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1.
The fuzzy-entropy-based complexity metric approach has achieved fruitful results in bearing fault diagnosis. However, traditional hierarchical fuzzy entropy (HFE) and multiscale fuzzy entropy (MFE) only excavate bearing fault information on different levels or scales, but do not consider bearing fault information on both multiple layers and multiple scales at the same time, thus easily resulting in incomplete fault information extraction and low-rise identification accuracy. Besides, the key parameters of most existing entropy-based complexity metric methods are selected based on specialist experience, which indicates that they lack self-adaptation. To address these problems, this paper proposes a new intelligent bearing fault diagnosis method based on self-adaptive hierarchical multiscale fuzzy entropy. On the one hand, by integrating the merits of HFE and MFE, a novel complexity metric method, named hierarchical multiscale fuzzy entropy (HMFE), is presented to extract a multidimensional feature matrix of the original bearing vibration signal, where the important parameters of HMFE are automatically determined by using the bird swarm algorithm (BSA). On the other hand, a nonlinear feature matrix classifier with strong robustness, known as support matrix machine (SMM), is introduced for learning the discriminant fault information directly from the extracted multidimensional feature matrix and automatically identifying different bearing health conditions. Two experimental results on bearing fault diagnosis show that the proposed method can obtain average identification accuracies of 99.92% and 99.83%, respectively, which are higher those of several representative entropies reported by this paper. Moreover, in the two experiments, the standard deviations of identification accuracy of the proposed method were, respectively, 0.1687 and 0.2705, which are also greater than those of the comparison methods mentioned in this paper. The effectiveness and superiority of the proposed method are verified by the experimental results.  相似文献   

2.
The thermodynamic properties of hydrophobic hydration processes can be represented in probability space by a Dual-Structure Partition Function {DS-PF} = {M-PF} · {T-PF}, which is the product of a Motive Partition Function {M-PF} multiplied by a Thermal Partition Function {T-PF}. By development of {DS-PF}, parabolic binding potential functions α) RlnKdual = (−Δdual/T) ={f(1/T)*g(T)} and β) RTlnKdual = (−Δdual) = {f(T)*g(lnT)} have been calculated. The resulting binding functions are “convoluted” functions dependent on the reciprocal interactions between the primary function f(1/T) or f(T) with the secondary function g(T) or g(lnT), respectively. The binding potential functions carry the essential thermodynamic information elements of each system. The analysis of the binding potential functions experimentally determined at different temperatures by means of the Thermal Equivalent Dilution (TED) principle has made possible the evaluation, for each compound, of the pseudo-stoichiometric coefficient ±ξw, from the curvature of the binding potential functions. The positive value indicates convex binding functions (Class A), whereas the negative value indicates concave binding function (Class B). All the information elements concern sets of compounds that are very different from one set to another, in molecular dimension, in chemical function, and in aggregation state. Notwithstanding the differences between, surprising equal unitary values of niche (cavity) formation in Class A <Δhfor>A = −22.7 ± 0.7 kJ·mol−1 ·ξw−1 sets with standard deviation σ = ±3.1% and <Δsfor>A = −445 ± 3J·K−1·mol−1·ξw−1J·K−1·mol−1·ξw−1 with standard deviation σ = ±0.7%. Other surprising similarities have been found, demonstrating that all the data analyzed belong to the same normal statistical population. The Ergodic Algorithmic Model (EAM) has been applied to the analysis of important classes of reactions, such as thermal and chemical denaturation, denaturation of proteins, iceberg formation or reduction, hydrophobic bonding, and null thermal free energy. The statistical analysis of errors has shown that EAM has a general validity, well beyond the limits of our experiments. Specifically, the properties of hydrophobic hydration processes as biphasic systems generating convoluted binding potential functions, with water as the implicit solvent, hold for all biochemical and biological solutions, on the ground that they also are necessarily diluted solutions, statistically validated.  相似文献   

3.
Acquiring knowledge about users’ opinion and what they say regarding specific features within an app, constitutes a solid steppingstone for understanding their needs and concerns. App review utilization helps project management teams to identify threads and opportunities for app software maintenance, optimization and strategic marketing purposes. Nevertheless, app user review classification for identifying valuable gems of information for app software improvement, is a complex and multidimensional issue. It requires foresight and multiple combinations of sophisticated text pre-processing, feature extraction and machine learning methods to efficiently classify app reviews into specific topics. Against this backdrop, we propose a novel feature engineering classification schema that is capable to identify more efficiently and earlier terms-words within reviews that could be classified into specific topics. For this reason, we present a novel feature extraction method, the DEVMAX.DF combined with different machine learning algorithms to propose a solution in app review classification problems. One step further, a simulation of a real case scenario takes place to validate the effectiveness of the proposed classification schema into different apps. After multiple experiments, results indicate that the proposed schema outperforms other term extraction methods such as TF.IDF and χ2 to classify app reviews into topics. To this end, the paper contributes to the knowledge expansion of research and practitioners with the purpose to reinforce their decision-making process within the realm of app reviews utilization.  相似文献   

