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1.
电子俘获材料的红外上转换效率   总被引:5,自引:3,他引:2  
范文慧  赵卫  刘英  侯洵 《光子学报》1999,28(2):188-192
采用稀土直接掺杂工艺提高了电子俘获材料CaS:Eu,Sm和CaS:Ce,Sm的发光亮度和制备效率,并利用超短脉冲红外激光测试了它们的红外上转换效率.借助等离子体质谱技术检测了硫化助熔剂法和稀土直接掺杂工艺合成电子俘获材料中主要掺杂剂的化学计量比,分析了影响电子俘获材料上转换发光效率的主要因素.  相似文献   

2.
采用高温固相法获得了一种只具有 微弱余辉的新型电子俘获型光存储材料Sr2SnO4:Tb3 +, Li +. 发光性能研究结果表明: 该材料对980 nm的红外激光具有很好的上转换光激励信息读出响应, 同时292 nm紫外光为其最佳信息写入光源. 光存储性能研究结果表明: 该材料的浅陷阱较少, 因此其余辉发光很弱, 不到500 s; 另一方面, 该材料中存在大量的深蓄能陷阱. 因此, Sr2SnO4: Tb3 +, Li+是一种具有较好实际应用价值的新型电子俘获型光存储材料. 此外, 还讨论了Sr2SnO4: Tb3 +, Li+的光存储发光机理.  相似文献   

3.
CaS:Eu,Sm是一种典型的电子俘获型光存储材料,文章采用湿法在还原气氛中制备了CaS∶Eu,Sm粉末样品.测量了这种光存储材料的XRD、激发光谱、发射光谱、光激励发光光谱、热释光谱以及光激励发光衰减曲线.XRD结果表明样品在1 050℃晶格已经形成.光谱测试结果说明紫外光可激发该材料,作为信息写入光源.样品被紫外光源饱和激发后,用980 nm红外激光激励,发射出峰值位于635 nm的红光.光激励发光起初衰减较快,随后有一个较长的平缓期.且样品具有合适深度的陷阱能级,能够稳定存储信息.对CaS∶Eu,Sm的光存储机理进行了探讨.  相似文献   

4.
SrS∶Eu,Sm光存储机理的研究   总被引:1,自引:0,他引:1  
采用高温固相反应法在还原气氛下制备了SrS:Eu,Sm样品,利用荧光光谱仪测量了这种光存储材料的激发光谱和发射光谱.将样品用紫外灯(265 nm)照射激发饱和后,再用980 nm的红外激光器激励,利用荧光光谱仪测试得到了峰值位于599 nm的光激励发光光谱.此外还利用热释光谱仪测试了样品的热释光谱.探讨了SrS:Eu,Sm的光存储机理,认为引入的稀土离子在SrS的带隙中形成分裂能级.当用紫外光照射材料时,Eu的电子从基态被激发到激发态或基质材料的导带,其中一部分电子被辅助激活剂Sm的陷阱俘获,实现信息写入.当材料被与陷阱深度相当的红外光激励时,电子陷阱Sm2 俘获的电子才可能跃出俘获能级,与空穴在Eu的激发态和基态能级上复合,多余的能量以可见光的形式释放出来,实现信息读出.  相似文献   

5.
范文慧  刘英 《光子学报》1998,27(9):855-859
利用等离子体质谱(ICP-MS)技术测试了硫化助熔剂法和稀土直接掺杂工艺合成电子俘获材料的化学计量比,结果表明,采用稀土直接掺杂工艺合成材料的化学计量比更接近设计值;通过分析电子俘获材料的发光机制和光谱测试结果,讨论了制备工艺条件对电子俘获材料中稀土离子化合价的影响.  相似文献   

6.
CaS:Eu,Sm及其在农用转光膜上的应用原理   总被引:4,自引:0,他引:4  
叶孔敦  光昭等 《光子学报》2001,30(4):487-491
利用稀土直接掺杂工艺合成了一种“常光充能”型电子陷获材料CaS:Eu,Sm,它不仅具有CaS:Eu无机发光材料的荧光光谱特性,而且具有红外升频转换特性,可将0.8~1.6μm的红外光直接转换为~672nm的红光、量子效率高达76%,是一种优于CaS:Eu的光转换农膜添加剂.而共掺Eu2+、Sm3+和Cu+的CaS荧光粉有望成为一种性能优于光转换农膜添加剂CaS:Eu2+,Cu+、可人工模拟叶绿素吸收光谱的新型农用转光膜材料.  相似文献   

7.
CaS∶Eu,Sm及其在农用转光膜上的应用原理   总被引:2,自引:2,他引:0  
利用稀土直接掺杂工艺合成了一种“常光充能”型电子陷获材料CaS∶Eu,Sm,它不仅具有CaS∶Eu无机发光材料的荧光光谱特性,而且具有红外升频转换特性,可将0.8~ 1.6μm的红外光直接转换为~672nm的红光、量子效率高达76%,是一种优于CaS∶Eu的光转换农膜添加剂.而共掺Eu2+、Sm3+和Cu+的CaS荧光粉有望成为一种性能优于光转换农膜添加剂CaS∶Eu2+,Cu+、可人工模拟叶绿素吸收光谱的新型农用转光膜材料.  相似文献   

