O(N) vector model with twisted boundary conditions

Prompted by a recent article of Chakravarty, we reexamine theO(N) vector model with twisted boundary conditions ind dimensions in the various frameworks of the =d–2 expansion, the =4–d expansion, and the large-N expansion. These continuum models describe the physics below the critical temperatureT _c and nearT _c of a latticeO(N) spin model. We determine the effect of the twisting on finite-size scaling functions, for various geometries.On leave from G. Nadjakov Institute of Solid State Physics, 1784 Sofia, Bulgaria.     

PAC Measurements on New Ferromagnetic Compound Pd2TiSn

Magnetic hyperfine field (mhf) acting on ¹⁸¹Ta at the Ti site has been investigated in the alloy Pd₂TiSn by Perturbed Angular Correlation (PAC) measurements using the (133–482) keV – cascade in ¹⁸¹Ta following the ^– decay of ¹⁸¹Hf. The magnetic hyperfine field was measured as a function of temperature in the range of 45–1000K. The magnetization measurements were carried out with a vibrating sample magnetometer. The interpretation of the experimental results is based on the assumption that the probe nuclei occupy both the regular Ti sites as well as the Ti atom sites randomly distributed on the Pd sublattice.     

Supertubes versus superconducting tubes

In this paper we show the relationship between cylindrical D2-branes and cylindrical superconducting membranes described by a generic effective action at the bosonic level. In the first case the extended objects considered, arose as blown up type IIA superstrings to D2-branes, named supertubes. In the second one, the cosmological objects arose from some sort of field theories. The Dirac–Born–Infeld action describing supertubes is shown to be equivalent to the generic effective action describing superconducting membranes via a special transformation. (Dedicated to Prof. Alberto García on the occasion of his 60th birthday)     

Electron Energy Loss Spectra of the Organic Complexes of Europium

In the electron energy loss spectra (EELS) of the organic europium complexes Eu³⁺ (BTFA)₃TPPO and Eu³⁺(BrBTFA)₃TPPO in a gas phase obtained on excitation by monokinetic beams of electrons of different energies in the range 12–50 eV, we have identified the bands associated with the electron transitions S ₀–S ₁, S ₀–S ₂, and S ₀–S ₃. The connection of these transitions with the structural groups of the complexes is established. The addition of the bromine atom to the phenyl ring of diketonate leads to the rise in the relative intensity of the S ₀–S ₂ band. The singlettriplet transitions manifest themselves in the region 2.5–3.2 eV and contribute to the S ₀–S ₂ band of the electron energy loss spectra.     

Threshold simulation of 1.3-μm oxide-confined in-plane quantum-dot (InGa)As/GaAs lasers

In the paper, the self-consistent optical–electrical–thermal-gain model of the oxide-confined long-wavelength 1.3-m quantum-dot (InGa)As/GaAs diode laser is demonstrated. The model has been applied to analyse room-temperature (RT) threshold-operation characteristics of the advanced laser of this kind. It may be used to describe physics of the above arsenide-based diode lasers to better understand their threshold performance and finally to optimize their structures.     

Manifestation of Intermolecular Interactions in the IR Spectra of 8-Azasteroids

We have investigated the intermolecular interactions of 8-aza-D-homogona-1,3,5(10),13-tetrane-12,17a-dione and 2,3-dimethoxy-8-azagone-1,3,5(10),13-tetran-12,17-dione with CHCl₃, binary solvents CHCl₃–CH₃OH, CCl₄–CHCl₃, and CCl₄–CH₃OH and also in the solid phase, which manifest themselves in the IR spectra. When the C=O groups of the studied 8-azasteroids form hydrogen bonding with the OH groups of alcohol, the frequencies (C=O) change insignificantly. We have found that they are higher than the corresponding frequencies in the IR absorption spectra of solid-phase samples, which is attributable not only to the effect of the medium but also to the possible shortened contacts of the C=O groups with the CH₃ and CH₂ groups of the molecules under study.     

Finite-size effects in a field-theoretic model with long-range exchange interaction

We present a systematic approach to the calculation of finite-size (FS) effects for anO(n) field-theoretic model with both short-range (SR) and long-range (LR) exchange interactions. The LR exchange interaction decays at large distances as 1/r ^d+2–2,0⁺,0⁺. Renormalization group calculations ind=d _u – are performed for a system with a fully finite (block) geometry under periodic boundary conditions. We calculate the FS shift of the critical temperature and the FS renormalized coupling constant of the model to one-loop order. The universal scaling variable is obtained and the FS scaling hypothesis is verified.     

Reflection Spectra of Single Crystals of La2CuO4−x ‐Type Metal‐Oxide Compounds

We have investigated the reflection spectra in polarized light at 80 and 295 K in an energy region of 1.0–4.8 eV for the single crystals of ternary and quaternary copperoxide systems with the participation of rareearth elements (La₂CuO_4–x , LaCuO₄, Pr₂CuO_4–x , GdBa₂Cu₃O_7–x , and LaSrCaCuO).     