4.
Despite the remarkable success of Carnot’s heat engine cycle in founding the discipline of thermodynamics two centuries ago, false viewpoints of his use of the caloric theory in the cycle linger, limiting his legacy. An action revision of the Carnot cycle can correct this, showing that the heat flow powering external mechanical work is compensated internally with configurational changes in the thermodynamic or Gibbs potential of the working fluid, differing in each stage of the cycle quantified by Carnot as caloric. Action (@) is a property of state having the same physical dimensions as angular momentum (mrv = mr2ω). However, this property is scalar rather than vectorial, including a dimensionless phase angle (@ = mr2ωδφ). We have recently confirmed with atmospheric gases that their entropy is a logarithmic function of the relative vibrational, rotational, and translational action ratios with Planck’s quantum of action ħ. The Carnot principle shows that the maximum rate of work (puissance motrice) possible from the reversible cycle is controlled by the difference in temperature of the hot source and the cold sink: the colder the better. This temperature difference between the source and the sink also controls the isothermal variations of the Gibbs potential of the working fluid, which Carnot identified as reversible temperature-dependent but unequal caloric exchanges. Importantly, the engine’s inertia ensures that heat from work performed adiabatically in the expansion phase is all restored to the working fluid during the adiabatic recompression, less the net work performed. This allows both the energy and the thermodynamic potential to return to the same values at the beginning of each cycle, which is a point strongly emphasized by Carnot. Our action revision equates Carnot’s calorique, or the non-sensible heat later described by Clausius as ‘work-heat’, exclusively to negative Gibbs energy (−G) or quantum field energy. This action field complements the sensible energy or vis-viva heat as molecular kinetic motion, and its recognition should have significance for designing more efficient heat engines or better understanding of the heat engine powering the Earth’s climates.  相似文献   

5.
The aim of this study was to analyze the effects of match location, quality of opposition and match outcome on match running performance according to playing position in a Portuguese professional football team. Twenty-three male professional football players were monitored from eighteen Portuguese Football League matches during the 2019–2020 season. Global positioning system technology (GPS) was used to collect time-motion data. The match running performance was obtained from five playing positions: central defenders (CD), fullbacks (FB), central midfielders (CM), wide midfielders (WM) and forwards (FW). Match running performance was analyzed within specific position and contextual factors using one-way analysis of variance (ANOVA) for repeated measures, standardized (Cohen) differences and smallest worthwhile change. CM and WM players covered significantly greater total distance (F = 15.45, p = 0.000, η2 = 0.334) and average speed (F = 12.79, p < 0.001, η2 = 0.294). WM and FB players covered higher distances at high-speed running (F = 16.93, p = 0.000, η2 = 0.355) and sprinting (F = 13.49; p < 0.001, η2 = 0.305). WM players covered the highest number of accelerations (F = 4.69, p < 0.001, η2 = 0.132) and decelerations (F = 12.21, p < 0.001, η2 = 0.284). The match running performance was influenced by match location (d = 0.06–2.04; CI: −0.42–2.31; SWC = 0.01–1.10), quality of opposition (d = 0.13–2.14; CI: –0.02–2.60; SWC = 0.01–1.55) and match outcome (d = 0.01–2.49; CI: −0.01–2.31; SWC = 0.01–0.35). Contextual factors influenced the match running performance with differential effects between playing positions. This study provides the first report about the contextual influence on match running performance in a Portuguese professional football team. Future research should also integrate tactical and technical key indicators when analyzing the match-related contextual influence on match running performance.  相似文献   

