The modulation instability development of intensive surface plasmon–polariton waves in a thin metal film is studied. It is shown both analytically and numerically that the modulation‐instability effect can give rise to spatial redistribution and longitudinal localization of surface plasmon–polariton wave energy on the subwavelength scale. Analytical expressions for the driving parameters of the modulation instability process ? nonlinearity and dispersion ? are derived. The impact of the film thickness and dielectric permittivities of constituents on the dynamics of surface plasmon–polariton wave transformation is considered. Numerical simulations show that in the layer structure comprising a silver film of subwavelength thickness a train of subpicosecond optical pulses with high repetition rate can be generated.
A theory of dielectric response of water under nanoscale confinement was long overdue. This work addresses the problem by establishing a relation between dielectric response and hydrogen‐bond frustration subsumed in a non‐Debye polarization term. The results hold down to the single‐molecule contribution and are validated vis‐à‐vis experimental measurements on a system where dielectric modulation entails removal of a single water molecule. The frustrated dielectric response down to molecular scales is assessed by contrasting two enantiomeric ligands in association with the same protein, with the complexes differing in the removal of a single interfacial water molecule.
The properties of the superconducting and the anomalous normal state were described by using the Eliashberg method. The pairing mechanism was reproduced with the help of the Hamiltonian, which models the electron‐phonon and the electron‐electron‐phonon interaction (EEPh). The set of the Eliashberg equations, which determines the order parameter function (φ), the wave function renormalization factor (Z), and the energy shift function (χ), was derived. It was proven that for the sufficiently large values of the EEPh potential, the doping dependence of the order parameter () has the analogous course to that observed experimentally in cuprates. The energy gap in the electron density of states is induced by Z and χ ‐ the contribution from φ is negligible. The electron density of states possesses the characteristic asymmetric form and the pseudogap is observed above the critical temperature.
The optical properties and sensing performances of the molecular sensors based on plasmonic Fano‐resonance (PFR) nanostructures have been numerically investigated in detail. The on‐resonance sensor, in which the Fano‐resonance position is overlapping with the absorption‐band of the detected molecules perfectly, reveals a powerful ability to detect the molecules with a low concentration or thin thickness. By the bias‐modulation of a single‐layer graphene, the Fano‐resonance position of the nanostructures can be tuned effectively. On being modulated properly, the PFR sensor shows an ultrahigh performance because of the unprecedentedly high overlap of the Fano‐resonance position with the absorption‐band of molecules, which is enabling superior signal strength in the molecular detections based on their vibrational fingerprints. Our proposed strategy may enable the development of dynamic sensors and open exciting prospects for bio‐sensing.
Following the Dirac‐Frenkel time‐dependent variational principle, transient dynamics of a one‐dimensional Holstein polaron with diagonal and off‐diagonal exciton‐phonon coupling in an external electric field is studied by employing the multi‐D2Ansatz, also known as a superposition of the usual Davydov D2 trial states. Resultant polaron dynamics has significantly enhanced accuracy, and is in perfect agreement with that derived from the hierarchy equations of motion method. Starting from an initial broad wave packet, the exciton undergoes typical Bloch oscillations. Adding weak exciton‐phonon coupling leads to a broadened exciton wave packet and a reduced current amplitude. Using a narrow wave packet as the initial state, the bare exciton oscillates in a symmetric breathing mode, but the symmetry is easily broken by weak coupling to phonons, resulting in a non‐zero exciton current. For both scenarios, temporal periodicity is unchanged by exciton‐phonon coupling. In particular, at variance with the case of an infinite linear chain, no steady state is found in a finite‐sized ring within the anti‐adiabatic regime. For strong diagonal coupling, the multi‐ Anstaz is found to be highly accurate, and the phonon confinement gives rise to exciton localization and decay of the Bloch oscillations.
