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1.
在铁掺杂的Tl-1223相中,铁对超导电性有明显的破坏作用,霍尔系数测量、热重分析和穆斯堡尔谱表明占据铜晶位的铁杂质原子不仅直接破坏CuO2面的完整性而使超导转变温度降低,更重要的是铁的掺入诱导了额外氧原子进入晶格,形成了对载流子的强局域束缚作用,致使载流子浓度随铁掺杂量呈线性下降.额外氧导致了与其近邻的铁和铜原子产生了偏离CuO2平面的位移,从而形成新的铁氧配位.针对额外氧缺陷精细结构的讨论,对研究额外氧和阳离子在CuO2平面上的无序排列  相似文献   

2.
本文报道通过对YBa2Cu1-xCox(Cu1-yZny)2Oz(0≤x,y≤0.1)体系晶体结构、氧含量、正常态电阻-温度关系、Hall效应以及超导临界温度等的综合测量,发现随着Co和Zn含量的增加,体系经历了从正交结构的超导金属向四方结构的非超导半导体的转变,超导临界温度Tc和载流子浓度nh均迅速下降,Co 关键词:  相似文献   

3.
In the system Bi-0212 the carrier concentration can be changed by both cation substitution and oxygen content. The crystal structure of Ca substituted material was refined from neutron powder diffraction data for Bi0.5Sr1.5Ca0.5Y0.5Cu1.5Fe0.5Oy. It is shown that extra oxygen is introduced in the cation layers between the double sheets of Cu/O pyramids. In superconducting material the familar dependence ofT c on the hole carrier concentration is observed. The higherT c is situated at 75 K.  相似文献   

4.
In the system Bi-0212 the carrier concentration can be changed by both cation substitution and oxygen content. The crystal structure of Ca substituted material was refined from neutron powder diffraction data for Bi0.5Sr1.5Ca0.5Y0.5Cu1.5Fe0.5Oy. It is shown that extra oxygen is introduced in the cation layers between the double sheets of Cu/O pyramids. In superconducting material the familar dependence ofT c on the hole carrier concentration is observed. The higherT c is situated at 75 K.  相似文献   

5.
Bond covalency and valence of elements in HgBa2Can−1CunO2n+2+δ (n=1, 2, 3, 4) were calculated and their relationship with Tc was discussed. For both oxygen and argon annealed samples, the results indicated that with the increase of n, the trend of bond covalency of Hg-O and Cu-O was the same or opposite compared with that of superconducting temperature. This may suggest that the magnitudes of Cu-O and Hg-O bond covalency are important in governing the superconducting temperature. For the highest Tc sample, Hg had the lowest valence, implying that lower valence of Hg was preferred in order to produce higher Tc. For fixed n, the valence of Cu in oxygen annealed samples was larger than that in argon annealed samples, indicating that oxygen annealed samples produced more carriers than argon annealed samples.  相似文献   

6.
对高品质单相多晶Bi2Sr2CaCu2O8+δ样品作真空或H2气氛中不同温度下的热处理。由X射线结构分析,其正常态和超导态性质(特别是载流子浓度)的系统测量结果表明:Bi2Sr2CaCu208+δ样品在H2气氛中热处理,其氧的释放可分为两个阶段:一是Bi-O层之间的过量氧原子的逸出,降低系统的载流子浓度,从而调节Tc;二是CuO2面内氧原子的迁移,产生氧空位,使CuO2面内Cu2+的短程二维反铁磁(2D-AFM)有序背景遭到破坏。可以认为:以往文献中报道的Bi2Sr2CaCu2O8+δ超导体的吸氢效应导致Tc的变化,很可能主要的并不是氢原子的电子掺杂行为,而是与吸氢过程中氧含量的变化相联系。 关键词:  相似文献   

7.
Electrical resistance measurements at low temperatures and high quasihydrostatic pressures on superconducting and non-superconducting varieties of Y0.8Ba1.2Cu2O5 (obtained by annealing in oxygen and air respectively) show striking anomalies in the vicinity of 100K and 40K. Arguments are presented to show that these anomalies as also the occurrence of T 's in the oxide superconductors either in the vicinity of 100K or of 40K are connected with their layered structure containing planes of Cu-O otahedral complexes.  相似文献   

8.
本文计算了高温超导材料YBa2Cu2ScO7的电子结构。对于Sc替代Cu1和Cu2晶位的两种情况都进行了研究。后者对Cu-O二维面的电子结构的影响较大,有可能破坏高温超导性。但计算表明,替代Cu1晶位的可能性要大一些。本文结果显示,Sc的成键分波轨道与其余四个3d轨道的交迭分裂约为4eV,据此可用近红外荧光实验判定在Sc-Y-Ba-Cu-O高温超导材料中,Sc究竟是替代Y晶位还是Cu晶位。 关键词:  相似文献   

9.
We have studied doping evolution of the temperature dependent local Cu-O displacements in the La2-x Sr x CuO4 superconductor by polarized Cu K-edge extended X-ray absorption fine structure (EXAFS) measurements. While temperature dependent Debye-Waller factor of the Cu-O bonds, measuring the local Cu-O displacements, shows an anomalous increase at low temperature for the underdoped single crystals, we do not find such a dependence for the case of the overdoped system. The results, which are discussed in the light of recent angle resolved photoemission measurements, provide an evidence for some important correlation between the doping dependent electron-lattice interaction, the charge inhomogeneities and the local Cu-O displacements in the copper oxide superconductors.Received: 9 July 2003, Published online: 19 November 2003PACS: 74.72.Dn La-based cuprates - 61.10.Ht X-ray absorption spectroscopy: EXAFS, NEXAFS, XANES, etc. - 74.81.-g Inhomogeneous superconductors and superconducting systems  相似文献   

10.
The energy distribution of particles ejected from single crystal surfaces has been calculated using classical dynamics. The model utilizes a microcrystallite of 4 layers with ~60 atoms/layer which is bombarded by 600 eV Ar+ at normal incidence. Calculations have been performed for the clean (100) face of copper as well as for copper with oxygen placed in various coverages and site geometries. The energy distributions for Cu, O, Cu2, CuO and Cu3 are reported for this system. The distribution for clean Cu exhibits structure which is shown to arise from preferred ejection mechanisms in the crystal. For oxygen adsorbates, the effect of the oxygen binding energy on the peak in the energy distribution of the ejected oxygen atoms is examined by arbitrarily varying the well-depth of the Cu-O pair potential. In general, higher values of the binding energy produce a maximum in the curve at higher energies and also produce a broader energy distribution. The O2 and Cu2 dimer distributions are found to peak at approximately the same energy as the O and Cu curves when compared on a kinetic energy/particle basis, although their widths are considerably smaller. Finally, we predict that the CuO energy distribution should be wider than either the Cu2 or O2 distributions since it results from the convolution of the Cu and O distributions which are quite different.  相似文献   

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