共查询到19条相似文献,搜索用时 296 毫秒
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研究了双钙钛矿Sr2CrWO6的磁性和输运性质.Sr2CrWO6多晶在Ar气及真空气氛中经固相烧结而形成.X射线衍射分析表明主相为Sr2CrWO6,少量杂相为SrWO4.热磁测量表明样品的居里温度为480K左右.电阻随温度降低而升高,类似于绝缘体,在外场5T,低温下(25K)磁致电阻(MR)可达20%,但MR随温度升高而趋于零.较大的矫顽力(5.97×1
关键词:
双钙钛矿氧化物
磁性质
磁致电阻 相似文献
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用溶胶-凝胶制备了La0.833K0.167MnO3-SrTiO3 (LKMO/STO)系列样品,并研究了它们的结构、磁性和输运特性.X射线衍射实验表明,1200℃烧结的LKMO/STO (STLK12)是一个均匀的固溶相.其电阻率表现为绝缘体的行为,而纯La0.833K0.167MnO3 (LKMO)样品随温度的升高则有金属-绝缘体转变.在低场下(μ0H=0.02 T),对STLK12样品,当温度从220 K降低到4 K时,磁电阻从0.2%升高到11%.在高场下(μ0H=5.5 T),随着温度降低,磁电阻几乎是线性增大.在4.2 K时,达到65%.比纯LKMO样品40%的磁电阻高出了25%. 我们用晶界处的自旋极化隧穿效应定性地解释了这种增强的磁电阻效应.
关键词:
低场磁电阻
高场磁电阻
自旋极化隧穿
钙钛矿 相似文献
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采用固相反应烧结法制备了(La1-yTby)0.67Sr0.33MnO3系列样品(y=0,0.05,0.15,0.20,0.25,0.33,0.40,0.50,0.60,1.00).X射线衍射表明,随着y值增大钙钛矿型晶体结构从菱面对称性向正交对称性转变.180K时,μ0H=7T条件下,在y=0.40样品的巨磁电阻可达900%.μ0H=1.7T时,y=0.20样品的室温磁致伸缩为-50×10-6.210K时,y=0.33样品的磁致伸缩可达-130×10-6.
关键词: 相似文献
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The effect of Fe-doping on the magnetic properties of the ABO3-type perovskite cobaltites La0.7Ba0.3Co1 yFeyO3 (0 ≤ y ≤ 0.80) is reported.With no apparent structural change in any doped sample,the Curie temperature (TC) and the magnetization (M) are greatly suppressed for y ≤ 0.30 samples,while a distinct increase in TC for the y = 0.40 sample is observed.With the further increase of Fe concentration,TC increases monotonically.Griffiths-like phases in 0.40 ≤ y ≤ 0.60 samples are confirmed.The formation of the Griffiths-like phase is ascribed to B-site disordering induced isolation of ferromagnetic (FM) clusters above TC. 相似文献
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研究了钙钛矿型锰氧化物La2/3Ca1/3Mn1-xTixO3(0≤x≤0.3)的结构、磁性和输运性质.发现Ti替代Mn强烈地抑制了La2/3Ca1/3MnO3的铁磁性和金属电导,并很大地提高了磁电阻值.在低掺杂情况下(x≤0.04),1%的Mn被Ti替代,居里温度TC和金属-绝缘体转变温度Tp分别平均下降了31和26.5K.当x=0.06时,铁磁态过渡为团簇玻璃态,并在x=0.20时完全变为自旋玻璃态.指出由于Ti的掺入而引起的磁稀释作用以及局域晶格畸变是产生上述结果的主要原因.
