一阶模的滤除及在Y分支和多模干涉结构中的应用

Y分支和多模干涉结构广泛应用于平面光波导器件中，在这些器件中，Y分支和多模干涉结构输出对称性具有重要意义。引入Y分支和多模干涉结构输出的不对称主要原因是这两种结构中产生了一阶导模，设计一种新的耦合器结构，在这个结构中．两根单模波导分别放置在一根多模波导两边，并且单模波导的传播常量与多模波导的一阶模的传播常量相同，这种结构可以将一阶导模滤除。在Y分支和多模干涉结构中使用了这种结构，模拟结果表明，采用这种耦合器的Y分支和多模干涉结构具有非常好的输出对称性。     

新型低损耗氧化硅Y分支光波导

提出了一种新型的Y分支光波导结构。该Y分支波导由一个人射波导,一个过渡波导和一对出射波导组成。过渡波导用于改善放射基模与出射偶对称模之间的场分布匹配,有效地提高了功率耦合效率,降低了分支耦合损耗,波束传播法（BPM）数字模拟计算表明,该结构在1．31μm和1．55μm波长下可分别达到0．041dB和0．052dB分支耦合损耗。实验中用等离子化学汽相沉积（CVD）技术制备了SiO2分支波导样品,在上述两波长下分别测得分支耦合损耗为0．08dB和0．09dB,基本达到了设计指标。     

质子交换Y分支光波导弯曲损耗研究

对采用退火质子交换技术(APE)制备的具有正弦型弯曲和余弦型弯曲两种不同的S型弯曲的Y分支光波导,利用宽角有限差分光束传播法,就过渡区长度、波导表面折射率增量、掩模版开口宽度等对波导弯曲损耗的影响进行了研究。结果表明,两种S弯曲下的Y分支波导的弯曲损耗,随波导结构参数的变化基本上是相同的,但二者的表现并不完全一致。数值计算结果为相应波导器件的设计和制备提供了一定的参考。     

聚合物Mach-Zehnder脊形波导的优化设计

 利用变分有效折射率法计算了TE基模和高阶模的光场分布,计算结果表明,该方法计算量小,精度高,为聚合物集成光电子器件中脊形光波导的理论分析与优化设计提供了简单高效的途径。利用有限差分束传播法对Mach-Zehnder波导的传播及损耗特性进行了理论分析,得到了不同Y分支角、波导宽度、波导间距时波导传输功率与距离的关系,优化得到的结构参数为：Y分支角1.1°,脊宽5 μm,波导间距20 μm。     

4通道交叉型二氧化硅光波导延迟线阵列的设计与制备

设计并制备了一种高集成度、低成本、低损耗4通道交叉型二氧化硅光波导延迟线阵列。利用BPM软件对交叉结构光波导延迟线的Y分支的损耗、弯曲损耗进行数值模拟。综合考虑器件尺寸和损耗参数,设计交叉型延迟线结构的弯曲半径最小为1 500 μm,引入优化的锥口Y分支结构和垂直相交波导结构。采用标准半导体制作工艺制备器件,测试得到了器件的红外输出光斑,延迟线延迟时间分别为0、113、226和339 ps。4通道二氧化硅延迟线阵列能实现相邻通道相等的延迟时间间隔,且可通过集成实现延迟时间的增加,同时输出端可以与光纤阵列集成。     

95 GHz TE03模回旋管内置渐变波导设计

在耦合波理论的基础上,结合波导渐变曲线给出了普适高阶渐变波导设计方法,研究了95 GHz回旋管内置 TE03模式改进Dolph-Chebychev渐变波导。采用编制的数值计算程序进行优化,得到了可靠的最优几何参量,设计出了紧凑的95 GHz渐变波导。经全电磁场仿真验证,该内置渐变输出结构对杂模的抑制达30 dB,满足设计要求。回旋管的热测实验中测出的模式样图表明,所设计的内置渐变波导有效地实现了回旋管内径变化。该方法可以高效地指导高阶过模圆波导渐变结构的设计。     

弯曲波导研究进展及其应用

本文主要分析了弯曲波导损耗机理,包括传输损耗、辐射损耗、模式转换损耗。重点综述了设计低损耗弯曲波导的方法,包括波导材料、弯曲波导的曲线形状、波导种类、脊型波导的宽度、脊高、弯曲半径、模场分布、弯曲波导曲线形状和其他新型波导结构等。简要概括了近年来设计和制备低损耗弯曲波导的代表性工作。介绍了弯曲波导在集成光学中的应用。通过对弯曲波导的损耗及耦合机制理论的不断完善,实现光在较小弯曲半径的低损耗传输,从而提高集成光学的集成度是弯曲波导今后的发展趋势。     

