Messungen des γi-Koeffizienten,der Zündspannung und des normalen Katodenfalls der Glimmentladung an gasbedeckten Mo- und Fe-Oberflächen in Edelgasen

Measurements of the γ_i-coefficient, the ignition voltage and the normal cathode fall of the glow discharge on gas-covered cathode surfaces for the combinations Mo—Ne⁺, Ar⁺, Kr⁺, Xe⁺ and Fe—Ne⁺ are described. H₂, N₂ and O₂ are used for covering the cathodes with a monomolecular adsorption layer. Measurements are carried out with a dynamic method according to VARNEY in the range 30 ? X/p₀ ? 400 V cm^?1 Torr^?1.     

A simple kinetic model of a Ne-H2 Penning-plasma laser

A simple kinetic model of the Ne-H₂ Penning-Plasma Laser (PPL) (NeI 585.3 nm) is proposed. The negative glow of a hollow cathode discharge at intermediate pressures is considered as the active medium. The balance equations for the upper and lower laser levels, electrons, ions and electron energy are solved. The dependences of the laser gain on the discharge conditions (Ne and H₂ partial pressures, discharge current) are calculated and measured. The calculated values are in a good agreement with the experimental data.     

Electron impact ionization and excitation rate coefficients in the negative glow region of a glow discharge

Some easy to use reasonable approximations for electron impact rate coefficients have been considered. The most important rate coefficients for electron collisions in noble gases are electron-neutral ionization and electron impact excitation. Electron-neutral ionization besides electron impact excitation of some states of the argon and helium atom in direct current (dc) glow discharge plasma has been calculated. The plasma parameters of electron are significant factors for computing the rate coefficients. We present first results of probe diagnostic that includes the double probe measurements of the plasma parameters, namely, electron temperature (T_e) and electron density (n_e). Electron properties obtained from the double probe characteristic curves including T_e and n_e as well as the calculated rate coefficients (ionization and excitation) were studied as a function of the axial distance from the cathode while the discharge operating parameters of voltage and pressure were varied. Two regions of the glow discharge were investigated: cathode fall region and negative glow. Particular emphasis was placed on the negative glow region.     

Density of fast electrons on the Axis of a Zylindrical Hollow-Cathode Discharge

Fast electrons leaving a hollow cathode discharge axially through the orifice of a hole probe undergo ionizing collisions with the discharge gas in and behind the orifice. Ar⁺⁺ ions produced in this way are used as a monitor for the density of fast electrons, N_ef, on the axis of the negative glow of a cylindrical hollow cathode discharge. Data on N_ef as dependent on the pressure of the Ar discharge gas and on the discharge current are obtained and an analytical expression for these dependences is found and discussed.     

Hollow Cathode Effect with Double Axial Electron Injection

The paper presents a new type of HCE glow discharge obtained with double plane-conical cathodes. The two identical cathodes are tronconical and screened with 1 mm² mailed wire net with a 3.5 mm diameter central washer each. The discharge is obtained between the two cathodes and a ring shaped anode equally distant from both. Optimum intercathodic span is 4 mm, allowing for maximum amplifications at the optimum pressure values for the two gases. Employed helium and argon are spectral pure. At the given distance and depending on voltage and gas pressure, a double axial electron self injection cathode effect is obtained between the electrodes, consisting of very large increase of current and radiations.     

Surface condition and electron emission from cold cathodes in vacuum and in noble gas glow discharge

An optogalvanic method is used to measure photoemission coefficient γ_ph in a gas discharge exposed to the resonant radiation of helium atoms. The range of working current j/P _He ² (j is the current density, and P _He is the gas pressure) extends from 2 to 1000 μA/(cm² Torr), and field strength E/N at the cathode varies from 0.45 to 13 kTd. Up to j/P _He ² = 10 μA/(cm²Torr²), photoemission coefficient γ_ph grows and then tends toward saturation at a level of γ_ph = 0.30 ± 0.01. Under the no-discharge conditions, γ_ph = 0.35 ± 0.05. It is concluded that the emissivity of cold cathodes in a gas discharge is governed by adsorption of the working gas on the cathode surface and its implantation into the cathode. With allowance for this factor, the contribution of photoemission to the discharge current is reconsidered. It is shown that, for cathodes with diameter d _c ? l _c (l _c is the length of the cathode layer), a normal or weakly abnormal glow discharge in noble gases is largely of a photoelectron character. In light noble gases, the photoelectron character of the discharge persists even for a strongly abnormal discharge. The energy dependences of coefficients γ of kinetic and potential emission in helium are calculated with allowance for implantation of helium atoms into the cathode and compared with published data. The influence of particle implantation on γ in a vacuum is estimated.     

