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1.
利用变温7LiNMR实验对Li电池正极材料LiMn2O4和LiCoO2中Li+的运动特性进行了研究,结果表明,随实验温度的提高,LiMn2O4的7LiNMR谱线窄化,表明其中Li+迁移能力增加,而LiCoO2的谱线无变化.此外随温度提高,LiMn2O4的7Li的T1变短,而LiCoO2的T1变长,产生这种不同变化趋势的原因在于LiMn2O4和LiCoO2晶相结构的差异造成其中Li+迁移能力的差别,它们各自的相关时间τc使7Li核的T1分别位于T1-τc曲线极小点两侧  相似文献   

2.
硼酸锂系列晶体的高压拉曼散射研究   总被引:1,自引:1,他引:0  
本文进行了硼酸锂系列晶体的高压拉曼散射及其压致相变的研究。对于三硼酸锂(LiB3O5),我们发现在5.0GPa有一可逆的晶态到晶态的相变,在27.0GPa有一不可逆的晶态到非晶态的相变。二硼酸锂(Li2B4O7)不可逆压致非晶相变发生在32.0GPa附近。对于一硼酸锂,我们研究了0—55.8GPa范围内的高压拉曼光谱,只在2.0GPa发现了一个晶态到晶态的相变,但未发现不可逆压致非晶化现象。在硼酸锂系列晶体中,不可逆压致非晶化的压力随Li2O的含量的增加而升高。硼酸锂晶体中Li2O的含量越高,压致非晶化越不容易发生,这与熔体急冷法制备硼酸锂玻璃的规律是一致的。  相似文献   

3.
本文主要介绍压致非晶化研究的进展,其中包括我们对β—BaB_2O_4,LiB_3O_5,Pb_5Ge_3O_11和Li_2Ge_7O_(15)的拉曼散射研究结果。综述了压致非晶的结构特征,压致非晶转变机制和重新晶化过程。  相似文献   

4.
高压拉曼散射研究表明.CuGeO3,Li2GeO3和Li6Ge2O7三种晶体分别在7,12和11GPa压力下转变为非晶。在高于起始转变压力以上一定范围压致非晶是可逆的,CuGeO3,Li2GeO3和Li6Ge2O7压致非晶的不可逆转变压力分别为14.1,20和20GPa。压致非晶CuGeO3的重新晶化温度在600℃附近。锗酸及系列晶体的压致非晶化与它们的成份和结构有关,随着在这一系列晶体中Li2O含量的增加,压致非晶化的压力趋于减小。  相似文献   

5.
新型蓝光衬底材料LiAlO2晶体的生长的缺陷分析   总被引:2,自引:2,他引:0  
徐科  邓佩珍 《光学学报》1998,18(3):81-384
LiAlO2和GaN的晶格失配率只有1.4%,是一种很有希望的GaN外延生长衬底材料。本文利用温度梯度法生长出透明的LiAlO2单晶,并通过化学浸蚀、光学显微镜、透射电子显微镜、同步辐射X射线貌相术对晶体中的缺陷进行了检测。结果表明:LiAlO2在钼坩埚中无籽晶自由凝固结日地,是沿(100)方向生长。用温度梯度法生长的AiAlO2晶体质量良好,晶体中无气泡和包裹物,在LiAlO2(100)方向晶面  相似文献   

6.
新型蓝光衬底材料LiAlO_2晶体的生长和缺陷分析   总被引:3,自引:0,他引:3  
LiAlO2和GaN的晶格失配率只有1.4%,是一种很有希望的GaN外延生长衬底材料。本文利用温度梯度法生长出了透明的LiAlO2单晶,并通过化学浸蚀、光学显微镜、透射电子显微镜、同步辐射X射线貌相术对晶体中的缺陷进行了检测。结果表明:LiAlO2在钼坩埚中无籽晶自由凝固结晶时,是沿(100)方向生长。用温度梯度法生长的LiAlO2晶体质量良好,晶体中无气泡和包裹物。在LiAlO2(100)晶面上测得的位错密度为(3.8~6.0)×104cm-2,晶体中的主要缺陷为亚晶界或镶嵌结构,可能是由于温场不稳定、生长速率太快造成的。  相似文献   

