表面修饰的Ag2S纳米微粒的光学非线性特性

用胶体法制备了表面分别修饰六偏磷酸钠 (HMP)和 2 ,2’ 联吡啶 (BPy)的Ag2 S纳米微粒。通过背向简并四波混频实验装置对它们在单光子非共振区域的三阶光学非线性进行了实验研究 ,分别测量了两种Ag2 S纳米微粒在它们超滤液中三阶非线性极化率 χ( 3 ) 随浓度的变化 ,并拟合得到了两种纳米微粒的三阶非线性极化率。实验结果表明 ,双光子共振增强是实验中非线性极化的主要过程 ,同时实验结果也表明了局域场效应对单光子非共振三阶非线性极化率的增强作用     

C60醛类衍生物非线性光学特性研究

研究了加合不同取代基团的C60醛类衍生物的光学非线性性质。利用简并四波混频（DFMW）方法获得了C60醛类各衍生物的三阶光学非线性超级化率γ^(3)及相应的三阶光学非线性系数χ^(3)值。同时也研究了它们各自的光限幅特性。结果表明：不同的取代基对C60醛类衍生物三阶光学非线性及光限幅特性的影响不同。     

三-α-(2,4-二甲基-3-戊氧基)溴硼亚酞菁的三阶非线性光学性质研究

应用Z扫描技术，在波长为532nm、脉宽为8ns条件下，对一种新型亚酞菁配合物三-α-(2,4-二甲基-3-戊氧基)溴硼亚酞菁的三阶非线性光学特性进行了研究，结果发现，该新化合物有较强的反饱和吸收(β=3.7×10^-10 m/W)效应和非线性自聚焦折射效应(n₂=7.2×10^-11esu)，其三阶非线性极化率χ⁽³⁾=1.1×10^-11esu.分析了溴硼亚酞菁配合物特殊的锥形分子结构和重原子溴的轴向配位等因素对其三阶非线性光学性质的重要影响. 关键词： 亚酞菁 Z扫描 三阶光学非线性     

一组Dawson型多金属氧酸盐和相应的有机-无机杂多化合物的超快非线性光学响应

通过时间分辨率为115fs的超快光克尔方法测量了多金属氧酸盐K8[P2Mo4W13M(H2O)O61] (M=Mn, Co, Ni, Cu, Zn)和相应的有机-无机杂多化合物(C19H25N2)7K3[P2Mo4W13MO62]在830nm处的三阶非线性光学性质。多金属氧酸盐阴离子和相应的杂多化合物都表现出很大的三阶非线性,其中M=Cu的取代物的非线性系数要比其他小一个数量级。通过比较有机-无机杂多化合物和生成前者的反应物的值,发现杂多化合物中的电荷转移效应极大的增强了三阶非线性光学性能。     

聚苯胺/碳纳米管复合体的制备及其三阶非线性光学性能研究

通过原位吸附-受限生长聚合法成功制备了聚苯胺/碳纳米管(PANI/MWCNT)复合体.红外光谱和拉曼光谱证实了在碳纳米管(MWCNT)表面的包覆层为聚苯胺(PANI).紫外—可见吸收光谱表明随着MWCNT含量的增加PANI的吸收发生红移且强度提高.扫描电子显微镜和透射电子显微镜观察发现，PANI/MWCNT复合体直径为40—70nm，其中PANI的包覆层厚度约为15—20nm.利用四波混频方法测试它们的三阶非线性光学系数，结果发现PANI/MWCNT复合体的三阶非线性光学系数比纯PANI大，这说明在MWC 关键词： 碳纳米管 聚苯胺 复合体 三阶非线性光学系数     

替位式掺杂的富勒烯分子C77X(X=B,N原子)的非线性光学性质

采用推广的Su-Schrieffer-Heeger模型和sum-over-state方法计算了掺杂的富勒烯分子C₇₇X(X=B或N原子)的三阶非线性极化率γ.计算结果表明：1)与C₇₈相比,各C₇₇X分子的三阶非线性极化率γ的静态值均有不同程度的提高(3—40倍);2) C₇₇X的非线性动态光学响应不仅与掺杂原子有关,还与异构体种类和掺杂位置有关. 关键词：     

GeS_2-Ga_2S_3-Sb_2S_3-AgCl玻璃的三阶非线性光学特性

采用熔融-急冷法制备了(100-x)Ge20Ga5Sb10S65-xAgCl(x=0,5,10,15,20mol%)系列硫卤玻璃,测试了样品的密度、从可见到中远红外的透过性能以及折射率参量,根据Z-扫描测试原理用钛宝石飞秒激光器测试了样品的三阶非线性特性随波长变化的特性.结果表明:非线性折射率n2和非线性吸收系数β随着波长的增加而增加,AgCl含量为20mol%的样品在800nm处的非线性折射率n2=1.581×10-10esu,非线性吸收系数β=4.707cm/GW.与传统硫系玻璃相比,三阶非线性性能明显提高.     