Theoretical explanation of spin-Hamiltonian parameters for the rhombic Mo5+ octahedral clusters in molybdenum phosphate glasses

The high-order perturbation formulas based on the two-mechanism model are used to calculate the spin-Hamiltonian parameters (g factors g_i and hyperfine structure constants A_i, where i = x, y, z) of the rhombic Mo⁵⁺ oxygen octahedral clusters in molybdenum phosphate glasses. These formulas consist of the crystal-field mechanism in the extensively applied crystal-field theory and of the charge-transfer mechanism (which is often neglected). In the calculations, only three adjustable parameters are applied and the six calculated spin-Hamiltonian parameters are reasonably coincident with the experimental values. The results are discussed.     

Feldstärke,Stromdichten und mittlere Energien im Katodenfallraum von Glimmentladungen

By integration of energy distribution functions for the cathode fall of H₂ glow discharges we may show:

• 1) Space charge is almost constant within a large part of the dark space, therefore the field strength is a nearly linearly decreasing function of distance from cathode. Deviations from linearity are quantitatively discussed.
• 2) Composition of space charge: The contribution of atomic ions to the space charge may range from 5 to 10%. and the contribution of electrons from 0,1 to 10%, increasing with growing voltage.
• 3) Relative ion and neutral current densities at the cathode (ion current from the glow edge = 1) are decreasing with growing voltage. Molecular neutral current density equals 3 to 10 times molecular ion current density, in case of atomic particles the relation is from 1 to 5.
• 4) Total current density is increasing from 2.0 · 10^?4 A/cm² torr² at the voltage U₀ = 0,19 kV to 3,7 A/cm² torr² at U₀ = 10 kV; cathode field strength is increasing from 0,53 kV/cm torr to 97 kV/cm torr.
• 5) The mean energy of neutrals is smaller than the mean ion energy by a factor of about 0.45…0.85, and the mean energy of molecules is smaller than the energy of atoms by a about 0.2…0.8. The dependence of the mean energies from voltage is discussed.
• 6) The energy gain of electrons is growing from 15% of total dark space energy at 0.19 kV to 70% at 10 kV; the energy gain of neutrals is decreasing at the same time.

     

Theoretical and Experimental Investigation of Neon-Hydrogen Penning Recombination Laser

A theoretical and experimental study of Ne - H₂ Penning Recombination Laser operating on the Nel 585.3 nm line in the negative glow of a helical hollow cathode discharge is presented. A detailed kinetic model of the plasma-chemical reactions determining the inversion population on the Nel (2p₁-1s₂) transition is developed. The time dependent behaviour of the main plasma and laser parameters is numerically calculated. The behaviour of the plasma and laser parameters as a function of the discharge conditions is investigated and compared with the experimental results.     

Magnetic Control of Diffuse Discharges

By application of a crossed magnetic field, the electron energy distribution in a gas discharge can be shifted to lower energy values, as demonstrated by means of Monte Carlo calculations for electrons in He:SF6 mixtures. Consequently, through the change in the rate coefficients for ionization and attachment, the sustaining field in the discharge plasma is increased. This magnetically induced voltage rise was studied in a low-pressure glow discharge. The cathode fall was found to be the dominant component in determining the characteristics of this magnetically controlled discharge. The drastic rise of the cathode fall above a threshold value could be utilized in operating a glow discharge as an opening switch for an inductive energy storage system.     

Profile of spectral-line intensity along a negative glow

The longitudinal profile of the spectral-line intensity has been measured in a plasma of a negative glow in helium, neon, and mixtures of these gases. Under the conditions of a normal glow discharge, the intensities of several spectral lines fall off exponentially toward the anode. The decay of the line intensity was used to evaluate the effective cross section for attenuation of the electron beam from the cathode dark space. There is a discussion of the mechanism for the change in the profile of the line intensity in the discharge gap at the transition on a normal glow discharge to an anomalous discharge.     

Determination of the specific ion erosion of the vacuum arc cathode by measuring the total ion current from the discharge plasma

The specific ion erosion γ_i of cathodes made of C, Mg, Al, Ti, Co, Cu, Y, Mo, Cd, Sm, Ta, W, Pt, Pb, and Bi is determined by measuring the total ion current from the vacuum arc plasma. It is demonstrated that the ratio of the total ion current to the discharge current, α_i in a vacuum arc varies from 5 to 19%, depending on the cathode material. It is found experimentally that the ion current fraction α_i is inversely proportional to the atomic bond energy of the cathode material. It is shown that an increase in the total ion current extracted from the discharge plasma when applying an external magnetic field to the cathode region of the discharge is related solely to the appearance of ions with higher charge numbers in the plasma, while the magnitude of the specific ion erosion γ_i remains unchanged.     

