Analyses of the endoreversible Carnot cycle with entropy theory and entransy theory

The endoreversible Carnot cycle is analyzed based on the concepts of entropy generation, entropy generation number, entransy loss, and entransy loss coefficient. The relationships of the cycle output power and heat-work conversion efficiency with these parameters are discussed. For the numerical examples discussed, the preconditions of the application for these concepts are derived. When the inlet temperatures and heat capacity flow rates of hot streams and environment temperature are prescribed, the results show that the concepts of entropy generation and entransy loss are applicable. However, in the presence of various inlet temperatures of streams, larger entransy loss rate still leads to larger output power, while smaller entropy generation rate does not. When the heat capacity flow rates of hot streams are various, neither larger entransy loss rate nor smaller entropy generation rate always leads to larger output power. Larger entransy loss coefficient always leads to larger heat-work conversion efficiency for the cases discussed, while smaller entropy generation number does not always.     

Applicability of the minimum entropy generation method for optimizing thermodynamic cycles

Entropy generation is often used as a figure of merit in thermodynamic cycle optimizations. In this paper, it is shown that the applicability of the minimum entropy generation method to optimizing output power is conditional. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power when the total heat into the system of interest is not prescribed. For the cycles whose working medium is heated or cooled by streams with prescribed inlet temperatures and prescribed heat capacity flow rates, it is theoretically proved that both the minimum entropy generation rate and the minimum entropy generation number correspond to the maximum output power when the virtual entropy generation induced by dumping the used streams into the environment is considered. However, the minimum principle of entropy generation is not tenable in the case that the virtual entropy generation is not included, because the total heat into the system of interest is not fixed. An irreversible Carnot cycle and an irreversible Brayton cycle are analysed. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power if the heat into the system of interest is not prescribed.     

Entransy analyses of heat–work conversion systems with inner irreversible thermodynamic cycles

In this paper, we try to use the entransy theory to analyze the heat–work conversion systems with inner irreversible thermodynamic cycles. First, the inner irreversible thermodynamic cycles are analyzed. The influences of different inner irreversible factors on entransy loss are discussed. We find that the concept of entransy loss can be used to analyze the inner irreversible thermodynamic cycles. Then, we analyze the common heat–work conversion systems with inner irreversible thermodynamic cycles. As an example, the heat–work conversion system in which the working fluid of the thermodynamic cycles is heated and cooled by streams is analyzed. Our analyses show that larger entransy loss leads to larger output work when the total heat flow from the high temperature heat source and the corresponding equivalent temperature are fixed.Some numerical cases are presented, and the results verify the theoretical analyses. On the other hand, it is also found that larger entransy loss does not always lead to larger output work when the preconditions are not satisfied.     

Ecological optimization for an irreversible magnetic Ericsson refrigeration cycle

An irreversible Ericsson refrigeration cycle model is established, in which multi-irreversibilities such as finite-rate heat transfer, regenerative loss, heat leakage, and the efficiency of the regenerator are taken into account. Expressions for several important performance parameters, such as the cooling rate, coefficient of performance （COP）, power input, exergy output rate, entropy generation rate, and ecological function are derived. The influences of the heat leakage and the time of the regenerative processes on the ecological performance of the refrigerator are analyzed. The optimal regions of the ecological function, cooling rate, and COP are determined and evaluated. Furthermore, some important parameter relations of the refrigerator are revealed and discussed in detail. The results obtained here have general significance and will be helpful in gaining a deep understanding of the magnetic Ericsson refrigeration cycle.     

Diode Pumped Operation of Tm,Ho：YVO4 Microchip Laser

A cryogenic and room-temperature diode pumped Tm,Ho：YVO4 microchip laser with 0.5 mm crystal length lasing around 2μm is demonstrated for the first time to our knowledge. Under cryogenic temperature of 77 K, as much as 1.2 W output and slope efficiency of 35% with respect to absorbed pump power are obtained. At temperature of 5℃ the maximum output power of 48mW is obtained at an absorbed pump power of 503 mW, representing a 9.5% optical to optical conversion efficiency. In addition, as much as 8 mW single-frequency output lasing at 2052.6 nm is achieved at room temperature of 15℃.     

