Hyperfine interactions in molecules through laser spectroscopy

The infrared and millimeter wave spectroscopy, laser Stark spectroscopy, and beam maser spectroscopy of CH₃CN and its isotopic species will be discussed. The beam maser spectroscopy and hyperfine structure of molecules like NCCCD, ClCCD and CH₃CCH are reviewed. The laser magnetic resonance and hyperfine structure in CF, CH and CH₂ free radicals will be discussed. The Lamb dip spectroscopy and laser-induced fluorescence in I₂ involving theB ³Π(0 _u ⁺ ) state are reviewed with special reference to its hyperfine structure. The splitting of the rotational levels of N ₂ ⁺ in itsX ²Σ _g ⁺ andB ²Σ _u ⁺ states due to hyperfine interactions (along with the hyperfine structure) in laser-induced fluorescence in theB−X transition is discussed. Recent results obtained in the laser photo-acoustic spectrum of ICl in the transitionX ¹Σ⁺ −A ³Π₁ will be presented and the possibility of the use of this technique in studying the hyperfine structure will be discussed.     

Hadronic weak decays of heavy mesons and nonfactorization

The parametersχ _1,2, which measure nonfactorizable soft gluon contributions to hadronic weak decays of mesons, are updated by extracting them from the data ofD, B→PP, VP decays (P: pseudoscalar meson,V: vector meson). It is found thatχ ₂ ranges from −0.36 to −0.60 in the decays fromD→Kπ toD ⁺→φπ ⁺,D→K*π, while it is of order 10% with a positive sign inB→ψK, Dπ, D*π, Dρ decays. Therefore, the effective parametera ₂ is process dependent in charm decay, whereas it stays fairly stable inB decay. This is in accordance with the picture that nonfactorizable soft gluon effects become stronger when the relative momentum of the decay particles becomes smaller. As forD, B→VV decays, the presence of nonfactorizable terms in general prevents a possible definition of effectivea ₁ anda ₂. This is reinforced by the observation of a large longitudinal polarization fraction inB→ψK* decay, implying nonfactorizable effects contributing differently toS-, P- andD-wave amplitudes. We found thatA ₁ ^nf /A ₁>0>A ₂ ^nf /A ₂,V ^nf/V (nf standing for nonfactorization) forB→ψK* decay and 0>A ₁ ^nf /A ₁>A ₂ ^nf /A ₂,V ^nf/V forD→K*ρ decay. A measurement of longitudinally and transversely polarized decay rates Γ _L and Γ _T in color-suppressed decay modesB ⁰→D*⁰ ρ ⁰,D*⁰ ω andD ⁺→φρ ⁺ is urged.     

Improved measurement of theB0 andB+ meson lifetimes

The lifetimes of theB ⁰ andB ⁺ mesons have been measured with theAleph detector at LEP, using approximately 3 million hadronic Z decays collected in the period 1991–1994. In the first of three methods, semileptonic decays ofB ⁰ andB ⁺ mesons were partially reconstructed by identifying events containing a lepton with an associatedD*⁻ or meson. The second method used fully reconstructedB ⁰ andB ⁺ mesons. The third method, used to measure theB ⁰ lifetime, employed a partial reconstruction technique to identifyB ⁰→D*⁻ π ⁺ X decays.     

Laser excited fluorescence of Na2

Fluorescence was excited in theB ¹Γ _u −X ¹Σ _g ⁺ system of Na₂, using the 488 and 514.5 nm radiations from a cw Ar⁺ laser. The fluorescence was monitored through a double monochromator employing photoelectronic detection. In the spectrum resulting from the 488 nm excitation, apart from a large number of fluorescence series, a previously unreported series could be identified. On either side of all the members of the strongest series a large number of collisional satellites were observed and assigned.     

Rotational analysis of the 0–9, 0–10 and 0–11 bands of theA 2II u -X 2II g band system of (16O18O)+

High-resolution spectra of the 0–9, 0–10 and 0–11 bands of theA ²II _u —X ²II _g system of (¹⁶O¹⁸O)⁺ ion have been studied for their rotational structure. This study enables a direct determination of the Λ-doubling parameters of theA ²II _u andX ²II _g states. The model of ‘pure precession’ explains, though not entirely, the Λ-doubling of theX ²II _a state as arising out of its interaction with theB ² Σ _g ⁻ state. The Λ-doubling in theA ²II _u state was found insignificant.     

