光声喇曼光谱的理论分析

对光声喇曼光谱(PARS)作了系统的理论分析,分别导出固体和液体介质中的光声喇曼光谱的信号表达式,并进行了数值估算。 关键词：     

430-490nm激光作用下CH_3I分子的多光子电离离解研究

利用飞行时间质谱仪研究了CH3I分子在 4 30～ 4 90nm激光作用下的多光子电离 (MPI)离解过程和机制。得到了分子的飞行时间质谱 ,从整个实验波段 4 30～ 4 90nm的MPI离子谱发现 ,短波的MPI离子谱峰相对较高 ,长波的MPI离子谱峰相对较宽而弥散。对MPI离子谱中的一些共振峰标识为分子的 ( 5pπ ,8s) ,( 5pπ ,6p)以及 ( 5pπ ,7s)里德堡态共振吸收峰。还标识了 ( 5pπ ,7s)里德堡态的系列振动模。在短波段CH3I分子为 ( 3+1)多光子过程 ,长波段为 ( 2+2 )多光过程。     

用喇曼增强非简并四波混频测量喇曼模的横向弛豫时间

在频率域研究了用喇曼增强非简并四波混频(RENFWM)测量喇曼模的横向弛豫时间,得到消背底的RENFWM光谱,对实验曲线进行拟合,获得苯和甲苯的振动模的横向弛豫时间分别为1.5ps和2ps。     

两级喇曼压缩系统配偏振干涉仪诊断等离子体电子密度

 在星光Ⅱ铷玻璃激光装置上,采用两级喇曼压缩系统产生的波长为308 nm的紫外光作为探针束，配合Nomarski偏振干涉仪对金平面靶冕区激光等离子体进行诊断。308 nm光具有波长短、亮度高、脉冲时间短、相干性好的优点,作为探针束诊断冕区产生的等离子体电子密度，可以与高功率激光装置打靶激光同步,实现有效地脉冲压缩，同时避免等离子体中谐波分量的干扰。实验获得了308 nm紫外探针光偏振干涉条纹图，在研究Abel反演算法的基础上，利用自行研制的基于Windows操作系统的实验数据处理软件,对实验数据进行了处理和分析，得到了冕区等离子体电子密度的空间分布。结果表明：两级喇曼压缩系统配偏振干涉能有效抑制主束谐波影响,以更高时间分辨测量等离子体的更高密度区域。     

高效率599 nm Ba(NO3)2外腔喇曼激光器

橘黄色波段固体激光器在基于荧光探测的生物医学诊断和显示等众多方面有着广泛的实际应用. 报道了利用532 nm的Nd∶YAG倍频激光抽运外置喇曼腔内的硝酸钡晶体,获得高效率的599 nm橘黄色喇曼激光的实验结果.对外置喇曼腔实验装置和运转参量进行了优化,喇曼振荡腔由对二阶斯托克斯光有最优化反射率的腔镜构成,对实验中所得到的二阶斯托克斯喇曼激光脉宽压缩及出现双尖峰的现象进行了分析.当抽运光功率达到4.1 W时,获得二阶斯托克斯喇曼激光功率为710 mW,输出光中心波长为599.38 nm,半峰全宽（FWHM）为1.1 nm,激光器最大光光转换效率为17.5%,斜率效率为24.8%.     

固体的光散射讲座第二讲 分子振动及其喇曼光谱

分子的振动能量是量子化的,这些不连续的能量可用对应的一组振动量子数表示.当光和分子相互作用时,分子从一个振动量子态跃迁到另一个量子态所产生的光谱(喇曼谱和红外谱),我们称它为分子振动光谱.喇曼谱与红外谱,都是用来研究分子振动、分子碰撞所导致的能级跃迁、分子与光子以及其他粒子之间的相互作用等物理过程,从而提供对分子或固体的某些信息并推断分子或固体的空间构型及其对称性.喇曼光谱术已成为分析分子振动和晶格振动的重要实验手段.振动喇曼谱的理论是分子光谱学的一个重要方面. 激光出现以后,大大推动了喇曼光谱实验和理论研究…     