介质内高阶非线性效应引起的超加宽现象的研究

当入射激光强度较高时(～10~(13)W/cm~2),非线性介质的五阶非线性效应巳不能忽略.前文仅考虑三阶非线性效应的影响,得到输出脉冲的非对称展宽,计算结果与实验结果基本符合.本文在前文的基础上,同时考虑三阶和五阶非线性x~(3)和x~(5)的影响,得到更好的结果.     

三种金属酞菁配合物的非线性光学性质研究

用YAG皮秒激光器 ,利用“Z scan”方法测量了三种金属钛菁配合物苯硫基钛菁锌 (C56H3 2 N8S4Zn) ,苯硫基铝钛菁 (C56H3 2 AlClN8S4) ,烷氧基铝钛菁 (C56H3 2 AlClN8O4)二甲基甲酰胺 (DMF)溶液的非线性折射率 ,并计算了三阶非线性光学极化率Χ(3 ) 。比较发现 ,不同中心离子 ,不同取代基的金属钛菁配合物的三阶非线性系数不同。文章对引起三阶非线性光学效应的机制做了初步的探讨和分析 ,并简单分析了光动力治疗过程中能量传递的分子机制     

甲酚紫三阶非线性极化率的测量

甲酚紫(Cresyl Violet)是一种常用的有机染料。H.Telle和W.Huller测量出甲酚紫在乙醇溶液中(浓度为2.0×10~(-3)mol/1)的吸收峰值波长为613nm,半宽度为68nm。我们利用简并四波混频技术(DFWM)测量了甲酚紫的三阶非线性极化率X_(?)。实验结果表明,甲酚紫具有大的三阶光学非线性。     

Effective response in nonlinear spherical coated composites under external AC and DC electric fields

By using the perturbation method,effective nonlinear direct current(DC) and alternating current(AC) responses of nonlinear composites with spherical coated inclusions randomly embedded in a host medium are studied under the action of an external electric field E a = E 0 + E 1 sin ωt + E 3 sin 3ωt with different amplitudes and frequencies.The local potentials of composites at all harmonics are given in the inclusion particles and the host regions.All effective nonlinear responses to composites and the relationship between the effective nonlinear responses at all harmonics are also deduced for the spherical coated inclusions in a dilute limit.     

The third-order optical nonlinearity of The pyrochlore phase 0.7Pb(Mg1/3Nb2/3)O3–0.3PbTiO3 thin film on quartz

The xPb(Mg_1/3Nb_2/3)O₃–(1−x)PbTiO₃ (PMNT) (with x=0.7) thin film is prepared on quartz substrates prepared using a sol–gel process. The PMNT thin film has a well-crystallized pyrochlore phase structure. The sign and magnitude of both real and imaginary parts of third-order nonlinear susceptibility χ⁽³⁾ of the thin film have been determined by the Z-scan technique performed at 800 nm with a femtosecond laser. The nonlinear refraction index coefficient γ, the nonlinear absorption coefficient β of the thin film are 1.37×10⁻¹² cm²/W and −6.73×10⁻⁸ m/W, respectively. The real and imaginary part of the third-order nonlinear susceptibility of the film are 1.06×10⁻¹⁷ and −1.65×10⁻¹⁹ m²/V², respectively. The results suggested that the nonlinearity is dominated by the refractive for the film.     

Effective AC response of nonlinear spherical coated composite

An effective nonlinear response of a nonlinear composite with spherical coated inclusions randomly embedded in a host medium under the action of an external AC electric field, ${{\bm E}}_a = {{\bm E}}_1 \sin (\omega t) + {{\bm E}}_3 \sin (3\omega t)$, is investigated using a perturbation method. The local potentials of the composite at higher harmonics are given both in the region of local inclusion particles and in the local host region under the external AC electric field. All effective nonlinear responses of the composite and the relationship between the effective nonlinear responses at the fundamental frequency and third harmonics are also studied for spherical coated inclusion in a dilute limit.     