8.
研究了电子俘获材料CaS∶Eu,Sm多晶粉末的紫外-可见-红外吸收光谱及红外激励光谱.研究结果表明,CaS∶Eu,Sm中主激活剂Eu和辅助激活剂Sm分别以Eu2 离子和Sm3 离子的形式存在;ETM的吸收差谱及红外激励光谱所反映的光谱特性是不同的.紫外-可见光区的吸收差谱给出了ETM光谱存储灵敏度的信息,而红外光谱区的吸收差谱给出了ETM所俘获电子数量的信息及电子陷阱能级的特征(深度和宽度)信息.红外激励光谱则反映了ETM将不同波长的红外激励光的能量转换为特定波长处的红外辐射光能量的光谱转换灵敏度.二者结合起来可以更完整地描述ETM的光谱特性.  相似文献   

9.
SrS:Eu与SrS:Eu,Sm中电子陷阱与光存储研究   总被引:7,自引:0,他引:7       下载免费PDF全文
何志毅  王永生  孙力  徐叙瑢 《物理学报》2000,49(7):1377-1382
对SrS:Eu和SrS:Eu,Sm激发初始阶段的荧光上升过程和余辉进行了研究,并进一步考证其中 电子陷阱的属性.通过两种样品和两个阶段的比较,对陷阱数量和深度的变化、量子效率以 及电子俘获和释放、复合过程进行了分析,发现Sm离子并不影响陷阱的数量.利用吸收光谱 方法研究了SrS:Eu,Sm中电子由陷阱能级向导带的跃迁.通过陷阱饱和-倒空吸收谱差,即激 励吸收谱及其强度随Eu,Sm浓度的变化,探讨了掺杂浓度对陷阱浓度和光存储饱和量的影响. 结果表明Sm离子的作用是使陷阱能级加深从而能稳定地储存电子.通过激励吸收谱峰值强度 可确切地比较光存储材料在这方面的性能,并与光激励谱的测量方法作了对照. 关键词: 电子陷阱 光存储 电子俘获 光激励发光  相似文献   

10.
潘华强  黄丽清  童慧敏  王永昌 《光子学报》2007,36(11):2083-2086
研究了电子俘获材料CaS∶Eu,Sm多晶粉末的紫外-可见-红外吸收光谱及红外激励光谱.研究结果表明,CaS∶Eu,Sm中主激活剂Eu和辅助激活剂Sm分别以Eu2+离子和Sm3+离子的形式存在;ETM的吸收差谱及红外激励光谱所反映的光谱特性是不同的.紫外-可见光区的吸收差谱给出了ETM光谱存储灵敏度的信息,而红外光谱区的吸收差谱给出了ETM所俘获电子数量的信息及电子陷阱能级的特征(深度和宽度)信息.红外激励光谱则反映了ETM将不同波长的红外激励光的能量转换为特定波长处的红外辐射光能量的光谱转换灵敏度.二者结合起来可以更完整地描述ETM的光谱特性.  相似文献   

11.
一类电子俘获型红外可激发材料光学性能研究   总被引:10,自引:0,他引:10  
测试了硫化助熔剂法制备的电子俘获型红外可激发材料Eu,Sm∶CaS和Ce,Sm∶CaS的激发光谱、红外激励光谱、荧光光谱及红外上转换发光光谱等,结果表明:这类材料不仅具有红外上转换及光存储功能,而且具有光谱响应范围广、可在室温下工作以及造价低等优点,是一类很有发展前途的光学功能材料。  相似文献   

12.
High-quality electron-trapping thin films CaS: Eu, Sm with red light output have been successfully deposited on quartz and single-crystal silicon substrates by electron beam evaporation (EBE) and radio frequency (RF) magnetron sputtering in vacuum and H2S partial pressures. Infrared upconversion efficiency of CaS: Eu, Sm thin films under different growth conditions has been investigated by using ultrashort infrared (IR) laser pulse with 20 ps (full width at half-maximum (FWHM)). The results show that upconversion efficiency of CaS: Eu, Sm thin films depends strongly on growth conditions in spite of the existence of “exhaustion” phenomena. Microstructures identified by X-ray diffraction (XRD) indicate that crystallinity of CaS films relies on both substrate materials and growth conditions. The stoichiometric composition of CaS films was measured by secondary-ion mass spectrometry (SIMS). The post-annealing process was found to promote grain growth and activate strong luminescence so that it could obviously improve upconversion efficiency of CaS: Eu, Sm films, even though it had negative influence on transmittance and spatial resolution of these films. Received: 5 June 2000 / Accepted: 7 June 2000 / Published online: 23 August 2000  相似文献   