CH4分子ν1模拉曼诱导克尔效应谱与受激拉曼光声光谱峰形的比较

以气相甲烷分子ν₁模Q支的拉曼光谱为例，采用拉曼诱导克尔效应谱(RIKES)进行峰形测量，并将其与同时测量的受激拉曼光声光谱(PARS)的峰形进行了比较.结果表明，在pump光和Stokes光均为线偏振的情况下，两者存在着差异；在拉曼共振峰的低频端，RIKES谱强度略高；而高频端则恰好相反.从信号产生机制出发，对此进行了合理解释. 关键词： 拉曼诱导克尔效应谱 受激拉曼光声光谱 峰形     

喇曼感应克尔效应光谱学

喇曼感应克尔效应光谱学记作RIKES(是Raman Induced Kerr-Effeet Spectroscopy的缩写),是相干喇曼光谱学的一个分支.喇曼感应克尔效应是 1975年由 D.Heiman,R.W.Hellwarth等人首先演示的[1].之后,G.L.Eesley,M.D.Levenson[2]和 A.Owyoung等发展了光外差喇曼感应克尔效应光谱学(Optically heterdynedRIKES,缩写作OHD-RIKES),并很快在液相介质及气相介质的高分辨率喇曼光谱的研究中得到成功的应用. 用两束激光同时照射介质,我们把其中强的一束偏振光(圆频率为ω1)称为抽运光,另一束弱的线偏振光(圆频率为ω2)称为探测光.在抽运…     

(O)H自由基LIF光谱研究

利用脉冲高压直流放电技术产生(O)H超声分子束,以纳秒染料激光二倍频输出(282 nm)作为激发光源,通过LIF光谱测量方法,获得了(O)H A2∑+-X2Ⅱ(1,0)带转动分辨激发荧光谱,并通过对谱线强度分布的分析和计算,得到X2Ⅱ态OH的转动温度为(30±1)K;通过对A2∑+-X2Ⅱ(1,1)带及(0,0)带跃迁的荧光衰减时间谱测量,拟合得出(O)H激发态A2∑+(ν=1)及X2Ⅱ(ν″=0)的寿命分别为(637±6)和(675±13)ns.     

准分子激光束的喇曼组束

受激喇曼散射可以将紫外准分子激光辐射频移到特定的近紫外或可见光波长,采用喇曼整形技术可以改善斯托克斯光的光束质量,本文报道喇曼组束提高喇曼整形效率的实验结果.     

Theoretical analysis and simulation of conjugate heights for dual-conjugate AO system in lidar

A multi-conjugate adaptive optics （MCAO） can offer a possibility of widening field of view （FOV） characterized by the isoplanatic angle, and the choose of conjugate height becomes a basic problem for MCAO, which influences the size of iosplanatic angle. Considering the application of lidar, the isoplanatic angle＇s expressions of two deformable mirrors （DMs） MCAO for uplink and downlink are deduced. The effects of conjugate heights for dual-conjugate AO are thoughtfully discussed, and the isoplanatic angles are further analyzed. The results show that the isopanatic angle varies with the conjugate height and reaches the maximum as the conjugate height is at the optimal altitude. Moreover, the optimal conjugate height changes with the propagation distance.     

Quick single-photon detector with many avalanche photo diodes working on the time division

Due to the limit of response speed of the present single-photon detector, the code rate is still too low to come into practical use for the present quantum key distribution (QKD) system.A new idea is put up to design a quick single-photon detector.This quick single-photon detector is composed of a multi-port optic-fiber splitter and many avalanche photo diodes (APDs).Au of the ports with APDs work on the time division and cooperate with a logic discriminating and deciding unit driven by the clock signal.The operation frequency lies on the number N of ports, and can reach N times of the conventional single-photon detector.The single-photon prompt detection can come true for high repetition-rate pulses.The applying of this detector will largely raise the code rate of the QKD, and boost the commercial use.     

Characterization of PolyA and PolyC mismatches by Raman spectroscopy

A.C mismatches are studied by Raman spectral characterization of PolyA, PolyC, and their equimolar complex in solution of 0.14 mol/L Na ,pH7.0.Experimental results show that A·C mismatches occur to be A/B (mainly A) conformers, and unlike Watson-Crick base pairing, this kind of mismatches is stabilized by only one hydrogen bond involving cytosine N4H2 and adenine N7.The formation of A·C complex makes the base stacking interactions much stronger, and conformation of the backbone more ordered, which leads to obvious Raman hypochromic effect with some shifts in corresponding bands.     

