水蒸气在垂直钛板表面的冷凝传热特性

对水蒸气在垂直钛板表面的冷凝传热特性进行了可视化实验研究。实验结果表明,蒸汽在钛表面为液滴和沟流状液膜共存的混合冷凝形式。随着表面过冷度的增大,滴状区所占的面积比η逐渐减小,且液滴的脱落直径逐渐增大,导致表面的冷凝传热系数随之下降。η值大于50%时,冷凝传热系数随滴状区所占面积比的减小而陡降,滴状区面积小于膜状区后,η值对冷凝表面传热性能的影响较小。     

水蒸气在超疏水表面上的冷凝传热

用高温裂解法在紫铜基底上制备了疏水性碳纳米管膜,通过对此碳纳米管膜进行氟化处理,改善了表面的疏水性.在室温下,实验测得水在这种表面上的接触角在90°～130°之间.以水蒸气为冷凝介质的冷凝传热实验表明,水蒸气在超疏水纳米材料表面上能形成较好的滴状冷凝,冷凝传热膜系数可达40000 W/(m2·K).与纯粹膜状冷凝相比,冷凝传热系数提高3～4倍.分析表明,此碳纳米管膜所产生的附加热阻只占冷凝传热热阻的千分之一,对冷凝传热膜系数的影响可以忽略.     

分子自组装膜表面滴膜共存冷凝传热的研究

本文以不同处理工艺制备十八烷基硫醇自组装膜,研究制备的表面上蒸气冷凝传热过程.结果表明不同的成膜温度,可以实现膜表面上水蒸气冷凝形态从膜状到滴状的过渡.并研究了该表面上滴膜共存状态下的冷凝传热特性,表明过渡状冷凝传热随固液自由能差渐进变化的实质是冷凝形态的渐进变化,表面上冷凝液运动形态的不同也将导致传热性能的改变,并对自组装膜表面上的冷凝传热系数可能随操作时间的增加而回升的现象进行了分析.     

表面纳米结构及其自由能对滴状冷凝传热的影响

通过抛光和氧化刻蚀方法在基体壁面形成微米和纳米尺度的微观结构,然后制备十八烷基硫醇分子自组装膜,从而得到空气中表观接触角为160°的SAM-1表面和空气中表观接触角为116°的SAM-2表面.实验研究了常压条件下两类表面的滴状冷凝传热特性.结果表明两种表面都能够有效提高冷凝传热效果.但是,具有表面纳米结构的SAM-1表面的滴状冷凝传热特性低于SAM-2表面.分析了纳米结构和液固自由能差效应对滴状冷凝传热影响的共同作用机理.     

烧结多孔表面强化冷凝传热的实验研究

实验研究了不同粒径金属粉末烧结制备的多孔涂层表面对垂直管外水蒸气冷凝传热的强化作用。发现:粒径为50μm的细粉覆盖一层及两层的多孔管的传热效果反而不如光管,使冷凝传热效果恶化;而粉末粒径为250μm的烧结表面的强化传热特性比光管提高10％～15％,而且也明显优于粒径为50μm的表面。同时,两种不同粒径表面,两层粉末错落堆积烧结表面的传热效果也优于单层粉末烧结表面。基于孔隙微观结构变化对冷凝液流动与导热的影响分析讨论了多孔烧结表面强化膜状冷凝传热的机理。     

含有不凝气体的蒸汽滴状冷凝传热实验研究

本文对饱和水蒸气和空气的混合物在垂直表面上滴状冷凝传热特性进行了实验研究。考察了不同的压力条件下不凝气对冷凝传热的影响。与膜状冷凝实验结果对比表明,滴状冷凝对含有不凝气的蒸汽冷凝传热有强化作用;在较高的冷凝压力下不凝气体对传热的影响相对较小。     