The non‐centrosymmetric polar tetragonal (P 41) barium antimony tartrate trihydrate, Ba[Sb2((+)C4H2O6)2]·3H2O, was found to be an attractive novel semi‐organic crystal manifesting numerous χ (2)‐ and χ (3)‐nonlinear optical interactions. In particular, with picosecond single‐ and dual‐wavelength pumping SHG and THG via cascaded parametric four‐wave processes were observed. High‐order Stokes and anti‐Stokes lasing related to two SRS‐promoting vibration modes of the crystal, with ωSRS1 ≈ 575 cm?1 and ωSRS2 ≈ 2940 cm?1, takes place. Basing on a spontaneous Raman investigation an assignment of the two SRS‐active vibration modes is discussed.
The recently discovered two‐dimensional oxide quasicrystal (OQC) derived from BaTiO3 on Pt(111) is the first material in which a spontaneous formation of an aperiodic structure at the interface to a periodic support has been observed. Herein, we report in situ low‐energy electron microscopy (LEEM) studies on the fundamental processes involved in the OQC growth. The OQC formation proceeds in two steps via of an amorphous two‐dimensional wetting layer. At 1170 K the long‐range aperiodic order of the OQC develops. Annealing in O2 induces the reverse process, the conversion of the OQC into BaTiO3 islands and bare Pt(111), which has been monitored by in situ LEEM. A quantitative analysis of the temporal decay of the OQC shows that oxygen adsorption on bare Pt patches is the rate limiting step of this dewetting process.
Uniform, graded and spaced arrays of 3 μm triangular antidots in pulsed laser deposited YBa2Cu3O7 (YBCO) superconducting thin films are compared by examining the improvements in the critical current density they produced. The comparison is made to establish the role of their lithographically defined (non‐)uniformity and the effectiveness to control and/or enhance the critical current density. It is found that almost all types of non‐uniform arrays, including graded ones enhance over the broad applied magnetic field and temperature range due to the modified critical state. Whereas uniform arrays of antidots either reduce or produce no effect on compared to the original (as‐deposited) thin films.
Single neutral atom mechanics is controllable by focused, high‐intensity optical vortices. The intensity‐dependent, laser‐driven motion of the atom's active electrons subsumes to a net transfer of the orbital angular momentum of the light to the neutral atom. The ponderomotive force on these electrons translates so into an unbounded or a bounded radial drift of the atom depending on its initial kinetic energy, as set by the temperature. Appropriate combination of laser beams results in sub‐wavelength, dynamical radial traps for tweezing atoms controllably, an effect that can be exploited for atom guiding, structuring, and lithographic applications.
Here we report on the hybrid nanostructures where a single ZnS nanobelt was half‐covered with an aluminum (Al) film, which is an ideal platform for studying the second‐harmonic generation (SHG) enhancement effects of the Al coating. It was fabricated by the lift‐off process and allowed for the accurate comparison of the SHG intensity between the Al‐covered and the same bare ZnS nanobelt under consistent test conditions. The results indicate that the Al coating in the hybrid nanostructures not only confines the pumping laser in the ZnS effectively, but also concentrates the emitted SHG signal greatly, increasing the signal collection efficiency. By the combination of these two effects, ∼60 times enhancement of the SHG intensity is achieved at the optimized geometry size (width and thickness) of the ZnS nanobelts. The Al‐based hybrid nanostructures open up new possibilities for low‐cost, highly efficient and directional coherent nanolight sources at short wavelengths.
A mid‐infrared (MIR) supercontinuum (SC) has been demonstrated in a low‐loss telluride glass fiber. The double‐cladding fiber, fabricated using a novel extrusion method, exhibits excellent transmission at 8–14 μm: < 10 dB/m in the range of 8–13.5 μm and 6 dB/m at 11 μm. Launched intense ultrashort pulsed with a central wavelength of 7 μm, the step‐index fiber generates a MIR SC spanning from ∼2.0 μm to 16 μm, for a 40‐dB spectral flatness. This is a fresh experimental demonstration to reveal that telluride glass fiber can emit across the all MIR molecular fingerprint region, which is of key importance for applications such as diagnostics, gas sensing, and greenhouse CO2 detection.