Theory of a normal high-pressure glow discharge

In the present work, a theoretical model considering the processes of generation and losses of charged particles in the cathode region of a glow discharge in the drift approximation for ion and electron motion is developed. Exact analytical solutions, which can be used to calculate the current-voltage characteristics of the glow discharge in an arbitrary gas with the known Townsend ionization coefficient, are derived. The calculated parameters of the normal glow discharge (the current density, discharge burning voltage, and width of the space charge region) for different gases are in good agreement with the available experimental data. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 71–77, February, 2006.     

Messungen von Anregungstemperaturen in der Hochstromhohlkathode

Measurements of excitation temperatures in the negative glow light of a high-current hollow cathode discharge lamp with a gas temperature of about 1,500 °K have shown values forT _a of approximately 5,000 °K, when the atomic spectral lines are used as indicator. However, from ionic lines a temperature of 30,000–100,000 °K is deduced depending on the nature of the discharge gas. This big difference indicates that there is no Maxwell distribution in the hollow cathode discharge. A possible explanation could be that two energetically distinct types of electrons take part in ionisation and recombination respectively.     

On distribution over the cathode surface of the current due to positive ions in discharge with oscillating electrons

The mechanisms of processes determining distribution of positive ions on the cathode surface in a discharge with oscillating electrons are studied. At low pressures P≤5×10⁻⁵ torr over the entire range of anode length variation l _a=0.5–11 cm, the ion current distribution over the cathode radius J _i(r) features a single maximum in the center and drops steeply with distance from the axis. At pressures P=1–4×10⁻⁴ torr, the distribution J _i(r) for short anodes (l _a<6 cm) is similar to the previous one but, for long anodes (l _a=6–10 cm), new maxima at higher J _i values have been detected. A physical explanation for the obtained results is proposed.     

The effect of magnetic field on plasma particles in dusty plasma

In this work, we present the investigation of the formation features and internal structure of dust clouds created in plasma of glow discharge in the external magnetic field corresponding to a range of moderate and strong fields, at which the ion component is magnetized. The analysis of the plasma magnetization in the presence of dust components is carried out. We defined the values of magnetic induction at which the changes in dynamics of plasma particles in magnetic field in light inert gases are expected. The experimental setup was built in two versions. For the purpose of generating of magnetic field, the first setup was equipped with ordinary magnetic coils, and the second one included a superconducting solenoid. The discharge tubes, the main chambers where plasma was ignited and maintained in a glow discharge in lowered pressure, also have certain peculiarities, which we describe below. While using helium as a bulk gas, our study focused only on the dust trap in the region of narrowing discharge current. For neon, we used two traps: the striation trap and one just mentioned above placed in the narrowing of the discharge tube. As a result, the steady dust structures in a glow discharge under the magnetization of ions and electrons were obtained for the first time. Dust structures were rotated and tended to form a dust cluster and shell structure. A number of parameters of magnetization achieved in experiments were calculated.     

Two-point method for kinetic analysis of a thermoluminescence glow peak

We present a method for the estimation of defect (trap) physical parameters from thermoluminescence (TL) glow peaks. In this method, the order of kinetics b is determined using two values of TL intensity each of which corresponds to the same temperature (T ₁) on two separate glow peaks of a phosphor. The two glow peaks are obtained from two aliquots of the phosphor irradiated to same dose but read out at different heating rates. The proposed method requires a minimum of only two data points in contrast to standard peak shape (PS) methods that require three points corresponding to three different temperatures on the same glow peak. Once the order of kinetics b is determined, the activation energy E is calculated by taking a second point (T ₂) on any one of the two glow peaks. The values of b and E thus obtained are used to evaluate the frequency factor S ^′′ and the number of trapped electrons before the heating begins n _o. The validity of the method was checked using two numerically generated glow peaks. For the two cases, the method reproduced the input values reasonably well. The method was also used to analyse two experimental glow peaks. The results obtained provide a reasonably good fit to the experimental data. The kinetic parameters calculated using the present technique are comparable to those calculated using PS and initial rise methods. Initial guesses can easily be obtained for E and S ^′′ using the present technique when a glow curve is to be deconvoluted with a model consisting of many unknown parameters with E and S″ inclusive.     

介质阻挡均匀大气压辉光放电数值模拟研究

通过数值求解一维电子、离子连续性方程和动量方程，以及电流连续性方程，计算了氦气介 质阻挡大气压辉光放电电子、离子密度和电场在放电空间的时空分布，以及放电电流密度和 绝缘介质板充电电荷密度随时间的变化. 分析讨论所加电压频率、幅值及介质板性质等对均 匀大气压辉光放电性质的影响. 当外加电压频率足够高时，大量离子被俘获在放电空间，空 间电荷场又引起足够多的电子滞留在放电空间. 这些种子电子使得在大气压下发生汤森放电 ，放电空间结构类似于低气压辉光放电，即存在明显的阴极位降区、负辉区、法拉第暗区和 等离子体正柱 关键词： 大气压辉光放电 介质阻挡 数值模拟 等离子体