A comparison of different entransy flow definitions and entropy generation in thermal radiation optimization

In thermal radiation, taking heat flow as an extensive quantity and defining the potential as temperature T or the black body emissive power U will lead to two different definitions of radiation entransy flow and the corresponding principles for thermal radiation optimization. The two definitions of radiation entransy flow and the corresponding optimization prin ciples are compared in this paper. When the total heat flow is given, the optimization objectives of the extremum entransy dissipation principles （EEDPs） developed based on potentials T and U correspond to the minimum equivalent temperature difference and the minimum equivalent blackbody emissive power difference respectively. The physical meaning of the definition based on potential U is clearer than that based on potential T, but the latter one can be used for the coupled heat transfer optimization problem while the former one cannot. The extremum entropy generation principle （EEGP） for thermal radiation is also derived, which includes the minimum entropy generation principle for thermal radiation. When the radiation heat flow is prescribed, the EEGP reveals that the minimum entropy generation leads to the minimum equivalent thermodynamic potential difference, which is not the expected objective in heat transfer. Therefore, the minimum entropy generation is not always appropriate for thermal radiation optimization. Finally, three thermal radiation optimization examples are discussed, and the results show that the difference in optimization objective between the EEDPs and the EEGP leads to the difference between the optimization results. The EEDP based on potential T is more useful in practical application since its optimization objective is usually consistent with the expected one.     

Low Threshold and High Conversion Efficiency Nanosecond Mid-Infrared KTA OPO

Based on a Type II non-critically phase-matched KTA crystal, a low-threshold and high conversion efficiency mid-infrared optical parametric oscillator （OPO） pumped by a diode-end-pumped Nd：YVO4 laser is demonstrated. The OPO threshold is only 0.825W. The maximum output power of 435mW at 3.47μm is achieved with the repetition rate of 30kHz, corresponding to an optical-to-optical conversion efficiency of 4.4%. The photon conversion efficiency is as high as about 64%. The pulse width is 3.5ns with a peak power of 4kW for the maximum output power.     

Efficient femtosecond optical parametric oscillator pumped by all solid-state mode-locking Yb:YCOB laser

We experimentally demonstrate a femtosecond optical parametric oscillator(OPO) synchronously pumped by a home-made solid-state mode-locking Yb:YCOB laser, which is capable of laser pulse as short as 102 fs and average power of 620 m W at the central wavelength of 1052 nm. By using a periodically poled lithium niobate with tuning of the grating periods from 28.5 to 31.5 μm as the nonlinear gain crystal, tunable femtosecond pulses from 1444 to 1683 nm are realized by conveniently adjusting the OPO cavity length with 76.8 MHz repetition rate. The maximum average output power is 152 m W at 1568 nm, corresponding to an idler power of 75 m W at 3197 nm as well as 36.6% total extraction efficiency.     

Analysis of heating effect on the process of high deposition rate microcrystalline silicon

A possible heating effect on the process of high deposition rate microcrystalline silicon has been studied.It includes the discharge time-accumulating heating effect,discharge power,inter-electrode distance,and total gas flow rate induced heating effect.It is found that the heating effects mentioned above are in some ways quite similar to and in other ways very different from each other.However,all of them will directly or indirectly cause the increase of the substrate surface temperature during the process of depositing microcrystalline silicon thin films,which will affect the properties of the materials with increasing time.This phenomenon is very serious for the high deposition rate of microcrystalline silicon thin films because of the high input power and the relatively small inter-electrode distance needed.Through analysis of the heating effects occurring in the process of depositing microcrystalline silicon,it is proposed that the discharge power and the heating temperature should be as low as possible,and the total gas flow rate and the inter-electrode distance should be suitable so that device-grade high quality deposition rate microcrystalline silicon thin films can be fabricated.     

