共查询到19条相似文献,搜索用时 156 毫秒
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提出了布朗马达的非均匀高斯跃迁理论,用布朗粒子在多态之间的跃迁模型描述分子马达的定向运动.假定跃迁速率与位置有关,且在跃迁点附近具有高斯函数形式,将布朗粒子在x处的概率密度Pm(x,t)在跃迁点附近展开,可以进行任意阶的近似计算.这一理论涵盖了以往的定点跃迁模型和均匀跃迁模型.作为具体例子,研究了系统在两态之间的跃迁问题.假定在一个周期内有两个跃迁点,讨论了布朗粒子定向运动产生的概率流随温度、跃迁速率和
跃迁宽度的变化关系.
关键词:
布朗马达
高斯跃迁
概率流 相似文献
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对Br2分子在可见-近紫外吸收带的光解离行为进行了研究. 运用波包动力学方法在ab initio势能面的基础上获得了分立电子态的激发截面和电子态跃迁的吸收光谱,同时也确定了溴原子碎片的相对量子产额. 对解离途径中可能涉及到的非绝热机制进行了考察.结果表明, 电子-振动耦合作用对(Br*+Br)产物通道的影响是可以忽略的,并借助于Landau-Zener模型获得了两个不同对称性的电子态B3Π+0u和C1Πu之间的耦合强度. 相似文献
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非线性跃迁动力学的研究是量子操控中的一个重要课题,在原子分子光物理、量子信息以及固体物理等领域都有着重要的应用.本文研究了具有粒子间相互作用两能级系统中的Landau-Zener-Coulomb跃迁动力学.结果表明,对于能级的斜率正负不同的情况,粒子间相互作用对系统跃迁动力学的影响完全不同.为正时,粒子间相互作用总是抑制能级间的非绝热跃迁,且相互作用强度越大,两能级间的非绝热跃迁越难发生.而为负时,弱相互作用会促进能级间的非绝热跃迁,在强相互作用情况下,跃迁概率会出现振荡.随着相互作用强度的增大,振荡幅度逐渐减小,能级间的非绝热跃迁受到抑制. 相似文献
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应用多组态Dirac-Fock(MCDF)方法,对Xe10+离子进行了理论计算,获得了跃迁波长和概率等数据.通过逐步引入4dn—5pn(n=1, 2, 3)电子相关的相互作用组态,重点研究了电子相关效应对4d8—4d75p跃迁系跃迁概率的影响.结果显示电子相关效应显著,表明了欲得到精确的4d8—4d75p的振子强度(跃迁概率)数据,理论计算中至少要包括到4d2—5p2的电子相关组态的影响.与实验测得的跃迁波长比较发现,理论结果与之有着较好的一致性;同时理论跃迁概率在两种规范下的结果符合得相当精确,显示了计算结果的可靠性.
关键词:
多组态Dirac-Fock(MCDF)方法
电子相关
跃迁概率 相似文献
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作为量子信息处理的载体,量子纠缠态一直以来都是量子信息领域的研究热点.相比于低维纠缠态,高维纠缠态使得量子通信具有更快的传输速度、更强的安全性、更高的噪声容忍阈值等特点.另外,绝热技术因其对实验参数起伏不敏感而被广泛应用于纠缠态的制备,然而绝热过程需要相当长的演化时间,因此绝热捷径应运而生.本文提出了一种采用无跃迁量子驱动构建绝热捷径实现快速制备两个原子的四维纠缠态的理论方案,该系统中的两个原子分别被囚禁在两个由光纤连接的双模腔中.为了获得一个技术上可操作的物理系统,本方案采用能级失谐设计出一个可精确驱动系统沿着某一个系统的瞬时本征态演化的哈密顿.该方案所采用的无跃迁量子驱动构建绝热捷径不仅大大缩短了演化时间,而且在实验上也比较容易实现.本文还数值模拟了消相干因素对四维纠缠态保真度的影响,结果表明,只要脉冲参数选取在一定范围内,光纤耗散、腔场耗散和原子自发辐射等不利因素都会被大大抑制. 相似文献
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We investigate the acceleration of an adiabatic process with the same survival probability of the ground state by sweeping a parameter nonlinearly, fast in the wide gap region and slowly in the narrow gap region, in contrast to the usual linear sweeping. We find the expected acceleration both in the Landau-Zener tunneling model and in the adiabatic quantum computing model for factorizing the number N - 21. 相似文献
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We investigate the ultrafast control of coherent population transfer in a Λ-type three-level system with a train of pump-Stokes femtosecond pulse pairs, where the pulse sequences can be produced either by optical delay line or by pulse shaping with sinusoidal phase modulation. It is shown that when the pump and Stokes pulses in each pair are applied in the counterintuitive order, similar to that in the stimulated Raman adiabatic passage technique, due to temporal quantum interference (besides optical interference in the case of overlapped subpulses), ultrafast control of coherent population transfer can be achieved by scanning the inter-pair time delay or by changing the sinusoidal phase modulation parameters. This method has potential applications in ultrafast control of chemical reactions and quantum information processing. 相似文献
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Zhi-Rong Zhong Lei Chen Jian-Qi Sheng Li-Tuo Shen Shi-Biao Zheng 《Frontiers of Physics》2022,17(1):12501