Lepton polarization asymmetry and forward–backward asymmetry in exclusive B→K<Subscript>1</Subscript>τ<Superscript>+</Superscript>τ<Superscript>-</Superscript> decay in universal extra dimension scenario

Decay rate, forward–backward asymmetry and polarization asymmetries of the final state leptons in B→K₁τ⁺τ^-, where K₁ is the axial vector meson, are calculated in the standard model and in the universal extra dimension (UED) model. The sensitivity of the observables to the compactification radius R, the only unknown parameter in the UED model, is studied. Finally, the helicity fractions of the final state K₁ are calculated and their dependence on the compactification radius is discussed. This analysis of the helicity fraction is briefly extended to B→K^*ℓ⁺ℓ^- (ℓ=e,μ) and compared with the other approaches existing in the literature.     

Exploring CP violation and penguin effects through B0d→D+D- and B0s→D+sD-s

The decay B⁰ _d→D⁺D^- offers an interesting probe of CP violation, but it requires control of penguin effects, which can be done through B⁰ _s→D⁺ _sD^- _s by means of the U-spin flavour symmetry of strong interactions. Recently, the Belle collaboration reported indications of large CP violation in the B⁰ _d decay, which were, however, not confirmed by BaBar, and first signals of the B⁰ _s channel were observed at the Tevatron. In view of these developments and the quickly approaching start of the LHC, we explore the allowed region in observable space for CP violation in B⁰ _d→D⁺D^-, perform theoretical estimates of the relevant hadronic penguin parameters and observables, and we address questions both about the most promising strategies for the extraction of CP-violating phases and about the interplay with other measurements of CP violation and the search for new physics. As far as the latter aspect is concerned, we point out that the B⁰ _q→D_q ⁺D^- _q system provides a setting for the determination of the B⁰ _q–B̄⁰ _q mixing phases (q∈{d,s}) that is complementary to the conventional B⁰ _d→J/ψK_S and B⁰ _s→J/ψφ modes with respect to possible new-physics effects in the electroweak penguin sector.     

Incorporation of deep centres in VPE GaAs

The incorporation of deep levels in high purity vapour phase epitaxy (VPE) GaAs is studied as a function of the crystal growth conditions. Two deep levels, at 0.4 eV and 0.75 eV above the valence band, are investigated using photocapacitance. It is shown that their concentrations are always equal and vary together as a function of the AsCl₃ mole fractionX. Two regimes are observed, respectively, characterized by different variations of the total deep level concentrationN _T:N _TαX for lowX, andN _TαX⁻² for highX. In this last range,N _T andN _D are found to vary similarly. This work has been supported by the DRME.     

Rethinking the QCD collisional energy loss

It is shown that to leading order the collisional energy loss of an energetic parton in the hot quark gluon plasma reads dE/dx∼α(m_D ²)T², where the scale of the coupling is determined by the (parametrically soft) Debye screening mass. Compared to previous expressions derived by Bjorken and other authors, dE^B/dx∼α²T²ln(ET/m_D ²), the rectified result takes into account the running of the coupling, as dictated by quantum corrections beyond tree level. As one significant consequence, due to asymptotic freedom, the QCD collisional energy loss becomes independent of the jet energy in the limit E≫T. It is argued why this resummation-improved perturbative result is useful to (re-) estimate the collisional energy loss for temperatures relevant in heavy ion phenomenology. PACS 12.38.Mh; 25.75.-q     

Exact solution of two-species ballistic annihilation with general pair-reaction probability

The reaction processA + B → ∅ is modeled for ballistic reactants on an infinite line with particle velocitiesυ _A =c andυ _B = -c and initially segregated conditions, i.e., allA particles to the left and allB particles to the right of the origin. Previous models of ballistic annihilation have particles that always react on contact, i.e., pair-reaction probabilityp = 1. The evolutions of such systems are wholly determined by the initial distributions of particles and therefore do not have a stochastic dynamics. However, in this paper the generalization is made to p< 1, allowing particles to pass through each other without necessarily reacting. In this way, theA andB particle domains overlap to form a fluctuating, finitesized reaction zone where the product ∅ is created. Fluctuations are also included in the currents ofA andB particles entering the overlap region, thereby inducing a stochastic motion of the reaction zone as a whole. These two types of fluctuations, in the reactions and particle currents, are characterised by theintrinsic reaction rate, seen in a single system, and theextrinsic reaction rate, seen in an average over many systems. The intrinsic and extrinsic behaviors are examined and compared to the case of isotropically diffusing reactants     

Laser photoacoustic spectroscopy of iodine molecule: Single and two-photon absorption

