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1.
采用溶胶-凝胶法制备了TiO2/Sm3+下转换薄膜,利用其下转换特性将紫外光转换为可见光,提高了可见光光照强度。利用X射线衍射和荧光光谱对TiO2/Sm3+粉体进行了表征,并对TiO2/Sm3+下转换薄膜进行了荧光光谱测试和紫外-可见分光光度计测试。荧光光谱显示,TiO2/Sm3+薄膜在受到395 nm紫外光照射时可发射出540~600 nm连续波长的可见光,具有下转换特性。二层TiO2/Sm3+下转换薄膜的可见光透过率与单纯的TiO2薄膜基本相同,利用其下转换特性使电池短路电流提高了13.2%,光电转换率提高了16.2%。  相似文献   

2.
提高微晶硅薄膜太阳电池效率的研究   总被引:2,自引:0,他引:2       下载免费PDF全文
采用甚高频等离子体增强化学气相沉积技术制备了系列微晶硅薄膜太阳电池,指出了气体总流量和背反射电极的类型对电池性能参数的影响.电池的I-V测试结果表明:随反应气体总流量的增加,对应电池的短路电流密度、开路电压和填充因子都有很大程度的提高,结果使得电池的光电转换效率得以提高.另外,ZnO/Ag/Al背反射电极能明显提高电池的短路电流密度,进而也提高了电池的光电转换效率.对气体总流量和背反射电极类型影响电池效率的原因进行了分析. 关键词: 微晶硅薄膜太阳电池 气体流量 ZnO/Ag/Al背反射电极  相似文献   

3.
选择硫酸氧钛(TiOSO4)作为无机钛源前驱体,通过温和的水热法在掺氟氧化锡导电玻璃基底(FTO)上直接合成单晶金红石相TiO2纳米棒薄膜,呈现阵列-簇双层结构。在模拟太阳光照射下,该纳米棒薄膜的短路电流可达到0.17 mA/cm2,是相同条件下由四异丙醇钛[Ti(iPro)4]为有机钛源而制备的TiO2纳米棒薄膜的2倍多。实验结果表明,多维层状结构和无机硫酸氧根离子(OSO4-4)的存在对TiO2纳米棒薄膜的光电流响应有促进作用。  相似文献   

4.
采用溶胶-凝胶法制备了TiO2/Eu3+,Y3+下转换薄膜,将其应用到染料敏化太阳能电池中,利用其下转换特性将紫外光转换为可见光,提高了电池的可见光照强度.利用X射线衍射和荧光光谱对TiO2/Eu3+,Y3+粉体进行表征,利用荧光光谱和紫外-可见分光光度计对TiO2/Eu3+,Y3+下转换薄膜进行测试,荧光光谱显示,下转换薄膜受到396nm紫外光照射时可发射出535~620nm连续波长的可见光,具有下转换功能特性.与TiO2薄膜相比,二层下转换薄膜仍能保持较高的可见光透过率.当稀土元素总掺量为4%时,利用下转换特性使短路电流提高了21.5%,光电转换效率提高了14.1%.  相似文献   

5.
采用sol-gel法制备了Zn2 掺杂的锐钛矿相纳米TiO2薄膜电极.通过光电流作用谱和电流-电位(I-U)曲线研究了掺杂不同浓度Zn2 的TiO2薄膜电极的光电特性.由光电流作用谱可知,Zn2 的掺杂可显著影响薄膜电极的光电流大小,且掺杂的最佳浓度与薄膜晶粒尺度有关.在320nm单色光照射下,掺杂浓度(摩尔浓度)为0.1%的薄膜电极光电流最大,与未掺杂的本征薄膜电极相比增幅达40%.I-U曲线表明,光照下,随电极电位由正到负逐渐降低,不同掺杂浓度的TiO2薄膜电极中均出现了阳极电流向阴极电流转换的现象,且Zn2 掺杂浓度可影响电极阳极电流的初始电位.另外,无光照的暗态下,各薄膜在负电位区域观察到了相似的随电位降低而迅速增大的阴极暗电流.  相似文献   

6.
染料敏化TiO2/WO3薄膜电池的光电变色   总被引:2,自引:0,他引:2  
用光电化学方法研究了染料Ru(П) (4, 4′di COOEt 2, 2′bpy)2 (2, 2′bpy 4, 4′di CONH L tyrosineethylester) (PF6)2 (简写为Ru4)敏化TiO2 纳米结构电极的光电转换过程,同时,在导电玻璃上电沉积得到WO3 薄膜.结果表明,染料敏化的TiO2 多孔膜具有光电转换性能, WO3 薄膜具有良好的电致变色效应,将前者与电沉积得到的WO3 薄膜组成电池,在白光照射下可产生显著的颜色变化,有望用于自供电源的电色灵巧窗(Self poweredsmartwindow).  相似文献   