7.
NdvCa4GdO(BO3)3(简称NdvGdCOB)是一种新型自倍频晶体[1]。利用该晶体实现1060.0nm的自倍频绿光输出,因内外均已有报道[2]。我们利用Datachrom5000型染料激光器泵浦该晶体成功地实现了1331.0nm基频光和665.5nm自倍频红光的输出。NdvGdCOB属单斜双轴晶体,具有明显的偏振吸收特性。生长该晶体所用原料为Ca4Nd0.08Gd0.92O(BO3)3。晶体样品尺寸为3mm×3mm×8mm,通光方向为x(x轴与晶体的c轴的夹角为12°,z轴与a轴的夹…  相似文献   

8.
XRF光谱测定钨精矿WO3(%)简便方法   总被引:10,自引:0,他引:10  
本提出用PW1404型X-射线荧光光谱仪快速测定钨精矿WO3(%)主量成分。用Li2B2O7和Na2B2O7混合溶剂,把钨精矿粉样和纯WO3作高倍稀熔融制成玻璃片,按WLa分析线测定其强度值,并换算成相对强度 即得出WO3(%)《  相似文献   

9.
5.9GHz高温超导圆极化微带天线的研制   总被引:2,自引:0,他引:2  
本首次报道了用YBCO/LaAl03超导薄膜制成的频率为5.9GHz极化度为2.7dB的高温超导园极化微带天线,匹配电路和天线辐射器集成于同一块10×15mm^2的YBCO/LaA103片子上。在77K时与相同尺寸的圆极化银膜天线相比,超导天线传输系数增加5.5dB,辐射效率提高5.4dB,实验结果证实了用高温超材料制备圆极化微带天线的优越性。  相似文献   

10.
(GdO)3BO3:Eu^3+的合成及其荧光与结构的关系   总被引:2,自引:0,他引:2  
以Li2CO3为助熔剂合成了(GdO)3BO3纯物相,并利用多晶X射线衍射研究了(GdO)3BO3的结构,根据(GdO)3BO3所属空间群中等效点系的对称性及Eu^3+的荧光光谱,推断出Gd^3+在(GdO)3BO3中所处格位的点对称性为C1,C2或C3。  相似文献   

11.
胡伯清  李永津  周棠  张道范 《物理学报》1984,33(12):1707-1712
本文研究了2KIO3·HCI单晶的水溶液生长条件、结晶形态及其极性。就该晶体的透过率、光性方位及折射率等光学性质作了测量和讨论。观察到了YAG激光1.064μm位相匹配倍频现象。对该晶体的热电、压电、介电及电导等电学性质也作了测量。该晶体的各向异性现象很值得注意。 关键词:  相似文献   

12.
Efficient intracavity second-harmonic generation (SHG) has been realized in a new Li-doped GdCa4O(BO3)3 (GdCOB) crystal. 2.55 W CW SHG output power was obtained with an optical conversion efficiency of 19.6%, while the effective intracavity SHG efficiency was determined to be 44%. Compared to that of undoped GdCOB crystal, the effective SHG efficiency of the Li-doped GdCOB crystal was found to increase by 12.5%.  相似文献   

13.
准相位匹配PPLN倍频理论研究与优化设计   总被引:2,自引:0,他引:2       下载免费PDF全文
对准相位匹配周期性极化铌酸锂(PPLN)倍频进行了理论研究,并对聚焦高斯光束条件下的倍频耦合波方程进行了求解,给出了准相位匹配倍频转换效率公式,分析了晶体长度与聚焦程度的关系,在此基础上对倍频谐振腔进行了优化设计,以期获得最大的倍频转换效率.本结果对准相位匹配倍频器件的设计具有一定的指导意义. 关键词: 倍频 准相位匹配 周期性极化铌酸锂  相似文献   

14.
王业宁  朱劲松  谈云鹏 《物理学报》1980,29(12):1629-1635
本文研究用声光调Q-YAG激光器作为基波光源,测量了LiNbO3及BNN晶体中倍频光强-温度曲线。在生长层区,倍频曲线上往往出现双峰,同时有一一对应的NPM双光环出现。LiNbO3的双峰之一在极化处理后消失,本文对此峰的产生进行了分析。LiNbO3多畴层带区倍频光强比单畴区大10倍左右,实验表明此乃层带区180°畴的形成导致应力松弛的结果。 关键词:  相似文献   

15.
李如康  陈创天 《物理学报》1985,34(6):823-827
本文从“离子基团理论”出发,并考虑A位离子晶格电场对(B3O6)3-环的影响,采用CNDO/S近似计算了(B3O6)3-基团的分子轨道,进而求得低温相偏硼酸钡(β-BaB2O4)晶体的倍频系数。计算结果与实验值符合,由此进一步证实了这一论点:β-BaB2O4晶体的倍频系数主要来自(B关键词:  相似文献   

