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1.
将还原氧化石墨烯(r GO)沉积在侧边抛磨光纤(SPF)上制作了一种新型的光纤湿度传感器。在高湿度区域[相对温度(RH)为70%~95%],传感器的光功率变化达到6.9 d B,尤其在RH为75%~95%区域,传感器对湿度变化能实现相关系数为98.2%的线性响应,灵敏度可达0.31 d B/(%RH),响应速度快于0.13(%RH)/s,并且具有很好的可重复性。对传感机理的理论分析可以解释实验结果,并且表明这种基于石墨烯的光纤传感器亦可广泛应用于其他种类化学气体的探测。这种全新机理的光学传感器是对石墨烯电化学传感器的一种很好的补充,并将促进石墨烯在化学传感技术中的应用。  相似文献   

2.
光纤光栅锈蚀传感器在不同湿度下的特性研究   总被引:3,自引:3,他引:0  
钢结构的锈蚀监测对于钢结构安全的早期预警非常重要.本文提出了一种制备布喇格光纤光栅锈蚀传感器的方法,并研究了该传感器在不同湿度环境下的传感规律.结合磁控溅射和电镀的方法在光栅侧表面制备了Fe-C合金传感膜;利用扫描电子显微镜观察其侧表面形貌;检测在相对湿度60%和99%下中心波长的变化,进而分析该光纤光栅探头在不同湿度...  相似文献   

3.
近年来,随着着光纤技术和光集成技术的发展,光学气敏湿度传感器被广泛应用,在气敏传感材料领域中,由于TiO2具有灵敏度高、响应时间快等优点而受到广泛关注。本文采用基于密度泛函理论(DFT)的平面波超软赝势方法,模拟计算H2O分子在锐钛矿型TiO2(101)无氧空位和有氧空位表面的吸附行为,对吸附能、吸附距离、吸附前后表面电子态密度以及光学性质分别进行分析,结果表明:H2O分子在无氧空位锐钛矿型TiO2(101)表面不容易被吸附,在含有氧空位缺陷的表面容易被吸附;稳定吸附后,H2O分子平面垂直于TiO2表面;负电中心(O端)距空位越近,吸附越稳定,且氧空位浓度越高,吸附效果越明显;通过电子态密度分析发现,H2O分子吸附于含氧空位的表面后,由于H2O分子中O原子的2p孤对电子掺入,在费米能级附近出现新峰值,提高了材料在可见光低能区域的跃迁几率,明显改善了对可见光的吸收系数和反射率,光学气敏传感特性显著。  相似文献   

4.
药物溶出度试验是药品检验的重要项目,在药物质量评价方面起着非常重要的作用。利用光纤传感技术可以实现药物溶出度的自动化、过程化监测。以氙灯、氘灯或卤钨灯作为荧光、紫外光及可见光的光源,以Y型分支光纤作为光路传输介质,紫外-可见吸收探头或荧光分子探头作为光响应器件,CCD作为检测器,通过自编软件实现紫外-可见吸收及荧光猝灭两种模式的检测。光纤传感药物溶出度监测仪不但解决了目前离线取样分析方法耗时、耗力的缺点,而且提供了药物溶出过程的实时信息,为药物质量控制提供了更好的评价手段。  相似文献   

5.
结合溶胶-凝胶固定酶的方法和介质膜金属空芯光纤,提出了一种新型空芯光纤结构的化学发光传感腔。研究了将溶胶-凝胶敏感膜镀制在空芯光纤内壁的工艺,并对此种新型传感器件的发光和导光模式进行了仿真计算,讨论了传感腔各项参数的优化。设计和搭建了基于新型空芯光纤化学发光腔的传感系统,对隐形眼镜液中双氧水含量的实际测量表明,系统具有较高的检测灵敏度(10μM)和良好的重复性。传感系统操作简单、响应快速、可小型化,在生化研究、环境监测以及食品工业等领域有广阔的应用前景。  相似文献   

6.
提出了一种聚苯胺膜微纳光纤液体氢离子浓度探针,并研究了该光纤探针的氢离子浓度传感特性。传感部分由单模光纤-小芯径光纤-单模光纤对芯熔接而成,聚苯胺材料作为敏感膜涂覆于小芯径光纤。首先,对光纤探针传感原理和聚苯胺主链结构变化机理进行理论分析;然后,通过氢离子浓度传感实验进行验证并分析不同膜厚对光纤探针传感特性的影响;最后,完成液体折射率变化实验干扰测试,并评价探针响应-恢复时间和稳定性能。实验结果表明:在氢离子的作用下聚苯胺主链结构发生改变,光纤探针干涉光谱随氢离子浓度增大向短波方向漂移,检测范围随着聚苯胺膜厚增大而增大,但灵敏度与线性度均有明显下降;氢离子浓度范围在10~(-6)~10~(-1)mol/L时,光纤探针灵敏度为-15.74 nm/mol/L,响应与恢复时间分别为25 s和35 s。实验验证了聚苯胺膜与氢离子反应后的光学性质变化,同时也为液体氢离子浓度检测提供了一种新的方法。该光纤氢离子浓度探针还具有固膜强度高、制作简单和成本低等优点。  相似文献   

