共查询到20条相似文献,搜索用时 93 毫秒
1.
利用变温7LiNMR实验对Li电池正极材料LiMn2O4和LiCoO2中Li+的运动特性进行了研究,结果表明,随实验温度的提高,LiMn2O4的7LiNMR谱线窄化,表明其中Li+迁移能力增加,而LiCoO2的谱线无变化.此外随温度提高,LiMn2O4的7Li的T1变短,而LiCoO2的T1变长,产生这种不同变化趋势的原因在于LiMn2O4和LiCoO2晶相结构的差异造成其中Li+迁移能力的差别,它们各自的相关时间τc使7Li核的T1分别位于T1-τc曲线极小点两侧 相似文献
2.
硼酸锂系列晶体的高压拉曼散射研究 总被引:1,自引:1,他引:0
本文进行了硼酸锂系列晶体的高压拉曼散射及其压致相变的研究。对于三硼酸锂(LiB3O5),我们发现在5.0GPa有一可逆的晶态到晶态的相变,在27.0GPa有一不可逆的晶态到非晶态的相变。二硼酸锂(Li2B4O7)不可逆压致非晶相变发生在32.0GPa附近。对于一硼酸锂,我们研究了0—55.8GPa范围内的高压拉曼光谱,只在2.0GPa发现了一个晶态到晶态的相变,但未发现不可逆压致非晶化现象。在硼酸锂系列晶体中,不可逆压致非晶化的压力随Li2O的含量的增加而升高。硼酸锂晶体中Li2O的含量越高,压致非晶化越不容易发生,这与熔体急冷法制备硼酸锂玻璃的规律是一致的。 相似文献
3.
本文主要介绍压致非晶化研究的进展,其中包括我们对β—BaB_2O_4,LiB_3O_5,Pb_5Ge_3O_11和Li_2Ge_7O_(15)的拉曼散射研究结果。综述了压致非晶的结构特征,压致非晶转变机制和重新晶化过程。 相似文献
4.
高压拉曼散射研究表明.CuGeO3,Li2GeO3和Li6Ge2O7三种晶体分别在7,12和11GPa压力下转变为非晶。在高于起始转变压力以上一定范围压致非晶是可逆的,CuGeO3,Li2GeO3和Li6Ge2O7压致非晶的不可逆转变压力分别为14.1,20和20GPa。压致非晶CuGeO3的重新晶化温度在600℃附近。锗酸及系列晶体的压致非晶化与它们的成份和结构有关,随着在这一系列晶体中Li2O含量的增加,压致非晶化的压力趋于减小。 相似文献
5.
新型蓝光衬底材料LiAlO2晶体的生长的缺陷分析 总被引:2,自引:2,他引:0
LiAlO2和GaN的晶格失配率只有1.4%,是一种很有希望的GaN外延生长衬底材料。本文利用温度梯度法生长出透明的LiAlO2单晶,并通过化学浸蚀、光学显微镜、透射电子显微镜、同步辐射X射线貌相术对晶体中的缺陷进行了检测。结果表明:LiAlO2在钼坩埚中无籽晶自由凝固结日地,是沿(100)方向生长。用温度梯度法生长的AiAlO2晶体质量良好,晶体中无气泡和包裹物,在LiAlO2(100)方向晶面 相似文献
6.
新型蓝光衬底材料LiAlO_2晶体的生长和缺陷分析 总被引:3,自引:0,他引:3
LiAlO2和GaN的晶格失配率只有1.4%,是一种很有希望的GaN外延生长衬底材料。本文利用温度梯度法生长出了透明的LiAlO2单晶,并通过化学浸蚀、光学显微镜、透射电子显微镜、同步辐射X射线貌相术对晶体中的缺陷进行了检测。结果表明:LiAlO2在钼坩埚中无籽晶自由凝固结晶时,是沿(100)方向生长。用温度梯度法生长的LiAlO2晶体质量良好,晶体中无气泡和包裹物。在LiAlO2(100)晶面上测得的位错密度为(3.8~6.0)×104cm-2,晶体中的主要缺陷为亚晶界或镶嵌结构,可能是由于温场不稳定、生长速率太快造成的。 相似文献
7.
NdvCa4GdO(BO3)3(简称NdvGdCOB)是一种新型自倍频晶体[1]。利用该晶体实现1060.0nm的自倍频绿光输出,因内外均已有报道[2]。我们利用Datachrom5000型染料激光器泵浦该晶体成功地实现了1331.0nm基频光和665.5nm自倍频红光的输出。NdvGdCOB属单斜双轴晶体,具有明显的偏振吸收特性。生长该晶体所用原料为Ca4Nd0.08Gd0.92O(BO3)3。晶体样品尺寸为3mm×3mm×8mm,通光方向为x(x轴与晶体的c轴的夹角为12°,z轴与a轴的夹… 相似文献
8.
XRF光谱测定钨精矿WO3(%)简便方法 总被引:10,自引:0,他引:10
本提出用PW1404型X-射线荧光光谱仪快速测定钨精矿WO3(%)主量成分。用Li2B2O7和Na2B2O7混合溶剂,把钨精矿粉样和纯WO3作高倍稀熔融制成玻璃片,按WLa分析线测定其强度值,并换算成相对强度 即得出WO3(%)《 相似文献
9.