16.
Nd:Ca4YO(BO3)3 (Nd:YCOB) crystal was grown by the Czochralski method, and its structure was measured by using a four circle X-ray diffractometer. The transparent spectrum from 200 to 2600 nm was measured at room temperature. The fluorescence spectrum near 1.06 μm showed that the main emission wavelength of Nd:YCOB crystal was centered at 1060.8 nm. Laser output at 1.06 μm has been demonstrated when it was pumped by a Ti:sapphire laser at the wavelength of 794 nm, the highest output power was 68 mW under pumping power of 311 mW, the pumping threshold was 163 mW and slope efficiency was 46.9%. The self-frequency doubled green light has been observed when it was pumped by a Ti:sapphire or a laser diode (LD). A 14.5 mm Nd:YCOB crystal sample cut at (θ, φ)=(90°, 33°) was used for type I second-frequency generation (SHG) of the 1.06 μm laser pulse. The SHG conversion efficiency was 22%.  相似文献   

17.
Sodium p-nitrophenolate dihydrate (NPNa.2H2O) is a highly polarisable non linear optical material. It has a deff about 1.45 times than that of potassium titanyl phosphate. Single crystals of (NPNa.2H2O) have been grown successfully by slow solvent evaporation having water and methanol as solvent. The structure of the crystal is verified by single X-ray analysis. Optical absorption shows that the crystal is highly transparent between 1500 and 300 nm. Microhardness of the crystal is found to increases with increase in load and the hardness number is found to be high for methanol grown crystal as compared to the water grown crystal. Electrical conductivity as evaluated from the cole-cole plot is found to be 1.26 × 10−5 mho m−1. The dielectric constant of the crystal is low and independent at higher frequencies. The crystal has prominent photoconduction in the presence of trap energy levels formed by the Na+ ions. The SHG efficiency of the crystal is studied by performing Kurtz powder test and the results of scanning electron microscope analysis indicate that the major part of the crystal surface is free from inclusion and dislocation.  相似文献   

18.
Semiorganic nonlinear optical material of dichloro(beta-alanine)cadmium(II) (DCBAC) have been synthesized and single crystals were grown by solvent evaporation method at room temperature. The lattice parameters of the grown crystals are determined by single crystal XRD. The modes of vibration of different molecular groups present in the sample were identified by the FTIR spectral analysis. Thermal stability of the crystal was investigated using thermo gravimetric analysis (TGA) and differential thermal analysis (DTA). The dielectric constants of the crystal were studied as a function of frequency and the results are discussed. The grown crystals are subjected to microhardness studies and the variation of the microhardness with the applied load is studied. The optical transmission spectra and second harmonic generation (SHG) were investigated to study its linear and nonlinear optical properties. The nonlinear optical (NLO) property of the crystal was confirmed by powder second harmonic generation (SHG) test. SHG efficiency is comparable to that of KDP.  相似文献   

19.
An organic nonlinear optical single crystal of urea p-nitrophenol has been synthesized and grown by slow evaporation solution growth technique. The grown crystals were characterized by single crystal and powder X-ray diffraction analysis and it was found to be the structure of the crystal belongs to triclinic system. The various functional groups were identified by FT-IR and Raman spectral analysis. Thermal stability of the grown crystal was studied by TGA/DTA. The optical properties of the grown crystals were analyzed by UV–vis. The mechanical properties of the grown crystal were studied by Vickers microhardness measurements. Nonlinear optical property of the crystal was confirmed using the Kurtz and Perry powder technique and a study of its SHG efficiency in comparison with KDP has made.  相似文献   

20.
吴克琛  陈创天 《物理学报》1992,41(9):1436-1439
本文使用阴离子基团理论计算了Na2SbF5晶体的倍频系数,得到d123=4.48×10-10esu,与实验值符合较好。计算结果表明,阴离子基团中孤对电子的存在有利于产生大的倍频效应。本文还分析了Na2SbF5晶体倍频系数小的原因:尽管(SbF5)2-基团存在孤对电子可以对晶体倍频系数有较大贡献,但孤对电子能级的相对位置对其倍频系数有不利影响,从而导致它的倍频系数d123较小。 关键词:  相似文献   

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