splittings (∼50%) is observed in bottomonium. For nS b states (n = 1, 2, ..., 6), our predicted splittings (in MeV) are 28, 12, 10, 5, 6, 3. For the 3S and 4S charmonium states, the splittings 16(2) and 12(4) MeV are obtained. The text was submitted by the authors in English.     

Ordered phases of lithium nickelite Li<Subscript>1−<Emphasis Type="Italic">x</Emphasis>−<Emphasis Type="Italic">z</Emphasis></Subscript>Ni<Subscript>1+<Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>2</Subscript>

A symmetry analysis of ordering in lithium nickelite Li_1?x?zNi_1+xO₂ (Li_1?x?z□_yNi_1+xO₂) was performed with regard to the substitution of Li and Ni atoms and the occurrence of structural vacancies □ in the metal sublattice. For all the ordered phases, the k ₉ ⁽³⁾ ray of the Lifshitz {k₉} star is present in the order-disorder transition channel. This ray determines the consecutive alternation of atomic planes filled with only Ni atoms or only Li atoms and vacancies in the \([1\bar 11]_{B1} \) direction. It was shown that the rhombohedral ordered LiNiO₂ phase is formed in the defect-free lithium nickelite, whereas a family of three monoclinic Li₃□Ni₄O₈ (C2/m space group) and Li₂□Ni₃O₆ (C2/m and C2 space groups) superstructures arises as the concentration of structural vacancies increases. For all the superstructures, the order-disorder phase-transition channels were determined and the distribution functions of Li and Ni atoms have been calculated. The long-range order parameters describing each superstructure were found as functions of the Li_{1?x? z}Ni_1+xO₂ composition.     

Magnetic Properties of a Layered Cobaltite Sr<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Y<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>CoO<Subscript>3–δ</Subscript> (<Emphasis Type="Italic">x</Emphasis> = 0.1)

The structure, the magnetic and magnetotransport properties of perovskite Sr_0.9Y_0.1CoO_2.63 have been studied. The sample is shown to have a two-phase structure. The main phase has a tetragonally distorted unit cell and is described by space group I4/mmm. The broadening of the reflections with indices corresponding to doubling unit cell parameter c indicates the absence of the rigorous translation symmetry along axis c. The existence of the broadened superstructure reflection observed in the diffraction pattern at small angles at temperature lower than 400 K is explained by the existence of the monoclinic phase whose content is significantly lower than that of the tetragonal phase, but is dominant in the Sr_0.8Y_0.2CoO_3–δ composition. The spontaneous magnetization appears as the monoclinic phase forms. The magnetic structure is mainly G-type antiferromagnetic with magnetic moments 1.5μ_B in the layers of CoO₆ octahedra and 2μ_B in the anion-deficit CoO_{4 + γ} layers. The conduction of the Sr_0.9Y_0.1CoO_2.63 composition has a semiconducting character. The magnetoresistance is 57% in a field of 14 T at a temperature of 5 K and strongly decreases with the temperature increase.     

Short-range order in Fe<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Si<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>(<Emphasis Type="Italic">x</Emphasis>=0.05−0.08) alloys with induced magnetic anisotropy

Previously, iron—silicon alloys were investigated using X-ray diffraction and Mössbauer spectroscopy. It was demonstrated that, at low silicon concentrations, the alloys undergo a local separation into regions of the α iron phase depleted in silicon and silicon-rich clusters with a B2 ordering. The structure of locally ordered regions of the B2 phase is characterized by a pair ordering of silicon atoms: the Si—Si pairs are formed by next-nearest neighbors, and the axes of pairs are oriented along the 〈100〉 directions, which are the easy-magnetization axes. The thermomagnetic treatment in a constant magnetic field applied along the 〈100〉 axis induces an axial magnetic anisotropy, results in the formation of an anisotropic distribution of the B2 phase, and leads to a slight decrease in the volume fraction of the coordination 6: 2 with two silicon atoms in the first coordination shell of the iron atom. Therefore, the formation of an anisotropic local order of pairs of silicon atoms occurs as a result of their reorientation.     

Inclusive <Emphasis Type="Italic">J</Emphasis>/<Emphasis Type="Italic">ψ</Emphasis> photoproduction and polarization at HERA in the <Emphasis Type="Italic">k</Emphasis><Subscript><Emphasis Type="Italic">T</Emphasis></Subscript>-factorization approach

We investigate the inclusive photoproduction of J/ψ mesons at HERA within the framework of the k _T -factorization QCD approach. Our study is based on the color singlet model supplemented with the relevant off-shell matrix elements and the CCFM and KMR unintegrated gluon densities in a proton and in a photon. Both the direct and resolved photon contributions are taken into account. Our predictions are compared with the recent experimental data taken by the H1 and ZEUS collaborations. Special attention is put on the J/ψ polarization parameters λ and ν, which are sensitive to the production dynamics.     