Nonlinear wave mixing in mesoscopic silicon structures is a fundamental nonlinear process with broad impact and applications. Silicon nanowire waveguides, in particular, have large third‐order Kerr nonlinearity, enabling salient and abundant four‐wave‐mixing dynamics and functionalities. Besides the Kerr effect, in silicon waveguides two‐photon absorption generates high free‐carrier densities, with corresponding fifth‐order nonlinearity in the forms of free‐carrier dispersion and free‐carrier absorption. However, whether these fifth‐order free‐carrier nonlinear effects can lead to six‐wave‐mixing dynamics still remains an open question until now. Here we report the demonstration of free‐carrier‐induced six‐wave mixing in silicon nanowires. Unique features, including inverse detuning dependence of six‐wave‐mixing efficiency and its higher sensitivity to pump power, are originally observed and verified by analytical prediction and numerical modeling. Additionally, asymmetric sideband generation is observed for different laser detunings, resulting from the phase‐sensitive interactions between free‐carrier six‐wave‐mixing and Kerr four‐wave‐mixing dynamics. These discoveries provide a new path for nonlinear multi‐wave interactions in nanoscale platforms.
We consider a universe with a bulk viscous cosmic fluid, in a flat Friedmann‐Lemaitre‐Robertson‐Walker geometry. We derive the conditions for the existence of inflation, and those which at the same time prevent the occurrence of self‐reproduction. Our theoretical model gives results which are in perfect agreement with the most recent data from the PLANCK surveyor.
By considering (non‐relativistic) quantum mechanics as it is done in practice in particular in condensed‐matter physics, it is argued that a deterministic, unitary time evolution within a chosen Hilbert space always has a limited scope, leaving a lot of room for embedding the quantum‐classical transition into our current theories without recurring to difficult‐to‐accept interpretations of quantum mechanics. Nonunitary projections to initial and final states, the breaking of time‐reversal symmetry, a change of Hilbert space, and the introduction of classical concepts such as external potentials or localized atomic nuclei are widespread in quantum mechanical calculations. Furthermore, quantum systems require classical environments that enable the symmetry breaking that is necessary for creating the atomic configurations of molecules and crystals. This paper argues that such classical environments are provided by finite‐temperature macroscopic systems in which the range of quantum correlations and entanglement is limited. This leads to classical behavior on larger scales, and to collapse‐like events in all dynamical processes that become coupled to the thermalized degrees of freedom.
In this article a particular solution of Heun equation is derived by making use of the Nikiforov‐Uvarov (NU) method which provides exact solutions for general hypergeometric equation and eigenvalues together with eigenfunctions of the Heun equation for this particular solution are obtained. One to one correspondence (isomorphism) of the aforesaid equation with the radial Schrödinger equation is emphasized and also physical counterparts of the parameters in this equation are put forward by introducing solutions for two different potential functions (Hulthen and Woods‐Saxon potentials).
The FeTe parent compound for iron‐superconductor chalcogenides was studied applying Mössbauer spectroscopy accompanied by ab initio calculations of electric field gradients at the iron nuclei. Room‐temperature (RT) Mössbauer spectra of single crystals have shown asymmetric doublet structure commonly ascribed to contributions of over‐stoichiometric iron or impurity phases. Low‐temperature Mössbauer spectra of the magnetically ordered compound could be well described by four hyperfine‐split sextets, although no other foreign phases different from Fe1.05Te were detected by XRD and microanalysis within the sensitivity limits of the equipment. Density functional ab initio calculations have shown that over‐stoichiometric iron atoms significantly affect electron charge and spin density up to the second coordination sphere of the iron sub‐lattice, and, as a result, four non‐equivalent groups of iron atoms are formed by their local environment. The resulting four‐group model consistently describes the angular dependence of the single crystals Mössbauer spectra as well as intensity asymmetry of the doublet absorption lines in powdered samples at RT. We suppose that our approach could be extended to the entire class of FeSeTex compounds, which contain excess iron atoms.