5.9GHz高温超导圆极化微带天线的研制 总被引:2,自引:0,他引:2
本首次报道了用YBCO/LaAl03超导薄膜制成的频率为5.9GHz极化度为2.7dB的高温超导园极化微带天线,匹配电路和天线辐射器集成于同一块10×15mm^2的YBCO/LaA103片子上。在77K时与相同尺寸的圆极化银膜天线相比,超导天线传输系数增加5.5dB,辐射效率提高5.4dB,实验结果证实了用高温超材料制备圆极化微带天线的优越性。 相似文献
10.
(GdO)3BO3:Eu^3+的合成及其荧光与结构的关系 总被引:2,自引:0,他引:2
以Li2CO3为助熔剂合成了(GdO)3BO3纯物相,并利用多晶X射线衍射研究了(GdO)3BO3的结构,根据(GdO)3BO3所属空间群中等效点系的对称性及Eu^3+的荧光光谱,推断出Gd^3+在(GdO)3BO3中所处格位的点对称性为C1,C2或C3。 相似文献
11.
12.
Junhai Liu Zhenyi Fei Shujun Zhang Chenlin Du Jiyang Wang Huanchu Chen Zongshu Shao 《Optics & Laser Technology》2001,33(8):597-600
Efficient intracavity second-harmonic generation (SHG) has been realized in a new Li-doped GdCa4O(BO3)3 (GdCOB) crystal. 2.55 W CW SHG output power was obtained with an optical conversion efficiency of 19.6%, while the effective intracavity SHG efficiency was determined to be 44%. Compared to that of undoped GdCOB crystal, the effective SHG efficiency of the Li-doped GdCOB crystal was found to increase by 12.5%. 相似文献
13.
14.
15.
16.
H. J. Zhang X. L. Meng L. Zhu C. Q. Wang R. P. Cheng W. T. Yu S. J. Zhang L. K. Sun Y. T. Chow W. L. Zhang H. Wang K. S. Wong 《Optics Communications》1999,160(4-6):273-276
Nd:Ca4YO(BO3)3 (Nd:YCOB) crystal was grown by the Czochralski method, and its structure was measured by using a four circle X-ray diffractometer. The transparent spectrum from 200 to 2600 nm was measured at room temperature. The fluorescence spectrum near 1.06 μm showed that the main emission wavelength of Nd:YCOB crystal was centered at 1060.8 nm. Laser output at 1.06 μm has been demonstrated when it was pumped by a Ti:sapphire laser at the wavelength of 794 nm, the highest output power was 68 mW under pumping power of 311 mW, the pumping threshold was 163 mW and slope efficiency was 46.9%. The self-frequency doubled green light has been observed when it was pumped by a Ti:sapphire or a laser diode (LD). A 14.5 mm Nd:YCOB crystal sample cut at (θ, φ)=(90°, 33°) was used for type I second-frequency generation (SHG) of the 1.06 μm laser pulse. The SHG conversion efficiency was 22%. 相似文献
17.
B. Milton Boaz R. Samuel Selvaraj K. Senthil Kumar S. Jerome Das 《Indian Journal of Physics》2009,83(12):1647-1657
Sodium p-nitrophenolate dihydrate (NPNa.2H2O) is a highly polarisable non linear optical material. It has a deff about 1.45 times than that of potassium titanyl phosphate. Single crystals of (NPNa.2H2O) have been grown successfully by slow solvent evaporation having water and methanol as solvent. The structure of the crystal
is verified by single X-ray analysis. Optical absorption shows that the crystal is highly transparent between 1500 and 300
nm. Microhardness of the crystal is found to increases with increase in load and the hardness number is found to be high for
methanol grown crystal as compared to the water grown crystal. Electrical conductivity as evaluated from the cole-cole plot
is found to be 1.26 × 10−5 mho m−1. The dielectric constant of the crystal is low and independent at higher frequencies. The crystal has prominent photoconduction
in the presence of trap energy levels formed by the Na+ ions. The SHG efficiency of the crystal is studied by performing Kurtz powder test and the results of scanning electron microscope
analysis indicate that the major part of the crystal surface is free from inclusion and dislocation. 相似文献
18.
Semiorganic nonlinear optical material of dichloro(beta-alanine)cadmium(II) (DCBAC) have been synthesized and single crystals were grown by solvent evaporation method at room temperature. The lattice parameters of the grown crystals are determined by single crystal XRD. The modes of vibration of different molecular groups present in the sample were identified by the FTIR spectral analysis. Thermal stability of the crystal was investigated using thermo gravimetric analysis (TGA) and differential thermal analysis (DTA). The dielectric constants of the crystal were studied as a function of frequency and the results are discussed. The grown crystals are subjected to microhardness studies and the variation of the microhardness with the applied load is studied. The optical transmission spectra and second harmonic generation (SHG) were investigated to study its linear and nonlinear optical properties. The nonlinear optical (NLO) property of the crystal was confirmed by powder second harmonic generation (SHG) test. SHG efficiency is comparable to that of KDP. 相似文献
19.
An organic nonlinear optical single crystal of urea p-nitrophenol has been synthesized and grown by slow evaporation solution growth technique. The grown crystals were characterized by single crystal and powder X-ray diffraction analysis and it was found to be the structure of the crystal belongs to triclinic system. The various functional groups were identified by FT-IR and Raman spectral analysis. Thermal stability of the grown crystal was studied by TGA/DTA. The optical properties of the grown crystals were analyzed by UV–vis. The mechanical properties of the grown crystal were studied by Vickers microhardness measurements. Nonlinear optical property of the crystal was confirmed using the Kurtz and Perry powder technique and a study of its SHG efficiency in comparison with KDP has made. 相似文献