6.
A novel zerovalent ruthenium complex with a π-acidic ligand, Ru(η6-cyclooctatriene)(η2-dimethyl fumarate)2 (1), was prepared from Ru(η4-cyclooctadiene)(η6-cyclooctatriene) [Ru(cod)(cot)]. Complex 1 or Ru(cod)(cot) catalyzes various new carbon-carbon bond-forming reactions that include the [2 + 2] cycloaddition of alkenes and alkynes via ruthenacycles, the creation of a new hydrocarbon, pentacyclo[6.6.0.02,6.03,13.010,14]tetradeca-4,11-diene [PCTD], by dimerization of 2,5-norbornadiene via C-C bond cleavage, and the codimerization of alkynes and/or alkenes. Complex 1 was shown to be an excellent mother complex for various zerovalent ruthenium complexes. Complex 1 reacts with amines, phosphines or water to give new zerovalent ruthenium complexes with the ligands. The resulting aqua complexes have a water ligand with an oxygen atom that is a chiral center, i.e., ruthenium complexes with a ‘chiral water’ ligand were prepared and fully characterized.  相似文献   

7.
The effects of spatial averaging in measurements of scalar variance and scalar dissipation in three piloted methane/air jet flames (Sandia flames C, D, and E) are investigated. Line imaging of Raman scattering, Rayleigh scattering, and laser-induced CO fluorescence is applied to obtain simultaneous single-shot measurements of temperature, the mass fractions of all major species, and mixture fraction, ξ, along 7-mm segments. Spatial filters are applied to ensembles of instantaneous profiles to quantify effects of spatial averaging on the Favre mean and variance of mixture fraction and scalar dissipation at several locations in the three flames. The radial contribution to scalar dissipation, χr = 2Dξ (∂ξ/∂r)2, is calculated from the filtered instantaneous profiles. The variance of mixture fraction tends to decrease linearly with increasing filter width, while the mean and variance of scalar dissipation are observed to follow an exponential dependence. In each case, the observed functional dependence is used to extrapolate to zero filter width, yielding estimates of the “fully resolved” profiles of measured quantities. Length scales for resolution of scalar variance and scalar dissipation are also extracted from the spatial filtering analysis and compared with length scales obtained from spatial autocorrelations. These results provide new insights on the small scale structure of turbulent jet flames and on the spatial resolution requirements for measurements of scalar variance and scalar dissipation.  相似文献   

8.
Electrocardiography (ECG) and electroencephalography (EEG) signals provide clinical information relevant to determine a patient’s health status. The nonlinear analysis of ECG and EEG signals allows for discovering characteristics that could not be found with traditional methods based on amplitude and frequency. Approximate entropy (ApEn) and sampling entropy (SampEn) are nonlinear data analysis algorithms that measure the data’s regularity, and these are used to classify different electrophysiological signals as normal or pathological. Entropy calculation requires setting the parameters r (tolerance threshold), m (immersion dimension), and τ (time delay), with the last one being related to how the time series is downsampled. In this study, we showed the dependence of ApEn and SampEn on different values of τ, for ECG and EEG signals with different sampling frequencies (Fs), extracted from a digital repository. We considered four values of Fs (128, 256, 384, and 512 Hz for the ECG signals, and 160, 320, 480, and 640 Hz for the EEG signals) and five values of τ (from 1 to 5). We performed parametric and nonparametric statistical tests to confirm that the groups of normal and pathological ECG and EEG signals were significantly different (p < 0.05) for each F and τ value. The separation between the entropy values of regular and irregular signals was variable, demonstrating the dependence of ApEn and SampEn with Fs and τ. For ECG signals, the separation between the conditions was more robust when using SampEn, the lowest value of Fs, and τ larger than 1. For EEG signals, the separation between the conditions was more robust when using SampEn with large values of Fs and τ larger than 1. Therefore, adjusting τ may be convenient for signals that were acquired with different Fs to ensure a reliable clinical classification. Furthermore, it is useful to set τ to values larger than 1 to reduce the computational cost.  相似文献   

9.
The working environment of wind turbine gearboxes is complex, complicating the effective monitoring of their running state. In this paper, a new gearbox fault diagnosis method based on improved variational mode decomposition (IVMD), combined with time-shift multi-scale sample entropy (TSMSE) and a sparrow search algorithm-based support vector machine (SSA-SVM), is proposed. Firstly, a novel algorithm, IVMD, is presented for solving the problem where VMD parameters (K and α) need to be selected in advance, which mainly contains two steps: the maximum kurtosis index is employed to preliminarily determine a series of local optimal decomposition parameters (K and α), then from the local parameters, the global optimum parameters are selected based on the minimum energy loss coefficient (ELC). After decomposition by IVMD, the raw signal is divided into K intrinsic mode functions (IMFs), the optimal IMF(s) with abundant fault information is (are) chosen based on the minimum envelopment entropy criterion. Secondly, the time-shift technique is introduced to information entropy, the time-shift multi-scale sample entropy algorithm is applied for the analysis of the complexity of the chosen optimal IMF and extract fault feature vectors. Finally, the sparrow search algorithm, which takes the classification error rate of SVM as the fitness function, is used to adaptively optimize the SVM parameters. Next, the extracted TSMSEs are input into the SSA-SVM model as the feature vector to identify the gear signal types under different conditions. The simulation and experimental results confirm that the proposed method is feasible and superior in gearbox fault diagnosis when compared with other methods.  相似文献   