一类非线性方程的compacton解及其移动compacton解

研究一类非线性方程,即广义Camassa-Holm方程C(n):ut+kux+β1u\{xxt\}+β2u\{n+1\}x+β3uxun\{xx\}+β4uun\{xxx\}=0.通过四种拟设得到丰富的精确解，特别是当k≠0时得到了com pacton解,当k=0时得到了移动compacton解.最后利用线 性化的方法得到了其他形式的广义Camassa-Holm方程的compacton解. 关键词： 广义Camassa-Holm方程 compacton解 移动compacton解     

New Soliton Solutions with Compact Support for a Family of Two-Parameter Regularized Long-Wave Boussinesq Equations

Searching for special solitary wave solutions with compact support is of important significance in soliton theory. In this paper, to understand the role of nonlinear dispersion in pattern formation, a family of the regularized longwave Boussincsq equations with fully nonlinear dispersion (simply called R(m, n) equations), utt + a( un )xx + b(um )xxtt = 0(a, b const.), is studied. New solitary wave solutions with compact support of R(m, n) equations are found. In addition we find another compacton solutions of the two special cases, R(2, 2) equation and R(3, 3) equation. It is found that the nonlinear dispersion term in a nonlinear evolution equation is not a necessary condition of that it possesses compacton solutions.     

Damping of internal soliton modes in media with quadratic nonlinearity

Optical solitons in media with quadratic nonlinearity and frequency dispersion are theoretically analyzed. Internal soliton modes and the rate of their radiative damping as a function of detuning from the phase-matching condition and the nonlinear shift of phase velocity for different soliton dimensions (d=1, 2, 3) are found. The length of a nonlinear medium required to form a stationary soliton is determined.     

磁绝缘传输线振荡器中辐射场的非线性行为

 导出了磁绝缘传输线振荡器(MILO)中辐射场的非线性演化方程，并讨论了在临界值点附近可能出现非线性不稳定解的条件。结论是：(1)非线性增长速率与线性增长速率的比值g<1.2，且远离g+γ=1(γ为非线性相位增长率与线性相位增长率的比值)点时，出现非稳定解的失谐量临界值很小，而线性增长速率临界值临界值很大，容易出现非稳定解；(2)当g≥1.2时，任意小的失谐量都可以使场出现非稳定解；(3)线性增长速率越大，越不容易出现非稳定解。     

磁绝缘传输线振荡器中辐射场的非线性行为

导出了磁绝缘传输线振荡器 (MILO)中辐射场的非线性演化方程 ,并讨论了在临界值点附近可能出现非线性不稳定解的条件。结论是 :(1)非线性增长速率与线性增长速率的比值g <1.2 ,且远离 g γ =1(γ为非线性相位增长率与线性相位增长率的比值 )点时 ,出现非稳定解的失谐量临界值很小 ,而线性增长速率临界值临界值很大 ,容易出现非稳定解 ;(2 )当 g≥ 1.2时 ,任意小的失谐量都可以使场出现非稳定解 ;(3)线性增长速率越大 ,越不容易出现非稳定解     

Spectral characteristics and nonlinear studies of methyl violet 2B dye in liquid and solid media

Solid-state dye-doped polymers are attractive alternatives to the conventional liquid-dye solutions. In this paper, the spectral characteristics and nonlinear properties of the dye Methyl violet 2B has been studied. The third-order nonlinear optical properties of Methyl violet 2B dye in ethanol and a dye-doped polymer film were measured by the Z-scan technique. This material exhibits a negative optical nonlinearity. The dye exhibited a nonlinear refractive coefficient (n ₂ = ?4.14 × 10^?7 and ?4.291 × 10^?7 cm²/W in liquid and solid media, respectively), nonlinear absorption coefficient (β = ?4.634 × 10^?3 and ?4.66 × 10^?3 cm/W in liquid and solid media, respectively), and susceptibility (χ⁽³⁾ = 1.88 × 10^?5 and 1.963 × 10^?5 esu in liquid and solid media, respectively). These results show that Methyl violet 2B dye has potential applications in nonlinear optics.