A Weyl semimetal (WSM) features Weyl fermions in its bulk and topological surface states on surfaces, and is novel material hosting Weyl fermions, a kind of fundamental particles. The WSM was regarded as a three‐dimensional version of “graphene” under the illusion. In order to explore its promising photoelectric properties and applications in photonics and photoelectronics, here, we study the anisotropic linear and nonlinear optical responses of a WSM TaAs, which are determined by the relationship and balance between its topological surface states and Weyl nodes. We demonstrate that topological surface states which break the bulk symmetry are responsible for the anisotropy of the mobility, and the anisotropic nonlinear response shows saturable characteristic with extremely large saturable intensity. We also find that the mobility is anisotropic with the magnitude of 104 cm2V−1s−1 at room temperature and can be accelerated by the optical field. By analyzing the symmetry, the nonlinear response is mainly contributed by the fermions close to the Weyl nodes, and is related to the Pauli's blocking of fermions, electron‐electron interaction. This work experimentally discovers the anisotropic ultrahigh mobility of WSMs in the optical field and may start the field for the applications of WSMs in photonics and photoelectronics.
Recently a stable monolayer of antimony in buckled honeycomb structure called antimonene was successfully grown on 3D topological insulator Bi2Te3 and Sb2Te3, which displays novel semiconducting properties. By first‐principle calculations, we systematically investigate the electronic and optical properties of α‐ and β‐allotropes of monolayer arsenene/antimonene. The obtained electronic structures reveal that the direct band gap of α‐arsenene/antimonene is much smaller than the indirect band gap of their β‐counterpart, respectively. Significant absorption is observed in α‐antimonene, which can be used as a broad saturable absorber. For β‐arsenene/antimonene, the reflectivity is low and the absorption is negligible in the visible region when the polarization along the out‐plane direction, indicating that β‐arsenene/antimonene are polarizationally transparent materials.
We report on the transport properties of the super‐honeycomb lattice, the band structure of which possesses a flat band and Dirac cones, according to the tight‐binding approximation. The super‐honeycomb model combines the honeycomb lattice and the Lieb lattice and displays the properties of both. It also represents a hybrid fermionic and bosonic system, which is rarely seen in nature. By choosing the phases of input beams properly, the flat‐band mode of the super‐honeycomb lattice will be excited and the input beams will exhibit strong localization during propagation. On the other hand, if the modes of Dirac cones of the super‐honeycomb lattice are excited, one will observe conical diffraction. Furthermore, if the input beam is properly chosen to excite a sublattice of the super‐honeycomb lattice and the modes of Dirac cones with different pseudospins, e.g., by the three‐beam interference pattern, the pseudospin‐mediated vortices will be observed.
The threshold, temporal behavior, and conversion efficiency of stimulated Brillouin scattering (SBS) and stimulated Raman scattering (SBS) in three liquids (benzene, hexane, and dimethyl sulfoxide) and two crystals (calcite and barium nitrate) have been investigated under three largely different spectral linewidth conditions. Pumped with 532‐nm and nanosecond duration laser pulses of ≤ 0.01 cm?1 linewidth, only SBS can be generated in all tested liquids with a high nonlinear reflectivity. However when the pump spectral linewidth is ～0.07 cm?1 or ～0.8 cm?1, both SBS and SRS can be observed in benzene while only SRS can be generated in dimethyl sulfoxide; in all these cases SRS is the dominant contribution to the stimulated scattering but the efficiency values are drastically decreased due to the self‐termination behavior of SRS in liquids, which arises from the thermal self‐defocusing of both pump beam and SRS beam owing to Stokes‐shift related opto‐heating effect. In contrast, for SRS process in the two crystals, the thermal self‐defocusing influence is negligible benefitting from their much greater thermal conductivity, and a higher conversion efficiency of SRS generation can be retained under all three pump conditions.
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