Metal work-function changes induced by organic adsorbates: a combined experimental and theoretical study

The role of molecular dipole moment, charge transfer, and Pauli repulsion in determining the work-function change (Deltaphi) at organic-metal interfaces has been elucidated by a combined experimental and theoretical study of (CH(3)S)(2)/Au(111) and CH(3)S/Au(111). Comparison between experiment and theory allows us to determine the origin of the interface dipole layer for both phases. For CH(3)S/Au(111), Deltaphi can be ascribed almost entirely to the dipole moment of the CH(3)S layer. For (CH(3)S)(2)/Au(111), a Pauli repulsion mechanism occurs. The implications of these results on the interpretation of Deltaphi in the presence of strongly and weakly adsorbed molecules is discussed.     

Subcritical crack growth: the microscopic origin of Paris' law

We investigate the origin of Paris' law, which states that the velocity of a crack at subcritical load grows like a power law, da/dt ~ (DeltaK)(m), where DeltaK is the stress-intensity-factor amplitude. Starting from a damage-accumulation function proportional to (Deltasigma)(gamma), Deltasigma being the stress amplitude, we show analytically that the asymptotic exponent m can be expressed as a piecewise-linear function of the exponent gamma, namely, m=6-2gamma for gamma or =gamma(c), reflecting the existence of a critical value gamma(c)=2. We perform numerical simulations to confirm this result for finite sizes. Finally, we introduce bounded disorder in the breaking thresholds and find that below gamma(c) disorder is relevant, i.e., the exponent m is changed, while above gamma(c) disorder is irrelevant.     

Enhancement of the quantum-liquid phase by increased resistivity in thick a-MoxSi1-x films

Effects of normal-state resistivity rho(n) on the vortex phase diagram at low temperature T have been studied based on dc and ac complex resistivities for thick amorphous MoxSi(1-x) films. It is commonly observed irrespective of rho(n) that, in the limit T=0, the vortex-glass-transition line B(g)(T) is independent of T and extrapolates to a field below the T=0 upper critical field B(c2)(0), indicative of the quantum-vortex-liquid (QVL) phase in the regime B(g)(0)相似文献   

Ferromagnetic quantum critical fluctuations in YbRh2(Si0.95Ge0.05)2

The bulk magnetic susceptibility chi(T,B) of YbRh(2)(Si(0.95)Ge(0.05))(2) has been investigated close to the field-induced quantum critical point at B(c) = 0.027 T. For B < or= 0.05 T a Curie-Weiss law with a negative Weiss temperature is observed at temperatures below 0.3 K. Outside this region, the susceptibility indicates ferromagnetic quantum critical fluctuations, chi(T) proportional, variantT-0.6 above 0.3 K. At low temperatures the Pauli susceptibility follows chi(0) proportional, variant(B-B(c))(-0.6) and scales with the coefficient of the T(2) term in the electrical resistivity. The Sommerfeld-Wilson ratio is highly enhanced and increases up to 30 close to the critical field.     

Sensitivity-bandwidth product for electro-optic modulators

For lumped-element electro-optic modulators, the sensitivity ( partial differentialphi/ partial differentialV) of the phase, phi , in response to an applied voltage V is related to the optical group delay, T(g) , and the bandwidth, Domega . This relationship imposes a fundamental trade-off between the sensitivity and the bandwidth of electro-optic modulators: ( partial differentialphi/ partial differentialV)Domega= (dn/dV)(omega /n) , where n is the optical index. A similar relationship for traveling-wave modulators sets an upper limit on ( partial differentialphi/ partial differentialV) that is proportional to T(g) .     

Generalized sagnac effect

Experiments were conducted to study light propagation in a light waveguide loop consisting of linearly and circularly moving segments. We found that any segment of the loop contributes to the total phase difference between two counterpropagating light beams in the loop. The contribution is proportional to a product of the moving velocity v and the projection of the segment length Delta(l) on the moving direction, Deltaphi=4piv x Delta(l)/c(lambda). It is independent of the type of motion and the refractive index of waveguides. The finding includes the Sagnac effect of rotation as a special case and suggests a new fiber optic sensor for measuring linear motion with nanoscale sensitivity.     

Peculiar scaling of self-avoiding walk contacts

The nearest neighbor contacts between the two halves of an N-site lattice self-avoiding walk offer an unusual example of scaling random geometry: for N-->infinity they are strictly finite in number but their radius of gyration R(c) is power law distributed proportional to R(-tau)(c), where tau>1 is a novel exponent characterizing universal behavior. A continuum of diverging length scales is associated with the R(c) distribution. A possibly superuniversal tau = 2 is also expected for the contacts of a self-avoiding or random walk with a confining wall.     

Scaling relations for implantation of size-selected Au,Ag, and Si clusters into graphite

The deposition of size-selected clusters represents a new route to the fabrication of truly nanometer-scale surface architectures, e.g., nanopores. We report a systematic experimental study, coupled with molecular dynamics simulations, of the implantation depths of size-selected Au7, Ag7, and Si7 clusters in the model graphite substrate. For impact energies between 1.0 and 5.5 keV, we find that the implantation depth scales linearly with the momentum of the clusters for all three types of cluster. This "universal" behavior is consistent with a (viscous) retarding force proportional to the velocity of the cluster, akin to Stokes's law.     