功率容量大于1GW的组合式旋转关节

用耦合波理论分析了过模圆波导中不同模式之间的转换和波导弯曲半径之间的关系,研制了弯曲角度为90°的过模圆波导弯头,设计了一种结构简单的TM01过模圆波导旋转结构。对圆波导弯头和旋转结构的高功率测试证明,它们在X波段功率容量均大于1 GW,微波传输效率均大于93%。在此基础上,提出了一种组合式旋转关节,该关节能够在方位和俯仰上实现360°旋转,可应用于高功率微波的发射天线。     

过模结构0.14 THz高功率脉冲探测器研制

基于n型硅在强电场下的热电子效应,初步研制了一种采用过模结构的0.14 THz高功率太赫兹脉冲探测器。该探测器由基模波导WR6、过渡波导、过模波导WR10, n型硅探测芯片和偏置恒流源组成。模拟分析了探测器的工作过程,给出了相对灵敏度表达式,结果表明过模探测器能很好地工作在TE10模式。合理设计了探测芯片的结构参数和加工工艺,完成了探测芯片的加工和探测器样机的制作。将探测器样机在0.14 THz相对论表面波振荡器的辐射场进行了初步的验证性实验,并与二极管检波器的测量结果进行了对比分析。结果表明:过模探测器样机的响应时间在ps量级,相对灵敏度约为0.12 kW-1,最大承受功率至少为数十W,可用于0.14 THz高功率脉冲的直接探测。     

Cu2+离子注入的石英光波导的特性研究

利用Cu2+离子注入的方式在熔融石英和石英晶体上分别制备了平面光波导结构.通过棱镜耦合实验测试了两种光波导的导模特性,结果表明:在同样的注入条件下熔融石英上形成了增加型的光波导结构,而石英晶体上形成了位垒型的光波导结构.研究了退火温度对两种光波导导模折射率的影响,熔融石英光波导中导模的折射率随着退火温度的升高而降低,而石英晶体光波导中导模的折射率随着退火温度的升高先增加后降低.为了进一步分析离子注入两种材料形成光波导的微观机理,利用SRIM模拟了Cu2+离子注入两种材料的电子能量损失和核能量损失,并且模拟了两种光波导结构的折射率分布.模拟结果表明:熔融石英光波导的主要形成原因是离子注入表面的折射率大于其体材料的折射率,而石英晶体光波导的主要形成原因是离子射程末端的折射率小于其体材料的折射率.因此,在熔融石英光波导的形成中电子能量损失起主要作用,而在石英晶体光波导的形成中核能量损失起主要作用.     

Mapping of periodically poled crystals via spontaneous parametric down-conversion

A new method for characterization of periodically poled crystals is developed based on spontaneous parametric down-conversion. The method is demonstrated on crystals of Y:LiNbO₃, Mg:Y:LiNbO₃ with non-uniform periodically poled structures, obtained directly under the Czochralski growth procedure and designed for application of 1.064 μmpumped OPO in the mid-infrared range. Infrared dispersion of refractive index, effective working periods and wavelengths of OPO were determined by special treatment of frequency-angular spectra of spontaneous parametric down-conversion in the visible range. Two-dimensional mapping via spontaneous parametric down-conversion is proposed for characterizing spatial distribution of bulk quasi-phase matching efficiency across the input window of a periodically poled sample.     

Investigation on the pH-dependent binding of Eosin Y and bovine serum albumin by spectral methods

In this paper, the pH-dependent binding of Eosin Y and bovine serum albumin (BSA) was investigated by spectral methods, including resonance light scattering (RLS), absorption and fluorescence spectrometry. Due to the pH-dependent structure of Eosin Y and BSA, the interaction of BSA and Eosin Y depended on the solution pH value. Especially at pH 2.6 and 9.2, the RLS intensity of BSA was obviously enhanced in the presence of Eosin Y. However, the fluorescence intensity of BSA was quenched in the presence of Eosin Y. To fully understand the pH-dependent binding of BSA and Eosin Y, fluorescence quenching technique was introduced. Based on the fluorescence data obtained, the style of binding, the binding constant, the binding site number and the thermodynamic parameters for the interaction of BSA and Eosin Y were studied. Based on Förster non-radiation energy transfer theory, the distance between donor BSA and acceptor Eosin Y was obtained.     