Efficient pulsed chemical oxygen-iodine laser with instantaneous generation of atomic iodine by volumetric discharge

A pulsed chemical oxygen-iodine laser (COIL) using atomic iodine generated by volumetric discharge of CH 3 I is developed and tested. COIL with a gain length of 60 cm is energized by a square pipe-array jet singlet oxygen generator with basic hydrogen peroxide pumping circulations and operated at subsonic gas flow. Maximum output energy of 4.3 J, pulse duration of 50 μs, specific energy extraction from the active medium of 2.0 J/L, and the maximum chemical efficiency of 12.5% are achieved at a chlorine flow rate of 55 mmole/s.     

(火积)理论在热功转换过程中的应用探讨

分析和讨论了(火积)理论在热功转换过程的应用及其局限性.对Carnot循环的分析表明,Carnot循环中系统的(火积)是平衡的,但(火积)和熵之间不存在dG=T2dS这样的联系.对于一般热力学过程,分析表明,在热量传递到内可逆循环中间接对外做功时,现有的(火积)理论可用于系统的分析.讨论了热功转换过程分析中(火积)理论与熵理论的不同.分析表明,两个理论的分析角度及优化输出功的前提条件是不同的.熵产从可用能损失的角度分析热功转换过程,而(火积)理论则从热量势能消耗的角度.当输入系统的可用能给定或者输入系统的热量及热量进、出系统的热力学力给定时,熵产最小化对应于输出功最大;对于(火积)理论,则当输入系统的热量及热量进、出系统的温度给定时,最大(火积)损失对应于最大输出功.同时,它们各自均有局限性.当相应的前提条件不满足时,最大(火积)损失或最小熵产可能不与最大输出功相对应.     

Output power analyses of an endoreversible Carnot heat engine with irreversible heat transfer processes based on generalized heat transfer law

In this paper, an endoreversible Carnot heat engine with irreversible heat transfer processes is analyzed based on generalized heat transfer law. The applicability of the entropy generation minimization, exergy analyses method, and entransy theory to the analyses is discussed. Three numerical cases are presented. It is shown that the results obtained from the entransy theory are different from those from the entropy generation minimization, which is equivalent to the exergy analyses method. For the first case in which the application preconditions of the entropy generation minimization and entransy loss maximization are satisfied, both smaller entropy generation rate and larger entransy loss rate lead to larger output power. For the second and third cases in which the preconditions are not satisfied, the entropy generation minimization does not lead to the maximum output power, while larger entransy loss rate still leads to larger output power in the third case. For the discussed cases, the concept of entransy dissipation is not applicable for the analyses of output power.The problems in the negative comments on the entransy theory are pointed out and discussed. The related researchers are advised to focus on some new specific application cases to show if the entransy theory is the same as some other theories.     

基于(火积)理论的轧钢加热炉壁变截面绝热层构形优化

基于绝热过程(火积)耗散极值原理, 分别在对流传热和复合传热(对流和辐射传热)边界条件下, 对轧钢加热炉壁变截面绝热层进行构形优化, 得到(火积)耗散率最小的绝热层最优构形. 结果表明: 与等截面绝热层相比, (火积)耗散率最小的变截面绝热层整体绝热性能更优. 热损失率最小和(火积)耗散率最小的绝热层最优构形是不同的. 热损失率最小的绝热层最优构形使得其能量损失减小, 而(火积)耗散率最小的绝热层最优构形使得其整体绝热性能提高. (火积)耗散率最小和最大温度梯度最小的变截面绝热层最优构形差别较小, 此时(火积)耗散率最小的绝热层最优构形在提高绝热层整体绝热性能的同时也提高了其热安全性. 基于(火积)理论的绝热层构形优化为绝热系统的优化设计提供了新的指导.     

