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1.
We have measured the resistivities of Al2O3-Bi2Sr1.8Ca1.2Cu2Oy and MgO-Bi2Sr1.8Ca1.2Cu2Oy composites with the nominal Bi2Sr1.8Ca1.2Cu2Oy volume fraction, 2212, ranging from 0.15 to 1.00. For the Al2O3-Bi2Sr1.8Ca1.2Cu 2Oy composites, we find for the samples with 2212≥0.6 that the superconducting transition temperature, Tc, is not disturbed by the addition of Al2O3. For 2212<0.3, no zero-resistivity state is observed. For the MgO-Bi2Sr1.8Ca1.2Cu2Oy composites, Tc is barely disturbed for the samples with ρ2212≥0.7. No superconducting state is observed for the samples with ρ2212<0.35. The variation of (300 K) with ρ2212 indicates a three-dimensional percolating Bi-Sr-Ca-Cu-O matrix occurring at ρ2212≈0.19 and ≈0.15 in Al2O3-Bi2Sr1.8Ca1.2 Cu2Oy and MgO-Bi2Sr1.8Ca1.2Cu2Oy, respectively. Both resistivity and magnetization measurements suggest that the reactions of Bi2Sr1.8Ca1.2Cu2Oy with MgO are weaker than with Al2O3.  相似文献   

2.
We have investigated the effect of Hg addition on the superconducting properties of BiSrCaCuO system. Polycrystalline samples with nominal composition Bi2Sr2−xHgxCa1Cu2Oy and Bi2Sr2−xHgxCa2Cu3Oy (x=0.3) were synthesized and used to investigate the phase evolution by XRD, superconducting behaviour by RT measurement and the structural grain boundary effects by SEM. From these measurements, it has been noticed that the phases obtained with both types of compositions are the same as Bi2212 but the Tc values are different. With additional annealing, Tc zero values were raised from 60 to 72 K in Bi2Sr2−xHgxCa1Cu2Oy and 64 to 92 K in Bi2Sr2−xHgxCa2Cu3Oy. Also, an improved grain boundary linkage has been observed by SEM for the 92 K sample.  相似文献   

3.
We have studied the stationary Josephson effect on YBa2Cu3O7−δ (Tc=90 K) and Bi2Sr2Ca1Cu2 O8 (Tc=80 K and 87 K for two samples of different origin) ceramic based junctions. The temperature dependence of the critical current near Tc has been found as Ic≈(Tc-T) for the Y-Ba-Cu-O samples indicating that they should be classified as S-N-I-N-S type junctions. The I-V curves of the Bi-Sr-Ca-Cu samples show the typical behaviour of S-I-S structures. Using Ambegaokar-Baratoff's theory for Bi2Sr2Ca1Cu2O8, the temperature dependence of the superconducting state gap Δ(T) was calculated and it was evaluated that 1.452Δ(0)/kBTc3.5.  相似文献   

4.
Superconductivity and composition analysis of PbBaSr(Y, Ca)Cu3Oy with fixed ratio of Sr/Ba = 1 were studied. Synthesis condition and superconductivity of Pb(Ba, Sr)2(Y, Ca)Cu3Oy with various ratio of Sr/Ba and Ca/Y were also studied. It was found that Tc increased with increasing Ca concentration, and that Sr-rich specimens allowed to contain more Ca. PbBa0.8Sr1.2Y0.6Ca0.4Cu3O7 showed superconductivity with zero-resistance temperature of 42 K, which was higher than PbBaSrY0.7Ca0.3Cu3O7 with maximum Ca content for Sr/Ba = 1. Decrease in averaged ionic radii of Ba and Sr in Sr-rich compositions would be favorable for the contraction of Cu-O bonds by hole-doping via Ca substitution for Y.  相似文献   

5.
Samples of Bi2Sr2Ca1−xPrxCu2Oy have been characterized by resistivity and thermoelectric power measurements. All metallic samples show superconductivity with a maximum Tc = 90 K at X = 0.2. The sample of x = 0.6 shows a crossover from hopping conduction at low temperature above Tc to metallic conduction at high temperature. For the metallic samples below x = 0.6, the results of thermoelectric power are well fitted by both of a phenomenological band spectrum model and the Nagaosa and Lee model.  相似文献   

