真实体系光电离截面共振结构的理论研究

利用我们提出的普遍适用的精确光电离截面公式和介电影响函数研究了原子光电离共振结构受粒子数密度影响的效应.结果表明用新的光电离截面公式可以直接处理宏观环境对截面的影响,明显地优于孤立原子光电离截面公式.     

精确研究光电离散射截面的新方法

利用单个原子精确的光电离散射截面和物质的复介电常数，并考虑一定的分子力学模型，可以对凝聚态物质中的原子光电离截面进行定量研究。孙卫国等最近提出了一套研究真实体系中原子光电离截面的新方法。本首次应用它们来研究碱土金属钠在不同密度状态下的光电离截面，结果表明新的光电离截面公式比名的孤立原子光电离截面公式更具有优越性。     

精确研究光电离散射截面的新方法

利用单个原子精确的光电离散射截面和物质的复介电常数,并考虑一定的分子力学模型,可以对凝聚态物质中的原子光电离截面进行定量研究.孙卫国等最近提出了一套研究真实体系中原子光电离截面的新方法.本文首次应用它们来研究碱土金属钠在不同密度状态下的光电离截面,结果表明新的光电离截面公式比著名的孤立原子光电离截面公式更具有优越性.     

Alq+(q=0—12)的光电离截面和Bethe系数

使用Hartree-Fock加相对论修正(HFR)近似计算Al^q+(q=0—12)的光电离截面和Bethe系数,其中Bethe系数将光电离截面与电子碰撞电离截面联系起来,并且决定电子碰撞电离截面的高能行为.分析了光电离截面和Bethe系数随电离度q的变化规律,还与其他数据进行比较,结果表明其数据是可靠的 关键词： 光电离 截面 Bethe系数     

原子分子真空紫外光吸收和光电离绝对截面的精确测量

介绍了一种精确测量原子分子真空紫外光吸收和光电离绝对截面的实验方法。该方法的主要特点是使用圆筒形多级电极，有效地收集光电离产生的电子和离子，并利用高通量的同步辐射作光源，精确地测量分子（原子）的绝对光吸收、光电离和光离解截面，以及光电离量子产率和光学振子强度分布等。利用该方法获得了Ｘｅ原子和Ｎ２分子的一些实验结果。     

铝原子激发态近阈限光电离截面测量

本文利用激光烧蚀、激光泵浦-探测、共振增强多光子电离和飞行时间质谱相结合的实验技术,根据离子产额和电离激光能量的关系,获取铝原子激发态的光电离截面;并研究了光电离截面与电离富余能的依赖关系.电离富余能0-2.98 e V内光电离截面值范围为15.6±1.7 Mb-2.3±0.9 Mb,激发态的寿命为17.6±1.8,16.9±1.7 ns.在光电离截面的测量中,总的均方根误差上限约为17%.     

铝原子激发态近阈限光电离截面测量

本文利用激光烧蚀、激光泵浦-探测、共振增强多光子电离和飞行时间质谱相结合的实验技术,根据离子产额和电离激光能量的关系,获取铝原子激发态的光电离截面;并研究了光电离截面与电离富余能的依赖关系.电离富余能0-2.98 eV内光电离截面值范围为15.6±1.7 Mb-2.3±0.9 Mb,激发态的寿命为17.6±1.8,16.9±1.7ns.在光电离截面的测量中,总的均方根误差上限约为17%.     

溴的光电离和辐射复合——平均原子模型速率系数与细致组态速率系数

根据原子自洽场理论(即DCA)，计算了溴原子各种电离度各个壳层的DCA约化光电离截面.与AA模型的平均电子轨道约化光电离截面进行比较，总结出其内在规律.在AA的约化光电离截面的基础上，可以得到电离度分辨的DCA约化光电离截面；进而可以得到细致组态的光电离和辐射复合速率系数.为精密地描述非局域热动平衡(n-LTE)等离子体提供必要的基础. 关键词： 光电离 速率系数 平均原子模型     

Measurement of Photoionization Cross Sections of the Excited States of Titanium

实验研究了钛原子在293～321 nm波段的共振增强多光子电离. 采用激光烧蚀和超声射流相结合的实验技术来制备自由原子,由飞行时间质谱仪实现对钛原子光电离产物的检测. 从离子信号强度对和激光强度的依赖关系导出了钛原子价电子激发态的光电离截面. 实验测量的一些激发态光电离截面在0.2～6.0 Mb. 通过对⁴⁶Ti、⁴⁷Ti、⁴⁸Ti的光电离截面测量研究,没有发现明显的同位素依赖性.     

温稠密等离子体中Al12+离子的光电离过程

本文采用多组态Dirac-Hartree-Fock方法研究了温稠密等离子体环境中Al12+离子的光电离过程. 等离子体效应采用SM屏蔽势来模拟(Stanton和Murillo在2015年提出). 计算中固定标度温度1.3eV，在强耦合等离子体环境下，研究了等离子体密度对能级，连续态波函数以及光电离截面的影响. 通过与相同等离子体条件下的Debye-Hückel模型势计算的光电离截面对比，发现两种模型对应的结果中未同时出现势形共振峰，这是由于本文采用的屏蔽模型包含等离子体简并、有限温度对动能的梯度修正和量子交换关联效应，对光电离截面的大小和共振结构具有显著影响.     

Theoretical studies on the photoionization cross-sections of solid silver

An alternative expression for photoionization cross-section of atoms or molecules and a dielectric influence function （DIF） in a high-density system proposed recently are used to study the photoionization cross-sections of solid silver. It is suggested that a density turning point （DTP） of a photoionized system may be viewed as the critical point where the photoionization properties of atoms in a real system may have a notable change. The results show that the present theoretical photoionization cross-sections are in good agreement with the experimental results of a silver crystal both in structure and in magnitude.     