Synthesis of peptidomimetics using a polymer-bound Boc-linker

Boc-resin-bound -hydroxy--amino-aldehydes are accessible starting from N-terminally bound amino acidesters by using Dondoni's C₁-homologationreaction sequence. The conversion of these synthons totwo different peptide mimetics – 2-hydroxy-1,3-ethyl-diamines and -hydroxy--amino-vinyl sulfones – hasbeen investigated. The successful transfer of thecomplex -amino acid homologation reactionsequence into solid-phase chemistry demonstrates thepotentials of the Boc-resin for synthesis of peptidomimetics.     

Bi-Hamiltonian Formalism: A Constructive Approach

A method of generating a MMGD (Magri–Morosi-Gel'fand–Dorfman) bi-Hamiltonian structure leading to complete integrability of the associated Hamiltonian system is presented. The Hamiltonian formalism is defined in terms of the fundamental notions of the Poisson calculus.     

Interfacial free energies and solute diffusivities from data on Ostwald ripening

Using recent theoretical modifications of the kinetic constants characterizing Ostwald ripening, it is demonstrated that accurate values of the interfacial free energy, , and solute diffusivities, D, can be obtained from experimental data when the kinetics of particle growth are measured in conjunction with independent measurements of either the decrease of the matrix supersaturation or the increase in volume fraction with aging time. The accuracy of is limited only by the assumption that the matrix phase is an ideal solid solution, and is effectively independent of the influence of equilibrium volume fraction, _e, on the kinetics of coarsening. Analyses of the available data on the coarsening of -type (Ni₃X) precipitates in binary Ni–Al, Ni–Si and Ni–Ti alloys yield values of =6.9±0.3, 10.2±3.0 and 13.0 mJ/m², respectively, assuming ideal solution thermodynamics; a more realistic thermodynamic model for the Ni–Al solid solution raises the value of in Ni–Al alloys to 8.1±0.2 mJ/m². Proportional increases probably obtain in the other two alloys. The accuracy with which D can be evaluated from comparable data depends theoretically on _e. However, analyses of the same data yield values of D in very good agreement with the results of conventional diffusion experiments. This is consistent with the absence of an effect of _e on the kinetics of Ostwald ripening in these alloys over the ranges of _e investigated.     

Calculation of the Tautomeric Properties of 3‐Formyl‐Tetrinic Acid by the ab initio and DFT Methods

We have carried out a nonempirical quantumchemical calculation with full optimization of the geometry of all theoretically possible tautomeric forms of 3formyltetrinic acid (FTRA) according to the Møller–Plesset secondorder perturbation theory with the use of a 6–31G(d) double zeta basis set. The correlation corrections to the total energy of molecules for optimized geometric configurations were calculated in the 631G(d,p) basis. All the possible tautomeric forms of FTRA and the harmonic vibrational frequencies were also calculated within the density functional theory (DFT) with the use of the Perdew–Burke–Ernzerhof (PBE) functional in a threeexponent basis. It is shown that FTRA in vapors (in the perfect gas approximation) exists in the form of a mixture of three enol forms, among which two exoforms predominate. The frequencies and forms of normal vibrations for each cisenol tautomer in the region of vibrations of ketogroups and double bonds differ widely, which permits identification of the tautomers present in the mixture. The possible mechanisms of enolenol transformations of 3acyltetrinic acids are discussed.     

Thickness dependence of temperature coefficient of resistance of MnBi films

In-situ measurements of the temperature coefficient of resistance of electron-beam evaporated MnBi films are reported for the thickness range 30–180 nm. The thickness dependence of the temperature coefficient of resistance curves are plotted for different weight ratios, annealing times and substrate temperatures. The temperature coefficient of resistance shows marked size effect, and is negative for lower thicknesses (<100nm) and positive for higher thicknesses. The experimental data is in good agreement with the Mayadas-Shatzkes theory. The thickness dependence of the Curie temperature also indicates marked size effect.     

A Cathodoluminescent Screen of Columnar Structure for Field Emission Displays

We have suggested and implemented a method of creation (growing) of sublimatescreens formed by singlecrystal luminophor columns which are perpendicular to an amorphous (e.g., glass) substrate. The diameters of the columns are 3–5 m, the height 7–10 m. The columnar singlecrystal structure of the screen ensures the high light yield and radiation color needed for field emission displays. It is possible to select the growing regime so that the columns are very closely spaced (1–2 m). The gaps can be filled with a conducting opaque material that increases the contrast of the screen and improves their electrical conductivity.     