蒸汽冷凝过程的分子团聚模型及其对不凝性气体影响传热性能的解释

根据相变过程的微观物理机理和热力学特性,提出了冷凝传热过程中,近壁面蒸汽分子经由团聚阶段进而冷凝成宏观液滴的物理模型.并将团聚体分布与滴状冷凝传热性能相联系,从而研究不凝性气体对滴状冷凝传热过程的影响.在改进的Dillmann和Meier(DM)模型基础上,将分子团聚过程中的临界过饱和度与冷凝过程中的过冷度相联系,以及将团聚体的能量特性与液固界面物理化学特性相联系,将团聚模型与考虑固液界面效应的滴状冷凝传热模型相联系,建立了近壁面条件影响的分子团聚模型.利用模型计算了近壁面蒸汽中团簇体尺寸和分布,以及不凝性气体存在导致的蒸汽冷凝团聚体分布的变化,并结合滴状冷凝传热模型,定量解释了少量不凝性气体的存在,极大影响了冷凝传热性能的现象.模型计算结果与实验结果及文献中含不凝气的蒸汽冷凝传热实验数据进行了比较,两者符合较好,验证了所提出模型的合理性.     

滴状冷凝过程液滴自由表面温度场分析

对于滴状冷凝过程及其传热强化机理, 一般通过分析冷凝壁面上液滴分布和运动规律进行研究, 并且将单个液滴视为稳定的个体, 很少涉及液滴内部运动特征. 本文通过红外热像仪观测了纯蒸气滴状冷凝过程中, 液滴运动时自由表面温度场的演化过程. 发现在疏水壁面上, 液滴由于合并或脱落而发生移动过程中, 其自由表面温度先降低, 而后升高并高于移动前温度. 通过分析疏水表面上液滴移动过程的物理模型, 认为液滴移动时表面液膜发生履带式滚动现象, 或者发生液滴内部与自由表面附近的液体间形成对流和掺混现象. 对液滴运动时表面温度演变规律的分析表明: 触发液滴表面发生持续冷凝可能需要克服一个临界过冷度, 当气液间温差超过该临界值时才诱发冷凝; 液滴合并或脱落等整体运动过程, 导致了液滴内部的运动特征, 并促进了较大尺寸液滴表面发生直接冷凝, 这为强化冷凝传热的研究提供新的思路.     

聚合物表面滴状冷凝传热寿命的实验研究

在滴状冷凝传热寿命测试装置上，对采用离子束动态混合注入（DIMI）技术制备的聚四氟乙烯（PTFE）表面的商状冷凝传热寿命进行了间歇实验测试。满状冷凝已维持约500h（间歇操作总时间为1，000h），实验现象及传热性能趋于基本稳定。同时表明聚合物与金属基体具有较强的结合力。     

新型制冷机冷凝器壳侧的传热强化研究

针对现行制冷机冷凝器的不足 ,设计了适用于冷凝传热的新型折流杆冷凝器的壳程内部结构 ,并分析了其传热强化机理。在重力控制条件下 ,对不同内部支承结构与管束组合的冷凝器进行了传热实验研究 ,得到了水蒸汽在冷凝器壳侧的冷凝传热特性曲线。采用冷凝传热强化因子的概念 ,建立了预测该种折流杆冷凝器壳侧冷凝传热膜系数的计算公式 ,为折流杆冷疑器在制冷系统中的设计应用提供了理论依据。     

CONDENSATION HEAT TRANSFER OF STEAM ON VERTICAL DROPWISE AND FILMWISE COEXISTING SURFACES WITH A THICK ORGANIC FILM PROMOTING DROPWISE MODE

This article describes an experimental investigation of the condensation heat transfer of steam on dropwise and filmwise coexisting (DFC) surfaces, on which dropwise and filmwise exist simultaneously at adjacent positions. A fluor-containing organic film with thickness of more than 1 μm was coated on the dropwise regions of the external surface of a brass tube to promote dropwise condensation. The surfaces were divided horizontally into many regions according to the designed dropwise and filmwise condensation area ratio. The area ratio of dropwise regions and filmwise regions in the present study was fixed at 50%:50% for all the six surfaces, while the numbers of dropwise and filmwise regions ranged from 2 to 16. Experiments were conducted at atmospheric pressure and the treated tube was oriented vertically in the condensing chamber. It was found that the heat transfer performance for DFC surfaces increases with increasing number of dropwise and filmwise regions, and an enhancement ratio of 1.27 to 1.96 is realized compared with the results for bare surface. Visual observation revealed that the appearance of condensation near the boundary region between the dropwise and filmwise regions was dependent on the relative positions of the two condensation regions. The condensate flowed smoothly across the boundary for dropwise condensation in the upper region. With filmwise condensation in the upper region, a condensate ring was formed at the interface and was retained at the interface for a short period of time before collapsing and then continued to flow downward through the dropwise condensation region. The condensate ring made a remarkable contribution to the condensation heat transfer enhancement for DFC surfaces. Finally, the results also showed that the heat transfer enhancement for dropwise and filmwise coexisting surfaces depends not only on the area ratio on DFC surfaces, but also on the surface subcooling degree. An optimal coordinating condition between these two factors might realize a maximum heat transfer enhancement ratio.     