Photoacoustic spectroscopy of iodine molecule has been studied in gas phase using nitrogen laser-pumped tunable dye laser. The experiment yielded the vibrational spectrum corresponding toX ¹Σ⁺(0 _g ⁺ )→B ³Π(0 _g ⁺ ) transition up to the convergence limit. The photo-acoustic spectrum in the region 17580–18850 cm⁻¹ is presented along with the vibrational analysis. Five of the vibrational bands reported earlier by Venkateswarlu, Kumar and McGlynn have been partially resolved and the structure of one of them has been analyzed and shown to be due to an overlap of (14, 2) and (12, 1) bands. The analysis was based on a comparison with the highly resolved spectrum of Gerstenkorn and Luc. The structure observed in the region 20200–20750 cm⁻¹ which is beyond the convergence limit of the transitionX ¹Σ⁺(0 _g ⁺ )→B ³Π(0 _u ⁺ ) has been analyzed as due to two-photon absorption. Most of the bands could be assigned to two transitions both originating in the ground state and terminating in two different electronic states 1 _g andE(0 _g ⁺ ), atT _e=40821 cm⁻¹ (orT ₀=41355 cm⁻¹) andT _e=41411 cm⁻¹ (orT ₀=41355 cm⁻¹) respectively.     

Memorino on the ‘1/2 versus 3/2 puzzle’ in B̄→lν̄X<Subscript>c</Subscript> – a year later and a bit wiser

The OPE treatment that has been so successful in describing inclusive B̄→lν̄X_c decays yields sum rules (in particular the Uraltsev sum rule and its higher moments) implying the dominance of the P wave j_q=3/2 charm states in X_c over their j_q=1/2 counterparts. This prediction is supported by other general arguments as well as quark model calculations, which illustrate the OPE results, and by preliminary lattice findings. Its failure would indicate a significant limitation in our theoretical understanding of B̄→lν̄X_c. Some experimental issues have been clarified since a preliminary version of this note had appeared; yet, the verdict on the composition of the final states beyond D, D^* and the two narrow j_q=3/2 resonances remains unsettled. Establishing which hadronic configurations – D/D^*+π,D/D^*+2π,... – contribute, what their quantum numbers are, and their mass distributions will require considerable experimental effort. We explain the theoretical issues involved and why a better understanding of them will be of considerable value. Having significant contributions from a mass continuum distribution below 2.5 GeV raises serious theoretical questions for which we have no good answer. Two lists are given, one with measurements that need to be done and one with items of theoretical homework. Some of the latter can be done by employing existing theoretical tools, whereas others need new ideas.     

The temperature dependence of the spectral width of singlet oxygen dimole emission

In the temperature range of T = 150–400 K, the dependence of spectral widths (cm⁻¹) on temperature, 182 + 0.38(±0.01)T and 217 + 0.48(±0.01)T, respectively, has been obtained for dimole emission of O₂(a, 0) + O₂(a, 0) → O₂(X, 1) + O₂(X, 0) + hν (λ = 703 nm) and O₂(a, 0) + O₂(a, 0) → O₂(X, 0) + O₂(X, 0) + hν (λ = 634 nm). It was shown that the ratio of dimole emission rate constants does not depend on temperature in the range of 150–400 K and is 1.06 ± 0.01.     

B→K transition form factor up to $\mathcal{O}(1/m^2_b)$ within the kT factorization approach

We apply the k_T factorization approach to deal with the B→K transition form factor F^B→K _+,0(q²) in the large recoil regions. The B-meson wave functions Ψ_B and Ψ̄_B that include the 3-particle Fock states’ contributions are adopted to give a consistent PQCD analysis of the form factor up to . It has been found that the two wave functions Ψ_B and Ψ̄_B can give sizable contributions to the form factor and should be kept for a better understanding of the B-meson decays. Next the contributions from different twist structures of the kaon wave function are discussed, including SU_f(3)-breaking effects. A sizable contribution from the twist-3 wave function Ψ_p is found, whose model dependence is discussed by taking two groups of parameters that are determined by different distribution amplitude moments obtained in the literature. It is also shown that F^B→K _+,0(0)=0.30±0.04 and [F^B→K _+,0(0)/F^B→π _+,0(0)]=1.13±0.02, which are more reasonable and consistent with the light-cone sum rule results in the large recoil regions. PACS  12.38.Aw; 12.38.Bx; 13.20.He; 14.40.Aq     