IR Spectra of Derivatives of Immunotropic 8-Azasteroids

By the method of IR Fourier spectroscopy with the use of numerical differentiation of spectral line profiles we have studied the spectra of some structural and functional derivatives of immunotropic 8-azasteroids in the region of C=O and C=C bonds (1800–1400 cm^–1). We have established the dependence of vibration frequencies of the C=O and C=C groups on the size of the ring D, the presence of heteroatoms (O, S) in the ring D, transformations in the -acyl--aminovinylcarbonyl fragment and in its adjacent positions of the heterosteroid skeleton, and the composite character of the absorption bands that are due to the vibrations of the C=O and C=C groups. The role of the structural and stereoelectronic factors in the observed group frequencies of 8-azasteroids is discussed.     

Raman scattering of light in doped cubic boron nitride

The Raman spectra of single crystals of cubic boron nitride (cBN) doped with beryllium and also synthesized in the absence of dopants are investigated. It is shown that the wide bands at 215 and 535 cm^–1 can be registered in the Raman spectra of the ( ) faces of undoped cBN crystals and that the Be impurity penetrates into the cBN crystals predominantly in the direction of these faces. In the spectra of the investigated cBN samples doped with Be, the contour of the TO and LO phonon lines does not take the Fano shape, in contrast to diamond, which can point to an insufficient concentration of the dopant for attaining the Fano interference or to the absence of it in cBN. The wide bands have been investigated on the assumption that they are boson-like and result from small-size disorders in both undoped and doped cBN samples with the sp ³ bond deformed by Be.Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 71, No. 6, pp. 803–809, November–December, 2004.This revised version was published online in April 2005 with a corrected cover date.     

A study of the far-infrared optical properties of rexolite?

The far-infrared optical properties of Rexolite 1422 were characterized at the University of Lowell Research Foundation using Fourier transform spectroscopy. The spectroscopic transmission measurements were performed on a 0.0236 thick sample of material over the submillimeter wavelength region from 10 cm^–1 to 360 cm^–1. Using multiple reflection theory for transmission through an etalon, the frequency dependent complex refractive index of Rexolite is reported.     

A GaAs–InGaAs optoelectronic switch with multiple operation states

An optoelectronic switch with both n- and p-type delta-doped (-doped) quantum wells was investigated. The -doped structures formed potential wells for the carrier accumulation and potential barriers for the carrier injection. Being possessed of -doped sheets with different doping levels, the potential barriers were sequentially collapsed to produce a double negative-differential-resistance (NDR) phenomenon in the current–voltage (I–V) characteristics of the device, due to the carrier accumulation in the potential wells. The device also showed an optical function related to the barrier heights controllable by incident light.     

Tracer Diffusion of 63Ni in Nano-γ-FeNi Produced by Powder Metallurgical Method: Systematic Investigations in the C, B, and A Diffusion Regimes

⁶³Ni radiotracer diffusion in a well-compacted nanocrystalline (grain size d 80 to 100 nm) -Fe–40wt%Ni alloy was measured by the serial sectioning technique in an extended temperature range from about 610 to 1010 K. Since the material microstructure reveals two different length scales with nano-size grains forming micrometer-size clusters (or agglomerates), three main diffusion paths determine the diffusion behavior: the nanocrystalline grain interior, the nanocrystalline grain boundaries (GB), and the inter-agglomerate interfaces. The systematics of diffusion in a compacted nanostructured material with such a bimodal distribution of interface characteristics was elaborated and the experimental data were analyzed in dependence on the diffusion regime. The absolute values and the Arrhenius parameters of Ni GB diffusion in the nano--Fe–40wt%Ni alloy (D ₀ = 9.3 × 10^–4 m² s^–1 and Q = 177 kJ/mol) are similar to the Ni GB diffusivity in coarse-grained poly-crystalline -Fe. Accordingly, the nanocrystalline GBs are concluded to have quasi-equilibrium structures, particularly because of a pronounced grain growth (from about 30 to about 100 nm) during the production stage of the nanomaterial. In contrast, the inter-agglomerate interfaces, which present the fastest diffusion path in the present investigation (D ₀ = 1.9 × 10^–3 m² s^–1 and Q = 134 kJ/mol), are likely to be in a non-equilibrium state due to specific features of the applied powder metallurgical process.     

The Dependence of the Luminescence Intensity of Lanthanide Complexes with β-Diketones on the Ligand Form

The influence of -diketone forms on the luminescence intensity of lanthanide compounds in a series of ligands, acetylacetone (trifluoroacetylacetone, benzoylacetone)—their unsaturated analogues (monomeric form)—copolymers of the latter with styrene (methylmethacrylate), was studied. Lanthanides in compounds with copolymers have been established to demonstrate the brightest luminescence. It was found that its intensity depends not only on the character of the substituent (CH₃, CF₃, C₆H₅) in the -diketone molecule, but also on the distance between the -diketone fragments in the copolymer. Reasons explaining the high intensity of luminescence in lanthanide–copolymer compounds are considered.