Structural investigations on an amorphous Se90Te10 alloy produced by mechanical alloying using EXAFS, cumulant expansion and RMC simulations

We investigated an amorphous Se(90)Te(10) alloy produced by mechanical alloying using two different approaches. First, we used extended x-ray absorption fine structure (EXAFS) spectroscopy and the cumulant expansion method using the Einstein model for the temperature dependence of the cumulants to obtain the cumulants C(*)(1), C(*)(2), and C(*)(3). From these, we found information about the structure of the alloy as well as the thermal and structural disorder, anharmonicity of the effective interatomic pair potentials, thermal expansion of the Se-Se and Se-Te bonds and asymmetry of the partial distribution functions g(Se-Se)(r) and g(Se-Te)(r). The cumulants C(*)(1), C(*)(2), and C(*)(3) also allowed us to reconstruct the g(EXAFS)(ij)(r,T) functions from EXAFS. Then, we made reverse Monte Carlo (RMC) simulations using the total structure factor S(K) obtained from synchrotron x-ray diffraction and the EXAFS oscillations χ(k) on the Se K edge as input data to obtain the g(RMC)(ij)(r) functions. Both methods furnished very similar g(ij)(r) functions, and the structural data obtained from them were also very similar. The results obtained from both methods showed the presence of Se-Te pairs indicating that there is alloying at the atomic level. In addition, we could not find any evidence of the presence of Te clusters in the alloy.     

Creep and relaxation dynamics of domain walls in periodically poled KTiOPO4

Creep and relaxation of domain walls under ac electric fields are observed in an ideal model system, periodically poled KTiOPO4, to occur in different regimes, which are separated by dynamic phase transitions at frequencies f(m)(T)=f(m0)exp((-DeltaE/k(B)T), with f(m0)=3 x 10(9) Hz and DeltaE=0.6 eV. Power law dispersion of the creep susceptibility, chi proportional to 1+(iomegatau)(-beta), with beta approximately equal to 0.4, and large nonlinearity encountered at f < f(m), is contrasted with Cole-Cole-type relaxational dispersion, chi proportional to (1+[iomegatau](1-alpha))(-1), with alpha approximately 0.3, at f > f(m).     

Stretching and collapse of neutral polymer layers under association with ionic surfactants

We provide experimental evidence for stretching and collapse of neutral polymer layers, already adsorbed at an oil-in-water interface, due to its interaction with surfactants. Upon stretching, the first interaction length (2L(0)) follows a power law dependence on surfactant concentration ( proportional, variant C(x)(s), where x approximately 0.5 for cationic surfactants) and collapses in the presence of salt, as a relatively weak power law (C(-y)(s), where y=0.17), in good agreement with brush length decay for polyelectrolyte brushes.     

Superfluid density in the underdoped YBa2Cu3O7-x: evidence for d-density-wave order of the pseudogap

The investigation of the penetration depth lambda(ab)(T,p) in YBa2Cu3O7-x crystals allowed one to observe the following features of the superfluid density n(s)(T,p) proportional, variant lambda(-2)(ab)(T,p) as a function of temperature T0) depends on p slightly in the optimally and moderately doped regions (0.10相似文献   

Evidence for a nodeless gap from the superfluid density of optimally doped Pr(1.855)Ce(0.145)CuO(4-y) films

We present measurements of the ab-plane magnetic penetration depth, lambda(T), in five optimally doped Pr(1.855)Ce(0.145)CuO(4-y) films for 1.6 K< or =T < or =T(c) approximately 24 K. Low resistivities, high superfluid densities n(s)(T) proportional, variant lambda(-2)(T), high T(c)'s, and small transition widths are reproducible and indicative of excellent film quality. For all five films, lambda(-2)(T)/lambda(-2)(0) at low T is well fitted by an exponential temperature dependence with a gap, Delta(min), of 0.85k(B)T(c). This behavior is consistent with a nodeless gap and is incompatible with d-wave superconductivity.     

Effects of a parallel magnetic field on the metal-insulator transition in a dilute two-dimensional electron system

The temperature dependence of conductivity sigma(T) of a two-dimensional electron system in silicon has been studied in parallel magnetic fields B. At B = 0, the system displays a metal-insulator transition at a critical electron density n(c)(0), and dsigma/dT>0 in the metallic phase. At low fields ( B < or approximately equal to 2 T), n(c) increases as n(c)(B)-n(c)(0) proportional, variant Bbeta ( beta approximately 1), and the zero-temperature conductivity scales as sigma(n(s),B,T = 0)/sigma(n(s),0,0) = f(B(beta)/delta(n)), where delta(n) = [n(s)-n(c)(0)]/n(c)(0) and n(s) is electron density, as expected for a quantum phase transition. The metallic phase persists in fields of up to 18 T, consistent with the saturation of n(c) at high fields.     