BeXY、MgXY（X、Y=F、Cl、Br）与ClF3和ClOF3形成复合物的理论研究

与卤素原子相比,超卤素表现出电负性更大、结构更丰富、性质更新颖等更加丰富的特征。本文以碱土金属Be、Mg的卤化物BeXY、MgXY（X、Y=F、Cl、Br）为母体,分别与卤素氟化物ClF3、ClOF3形成的复合物为研究对象,设计了12种配合物。采用密度泛函理论研究了这些化合物的结构、垂直电离能(VDE)、绝热电离能(ADE)等性质。研究发现,配合物中存在超卤素阴离子,所表现出来的性质远远优于常见的超卤素阴离子,因此,此类化合物具有很好的应用前景。     

ITO负载单原子钇吸附NO和CO的第一性原理研究

基于密度泛函理论，对氧化铟锡(Indium Tin Oxide,ITO)表面负载单原子Y模型的表面性能进行了第一性原理计算.根据表面能计算结果可知，单原子Y最稳定负载位置为空位(H)，即确定了ITO负载单原子钇(Single-atom Y supported on ITO,Y/ITO)稳定模型.对ITO和Y/ITO表面吸附气体分子(NO和CO)模型的吸附性能进行了第一性原理计算.根据对比ITO和Y/ITO表面的吸附能和态密度计算结果可知，单原子钇负载提高了ITO表面的稳定性和吸附性能.根据对比Y/ITO表面吸附NO和CO气体分子的吸附能和态密度计算结果可知，NO和CO气体分子吸附均为自发行为，过程放热.且NO气体分子更容易吸附在Y/ITO表面，即Y/ITO对NO气体分子更敏感.     

First-principles investigation of structural,elastic, electronic and magnetic properties of Be0.75Co0.25Y (YS,Se and Te) compounds

We have theoretically investigated the structural, elastic, electronic and magnetic properties of Be_0.75Co_0.25Y (YS, Se and Te) alloys, in their zinc-blend phase. This study is carried out by using the full-potential augmented plane wave plus local orbitals method within the density functional theory. Foe computing the exchange-correlation potential, the Wu and Cohen generalized gradient approximation is employed to calculate structural and elastic properties whereas the modified Becke and Johnson potential local density approximation is utilized to examine electronic and magnetic properties. By minimizing the total energy in paramagnetic (PM) and ferromagnetic (FM) phases, it is found the studied compounds are stable in FM structure. The mechanical behavior of the studied compounds is reported with the calculation of shear modulus, Young's modulus, and Poisson's ratio provides. Such mechanical aspects might be useful for the experimentalists to study the mechanical properties upon alloying BeY compounds with Co. We also compute electronic structures, density of states (total and partial), pd-exchange splitting and magnetic moments. Moreover, bond nature is studied by estimating the spin polarized charge densities of Be_0.75Co_0.25Y (YS, Se and Te).     

Highly Sensitive Fluorescent Probe for Clenbuterol Hydrochloride Detection Based on its Catalytic Oxidation of Eosine Y by NaIO4

A highly sensitive fluorescent probe for clenbuterol hydrochloride (CLB) detection has been first designed based on its catalytic effect on NaIO₄ oxidating eosine Y (R). And this environment-friendly, simple, rapid, selective and sensitive fluorescent probe has been utilized to detect CLB in the practical samples with the results consisting with those obtained by GC/MS. The structures of R and CLB were characterized by infrared spectra. The mechanism of the proposed assay for the detection of CLB was also discussed.     

Structure and Curie temperature of Y2Fe17-xCrx

The structures of Y2Fe17-xCrx are simulated by the ab initio potentials. The site preference of Cr atom in Y2Fe17 is evaluated and the order is determined as 4f, 12j, which is close to the experimental result. Based on the site preference behavior, the calculated parameters and the atom sites of Y-Fe-Cr system are studied. The result corresponds well to observed data. Further, the DOS of the relaxed structures are calculated and the variation in Curie temperature is explained qualitatively by the spin-fluctuation theory.     

钇小团簇的结构和电离势的计算

采用密度泛函DFT中的B3LYP方法，选择LANL2DZ双ζ基组，优化并得到了Y_n=(n=2—8)小团簇的基态平衡结构，同时计算出其电离势.结果表明，钇原子之间形成团簇最稳定的结构是倾向于平均配位数最大，其电离势没有“奇-偶”振荡或“幻数”效应，表明Y_n团簇光致电离开始主要发生在Y原子局域化的4d轨道上的电子而不是在5s上.对Tomasz提出的钇团簇电离势的解析式进行合理地修正，修正后电离势解析式的计算值与实验值更接近. 关键词： Y团簇 密度泛函 平衡几何结构 电离势     

First-principles study of the electronic and optical properties of the （Y,N）-codoped anatase TiO2 photocatalyst

First-principles plane-wave pseudopotential calculations are performed to study the geometrical structures,formation energies,and electronic and optical properties of Y-doped,N-doped,and(Y,N)-codoped TiO 2.The calculated results show that Y and N codoping leads to lattice distortion,easier separation of photogenerated electron-hole pairs and band gap narrowing.The optical absorption spectra indicate that an obvious red-shift occurs upon Y and N codoping,which enhances visible-light photocatalytic activity.