两级中冷回热再热布雷顿热电联产装置的性能

应用有限时间热力学理论和方法建立了恒温热源不可逆两级中冷回热再热布雷顿热电联产装置模型,基于分析的观点,导出了装置无量纲输出率和效率的解析式。在给定总压比的情形下,通过数值计算分别研究了输出率和效率与两个中冷压比和两个再热压比的关系,当总压比变化时,发现输出率和效率对总压比存在最大值,并分别求出了两个相应的最佳的中冷压比和再热压比。分析了回热度、中冷度、再热度、压气机和涡轮机效率、压降损失等特征参数对装置性能的影响。最后发现分别存在最佳的用户侧温度使输出率和效率取得双重最大值。     

对流换热过程的热力学优化与传热优化

为了进一步明确对流换热过程中热力学优化与传热优化之间的差异,本文分别利用熵产最小原理、(火积)耗散极值原理针对两种边界条件下的对流换热问题进行分析,讨论熵产,(火积)耗散与有用能损失以及对流换热能力之间的关系.结果表明:熵产最小意味着系统的有用能损失最小,但并不反映系统的对流换热能力的强弱;而(火积)耗散取极值意味着系统的对流换热能力最强,但与系统的有用能损失不存在对应关系.因此,对于将降低有用能损失作为优化目标的换热问题应采用熵产最小原理进行分析;而对于需要将提高换热能力作为优化目标的对流换热问题应采用(火积)耗散极值原理进行分析.     

燃气-蒸汽联合循环余热回收系统性能研究

燃气发电是我国城市供电的主要形式之一,针对LNG接收站一体的电厂发电模式进行研究,提出一种新型燃气-蒸汽联合循环热电联供系统,利用超临界CO₂布雷顿循环结合有机朗肯循环(ORC)辅助发电,将LNG作为冷源,对烟气余热进行三级利用。通过构建热力学和经济模型,以Aspen Plus软件模拟值为基础,结果表明:在消耗燃料1.704 kg/s(LNG)的条件下,联合循环净发电功率可达45 MW,供热量41.5 MW,余热利用率,热效率和?效率分别为88.50%,52.79%和46.69%。结合热-经济学与参数分析,利用Matlab优化后的最小单位发电成本为0.1529 CNY/kWh。考虑到碳排放价格,供电、供热、供气收益,燃料价格和设备成本,电厂每年的理想收益可达2989.5万元。     

整体煤气化联合循环(IGCC)损分布结构研究

整体煤气化联合循环是一种先进的洁净煤发电技术。本文应用#［1316］分析方法,研究IGCC中七个子系统（空分、气化、净化、压气机、燃烧室、透平、余热锅炉及汽机)的#［1316］损失分布,指出系统中最大#［1316］损失过程为煤气化、燃气轮机燃烧和空分过程。同时,揭示了系统随不同空气整体化和氮气回注的规律。这些研究可以指导下一代IGCC系统的改进     

冷库预冷流动传热物理场分布研究

冷库预冷是传统的果蔬采后预冷方法,前人研究通过数值模拟使冷库预冷过程的流场和温度场可视化,本文进一步分析空气流速、局部平均空气龄、温度、熵产、(火用)损和(火积)耗散等物理场的分布特性,指出其间存在密切联系。塑料筐周围的空气流速和流向与内部的局部平均空气龄有关,并影响内部的传热速率。传热熵产率、传热(火用)损率和(火积)耗散率的分布特性及其变化趋势相似,局部高值与局部平均空气龄较低的区域均出现在塑料筐的表面。     

Applicability of minimum entropy generation methodto optimizing thermodynamic cycles

Entropy generation is often used as a figure of merit in thermodynamic cycle optimizations. In this paper, it is shown that the applicability of the minimum entropy generation method to optimizing output power is conditional. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power when the total heat into the system of interest is not prescribed. For the cycles whose working medium is heated or cooled by streams with prescribed inlet temperatures and prescribed heat capacity flow rates, it is theoretically proved that both the minimum entropy generation rate and the minimum entropy generation number correspond to the maximum output power when the virtual entropy generation induced by dumping the used streams into the environment is considered. However, the minimum principle of entropy generation is not tenable in the case that the virtual entropy generation is not included, because the total heat into the system of interest is not fixed. An irreversible Carnot cycle and an irreversible Brayton cycle are analysed. The minimum entropy generation rate and the minimum entropy generation number do not correspond to the maximum output power if the heat into the system of interest is not prescribed.