Magnetism and superconductivity in Eu(Fe<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Ni<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>)As<Subscript>2</Subscript> (<Emphasis Type="Italic">x</Emphasis> = 0, 0.04)

We report Eu-local-spin magnetism and Ni-doping-induced superconductivity (SC) in a 112-type ferroarsenide system Eu(Fe_1?xNi_x)As₂. The non-doped EuFeAs₂ exhibits two primary magnetic transitions at ~100 and ~40 K, probably associated with a spin-density-wave (SDW) transition and an antiferromagnetic ordering in the Fe and Eu sublattices, respectively. Two additional successive transitions possibly related to Eu-spin modulations appear at 15.5 and 6.5 K. For the Ni-doped sample with x = 0.04, the SDW transition disappears, and SC emerges at T_c = 17.5 K. The Eu-spin ordering remains at around 40 K, followed by the possible reentrant magnetic modulations with enhanced spin canting. Consequently, SC coexists with a weak spontaneous magnetization below 6.2 K in Eu(Fe_0.96Ni_0.04)As₂, which provides a complementary playground for the study of the interplay between SC and magnetism.     

Mössbauer studies of multiferroics BiFe<Subscript>1 – <Emphasis Type="Italic">x</Emphasis></Subscript>Cr<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>O<Subscript>3</Subscript> (<Emphasis Type="Italic">x</Emphasis> = 0–0.20)

The Mössbauer studies on ⁵⁷Fe nuclei in multiferroics BiFe_{1 – x} Cr _x O₃ (x = 0.05, 0.10, and 0.20) have been performed at room temperature. The multiferroics BiFe_{1 – x} Cr _x O₃ (x = 0.05, 0.10, and 0.20) with the rhombohedral R3c structure have been prepared by solid-state synthesis under high pressures. The effect of substitution of Cr cations for Fe cations on the spatial spin-modulated structure, and also hyperfine electrical and magnetic interactions of ⁵⁷Fe nuclei has been studied. The substituted ferrites demonstrate an anharmonic modulated spin structure of cycloid type, in which iron atoms with different cation environments take part. The anharmonism parameter of the cycloid linearly increases from m = 0.10 at x = 0 to m = 0.78 ± 0.02 at x = 0.20. The constants of magnetic uniaxial anisotropy K _u are estimated at room temperature: K _u ≈ 0.36 × 10⁶ erg/cm³ at x = 0 and K _u ≈ 4.22 × 10⁶ erg/cm³ at x = 0.20.     

Magnetocaloric effect in La(Fe<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Si<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>)<Subscript>13</Subscript> ferromagnets

The isothermal changes in the magnetic entropy and the lattice entropy and the adiabatic temperature change in La(Fe_0.88Si_0.12)₁₃ and La(Fe_0.86Si_0.14)₁₃ ferromagnets in a magnetic field are calculated. The calculations are performed with a generalized magnetostriction model of a ferromagnet; the calculation results are compared to experimental data. It is shown that the change in the lattice entropy decreases the magnetocaloric effect and makes it possible to explain the experimental data obtained for La(Fe _x Si_{1 − x} )₁₃ (x = 0.86, 0.88) ferromagnets. The temperature dependences of the bulk compression moduli of these ferromagnets are calculated, and these dependences indicate a strong lattice softening in the vicinity of the magnetic phase transition in them. The thermal expansion coefficient and some magnetic properties of the ferromagnet with x = 0.86 are measured to determine the numerical values of the parameters entering into calculation formulas.     

Spin-wave resonance in Ge<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> films exhibiting percolation ferromagnetism

Magnetic properties of Ge_{1 ? x} Mn _x (x = 0.02, 0.04, 0.08) thin films obtained by ion-implanting Mn⁺ ions into single-crystal Ge plates are investigated. The contributions of the subsystem of dispersed Mn²⁺ ions, Ge³Mn⁵ ferromagnetic clusters, and Mn-enriched ferromagnetic domains of Ge to the magnetic moment of Ge_{1 ? x} Mn _x films are distinguished. In the subsystem of dispersed Mn²⁺ ions in Ge_{1 ? x} Mn _x films at temperatures below 10 K, a spin-wave resonance is observed in the magnetically ordered state due to percolation ferromagnetism. It is established that, in the films with percolation ferromagnetism, the exchange integrals determined from static measurements correspond to those determined by dynamic measurements.     

Magnetic state of a Zn<Subscript>1 −<Emphasis Type="Italic">x</Emphasis></Subscript>Cr<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Se bulk crystal

The spin system of a Zn_{1 ?x} Cr _x Se bulk crystal (x = 0.045) was studied using thermal-neutron diffraction and magnetic measurements. Previously, it was reported in the literature that thin films (～200 nm thick) of this type of semiconductors exhibit a ferromagnetic order. In this study, the ferromagnetic order is found to be absent in the bulk crystal.     

Magnetic and magnetoresistive properties of Gd<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Mn<Subscript>1–<Emphasis Type="Italic">x</Emphasis></Subscript>Se selenides

Gd _x Mn_1–x Se (0 ≤ х ≤ 0.15) solid solutions are synthesized on the basis of manganese monoselenide. Their magnetic and electrical properties are studied in the temperature range of 80–900 K in magnetic fields up to 10 kOe. An FCC lattice with the Fm3m space group and antiferromagnetic ordering of the magnetic moments of manganese ions is found. A monotonic reduction in the Néel temperature and an increase in the effective magnetic moment along with the gadolinium concentration are observed. Anomalies in the temperature dependence of electrical resistivity and a shift in the temperatures of anomalies in a magnetic field are found.