Improvement of four-wave mixing-based wavelength conversion efficiency in dispersion shifted fiber by 40-GHz clock pumping

40-GHz clock modulated signal as a pump to improve the efficiency of four-wave mixing (FWM)-based wavelength conversion in a 26.5-km dispersion shifted fiber (DSF) is investigated. The experimental results demonstrate that the conjugated FWM component has higher intensity with the clock pumping than that with the continuous-wave (CW) light pumping. The improvement of FWM-based wavelength conversion efficiency is negligible when the pump power is less than Brillouin threshold. But when the pump power is greater than Brillouin threshold, the improvement becomes significant and increases with the increment of pump power. The improvement can increase up to 9 dB if pump power reaches 17 dBm.     

Speech enhancement by array crosstalk resistant ANC and spectrum subtraction

Microphone array-based speech enhancement has great importance for speech communications and speech recognition. To reduce the aperture of the microphone array and to increase the effect of the speech enhancement will greatly broaden the application areas of the microphone array. An array crosstalk resistant adaptive noise cancellation method is therefore presented. And then an improved spectral subtraction algorithm is further cascaded to obtain better enhancement results. Theoretic analysis and experiments indicate that the proposed scheme needs only a very small microphone array while it simultaneously achieves a higher SNR improvement. Besides, the proposed scheme can be used in many noisy environments and is easy for real-time implementation.     

Multi-pulse operation of a Kerr-lens mode-locked femtosecond laser

Our experimental results show that the presence of a proper amount of negative group velocity dispersion is essential to multi-pulse operation of a Kerr-lens mode-locked femtosecond laser. We demonstrate that the pulse separations and the number of pulses contained within a cavity round trip are strongly dependent on the initial perturbations. The results allow us to get a better understanding on the influences of the convoluted self-phase modulation and intra-cavity dispersions on the stable multi-pulse oscillation in a Kerr-lens mode-locked femtosecond laser.     

Propagation of Helmholtz-Gauss beams in weak turbulent atmosphere

Based on the Rytov approximation of light propagation in weak turbulent atmosphere,the closed-form expressions of field and average irradiance of each one of the four fundamental families of Helmholtz-Gauss (HzG)beams:cosine-Gauss beams,stationary Mathieu-Gauss beams,stationary parabolic-Gauss beams,and Bessel-Gauss beams,which are propagating in weak turbulent atmosphere,are obtained.The results show that the field and average irradiance can be written as the product of four factors:complex amplitude depending on the z-coordinate only,a Ganssian beam.a factor of complex phase perturbation induced by atmospheric turbulence,and a complex scaled version of the transverse shape of the non-diffracting beam.The effect of weak atmospheric turbulence on irradiance distribution of the HzG beam can be ignored.     

An effective method for reducing speckle noise in digital holography

An effective method for reducing the speckle noise in digital holography is proposed in this paper.Different from the methods based on classical filtering technique,it utilizes the multiple holograms which are generated by rotating the illuminating light continuously.The intensity images reconstructed by a series of holograms generated by rotating the illuminating light possess different speckle patterns.Hence by properly averaging the reconstructed intensity fields,the speckle noises can be reduced greatly.Experimental results show that the proposed method is simple and effective to reduce speckle noise in digital holography.     

Influence of purity of HfO2 on reflectance of ultraviolet multilayer

The impurities in two kinds of HfO2 materials and in their corresponding single layer thin films were determined through glow discharge mass spectrum technology and secondary ion mass spectrometry(SIMS) equipment respectively.It was found that ZrO2 was the main impurity in the two kinds of HfO2 either in the original HfO2 materials or in the electron beam deposited films.In addition,the difference of Zr content in the two kinds of HfO2 single laver films was much laxger than that of the other impurities such as Ti and Fe.which showed that it was just ZrO2 that made the difference between the optical performance of the film products including the two kinds of HfO2.With these two kinds of HfO2 and the same kind of SiO2.we deposited HfO2/SiO2 multilayer reflective coatings at the wavelength of 266 nm.Experimental results showed that the reflectances of these two mirrors were about 99.85% and 99.15% respectively,which agreed well with the designed results what were based on the optical constants obtained from the corresponding single layer thin films.