10.
In this paper the error due to the phase response of digital filters on acoustic decay measurements is analyzed. There are two main sources of errors when an acoustic decay is filtered: the error due to the bandwidth of the filters related to their magnitude response, and the error due to their phase response. In this investigation the two components are separated and the phase error analyzed in terms of the group delay of the filters. Linear phase FIR filters and minimum phase IIR filters fulfilling the class 1 requirements of the IEC 61260 standard have been designed, and their errors compared. This makes it possible to explain the behavior of the phase error and develop recommendations for the use of each filtering technique. The paper is focused on the filtering techniques covered by current versions of the standards for measurement of acoustic decays and in the evaluation of the acoustic decay for narrow filters at low frequencies and low reverberation times (BT < 16).  相似文献   

11.
During extensive studies on π-allylpalladium chemistry, we have developed classical β-keto ester and malonate chemistry to a new generation by discovering a variety of palladium-catalyzed reactions of their allylic esters. Palladium enolates are generated from allyl β-keto esters after decarboxylation and undergo the following transformations; a) reductive elimination to provide α-allyl ketones, b) elimination of β-hydrogen to give α, β-unsaturated ketones, c) formation of α-methylene ketones, d) hydrogenolysis to give ketones, e) aldol condensation, and f) Michael addition. Allyl malonates and cyanoacetes undergo similar reactions. Results of these studies, including several applications carried out by other researchers are summarized.  相似文献   

12.
A formulation and solution of the recurrent filtering problem are proposed for correlated nonstationary optical radiation intensity fluctuations with single-electron discrete-time registration. The Bayes theory is used to find a quasi-optimal algorithm for filtering of a Markov sequence with a gamma distribution in the class of Y2-minimax rules based on non-Gaussian approximations for a posteriori distributions.St. Petersburg State Telecommunications University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 37, No. 12, pp. 1587–1602, December, 1994.  相似文献   

13.
A theoretical analysis is presented of the problem of how distance-dependent electron transfer in photoinduced forward electron transfer followed by geminate backward electron transfer in liquid solution is reflected in the viscosity dependence of the magnetic field effect (MFE) on the efficiency of free radical formation (φce) in such reactions. The stochastic Liouville equation formalism is employed to model the reaction behaviour of distance-distributed, triplet-born radical pairs (RPs) undergoing free diffusion, distance- and spin-dependent backward electron transfer, coherent and incoherent spin evolution in the ps time domain. In comparison with real systems the spin situation is simplified by reducing it to a two state (S, T 0) problem, yet it is parametrized in a way that allows sensible comparison of the results with those of recent experiments. It is predicted that the MFE on φce exhibits characteristic minima in the MFE versus viscosity curves, and it is verified in detail that this feature is peculiar to the diffusional model with distance-dependent electron transfer, i.e. cannot be reproduced with the simpler (‘exponential’) RP model employing distance-independent rate constants. Thus, the MFE versus viscosity curves are established as a genuine fingerprint of distance-dependent electron transfer. The theoretical results compare favourably with recent experimental results obtained with RuIII complex/methylviologen RPs.  相似文献   

14.
J. Daly  M. Crane  H.J. Ruskin   《Physica A》2008,387(16-17):4248-4260
Random matrix theory (RMT) filters, applied to covariance matrices of financial returns, have recently been shown to offer improvements to the optimisation of stock portfolios. This paper studies the effect of three RMT filters on the realised portfolio risk, and on the stability of the filtered covariance matrix, using bootstrap analysis and out-of-sample testing.We propose an extension to an existing RMT filter, (based on Krzanowski stability), which is observed to reduce risk and increase stability, when compared to other RMT filters tested. We also study a scheme for filtering the covariance matrix directly, as opposed to the standard method of filtering correlation, where the latter is found to lower the realised risk, on average, by up to 6.7%.We consider both equally and exponentially weighted covariance matrices in our analysis, and observe that the overall best method out-of-sample was that of the exponentially weighted covariance, with our Krzanowski stability-based filter applied to the correlation matrix. We also find that the optimal out-of-sample decay factors, for both filtered and unfiltered forecasts, were higher than those suggested by Riskmetrics [J.P. Morgan, Reuters, Riskmetrics technical document, Technical Report, 1996. http://www.riskmetrics.com/techdoc.html], with those for the latter approaching a value of α=1.In conclusion, RMT filtering reduced the realised risk, on average, and in the majority of cases when tested out-of-sample, but increased the realised risk on a marked number of individual days–in some cases more than doubling it.  相似文献   