Inclusive production of neutral vector mesons in hadronic Z decays

A data sample of about 3.0 million hadronicZ decays collected by the ALEPH experiment at LEP in the years 1991 through 1994 is used to make an inclusive selection of B hadron events. In this event sample 4227±140±252B* mesons in the decayB*→Bγ and 1944±108±161B** _u,d mesons decaying into a B meson and a charged pion are reconstructed. Here and in the followingB** _u,d denotes the eightL=1(bū) and (bd) states and their charge conjugate. For the well establishedB* meson the following quantities are obtained:ΔM=M _B*−M_B=(45.30±0.35±0.87) MeV/c² andN _B*/(N _B+N _B*)=(77.1±2.6±7.0)%. The angular distribution of the photons in theB* rest frame is used to measure the relative contribution of longitudinalB* polarization states to beσ _L/(σ _L+σ _T)=(33±6±5)%.     

Ratio of the color suppressed decays Λ b →ΛJ/ψ andB 0→KJ/ψ

Based on the factorization approximation, we have estimated the ratio of the branching fractions for the color suppressed nonleptonic decays Λ _b →ΛJ/ψ andB ⁰→KJ/ψ. Treating thes-quark as heavy, we have used the HQET to calculate the hadronic matrix elements. The mesonic Isgur-Wise function is calculated in the quark model whereas for the baryonic IW function we have employed the bound state soliton picture. The results obtained agree very well with the recent CDF experimental data.     

Analytic Bethe ansatz for fundamental representations of Yangians

We study the analytic Bethe, ansatz in solvable vertex models associated with the YangianY(X _r ) or its quantum affine analogueU _q (X _r ⁽¹⁾ ) forX _r =B _r ,C _r andD _r . Eigenvalue formulas are proposed for the transfer matrices related to all the fundamental representations ofY(X _r ). Under the Bethe ansatz equation, we explicitly prove that they are pole-free, a crucial property in the ansatz. Conjectures are also given on higher representation cases by applying theT-system, the transfer matrix functional relations proposed recently. The eigenvalues are neatly described in terms of Yangian analogues of the semi-standard Young tableaux.     

The collisional energy transfer between the D1Π and d3Π states of the NaK dimer induced by argon buffer gas

1 Π→X¹Σ⁺ transitions and the continuum spectrum of d³Π→a³Σ⁺ transitions of the NaK dimer in a heat pipe could be observed in the range of 500–700 nm. The collision-induced enhancement effects of the intensities I_d→a and the quenching effect of the intensities I_D→X by collisions with argon buffer gas at different pressures were measured experimentally. Based on the stationary collisional model and lifetime measurements, the quenching cross sections and cross sections for collision-induced energy transfer between the D¹Π and d³Π states could be estimated. Received: 13 January 1997/Revised version: 20 October 1997     

Optical absorption spectrum of Cr3+ in natural ruby

Two sharp line-like bands calledN andR lines on the red side, a close doublet (B lines) on the violet side and two broad bands are observed for natural ruby. At liquid air temperature the splitting ofR line was found and also three sharp-bands calledR, R′ andB lines are identified with spin-forbidden transitions of² E,² T ₁ and² T ₂. The two broad bands calledU band andY band are assigned accordingly to the spin-allowed transitions⁴ T ₂ and⁴ T ₁ respectively. The observed bands of natural ruby have been attributed to Cr³⁺ ion in an octahedral environment with trigonal distortion. The crystal field parameters which gave a good fit to the observed band positions areB=732 cm⁻¹,C=4.25B,Dq=1830 cm⁻¹,V=−1996 cm⁻¹ andλ=34 cm⁻¹.     

B-decay CP-asymmetries in SUSY with a U(2)3 flavour symmetry

We study CP asymmetries in rare B decays within supersymmetry with a U(2)³ flavour symmetry, motivated by the SUSY flavour and CP problems, the hierarchies in the Yukawa couplings and the absence so far of any direct evidence for SUSY. Even in the absence of flavour-blind phases, we find potentially sizable CP violating contributions to b→s decay amplitudes. The effects in the mixing-induced CP asymmetries in B→ϕK _S and B→η′K _S , angular CP asymmetries in B→K ^∗ μ ⁺ μ ⁻ and the direct CP asymmetry in B→X _s γ can be in the region to be probed by LHCb and next generation B factories. At the same time, these effects in B decays are compatible with CP violating contributions to meson mixing, including a non-standard B _s mixing phase hinted by current tensions in the CKM fit mostly between S_yKS, e_KS_{\psi K_{S}}, \epsilon_{K} and DM_Bs/DM_Bd\Delta M_{B_{s}}/\Delta M_{B_{d}}.