7.
光纤光栅锈蚀传感器在不同湿度下的特性研究   总被引:1,自引:1,他引:0  
钢结构的锈蚀监测对于钢结构安全的早期预警非常重要.本文提出了一种制备布喇格光纤光栅锈蚀传感器的方法,并研究了该传感器在不同湿度环境下的传感规律.结合磁控溅射和电镀的方法在光栅侧表面制备了Fe-C合金传感膜|利用扫描电子显微镜观察其侧表面形貌|检测在相对湿度60%和99%下中心波长的变化,进而分析该光纤光栅探头在不同湿度下的传感规律.实验和数据分析结果表明:在相对湿度为60%时,锈蚀进程缓慢,随着时间的推移波长呈线性化增加|相对湿度达到99%时光栅光谱出现多峰现象.据此得出:一定湿度条件下,该传感器可监测锈蚀进展|当环境湿度较高(达到99%)时,该传感器可用于锈蚀出现的早期预警.  相似文献   

8.
设计并制作了一种高灵敏度且制作简单的聚甲基丙烯酸甲酯(Polymethyl Methacrylate,PMMA)微球与单模光纤复合的湿度传感器。该光纤湿度传感器由PMMA微球与单模光纤构成。由于在微球中形成了法布里-珀罗腔,当外界环境湿度升高时,PMMA微球吸收水分子体积膨胀,导致法布里-珀罗腔的腔长增长,使得传感器干涉光谱的波峰(谷)发生红移,从而实现湿度传感。对所制作传感器的湿度响应、稳定性和重复性等进行了实验研究,实验结果表明:在30%~80%湿度范围内,该湿度传感器的灵敏度达173.36 pm/%RH,波长漂移随相对湿度变化呈良好的线性关系,其线性度达0.992 26,且具有良好的稳定性和重复性。该PMMA微球与单模光纤复合的湿度传感器具有灵敏度高、结构简单、无需镀膜且易于制作的优点。  相似文献   

9.
对基于微锥的侧抛光纤马赫-曾德尔干涉仪(MZI)结构进行了理论和实验研究。与传统没有经过侧边抛磨的光纤MZI相比,可以看出控制光纤侧抛深度可以有效地提高MZI结构的折射率传感性能。研究结果表明:侧抛深度达41.7μm时,折射率在1.34附近的传感灵敏度达-117.145 nm/RIU。利用侧抛光纤MZI结构结合亲水性材料氧化石墨烯(GO),通过将其沉积在侧抛光纤MZI表面,实现了对温度和湿度双参量的同时测量。温度和相对湿度(RH)的传感灵敏度分别达131.77 pm/℃和-76.1 pm/%RH。所提侧抛光纤MZI传感器结构具有灵敏度高、低成本和制备简单等优点,在生物化学传感领域具有广泛的应用前景。  相似文献   

10.
基于光纤拉曼散射效应和Monte-Carlo法,建立了一种分布式光纤拉曼温度传感系统(DTS)传感模型。应用改进的PSO算法对所建立的传感模型进行参数辨识,分析了种群数目、迭代次数、惯性权重、加速度因子等参数选值对算法的影响,选取了最佳参数组合。搭建了分布式光纤温度传感系统实验平台,运用所建立的DTS传感模型对分布式光纤温度传感系统进行相关的仿真及预测。实验及仿真结果表明,传感模型在空间分辨率为1m时,预测误差≤±0.25%;该分布式光纤温度传感系统测温误差≤±0.40℃。  相似文献   

11.
In this paper, we demonstrated that chemically derived graphene oxide (GO) thin film as a humidity sensitive coating deposited on quartz crystal microbalances (QCMs) for humidity detection. By exposing GO thin film coated QCMs to various relative humidity (RH) environments at room temperature, the humidity sensing characteristics of the QCMs such as sensitivity and linearity, response and recovery, humidity hysteresis were investigated. The experiment results show that GO thin film coated QCMs exhibit an excellent humidity sensing performance. Moreover, the possible humidity sensing mechanism of GO thin film coated QCMs was also investigated by monitoring the crystal's motional resistance change. It is suggested that the frequency response of the QCMs is dependent on water molecules adsorbed/desorbed masses on GO thin film in the low RH range, and on both water molecules adsorbed/desorbed masses on GO thin film and variations in interlayer expansion stress of GO thin film derived from swelling effect in the high RH range.  相似文献   

