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研究了晶场二级效应在PrF3晶体中的作用,发现该效应可使Pr3+离子的晶场单态与其他态混合,对PrF3晶体磁化率产生明显影响.进一步研究了晶体内的交换作用有效场,其形式为Hin=(1.9-0.02556T)×10-5M,在100—300 K的温度范围内,以此计算的PrF3晶体的倒数磁化率和Verdet常数的倒数与实验值符合较好.结果表明,在PrF3晶体中,晶场二级效应与离子间的交换作用都不能忽略.
关键词:
晶场二级效应
交换作用有效场
Verdet常数
3晶体')" href="#">PrF3晶体 相似文献
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Ce3+基态在正交晶场影响下分裂的理论计算 总被引:1,自引:0,他引:1
基于晶场理论,通过模拟三种相同晶系化合物CePdGa3、Ce3Ag4Ge4和Ce3Ag4Sn4的磁化率倒数-温度曲线,得到了晶场分裂能和相应波函数,并从理论上分析了晶场效应对稀土离子基态的影响.计算表明:Kramers离子Ce3 在正交晶场的作用下,基态六重简并部分消除得到三个双态. 相似文献
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基于晶场理论,我们模拟了Kawasaki小组测量的磁化率倒数与温度关系曲线,使用点电荷晶场模型得到了伪二元合金CePt1-x,Rhx(0≤x≤0.9)的晶场分裂能和相应波函数.计算表明,Kramers离子Ce^3+在晶场效应的作用下,基态简并部分消除得到了三个双重态,模拟得到的化合物的磁化率倒数与温度关系曲线与实验曲线... 相似文献
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在一些磁性材料内, 磁性离子间交换作用和磁性离子的自旋涨落对材料磁性有影响. 本文根据磁比热实验值确定了晶场参数后, 利用包含自旋涨落的交换作用有效场Hm= n0 (1 + γ T + β eω T)M, 计算了PrNi2晶体晶场能级的Zeeman劈裂. 在温度为3.8 K ≤T≤ 30 K范围内, 计算了该晶体多晶磁矩随外磁场的变化, 以及外磁场H=5000 Oe时磁化率倒数随温度的变化, 计算结果和实验值符合较好. 当外磁场在0–50000 Oe时, 计算的该晶体的磁熵变与已有文献的理论结果相似. 计算结果说明, 提出的包含自旋涨落的交换作用有效场不仅适合亚铁磁性晶体, 而且也适合顺磁性晶体.
关键词:
2')" href="#">PrNi2
磁比热
交换作用有效场
磁矩
磁熵变 相似文献
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应用不可约张量理论构造了三角对称晶场中3d2/3d8态离子的45阶可完全对角化的微扰哈密顿矩阵,在考虑了以前工作中被忽略的自旋-自旋耦合作用的基础上计算了CsNiCl3晶体和CsNiCl3:Mg2+晶体的基态能级、晶体结构、零场分裂参量和Jahn-Teller效应,研究了掺入Mg2+对CsNiCl3晶体的光谱、零场分裂参量及Jahn-Teller效应的影响和自旋单重态对基态能级的贡献,发现掺杂使得晶体结构产生畸变,从而改变晶体光谱的精细结构和零场分裂参量,不改变Jahn-Teller效应的分裂规律但改变分裂的大小. 相似文献
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应用不可约张量理论构造了三角对称晶场中3d2/3d8态离子的45阶可完全对角化的微扰哈密顿矩阵,研究了CsNiCl3晶体的光谱精细结构、晶体结构、零场分裂参量、Jahn-Telller效应以及自旋单重态对Ni2+离子基态能级的影响,理论与实验相符合.在此基础上,进一步研究了以前工作中被忽略的自旋-自旋耦合作用和Trees修正对CsNiCl3晶体的光谱精细结构和零场分裂参量的影响,发现有四种机理会影响零场分裂参量:1)自旋-轨道耦合机理,2)自旋-自旋耦合机理;3)自旋-轨道与自旋-自旋联合耦合机理;4)自旋-轨道与Trees修正联合耦合机理,其中自旋-轨道耦合机理是最主要的,其他三种机理也是不可忽略的. 相似文献
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The investigation was made of the dependence of the intensity of Tl, Ga, Mo, Mg, Mn, Sn, Bi, Ni, Zn, Pt and Au spectral lines and the plasma parameters (temperature T, electron concentration ne, degree of 6 ionnization α) from concentration of lithium additive. 相似文献
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There is a tunnel connecting the beamcorridor and the target station in the spectrum hall in the CSNS project.The length of the tunnel is about 20 m.The shielding design of the tunnel is very significant for the persons working in the spectrum hall because the tunnel is not covered ed soil for shielding.In order to reduce the dose rate at the exit of the cable ducts,we use the ISIS construction,which is designed with four turnings,as a reference for the tunnel design.The thickness of the shielding is obtained by a simulationwith the Monte Carlo Code FLUKA.The result is compared with the data obtained with Moyer Mode and the reliability of the simulation is proved.This paper provides the basis for the design of the tunnel. 相似文献
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Design and analysis of the tunnel connecting the beamcorridor and the spectrum hall of the CSNS 总被引:1,自引:0,他引:1
There is a tunnel connecting the beamcorridor and the target station in the spectrum hall in the CSNS project. The length of the tunnel is about 20 m. The shielding design of the tunnel is very significant for the persons working in the spectrum hall because the tunnel is not covered by soil for shielding. In order to reduce the dose rate at the exit of the cable ducts, we use the ISIS construction, which is designed with four turnings, as a reference for the tunnel design. The thickness of the shielding is obtained by a simulation with the Monte Carlo Code FLUKA. The result is compared with the data obtained with Moyer Mode and the reliability of the simulation is proved. This paper provides the basis for the design of the tunnel. 相似文献