7.
唐鹿  薛飞  郭鹏  罗哲  李旺  李晓敏  刘石勇 《发光学报》2018,39(6):838-843
采用低压化学气相沉积方法在玻璃衬底上制备了B掺杂的ZnO(BZO)薄膜,通过氢退火对BZO进行处理,然后作为前电极进行了非晶硅薄膜太阳能电池的制备及性能研究。结果表明:在氢气气氛下退火后,BZO薄膜的载流子浓度基本无变化,但Hall迁移率显著提高,这使得BZO薄膜的导电能力提高;当采用厚度较小、透光率较高的BZO薄膜进行氢退火后作为前电极结构时,非晶硅薄膜太阳能电池的短路电流密度提高0.3~0.4 mA/cm2,电池的转化效率提高0.2%。实验结果可为通过优化前电极结构来提高非晶硅薄膜太阳能电池转化效率提供一种简易的方法。  相似文献   

8.
通过分析浆料分散性和粘度等因素,研究分散剂和粘结剂等对碳化硅晶须浆料流变行为的影响,确定合适的浆料制备工艺参数。结果表明:选择合适剂量的分散剂(2 wt%)能够有效减弱晶须之间的吸引力,减少晶须团簇,提高晶须分散性。同时选择3 wt%的粘结剂能够得到粘度适宜的浆料。优化工艺参数,最终获得分散性及稳定性较好且适于流延的晶须浆料。  相似文献   

9.
付姚  曹望和 《光子学报》2006,35(8):1187-1190
采用sol-gel法制备了Zn2+掺杂的锐钛矿相纳米TiO2薄膜电极.通过光电流作用谱和电流-电位(I-U)曲线研〖WTBZ〗究了掺杂不同浓度Zn2+的TiO2薄膜电极的光电特性.由光电流作用谱可知,Zn2+的掺杂可显著影响薄膜电极的光电流大小,且掺杂的最佳浓度与薄膜晶粒尺度有关.在320nm单色光照射下,掺杂浓度(摩尔浓度)为0.1%的薄膜电极光电流最大,与未掺杂的本征薄膜电极相比增幅达40%.I-U曲线表明,光照下,随电极电位由正到负逐渐降低,不同掺杂浓度的TiO2薄膜电极中均出现了阳极电流向阴极电流转换的现象,且Zn2+掺杂浓度可影响电极阳极电流的初始电位.另外,无光照的暗态下,各薄膜在负电位区域观察到了相似的随电位降低而迅速增大的阴极暗电流.  相似文献   

10.
采用ZnO:Ga2O3:TiO2为靶材,在玻璃衬底上射频磁控溅射制备了多晶Ga-Ti共掺杂ZnO(GTZO)薄膜,通过XRD、四探针、透射光谱测试研究了生长温度对薄膜结构和光电性能的影响.结果表明:所制备的薄膜具有c轴择优取向,光学带隙均大于本征ZnO的禁带宽度.当生长温度为620K时GTZO薄膜的结晶质量最佳、电阻率最低、透射率最大、品质因数最高.  相似文献   

11.
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.  相似文献   

12.
A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output.  相似文献   

13.
The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper.  相似文献   

14.
15.
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.  相似文献   

16.
A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users.  相似文献   

17.
A transient suppression method for piezoelectric ceramic transducer is presented. By adding some special pedestal pulses to the original transmitted signal, the transient effects in the output of the transducer can be just precisely transmission by use of a narrowband transducer. canceled, thereby achieving the broadband The experimental results show that the transient responses of the sinusoid pulses and coded signals are suppressed successfully and the acoustic waveforms radiated into the surrounding water are improved significantly.  相似文献   

18.
We experimentally demonstrate amplitude squeezed soliton utilizing intensity-dependent self-phase modulation in an asymmetric Sagnac interferometer.The system.whose components are connected via ferrule connector/physical connection(FC/PC)fiber connectors,constitutes all-fiber configuration to generate squeezed soliton.Soliton amplitude reduction measured by homodyne detection is near 4.0 dB below the shot-noise level.Optimal squeezing fields in both simple and compact all-fiber configuration are obtained.  相似文献   

19.
The(2 1)-dimensional nonlinear Schr(o)dinger(NLS)equation with spatially inhomogeneous nonlinearities is investigated,which describes propagation of light in(2 1)-dimensional nonlinear optical media with inhomogeneous nonlinearities.New types of optical modes and nonlinear effects in optical media are presented numerically.The results reveal that the regular split of beam can be obtained in (2 1)-dimensional nonlinear optical media with inhomogeneous nonlinearities,by adjusting the guiding parameter.Furthermore,the stability of beam regular split is discussed numerically,and the results reveal that the beam regular split is stable to the finite initial perturbations.  相似文献   

20.
In the real-world application of face recognition system, owing to the difficulties of collecting samples or storage space of systems, only one sample image per person is stored in the system, which is so-called one sample per person problem. Moreover, pose and illumination have impact on recognition performance. We propose a novel pose and illumination robust algorithm for face recognition with a single training image per person to solve the above limitations. Experimental results show that the proposed algorithm is an efficient and practical approach for face recognition.  相似文献   

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