13.
电子俘获型薄膜材料的结构与光学性能   总被引:17,自引:1,他引:16  
范文慧  刘英 《光学学报》1998,18(5):91-595
采用电子束沉积技术成功制务了以碱土金属硫化物为基质材料,稀土元素离子作为激活中心的输出红光的红外上转换及光存储薄膜材料CaS:Eu,Sm物相结构测试表明,基片温度和后退火晶化处理对薄膜的晶态有很大影响,在本实验的制备条件下,(200)面的衍射蜂最强;加硫共蒸或通入少量H2S有助于改善CaS薄膜的化学计量比,光谱测试表明,薄膜材料的光学性能与粉末材料基本相同。  相似文献   

14.
利用电子俘获材料实现光学IPA神经网络模型   总被引:3,自引:0,他引:3  
阮昊  陈述春 《光学学报》1997,17(6):66-771
报道用自行研制的CaS(Eu,Sm)电子俘获材料表示互联机重矩阵以实现光学IPA神经网络模型,由于CaS(Eu,Sm)的红外激励发光强度与俘获的电子密度及红外读出光强度之积成线性关系,故可用来表示互联权重矩阵以实现光学神经网络,这种互联权重矩阵具有很宽的数值范围,并可以用光学的办法进行快速擦除,重写。  相似文献   

15.
In order to improve visible light photocatalytic activities of the nanometer TiO2, a novel and efficient Cr,S-codoped TiO2 (Cr-TiO2-S) photocatalyst was prepared by precipitation-doping method. The crystalline structure, morphology, particle size, and chemical structure of Cr-TiO2-S were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and Fourier transform infrared (FT-IR) techniques, respectively. Results indicate that the doping of Cr and S, cause absorption edge shifts to the visible light region (λ > 420 nm) compare to the pure TiO2, reduces average size of the TiO2 crystallites, enhances desired lattice distortion of Ti, promotes separation of photo-induced electron and hole pair, and thus improves pollutant decomposition under visible light irradiation. The photocatalytic activities of Cr-TiO2-S nanoparticles were evaluated using the photodegradation of methyl orange (MO) as probe reaction under the irradiation of UV and visible light and it was observed that the Cr-TiO2-S photocatalyst shows higher visible photocatalytic activity than the pure TiO2. The optimal Cr-TiO2-S concentration to obtain the highest photocatalytic activity was 5 mol% for both of Cr and S.  相似文献   

16.
The magnetotransmission, magnetoreflection, and magnetoresistance of the La0.7Ca0.3MnO3 and La0.9Ag0.1MnO3 epitaxial films have been investigated. It has been found that the films exhibit a significant magnetorefractive effect in the case of reflection and transmission of light in the fundamental absorption region both in the vicinity of the Curie temperature and at low temperatures. It has been shown that the magnetorefractive effect in the infrared spectral region of the manganites is determined by a high-frequency response to magnetoresistance, whereas the magnetorefractive effect in the visible spectral region of these materials is associated with a change in the electronic structure in response to a magnetic field, which, in turn, leads to a change in the electron density of states, the probability of interband optical transitions, and the shift of light absorption bands. The obtained values of the magnetotransmittance and magnetoreflectance in the visible spectral region are less than those observed in the infrared region of the spectrum, but they are several times greater than the linear magneto-optical effects. As a result, the magnetorefractive effect, which is a nongyrotropic phenomenon, makes it possible to avoid the use of light analyzers and polarizers in optical circuits.  相似文献   

17.
CaS:Bi nanocrystalline powder of average grain size 35 nm was prepared by wet chemical co-precipitation method and irradiated with 100 MeV oxygen ions at fluences between 1×1012 and 1×1013 ion/cm2. The irradiation induced damage and modifications were studied using X-ray Diffraction (XRD), transmission electron microscopy (TEM) and photoluminescence (PL) spectroscopy. With the increase in ion fluences, the crystallinity of CaS was destroyed upto 25.9 % for the reflection (200) and 21.1 % for the reflection (220) and the peaks broadens at a much faster rate due to grain breaking process. Structural parameters such as grain size, strain and dislocation density have shown a significant change after ion irradiation. The effects of different dopant concentrations on PL emission intensity after irradiation were also investigated. A blue shift of the photoluminescence peak with increasing ion fluence was noticed and was also ascribed to a decrease in the CaS grain size.   相似文献   

18.
可利用不等价离子取代法或高能射线辐照法制备电子俘获材料,如长余辉发光材料znO-SiO2-B2O3-MnO、CaS:Eu2+,Tm3+、CaGa2S4:Eu2+,Ho3+和固体剂量材料Zn0.96(BO2)2:0.04Tb,Sr0.93Dy0.07B4O7等.利用俘获在缺陷中的电子-空穴对的复合,并把能量传递给Eu2+或Mn2+等激活离子而产生长余辉发光或热释光.它们将在弱光照明与显示,信息存储和辐射治疗与探测、监控等方面获得应用.  相似文献   

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