6.
Magnetic susceptibility, X-ray diffraction and resistivity measurements of the system Bi1.4Pb0.6Sr2Ca2−xGaxCu3Oy are reported for 0 x 2. The high-Tc 2223 phase with a Tc of 107 K for x = 0 exists for x 0.3. The low-Tc 2212 phase with a Tc of 75 K for x = 0 exists for the full range of x. The highest values of the critical temperature and the largest volume fraction of the low-Tc phase in compounds with Ga occur for x = 0.5 ± 0.1. The identification of CaO by X-ray diffraction for x 0.6 indicates that Ga replaces Ca in the compound.  相似文献   

7.
Oxy-anion (PO43−) substituted phases of the composition REBaSrCu2.8(PO4)0.2Oy have been synthesized. Single phase formation is achieved only for the larger rare earths (La → Ho and Y) and all the phases crystallize in the tetragonal 123 structure. IR studies confirm the presence of a phosphate group in the structure. The total oxygen content (including that associated with the oxy-anion PO43−) has been found to be in the range 7.01 to 7.10 per formula unit. Except for RE = La, Nd, Yb and Lu, all the phases exhibit superconductivity and the Tc,zero values vary from 18 to 38 K. The Tc,zero increases with decreasing size of RE3+. ErBaSrCu3O7 is multiphasic and single phase formation is achieved for the first time by phosphate substitution at the copper site. Single phase formation is encountered for x = 0.10 and 0.15 with Tc,zero values of 54 and 37 K respectively.  相似文献   

8.
New Pb based layered superconducting cuprates (Pb0.5Cd0.5)(Sr0.9R0.1)2(R′0.7Ce0.3)2Cu2Oy with (R,R′) = (Eu,Gd), (Eu,Dy) and (Nd,Gd), have been successfully synthesized. The structure of (Pb,Cd)(Sr,Eu)2(Gd,Ce)2Cu2Oy is determined using XRD data. The X-ray powder diffraction pattern can be indexed by the tetragonal structure with lattice parameters a = 3.8250 Å, C = 29.2235 Å and a space group of I4/mmm. The effects of synthesis conditions on (Pb,Cd)(Sr,Eu)2(Gd,Ce)2Cu2Oy are studied and a Tc(onset) of 26 K is obtained by resistance measurements. It is isostructural to the superconductor (Pb,Cu)(Sr,Eu)2(Eu,Ce)2Cu2Oy.  相似文献   

9.
The temperature dependence of the extended X-ray absorption fine structure (EXAFS) is studied in the high Tc superconductors, YBa2Cu3O7−δ. The measurements were done at the Cu K-edge for samples of two orthorhombic phases (Tc≈90 K and ≈58 K, respectively) and a nonsuperconducting tetragonal phase. Interatomic distances and mean square relative displacements σ2 for Cu-O bonds are determined by the least squares refinement. The results indicate that values of σ2 increase near Tc for both the orthorhombic samples. It is concluded that this anomalous behavior related to Tc is caused by an anomalous vibration of oxygen atoms in the Ba-O layer. Changes in the Cu-O distances from 300 to 20 K are not found.  相似文献   

10.
The dependence of Tc on oxygen content was determined for (Nd0.67Ce0.33)2(Ba0.67Nd0.33)2Cu3.01Oy. It was found that superconduction appears in a range of y=9.10−9.16 and that Tc is enhanced remarkably by the increase of oxygen content. In an oxygen content range where superconduction appeared, the Ce valence was nearly +4 and the Cu valence changed from 2.31 to 2.33. The conductivity was measured in a wide temperature range between Tc and 1200 K as a function of oxygen partial pressure. The high-temperature conductivity increased with increasing oxygen content. It was found that both carrier concentration and mobility are increased with oxygen content. The conduction at low temperatures was semiconductor-like, and increased with increasing oxygen content, where the energy gap EA-EV between acceptor level and top of filled band approached zero.  相似文献   

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