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1.
按照测量不确定度评定的通用规则,建立了数学模型,对氢化物发生-原子荧光光谱法测定食品添加剂磷酸中铅的测量不确定度进行了评定,分析了方法中的不确定度分量及其来源,计算了各分量的不确定度,最后计算出了检测结果的合成标准不确定度和扩展不确定度。检测结果和不确定度评定结果为(0.190±0.006)mg/kg,k=2。结果表明标准溶液配制是氢化物发生-原子荧光光谱法测定食品添加剂磷酸中铅含量不确定度的主要影响因素。  相似文献   

2.
建立氢化物发生-原子荧光法测定酱油中的总砷含量的不确定度模型,分析了方法中的不确定度分量及其来源,计算了各分量的不确定度,最后计算出了检测结果的合成标准不确定度和扩展不确定度.评定结果表明,校准曲线的线性回归和测量的重复性是影响该方法的不确定度的主要因素.  相似文献   

3.
孙红英 《光谱实验室》2012,29(2):992-995
采用直读光谱分析法测定高锰钢中锰含量,建立分析方法,并对锰测定值的不确定度分项进行了评估。结果表明,影响测量结果的主要不确定度分量为:校准曲线的不确定度、标样定值的不确定度、标准样品测量过程所产生的不确定度及样品测量过程随机性的不确定度,控制影响不确定度的主要因素,可以减少测量不确定度,保证分析结果的准确性,该方法也适合高锰钢中其他元素的评定。  相似文献   

4.
针对聚氨酯泡塑吸附-原子吸收光谱法测定金矿石中金的分析测定过程和数学模型,找出了影响测量不确定度的主要来源,对各不确定度分量进行了评定,并计算得到了合成标准不确定度和扩展不确定度,给出了相应的测定结果表示法.  相似文献   

5.
周韬  宋慧坚 《光谱实验室》2005,22(3):539-543
通过对影响测定结果的不确定度因素的分析和量化,评价了火焰原子吸收光谱法测定水样中铁的不确定度。计算得水中铁含量测定结果的扩展不确定度为0.015mg/L(veff=17)。  相似文献   

6.
张荷丽 《光谱实验室》2012,29(3):1501-1505
建立了原子吸收光谱法测定婴幼儿奶粉中铁含量不确定度评定的数学模型,分析了检测过程中不确定度来源并计算了各不确定度分量,得出合成标准不确定度和扩展不确定度。在婴幼儿奶粉中铁含量的测定中,测量值为8.156mg/100g,其扩展不确定度为0.11mg/100g,k=2。影响铁含量测量结果不确定度的最大因素是校准曲线拟合引入的不确定度。  相似文献   

7.
针对原子吸收光谱法测定金矿石中金的实验过程,详细地分析了引入的不确定度来源。测定结果的不确定度由标准配制、样品制备、曲线拟合、样品均匀性及检验重复性4个部分引入的不确定度分量组成,样品制备过程中考虑了活性炭吸附率的影响,求得测量结果的标准不确定度和扩展不确定度分别为0.043μg/g和0.09μg/g。  相似文献   

8.
王静  耿哲  赵莉 《光谱实验室》2013,30(5):2632-2635
根据GB/T15555.6-1995火焰原子吸收法测定固体废物中的铬,对影响测定结果的各不确定度来源进行了分析,计算不确定度.结果显示样品的校准曲线的拟合和校准曲线的配制过程是影响不确定度的主要因素.该样品测定结果为0.779土0.06mg/L.  相似文献   

9.
对氢化物发生-原子荧光法测定啤酒中总砷含量的不确定度进行了评定。分析了方法中不确定度的来源,测量结果的不确定度由样品制备、校准曲线、重复性试验、平行试验等所引入的不确定度分量组成。评定结果表明,校准曲线是影响该方法不确定度的主要因素。  相似文献   

10.
对荧光增白剂CXT紫外吸收测量不确定度进行了评估,分析了整个检测过程中不确定度的来源,测量结果的不确定度由重复性测量、仪器的校准及仪器显示读数的分辨力等所引入的不确定度分量组成.评估结果表明,重复性测量是影响该方法不确定度的主要因素.  相似文献   

11.
以色谱指纹图谱信息量为指标,用正己烷为萃取剂,采用均匀设计法优化了萃取时间、萃取温度和泵入萃取池溶剂量占池体积百分数3个因素对加速溶剂萃取法萃取烟叶挥发性成分的影响,由此提出了一快速测定烟叶挥发性成分的方法。所得萃取液用气相色谱-质谱联用(GC-MS)检测后,用NIST质谱数据库检索进行定性分析,共鉴定出44种化学组分,占挥发油总量的88.87%,所得结果能为烟叶化学成分的研究提供有利的科学依据。  相似文献   

12.
In this work we propose a method for scatter compensation in single photon emission computed tomography imaging, by which we can estimate the scatter components in projections in high speed with good accuracy. The method is that we first estimate the scatter components in projections based on scatter response kernels by one time of ordered subsets expectation maximization iterative reconstruction, and then subtract the estimated scatter components from the projections and complete reconstruction by filtered back-projection method. The principle is that the image corresponding to the scatter components in projections consists largely of low-frequency components of an activity distribution; these low-frequency components will converge faster than the high ones in iterative reconstruction. Therefore, we can estimate the low-frequency component image before the image converges with the high-frequency ones, and obtain the scatter components by re-projecting the low-frequency component image with scatter response kernels. The effects of the proposed method were compared with the dual- and triple-energy window methods using experimental measurements. The results show that good accuracy in estimated scatter components, good uniformity of scatter compensation at the center and the side of an object, and good noise property can be acquired by this method.  相似文献   