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T. Rador 《The European Physical Journal C - Particles and Fields》2007,52(3):683-688
Cosmologically stabilizing radion along with the dilaton is one of the major concerns of low energy string theory. One can
hope that T and S dualities can provide a plausible answer. In this work we study the impact of S and T duality invariances
on dilaton gravity. We have shown various instances where physically interesting models arise as a result of imposing the
mentioned invariances. In particular S duality has a very privileged effect, in that the dilaton equations partially decouple
from the evolution of the scale factors. This makes it easy to understand the general rules for the stabilization of the dilaton.
We also show that certain T duality invariant actions become S duality invariance compatible. That is, they mimic S duality
when the extra dimensions stabilize. 相似文献
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文章对微波背景辐射的各向异性、偏振及宇宙电离的历史给出了评述性介绍.从大爆炸理论的预言,到观测的发现,到其各向异性及偏振的探测,微波背景辐射(CMB)向人们揭示了丰富的宇宙学信息.文章在对基本理论作了简单介绍后,着重讲述了最新的CMB的观测结果及其物理意义.特别对微波背景各向异性探测器(Wilkinson Microwave Anisotropy Probe,WMAP)的偏振观测及其对宇宙重新电离的限制给出了较详细的叙述. 相似文献
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A model of symmetries and gauge interactions relating the electron and muon is considered. The model is based on the UL(1)?UR(1)?RL?RR group where UL(1)?UR(1) denotes the chiral e-μ rotation and RL?RR the chiral reflection of the electron field. The invariance under this group is spontaneously broken by the vacuum expectation values of scalar fields. A zeroth-order vacuum is found for which the zeroth-order electron mass vanishes, while one-loop corrections lead to a finite ratio. The decay process μ → e + γ is strictly forbidden in this model. 相似文献
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Summary Since September 1983, the Matera laser station started regular tracking activities with the geodetic satellites Lageos and
Starlette. The Matera station operates in co-ordination with the international network of geodetic laser stations, and participates
to the NASA Crustal Dynamics Project and to the MERIT Campaign promoted by IAU. The first part of this paper reports on the
operational activities at the station and on the performance of the instrumentation. The second part describes the models
adopted for data processing and presents the results obtained through the analysis of the Lageos observations acquired from
September '83 to August '84. The preliminary estimates of the geodetic co-ordinates of five European laser stations and of
their baselines are given.
The activity reported in this paper is performed under the contract of Consiglio Nazionale delle Ricerche-Piano Spaziale Nazionale-to
Telespazio for Matera laser station operation and performance analysis. 相似文献
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Hailiang ZhangMingfu Zhang Jiecai HanGuobing Ying Huaixin GuoChenghai Xu Haitao ShenNingning Song 《Applied Surface Science》2011,257(11):5012-5016
In this paper, MgO film is successfully grown on polycrystalline and monocrystalline alumina substrates using sol-gel method, and polycrystalline and monocrystalline Mg-Al spinels are fabricated by solid state reaction, respectively. The influence of annealing temperature and time on the lattice structure and growth of the formed Mg-Al spinel layer has been investigated. It is indicated that the annealing temperature and time on the as-synthesized polycrystalline Mg-Al spinel has more significant influence than that of single crystal Mg-Al spinel. The thickness of the Mg-Al spinel layer increases with the annealing temperature, both for polycrystalline and for monocrystalline alumina substrates. And the significantly intercrystalline diffusion of Mg2+ ions and Al3+ ions results in a quicker growth velocity of the Mg-Al spinel layer than that of intracrystalline diffusion. 相似文献