In this paper,we propose a scheme to achieve a multiphonon-resonance quantum Rabi model and adiabatic passage in a strong-coupling cavity optomechanical system.In the scheme,when the driving bichromatic laser beam is adjusted to the off-resonant j-order red-and blue-sideband,the interaction between the cavity and mechanical oscillator leads to a j-phonon resonance quantum Rabi model.Moreover,we show that there exists a resonant multi-phonon coupling via intermediate states connected by counter-rotating processes when the frequency of the simulated bosonic mode is near a fraction of the transition frequency of the simulated two-level system.As a typical example,we theoretically analyze the two-phonon resonance quantum Rabi model,and derive an effective Hamiltonian of the six-phonon coupling.Finally,we present a method of six-phonon generation based on adiabatic passage across the resonance.Numerical simulations confirm the validity of the proposed scheme.Theoretically,the proposed scheme can be extended to the realization of 3j-phonon state. 相似文献
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A. K. Belyaev 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):497-505
The new accurate two-state quantum calculations of the inelastic cross sections in
H + Li, Na collisions for energies from the thresholds and till 100 eV or 600 eV are
performed, and the results are compared with the Landau-Zener model cross sections
in both the diabatic and the adiabatic representations.
It is found that the low-energy inelastic cross section is very sensitive to
nonadiabatic coupling and, hence, the new NaH coupling is computed.
The numerical solutions of the coupled channel equations are checked by independent
calculations indicating that the quantum results are accurate.
These checks are done by means of the analytic formula for a nonadiabatic transition
probability derived within the perturbation approach.
Both the Landau-Zener-like and the non-Landau-Zener-like behaviour of the excitation
cross sections are found.
34.70.+e Charge transfer 相似文献
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We calculate the exact Landau-Zener transition probabilities for a qubit with an arbitrary linear coupling to a bath at zero temperature. The final quantum state exhibits a peculiar entanglement between the qubit and the bath. In the special case of diagonal coupling, the bath does not influence the transition probability, whatever the speed of the Landau-Zener sweep. It is proposed to use Landau-Zener transitions to determine both the reorganization energy and the integrated spectral density of the bath. Possible applications include circuit QED and molecular nanomagnets. 相似文献
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Yu. V. Menshova I. Yu. Yurova 《Russian Journal of Physical Chemistry B, Focus on Physics》2014,8(1):45-49
The probabilities of predissociation and vibronic transitions between the states of the oxygen molecule in the Schumann-Runge band in the presence of a strong laser field are examined. The interaction of the molecule with the laser field is described using the rotating wave approximation. The predissociation probabilities for the avoided crossing of two adiabatic molecular terms are calculated within the framework of the Landau-Zener model. The energies of the vibrational states in the laser field are determined by diagonalization of the adiabatic Hamiltonian in the harmonic oscillator basis set. The predissociation thresholds are determined and the Franck-Condon factors are calculated as functions of the frequency and intensity of the external electromagnetic field. 相似文献