13.
The aim of this paper is to examine the reliability of erasable programmable read only memory (EPROM) and electrically erasable programmable read only memory (EEPROM) components subjected to the influence of gamma radiation. This problem is of considerable significance for both military industry and space technology. We present total dose results for the NM27C512 8F85 EPROM and M24128 – B W BN 5 T P EEPROM components. There is evidence that EPROM components radioactive reliability is better than that of EEPROM components. Furthermore, the changes EPROM's undergoes are reversible, so that after erasing process and reprogramming all EPROM components are fully functional. On the other hand, EEPROM's changes are irreversible and when subjected to the influence of gamma radiation, all EEPROM components become permanently nonfunctional. The obtained results are analyzed and explained via the interaction of gamma radiation with oxide layers.  相似文献   

14.
In this paper, an analytical approach for nonlinear forced vibration of a multi-degree-of-freedom system is proposed using the component mode synthesis method. The whole system is divided into some components and a nonlinear modal equation of each component is derived using the free-interface vibration modes. The modal equations of all components and the conjunction conditions are solved simultaneously, and then the modal responses of components are derived. Finally, the dynamic responses of the whole system can be obtained. The degrees of freedom of modal equations can be reduced when the lower vibration modes are only adopted in each component. As a numerical example, a nine-degree-of-freedom system is considered, in which all spring have cubic type nonlinearity. As a result, it is shown that when there are no rigid modes in components, the compliance by the proposed method agrees very well with the exact one even if the lower vibration modes of components are only adopted. The other hand, in the case with rigid modes in components, the compliance has a little error compared with the exact result. It is recognized that the method proposed is very effective in the case without rigid modes in components for the actual application.  相似文献   

15.
The detection of multicomponent signals for which the components are not equidetectable is precisely investigated as a function of the level difference ΔL(i∕j) between components. The detection thresholds are determined for a seven-tone complex signal with random starting phases masked by white noise. Level differences between the components are examined. A model for non-equidetectable conditions based on the statistical summation model is described. The improvement in detection is calculated from the level difference between components that is related to the thresholds for single components. The model predictions are in accordance with the experimental results.  相似文献   

16.
采用热脱附-气相色谱/质谱联机技术(TD-GC/MS)分析了芦苇杆粉末在不同环境温度下的挥发物释放行为。结果表明:芦苇杆粉末在40℃及160℃的挥发物中,主要有益成分分别为主要有害成分的4.43倍和5.13倍,环境友好性良好;在60℃及90℃的挥发物中,主要有益成分比例也比主要有害成分高,90℃时的有益成分为有害成分的2.45倍,环境友好性较好。以芦苇杆粉末为基材,在木质素软化温度点和木质材料碳化温度点之间(150—180℃)实施高压无胶模塑成形工艺制备木质粉末基复合材料必将体现出良好的环境友好性。  相似文献   

17.
采用同时蒸馏萃取法,从鸢尾根中提取致香成分,对其主要化学成分进行GC/MS分析,用鸢尾根致香成分进行了造纸法再造烟叶加香试验,并将加香后的造纸法再造烟叶样品添加在卷烟配方中进行评吸。结果表明,鸢尾根致香成分中共鉴定出17个化合物,主要含有癸酸和棕榈酸;鸢尾根致香成分能改善造纸法再造烟叶的烟气品质,并具有降低刺激的作用,加香后的造纸法再造烟叶在卷烟中应用也具有相同的效果。  相似文献   

18.
采用红外光谱和紫外-可见谱线组法全面分析了广西特产罗汉果,并将紫外-可见谱线组法延伸至红外光谱,采集了4种浸泡液的红外谱图。罗汉果红外光谱中出现了羟基、亚甲基、链状羧酸酯羰基、酰胺和苷键的特征吸收峰,表明其中主要含有油脂、蛋白质和甜甙等成分。4种不同极性溶剂水、乙醇、氯仿和石油醚浸泡液的紫外-可见谱线中吸收峰个数、峰形和峰位都存在很大差别,全面反映出罗汉果所含成分的整体效应。4种浸泡液的红外谱图中分别出现了不同成分的特征峰,说明水浸泡液中含有蛋白质和甜甙等极性分子,乙醇浸泡液中既含有蛋白质、甜甙,也含有油脂等脂溶性成分,氯仿浸泡液中除了含有大量油脂,还含有少量蛋白质等成分,而石油醚浸泡液中只含有油脂等脂溶性成分。  相似文献   

19.
HL-2A装置的第一壁由石墨构件、Cu偏滤器靶板和AISI 304LN不锈钢真空室内壁组成。石墨构件总重量为44kg,覆盏面积为2.80,覆盖率为2.2%。由于HL-2A装置所用石墨件材料均为历经长期托卡马克实验和长期暴露大气的石墨材料,因此石墨构件的处理效果显得更为重要。介绍了EK98、SMF-800石墨材料、ASDEX装置用CFC、国产CFC的研究结果和HL-2A装置第一壁石墨材料预处理及其结果。  相似文献   

20.
李婵  万晓霞  吕伟 《发光学报》2019,40(5):673-679
因光学特性(吸收系数与散射吸收)与组分比例不呈严格的线性关系,基于K-M理论的配色模型无法保证比例预测精度,针对上述问题,建立了油墨组分比例预测模型与方法。首先利用与组分比例具有强线性相关性的特征波长处的光谱反射率倒数值替换K-M配色理论中的吸收系数与散射系数,引入非线性项,构建油墨混合呈色模型;然后在此基础上建立油墨组分比例预测模型。以两组二元基色油墨混合样本为例,对提出的油墨组分比例预测模型及方法进行验证。实验结果表明,文中方法可预测获得与真实结果较为接近的组分比例,两组实验样本的预测平均偏差分别为1.57%和3.6%,可为目标样油墨组分比例预测提供一种新的方法。  相似文献   

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