ON THE ENHANCEMENT OF FILMWISE CONDENSATION HEAT TRANSFER BY MEANS OF THE COEXISTENCE WITH DROPWISE CONDENSATION SECTIONS

This article describes work aimed at obtaining higher filmwise condensation heat flux by distributing dropwise condensation surfaces of optimal width promoted by an organic coating among filmwise surfaces, and to get higher mean overall heat transfer coefficients in condensing systems. Several different spacings were examined for the horizontal orientation, arranging a dropwise section above a filmwise one, to make clear the effect of the drops falling down to the filmwise section. The heat flux of the filmwise part increased with increasing the height of the dropwise part up to 2 mm, but then decreased above that. The extent of the filmwise part that was augmented by drops was also tested by changing the width of the filmwise section sandwiched between dropwise sections of constant width. The heat flux of the filmwise part increased abruptly at a width between 5 and 3 mm. Consequently, it was shown that there exists an optimum width for each section for enhancing condensation heat transfer in the filmwise sections.     

Dropwise Condensation of Steam on a Small Tube Bundle at Turbine Condenser Conditions

Application of dropwise condensation to utility turbine condensers is investigated by comparing the thermal performance of dropwise and filmwise bundles at industrially relevant conditions. Steam and steam-air mixtures were condensed on bundles of in-line, titanium tubes. The row-by-row heat transfer coefficients are presented against bundle position. They show the expected behavior for filmwise condensation but demonstrate a different one for dropwise. In air-free steam, the dropwise heat transfer coefficients are much larger and do not vary significantly with bundle position. In air-steam mixtures the dropwise values decrease similarly to their filmwise equivalents. The findings are in accord with those found for other geometries. The findings indicate that significant reductions in condenser size can be obtained if permanent dropwise condensation can be produced at industrially relevant conditions.     

酒精-水混合蒸气凝结换热系数的计算模型

通过将膜状凝结和珠状凝结理论相结合建立了一个新的模型,用于计算酒精-水混和蒸气Marangoni凝结换热系数,该模型引入一个特性系数将膜状凝结和珠状凝结理论相结合,并考虑了酒精浓度、蒸气压力和流速的影响.在不同的压力和流速下,模型计算的结果与实验和相关文献进行了比较,最大误差为±30%.     

镀层微观结构对凝结换热的影响

通过研究Ni-P化学镀层管不同微观结构对凝结传热的影响,表明用化学镀表面改性的镀管相对于普通的碳钢管,具有明显促进珠状凝结的效果,在凝结过程中表现为珠膜共存状态,可以获得较好的换热性能。同时镀层对换热性能的改善与镀层中纳米相的含量相关,随着纳米相含量的降低,镀层的表面能也随着降低,换热效率得到增强。增加镀层的非晶度可以获得更好的珠状凝结的效果。     

蒸气凝结相关问题探讨

讨论了几个与蒸气凝结相关的问题,指出壁面上球冠形液滴的内外压差和临界半径同样遵循经典的Laplace公式和Kalvin公式;蒸气在冷壁上的冷凝形态主要由后退接触角决定;空气中的水蒸气在换热器表面呈膜状冷凝时换热器的性能优于呈滴状冷凝时换热器的性能。     

氨的添加引发水蒸气凝结换热强化的实验研究

研究了添加极少量氨时,氨-水混合蒸气在水平圆管上的凝结传热特性。结果表明:由于氨的添加引发的Marangoni效应,水蒸气的凝结换热在实验工况范围内基本上都得到了强化。随着表面过冷度的增加,凝结换热系数表现出有峰值点的非线性变化规律。当氨蒸气的浓度为0.38%时,混合蒸气的最大凝结换热系数可达纯水蒸气的1.9倍,从液膜热阻和扩散热阻的角度分析了强化换热的机理。