Interference effects on the photoionization cross sections between two neighbouring atoms: nitrogen as an example

Interference effects on the photoionization cross sections between two neighbouring atoms are considered based on the coherent scattering of the ionized electrons by the two nuclei when their separation is less than or comparable to the de Broglie wave length of the ionized electrons.As an example,the single atomic nitrogen ionization cross section and the total cross sections of two nitrogen atoms with coherently added photoionization amplitudes are calculated from the threshold to about 60 A (1 A=0.1 nm) of the photon energy.The photoionization cross sections of atomic nitrogen are obtained by using the close-coupling R-matrix method.In the calculation 19 states are included.The ionization energy of the atomic nitrogen and the photoionization cross sections agree well with the experimental results.Based on the R-matrix results of atomic nitrogen,the interference effects between two neighbouring nitrogen atoms are obtained.It is shown that the interference effects are considerable when electrons are ionized just above the threshold,even for the separations between the two atoms are larger than two times of the bond length of N 2 molecules.Therefore,in hot and dense samples,effects caused by the coherent interference between the neighbours are expected to be observable for the total photoionization cross sections.     

Spectroscopy of He–Ne afterglow plasma

Implementation of promising control schemes for the intensity and position of X-ray-laser beams with a photon energy up to several tens of kiloelectronvolts requires knowledge of the angular dependence of cross sections for photoionization of noble gas atoms by hard photons. Estimates of quadrupole corrections to the cross section for photoionization of a Kr atom by X-ray photons with an energy of about 25 keV are reported in this paper. An analytic expression for the cross section of the process is parameterized in a compact form convenient for analyzing angular distributions with an arbitrary polarization of a photon beam.     

Mirroring doubly excited resonances in argon

New features are revealed in the low-energy photoionization spectrum of Ar by critically combining high photon resolution and differential photoelectron spectroscopic techniques. Two LS-forbidden doubly excited resonances are seen in the 3p(-1)(3/2, 1/2) partial cross sections which exhibit mirroring profiles, resulting in complete cancellation in the total photoionization cross section, as was predicted by Liu and Starace [Phys. Rev. A 59, R1731 (1999)]. These results demonstrate that a new class of weakly spin-orbit induced, mirroring resonances should be observable in partial, but not in total, collisional cross sections involving atoms, molecules, and solids in general.     

Theory of spin polarization phenomena in atomic and molecular photoeffects

A compact invariant expression for the angular distribution of photoelectrons formed as a result of photoionization of axisymmetrically polarized atoms and molecules, including optically active molecules, is derived from the general symmetry considerations and using a recently developed bipolar harmonic reduction technique. In the angular distribution of photoelectrons, as well as in the total photoionization cross section, the dependence on all the geometric parameters is separated completely. The polarization of ionizing radiation can be arbitrary, with the partial polarization being specified by the Stokes parameters. The expression for the angular distribution of photoelectrons escaping from an atomic-molecular system oriented in the first order also determines the structure of the expression for the photoionization cross section of an unpolarized system with allowance for the spin polarization of a photoelectron or a photoion with the spin 1/2. The roles played by circular dichroism, chirality, etc., in the process of photoionization of oriented and aligned systems are analyzed in detail.     

相对论小分量波函数对原子光电离截面的影响

利用相对论平均自洽场理论,　研究了相对论波函数的小分量对原子光电离截面的影响。原子核尺寸效应将使波函数小分量对原子光电离截面的影响减弱。由于波函数沿径向空间被压缩,　电子离核的平均半径较小,　波函数小分量对高离化态离子光电离截面的影响比对一般原子要强得多。波函数小分量反映了相对论效应的基本特征,　从而也定性地说明了光电离过程中相对论效应的强弱。The effects of relativistic small radial component on atomic photoionization cross sections have been studied within relativistic average self consistent field theory. Relativistic effects are relatively unimportant for low photon energy, along with a review of high energy photoionization the relativistic effects are quite important. The effects of relativistic small radial component on photoionization process should show breakdown when the nuclear finite size effects is taken into account. The compression of wavefunction into the space near nucleus is so strong in highly charged ions that the electronic radius greatly decreases, and the effects of relativistic small radial component on photoionization cross sections turn to stronger than ordinary atoms. Since relativistic effects are extremely sensitive to the behavior of small radial component, the results are in good agreement with relativistic effects on photoionization cross section.     

Double K-shell photoionization of low-Z atoms and He-like ions

We report on the investigation of the photon energy dependence of double 1s photoionization of light atoms and compare the cross sections for hollow atom and He-like ion production. Measurements of the Kα hypersatellite x-ray spectra of Mg, Al, and Si were carried out using the Fribourg high-resolution x-ray spectrometer installed at the ID21 and ID26 beam lines at the ESRF. The double-to-single photoionization cross section ratios were derived as a function of the incident photon beam energy and compared to convergent close-coupling (CCC) calculations for He-like ions. The dynamical electron-electron scattering contribution to the DPI cross-sections was found to be more important for neutral atoms than for the He isoelectronic series.     

钴、钛原子激发态光电离研究

本文报道紫外区钛和钴原子共振增强多光子电离(REMPI)谱和激发态绝对光电离截面。实验上通过激光烧蚀金属样品制备中性原子,由飞行时间质谱仪检测离子产物,在298-351nm范围扫描激光波长,得到钛原子和钴原子共振增强多光子电离谱;并根据共振离子信号强度与电离激光通量关系得到原子激发态的绝对光电离截面,这些激发态电离截面的实验值在0.5-4 Mb。