关键词: 相似文献
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The La1.32Sr1.68Mn2O7 layered manganite system has been studied by the low temperature electrical resistance and magnetoresistance under hydrostatic pressure up to 25 kbar. We have observe both, a Curie temperature (TC) and a metal-insulator transition (TMI) at 118 K in the ambient pressure. The applied pressure shifts the TMI to higher temperature values and induces a second metal-insulator transition (T2MI) at 90 K, in the temperature dependence of resistivity measurements. Also, the pressure suppresses the peak resistance abruptly at TC. When an external field of 5 T is applied, we have observed a large negative magnetoresistance of 300% at the transition temperature and a 128% at 4.5 K. However, the increased pressure decreases the magnetoresistance ratio gradually. When the pressure reaches its maximum available value of 25 kbar, the magnetoresistance ratio decreases at a rate of 1.3%/kbar. From our experimental results, the decrease of magnetoresistance ratio with pressure is explained by the pressure induced canted spin state which is not favor for the spin polarized intergrain tunneling in layered manganites. 相似文献
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Sh. Tabatabai Yazdi D. Sanavi Khoshnoud 《Journal of magnetism and magnetic materials》2010,322(20):3131-3136
La0.7Sr0.3Mn1−xCoxO3 (x=0, 0.05, 0.1) nanoparticles, prepared by sol-gel method, were studied by means of X-ray diffraction, transmission electron microscopy, resistivity, magnetoresistance, thermal expansion and magnetostriction measurements. Results show that partial substitution of Mn by Co leads to a reduction in lattice parameters, enhancement of resistivity and room temperature magnetoresistance MR, decrease of metal-insulator transition temperature TMI and TC, an increase in thermal expansion coefficient, volume magnetostriction and anisotropic magnetostriction. The latter increases about one order of magnitude with 10% Co substitution. In comparison with Mn ions, the Co ions possess higher anisotropy energy, larger magnetostriction effect, smaller ionic size and spin state transitions with increase in temperature and magnetic field; this suggests that Co substitution leads to double-exchange interaction weakening, resulting in suppression of ferromagnetic long-range order and metallic state and increase of magnetic anisotropy. Furthermore, our samples have a relatively lower TMI and TC, higher resistivity and MR, compared with the reported values for similar compounds with larger particle sizes. This is attributed to the nanometric grain size and spin-polarized tunneling between neighboring grains. 相似文献
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The structure, transport and magnetic properties of (La0.8Sr0.2)1−xMnO3 (0≤x≤0.30) polycrystalline perovskite manganites have been investigated. For all the samples the Curie temperatures, Tc, remain nearly unchanged (329±3 K). Resistivity versus temperature curves for the samples show a double-peak behavior. A significant magnetoresistance (MR) effect and different temperature dependences of the MR ratios of the samples are observed. The shapes of the MR-T curves of the samples can be adjusted by changing x. For the x=0.30 sample, a nearly constant MR ratio of (9.5±0.5)% is obtained over the temperature range from 205 to 328 K. 相似文献
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Vikram Sen Neeraj Panwar G.L. Bhalla 《Journal of Physics and Chemistry of Solids》2007,68(9):1685-1691
We report here the structural, magnetotransport and morphological studies of Sb-doped La2/3Ba1/3Mn1−xSbxO3 perovskite manganites. Pristine material La2/3Ba1/3MnO3 (LBMO) shows two insulator-metal (I-M) transitions in the electrical resistivity-temperature (ρ-T) behavior. While the higher temperature transition (TP1) at ∼340 K is reminiscent of the usual I-M transition in manganites, the lower temperature transition (TP2) at ∼250 K has been ascribed to the grain boundary (GB) effects arising out of the ionic size mismatch between the ions present at the rare-earth site (La3+ and Ba2+). With Sb-doping TP1 shifts to lower temperatures while TP2 remains invariant up to 3% and shifts to lower temperature for 5%. Room temperature electrical resistivity and the peak values also increase successively with Sb-doping. Scanning electron micrographs of the samples exhibit a gradual increase in their grain sizes with Sb indicating a gradual decrease in the GB density. Shift of TP1 with doping is explained on the basis of a competition between double-exchange and super-exchange mechanisms. The overall electrical resistivity increases and the shift in the electrical resistivity hump (TP2) with Sb-doping is found related to be gradually decreasing GB density and the ensuing lattice strain increase at the GBs. The intrinsic magnetoresistance (MR) gets suppressed and extrinsic MR gets enhanced with Sb-doping. At T>TP1, the electrical resistivity is found to follow the adiabatic polaron hopping model whereas the electron-magnon scattering is found to dominate in the metallic regime (T<TP1). 相似文献
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W. Chérif M. Ellouze A.-F. Lehlooh F. Elhalouani S.H. Mahmood 《Journal of magnetism and magnetic materials》2012
A sample of Pr0.67Sr0.33MnO3 nanoparticles was synthesized by the ball milling method. X-ray diffraction pattern of the sample showed orthorhombic system with Pnma space group. The average crystallite size of 110 nm was obtained by both Scanning Electron Microscopy and X-ray diffraction. Magnetic measurements showed para-to-ferromagnetic transition with a Curie temperature of TC=269 K. Electrical investigations showed that all our samples exhibit a semi-conducting behavior above TC and a metallic-like one at lower temperatures. The sample exhibited a large magnetoresistance of 30% at room temperature in an applied magnetic field of 2 T. The transport and the magnetic properties were interpreted in terms of the existence of magnetic polarons in the sample. 相似文献