Experimental constraints on the spin and parity of the Lambdac(2880)+

We report the results of several studies of the Lambda(c)(+)pi(+)pi(-)X final state in continuum e(+)e(-) annihilation data collected by the Belle detector. An analysis of angular distributions in Lambda(c)(2880)(+)-->Sigma(c)(2455)(0,++)pi(+,-) decays strongly favors a Lambda(c)(2880)(+) spin assignment of 5/2 over 3/2 or 1/2. We find evidence for Lambda(c)(2880)(+)-->Sigma(c)(2520)(0,++)pi(+,-) decay and measure the ratio of Lambda(c)(2880)(+) partial widths Gamma(Sigma(c)(2520)pi)/Gamma(Sigma(c)(2455)pi)=0.225+/-0.062+/-0.025. This value favors the Lambda(c)(2880)(+) spin-parity assignment of 5/2(+) over 5/2(-). We also report the first observation of Lambda(c)(2940)(+)-->Sigma(c)(2455)(0,++)pi(+,-) decay and measure Lambda(c)(2880)(+) and Lambda(c)(2940)(+) mass and width parameters. These studies are based on a 553 fb(-1) data sample collected at or near the Upsilon(4S) resonance at the KEKB collider.     

Cluster analysis and finite-size scaling for Ising spin systems

Based on the connection between the Ising model and a correlated percolation model, we calculate the distribution function for the fraction (c) of lattice sites in percolating clusters in subgraphs with n percolating clusters, f(n)(c), and the distribution function for magnetization (m) in subgraphs with n percolating clusters, p(n)(m). We find that f(n)(c) and p(n)(m) have very good finite-size scaling behavior and that they have universal finite-size scaling functions for the model on square, plane triangular, and honeycomb lattices when aspect ratios of these lattices have the proportions 1:square root[3]/2:square root[3]. The complex structure of the magnetization distribution function p(m) for the system with large aspect ratio could be understood from the independent orientations of two or more percolation clusters in such a system.     

Dynamics of fluctuations below a stationary bifurcation to electroconvection in the planar nematic liquid crystal N4

We fitted C(k,tau,epsilon) proportional to exp([-sigma(k,epsilon)tau] to time-correlation functions C(k,tau,epsilon) of structure factors S(k,t,epsilon) of shadowgraph images of fluctuations below a supercritical bifurcation at V(0)=V(c) to electroconvection of a planar nematic liquid crystal in the presence of a voltage V=sqrt[2]V(0)cos((2pift) [k=(p,q) is the wave vector and epsilon identical with V(2)(0)/V(2)(c)-1]. There were stationary oblique (normal) rolls at small (large) f. Fits of a modified Swift-Hohenberg form to sigma(k,epsilon) gave f-dependent critical behavior for the minimum decay rates sigma(0)(epsilon) and the correlation lengths xi(p,q)(epsilon).     

Lower critical field and superfluid density of highly underdoped YBa2Cu3O6+x single crystals

The lower critical field H(c1) for highly underdoped YBa2Cu3O(6+x) with T(c) between 8.9 and 22 K has been determined by measurements of magnetization M(H) curves with applied field parallel to the c axis. H(c1) is linear in temperatures below about 0.6T(c), and H(c1)(0) is proportional to T(1.64+/-0.04)(c), clearly violating the proportionality between rho(s)(0) and T(c). Moreover, the slope -dH(c1)/dT decreases steeply toward zero as T(c) approaches zero, indicating that the effective charge of the quasiparticles vanishes as the doping is decreased toward the insulating phase.     

Gapless magnetic and quasiparticle excitations due to the coexistence of antiferromagnetism and superconductivity in CeRhIn5: a study of 115In NQR under pressure

We report systematic measurements of ac susceptibility, nuclear-quadrupole-resonance spectrum, and nuclear-spin-lattice-relaxation time (T1) on the pressure (P)-induced heavy-fermion superconductor CeRhIn5. The temperature (T) dependence of 1/T(1) at P=1.6 GPa has revealed that antiferromagnetism (AFM) and superconductivity (SC) coexist microscopically, exhibiting the respective transition at T(N)=2.8 K and T(MF)(c)=0.9 K. It is demonstrated that SC does not yield any trace of gap opening in low-lying excitations below T(onset)(c)=2 K, but T(MF)(c)=0.9 K, followed by a T(1)T=const law. These results point to the unconventional characteristics of SC coexisting with AFM. We highlight that both of the results deserve theoretical work on the gapless nature in the low-lying excitation spectrum due to the coexistence of AFM and SC and the lack of the mean-field regime below T(onset)(c)=2 K.     

Rheothermodynamics of the Doi-Edwards reptation model

The Doi-Edwards reptation model is found to be thermodynamically consistent, both in the Independent Alignment Approximation and in its full formulation including the effect of tube extension. In the latter case, a new expression for the stress tensor is uncovered. Both the stress and the birefringence tensors after a step shear gamma obey the Lodge-Meissner relation; when gamma>1 the shear stress at t=0(+) is proportional to gamma(-1)lngamma, the first normal stress is proportional, lngamma and both the stress-optical law and the time-strain factorability are violated. A principle of virtual work applies to fast deformations.