15.
Longyan Gong  Zicong Zhou 《Physica A》2011,390(17):2977-2986
By the Fourier filtering method, we generate one-dimensional binary sequences from coarse-grained continuous sequences with preset exponents α0. Using the spectrum analysis, we find that the corresponding binary sequences have pure 1/fα power spectrum and spectrum exponents α∈[0.0,2.0], where f is the frequency. We evaluate numerically the relation between α and α0. Using the autocorrelation function analysis, the detrended fluctuation analysis, the duration time analysis and the entropy analysis, we investigate extensively the statistical properties of such binary sequences. We find that the statistical properties are basically different for α<1 and α>1, and binary sequences become more and more ordered as α increases.  相似文献   

16.
The filtering properties of a 2D square lattice made of metallic wires are investigated through the band structures and transmission spectra by the finite-difference time-domain method. All the results show that the transmission can be affected by factors such as wave polarization, incidence direction, and wire radius. It is found that the ΓM direction and smaller radius of metal wires are preferable for a high-frequency-pass filter for TE waves, while the ΓX direction and comparatively greater radius of metal wires are suitable for a low-frequency-pass and a wide stop-band filter for TM waves. Band edges of the filters can be tuned by adjusting the radius of wires and lattice constant. The key features of the band structure and the corresponding transmission spectrum are strongly correlated. Our work demonstrates that detailed band maps can help understanding the transmission properties, which are essential for designing wave filters.  相似文献   

17.
Importance sampling is used to approximate Bayes’ rule in many computational approaches to Bayesian inverse problems, data assimilation and machine learning. This paper reviews and further investigates the required sample size for importance sampling in terms of the χ2-divergence between target and proposal. We illustrate through examples the roles that dimension, noise-level and other model parameters play in approximating the Bayesian update with importance sampling. Our examples also facilitate a new direct comparison of standard and optimal proposals for particle filtering.  相似文献   

18.
19.
We present computer simulation and theoretical results for a system of N Quantum Hard Spheres (QHS) particles of diameter σ and mass m at temperature T, confined between parallel hard walls separated by a distance Hσ, within the range 1H. Semiclassical Monte Carlo computer simulations were performed adapted to a confined space, considering effects in terms of the density of particles ρ*=N/V, where V is the accessible volume, the inverse length H1 and the de Broglie’s thermal wavelength λB=h/2πmkT, where k and h are the Boltzmann’s and Planck’s constants, respectively. For the case of extreme and maximum confinement, 0.5<H1<1 and H1=1, respectively, analytical results can be given based on an extension for quantum systems of the Helmholtz free energies for the corresponding classical systems.  相似文献   

20.
This paper analyses the complexity of electroencephalogram (EEG) signals in different temporal scales for the analysis and classification of focal and non-focal EEG signals. Futures from an original multiscale permutation Lempel–Ziv complexity measure (MPLZC) were obtained. MPLZC measure combines a multiscale structure, ordinal analysis, and permutation Lempel–Ziv complexity for quantifying the dynamic changes of an electroencephalogram (EEG). We also show the dependency of MPLZC on several straight-forward signal processing concepts, which appear in biomedical EEG activity via a set of synthetic signals. The main material of the study consists of EEG signals, which were obtained from the Bern-Barcelona EEG database. The signals were divided into two groups: focal EEG signals (n = 100) and non-focal EEG signals (n = 100); statistical analysis was performed by means of non-parametric Mann–Whitney test. The mean value of MPLZC results in the non-focal group are significantly higher than those in the focal group for scales above 1 (p < 0.05). The result indicates that the non-focal EEG signals are more complex. MPLZC feature sets are used for the least squares support vector machine (LS-SVM) classifier to classify into the focal and non-focal EEG signals. Our experimental results confirmed the usefulness of the MPLZC method for distinguishing focal and non-focal EEG signals with a classification accuracy of 86%.  相似文献   

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