共查询到17条相似文献,搜索用时 139 毫秒
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应用单次碰撞的直接Monte Cado方法计算能量范围从100 ev~10 keV的电子在固体Al,Si,Au表面的背散射系数,其中低能电子在固体中的弹性散射和非弹性散射截面分别应用Mott散射截面和Bom近似下的广义振子强度计算模型得到.通过与压缩历史Monte Carlo方法的模拟计算结果及实验值的比较,结果表明,对于100 eV~10 keV 范围的低能区电子,采用直接方法计算得到的电子背散射系数与实验值符合较好,直接方法比压缩历史方法更适合于能量在10 kev以下的电子输运计算. 相似文献
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利用Born近似可以计算高能电子与原子或离子碰撞激发的微分截面和总截面。微分截面正比于广义振子强度。电子碰撞过程可将靶原子或离子激发到无数个束缚态以及相应的连续态。量子亏损理论能够统一处理这些激发态;因此可定义广义振子强度密度——即每单位激发能内的广义振子强度。我们计算了Li的等电子系列Li,Be+,B++,C3+,Ne7+,Na8+,K16+等从基态到S,P,D,F通道的激发的广义振子强度密度,总结了类Li等电子系列离子的广义振子强度密度的标度关系。
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为了提高原子分子动力学参数的测量精度,本文把气体相对流量技术应用到快电子碰撞研究中. 并且在此基础上测量了氙原子6s激发的广义振子强度,所得结果在小动量转移区间与前人的结果符合很好,表明气体相对流量技术在电子碰撞方法中的适用性. 大动量转移区间6s的表观广义振子强度对电子碰撞能量的依赖行为,说明500eV的电子碰撞能量还不满足一阶玻恩近似条件. 与Hartree-Fock方法相比,考虑电子关联效应更全面的随机相移近似计算结果与本文的实验结果符合更好,说明对于像Xe这样的重原子,电子关联效应十分重要. 相似文献
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Heloisa Maria Boechat-Roberty Elmar O. Uhl Flavio N. Rodrigues Maria Cristina A. Lopes Maria Luiza M. Rocco Carlos A. Lucas Alexandre B. Rocha Carlos E. Bielschowsky Gerardo Gerson B. de Souza 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2013,67(2):1-6
Electron energy-loss spectra for the butadiene molecule were measured in the scattering angular range of 2.0° to 8.0°, in an energy-loss range from 2 to 50 eV, using 1000 eV incident electrons. The absolute generalized oscillator strength (GOS) and inelastic cross section have been determined for the \hbox{$\tilde{\rm X}^{1}$}?X1A g → 11B u transition. The absolute elastic differential cross section was also determined spanning an angular range from 2.0° to 40.0°. From a small angle electron energy-loss spectrum, the optical oscillator distribution (photoabsorption spectrum) for the butadiene molecule was obtained in the 2 to 100 eV photon energy range. Accurate ab initio calculations have been performed, within the First Born Approximation, for generalized oscillator strength (GOS) and excitation energies for the \hbox{$\tilde{\rm X}^{1}$}?X1A g → 11B u and \hbox{$\tilde{\rm X}^{1}$}?X1A g → 21A g transitions. Our results emphasize the importance of using highly correlated wavefunctions and accurate methodologies in the calculation of the GOS for electron impact-induced electronic transitions in molecules. 相似文献
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Experimental and theoretical investigations of absolute optical oscillator strengths for valence excitations of nitric oxide 下载免费PDF全文
The absolute optical oscillator strength density spectra of nitric oxide in the energy region of 5.0-22.0 eV have been measured by a high-resolution fast-electron energy loss spectrometer. With the calculated results obtained by the multiscattering self-consistent-field method and channel characteristics, the strongly overlapped spectra in the energy region of 7.5-9.3 eV have been analysed and the corresponding partially vibrationally resolved optical oscillator strengths have been estimated from the experimental spectra. 相似文献
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R. Müller-Fiedler P. Schlemmer K. Jung H. Ehrhardt 《Zeitschrift für Physik A Hadrons and Nuclei》1985,320(1):89-94
Triple differential cross sections have been measured for electron impact ionization of helium at 256 eV collision energy, 3 eV energy of the slow outgoing electrons and scattering angles of the fast outgoing electrons of 4°, 6°, 8°, and 10°. The data have been put on absolute scale by extrapolating the generalized oscillator strength to zero momentum transfer. In this optical limit the triple differential cross sections can be normalized by using the well-known cross sections for photoionization. The experimental data are compared with results of different theoretical approaches. For nearly all calculated curves rather good agreement with the measurements is obtained for the relative shape of the binary peak, while often its absolute cross section is overestimated. Concerning the recoil peak, larger discrepancies are found with respect to both, relative shapes and cross sections. A perceptible improvement can be stated for calculations which have been performed in a distorted wave approximation and in second Born approximation. 相似文献
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We analyze new experimental and theoretical results for photon and electron impact ionization of Xe at energy transfers of 60 to 110 eV in terms of the generalized oscillator strength. 相似文献
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The optical properties of Tl4Ga3InSe8 layered single crystals have been studied by means of transmission and reflection measurements in the wavelength range of 500–1100 nm. The analysis of the room temperature absorption data revealed the presence of both optical indirect and direct transitions with band gap energies of 1.94 and 2.20 eV, respectively. Transmission measurements carried out in the temperature range of 10–300 K revealed that the rate of change of the indirect band gap with temperature is γ=−4.1×10−4 eV/K. The absolute zero value of the band gap energy was obtained as Egi(0)=2.03 eV. The dispersion of the refractive index is discussed in terms of the Wemple–DiDomenico single-effective-oscillator model. The refractive index dispersion parameters: oscillator energy, dispersion energy, oscillator strength and zero-frequency refractive index were found to be 4.10 eV, 23.17 eV, 6.21×1013 m−2 and 2.58, respectively. From X-ray powder diffraction study, the parameters of monoclinic unit cell were determined. 相似文献
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The optical properties of Tl2In2Se3S layered single crystals have been analyzed using transmission and reflection measurements in the wavelength region between 500 and 1100 nm. The optical indirect transitions with a band gap energy of 1.96 eV and direct transitions with a band gap energy of 2.16 eV were determined from analysis of absorption data at room temperature. Dispersion of the refractive index is discussed in terms of the Wemple–DiDomenico single-effective-oscillator model. The refractive index dispersion parameters – oscillator energy, dispersion energy, oscillator strength and zero-frequency refractive index – were found to be 4.67 eV, 45.35 eV, 1.38 × 1014 m ? 2 and 3.27, respectively. Transmission measurements were also performed in the temperature range 10–300 K. As a result of temperature-dependent transmission measurements, the rate of change in the indirect band gap with temperature, i.e. γ = ?5.6 × 10?4 eV/K, and the absolute zero value of the band gap energy, E gi(0) = 2.09 eV, were obtained. 相似文献
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Partial oscillator strengths (β dependent), from threshold to 49 eV, for the ionisation of 1b1, 2a1, 1b2, 1a1 electrons from the valence shell of water vapour have been determined using fast (3.5 keV) electron impact with coincidence detection of the scattered and ejected electrons. The total oscillator strength (photoabsorption) was determined from the forward scattered electron intensity and placed on an absolute basis by normalisation to a total f value of 8 for the valence shell. 相似文献