Singular Perturbations of Self-Adjoint Operators

Singular finite rank perturbations of an unbounded self-adjoint operator A ₀ in a Hilbert space ₀ are defined formally as A ₍₎=A ₀+GG ^*, where G is an injective linear mapping from = ^d to the scale space _-k(A₀)k , kN, of generalized elements associated with the self-adjoint operator A ₀, and where is a self-adjoint operator in . The cases k=1 and k=2 have been studied extensively in the literature with applications to problems involving point interactions or zero range potentials. The scalar case with k=2n>1 has been considered recently by various authors from a mathematical point of view. In this paper, singular finite rank perturbations A ₍₎ in the general setting ran G – _k (A ₀), kN, are studied by means of a recent operator model induced by a class of matrix polynomials. As an application, singular perturbations of the Dirac operator are considered.     

Absolute Continuity of Vitali–Hahn–Saks Measure Convergence Theorems

In this paper, we prove the following improved Vitali–Hahn–Saks measure convergence theorem: Let (L, 0, 1) be a Boolean algebra with the sequential completeness property, (G, ) be an Abelian topological group, be a nonnegative finitely additive measure defined on L, {_n: n N} be a sequence of finitely additive s-bounded G-valued measures defined on L, too. If for each a L, {_n(a)}_{n N} is a -convergent sequence, for each nN, when { (a)} convergent to 0, {_n(a)} is -convergent, then when { (a)} convergent to 0, {_n(a)} are -convergent uniformly with respect to nN     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

An investigation of finite-size scaling for systems with long-range interaction: The spherical model

A method is suggested for the derivation of finite-size corrections in the thermodynamic functions of systems with pair interaction potential decaying at large distancesr asr ^{–d –} , whered is the space dimensionality and>0. It allows for a unified treatment of short-range (=2) and long-range (<2) interaction. The asymptotic analysis is illustrated by the mean spherical model of general geometryL ^d–d× ^d subject to periodic boundary conditions. The Fisher-Privman equation of state is generalized to arbitrary real values ofd, 0d. It is shown that the-expansion may be used to study the breakdown of standard finite-size scaling at the borderline dimensionalities.     

The twisted SU(3) group. Irreducible *-representations of the C *-algebra C(SμU(3))

Irreducible ^*-representations of C(SU(3)) are constructed for ]0, 1[. It is proved that C(SU(3)) is a type-I C ^*-algebra.     

The phase transition in a general class of Ising-type models is sharp

For a family of translation-invariant, ferromagnetic, one-component spin systems—which includes Ising and ⁴ models—we prove that (i) the phase transition is sharp in the sense that at zero magnetic field the high- and low-temperature phases extend up to a common critical point, and (ii) the critical exponent obeys the mean field bound 1/2. The present derivation of these nonperturbative statements is not restricted to regular systems, and is based on a new differential inequality whose Ising model version isMh+M ³+ M ²M/. The significance of the inequality was recognized in a recent work on related problems for percolation models, while the inequality itself is related to previous results, by a number of authors, on ferromagnetic and percolation models.     

Differential calculus on quantum spheres

Three-dimensional differential calculus on quantum spheres S _infc ^sup2 ,]–1, 1[{0}, c[0, ], is introduced and investigated. Spectra of generalized Laplacians are found. These operators are expressed by generalized directional derivatives. Classical limits of these objects are obtained and a simple approach to quantum mechanics on a quantum sphere is presented.     

Solutions of the braid equation related to a Hopf algebra

Two solutionsT andT of the braid equation acting onA A (whereA is a Hopf algebra) are described. IfA is a cocommutative, thenT=. IfA is commutative, thenT= ( denotes the flip: (a b) =b a for anya,b A).Supported by a grant of the Ministry of Education of Poland.     

Photophysical Behavior of β-Carboline-3-Carboxylic Acid N-Methylamide

The solvent and temperature effect of fluorescence and phosphorescence and its polarization characteristics for -carboline-3-carboxylic acid N-methylamide were studied. From the results obtained it is concluded that the first excited singlet state changes from the * type in a polar solvent (EPA) to the n* type in a nonpolar solvent (MC) and that the lowest singlet excited states (* type and n* type) interact by vibronic coupling. In the nonpolar solvent (MC) the lowest singlet excited states are very close in energy and consequently the vibronic coupling is stronger. It has been found that the 0–0 band of the phosphorescence emission in EPA is polarized out of plane, using the excitations corresponding to absorptions into the first and second excited * singlet states. This fact and the order of lifetime measured indicate an emitting triplet that is *. The origin of this polarization is very likely mixing as a result of spin–orbit coupling. However, the vibrational structures and changing polarization outside the 0–0 band indicate that second-order effects involving spin–orbit coupling and vibronic interactions are important and the mixing scheme appears to be and . The proximity effect can qualitatively explain the absence of phosphorescence and the stronger vibronic interaction between the n* and the * states of -carboline-3-carboxylic acid .N-methylamide in a hydrocarbon solvent (MC).     

Existence of a Constant for Finite System Extinction

We show the existence of a constant (0, ) such that if ⁿ is the extinction time for a supercritical contact process on [1, n] ^d starting from full occupancy, then {log(E[ ⁿ])}/n ^d tend to as n tends to infinity.