12.
A polyvinyl butyral film incorporating a radiochromic leuco crystal violet dye (LCV) and a UV-absorber of tinuvin-P has been investigated as a high-dose dosimetry for 60Co radiation processing in the dose range of 1–100 kGy. Upon γ-ray exposure, the prepared film undergoes visual color change to deep purple color characterized with an absorption band peaking at 594 nm with a shoulder around 552 nm. The response of films stored in dark place at room temperature overall a period of 55 days exhibited good stability, that the increase in response of irradiated and unirradiated films did not exceed 2% and 4%, respectively overall this storage period. The results indicate that no further protection of films from laboratory fluorescent light during the measurement of irradiated film is required. The effect of temperature and relative humidity on the performance of film during irradiation and the overall uncertainty associated with absorbed dose monitoring were investigated in the present study.  相似文献   

13.
Humidity induced change in the refractive index and thickness of the polyethylene glycol (PEG) coatings are in situ investigated for a range from 10 to 95%, using an optical waveguide spectroscopic technique. It is experimentally demonstrated that, upon humidity change, the optical and swelling characteristics of the PEG coatings can be employed to build a plastic fibre optic humidity sensor. The sensing mechanism is based on the humidity induced change in the refractive index of the PEG film, which is directly coated onto a polished segment of a plastic optical fibre with dip-coating method. It is observed that PEG, which is a highly hydrophilic material, shows no monotonic linear response to humidity but gives different characteristics for various ranges of humidity levels both in index of refraction and in thickness. It undergoes a physical phase change from a semi-crystalline structure to a gel one at around 80% relative humidity. At this phase change point, a drastic decrease occurs in the index of refraction as well as a drastic increase in the swelling of the PEG film. In addition, PEG coatings are hydrogenated in a vacuum chamber. It is observed that the hydrogen has a preventing effect on the humidity induced phase change in PEG coatings. Finally, the possibility of using PEG coatings in construction of a real plastic fibre optic humidity sensor is discussed.  相似文献   

14.
Pd2+-doped ZnO nanotetrapods were prepared and studied for the humidity detection application. The humidity sensors developed were featured by combination of a quartz crystal microbalance (QCM) as a transducer and Pd2+-doped ZnO nanotetrapods as a sensing element. The ZnO nanotetrapods were synthesized by evaporating highly pure zinc pellets (99.999%) at 900 °C in air and PdCl2 was doped on by traditional solution mixing process. Then the mixed solution distributed onto the electrode surfaces of the quartz crystal at room temperature. Pd2+-doped ZnO nanotetrapods were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The experimental results indicated that the response of the sensors varied with the different dosage PdCl2. Linear regression algorithm was used for evincing the highly linear behavior of the Pd2+-doped ZnO nanotetrapods sensor. In this humidity sensing system, the Pd2+-doped ZnO nanotetrapods sensing material coated on the gold electrode of QCM showed good sensitivity (∼74.24324 Hz/%RH (relative humidity)), reproducibility, linearity (R2 = −0.98834), short response and recovery time (less than 5 s).  相似文献   

15.
《Physics letters. A》2020,384(26):126678
We proposed an enhanced-performance relative humidity (%RH) nano-sensor based on MOF-801/TiO2 one-dimensional photonic crystals (1DPC). The maximum reflectance-peak wavelength of it shifted obviously in the range of 20%-90% under varying %RH levels, due to the highly moisture-sensitive MOF-801 film in the 1DPC structure. It was demonstrated that the linear spectrum sensitivity of the MOF-801/TiO2 %RH 1DPC sensor is exceeding 119 pm/%RH from 20%RH to 90% RH, and the sensitivity of reflection power variations exhibits 1.34 dB/%RH with the resolvable relative humidity variation less than 0.1%RH at 15°C. Meanwhile, the sensor shows a fast optical response time less than 100 ms with exceptional repeatability and reliability, which promises successful measurements of human respiration. Moreover, the sensor performance on the structure of 1DPC is investigated, representing a tradeoff between the sensing sensitivity and response time.  相似文献   

16.
The degradation of crystal violet in aqueous solution was investigated using kaolin-supported zero-valent iron nanoparticles (K-nZVI). It was found that K-nZVI with a ratio of kaolin:zero-valent iron nanoparticles (nZVI) at 1:1 was most effective in removing crystal violet. Batch experiments show that more than 97.29?% crystal violet was degraded using K-nZVI, while only 24.36?% was removed using nZVI after reacting for 7?min, where the solution contained 100?mg?L?1 crystal violet at pH 6.5. This is due to a decrease in aggregation of Fe0 nanoparticles and enhanced their reactivity in the presence of kaolin, which was confirmed by the characterization using scanning electron microscopy. X-ray diffraction shows the formation of iron oxide and hydroxide, while UV?CVis spectral shows that the absorption peak of crystal violet was reduced, as well as Fourier transform infrared shows that new bands were formed after K-nZVI reacting with crystal violet. These suggest that degradation of crystal violet by K-nZVI include the oxidation of iron, the adsorption of crystal violet onto the K-nZVI, the transformation of crystal violet to leuko-crystal violet, and finally the cleavage of C=C bond.  相似文献   

17.
提出并研制了基于光纤SPR传感探针的新型湿敏传感器。首先研究了光纤SPR传感探针对环境湿度变化的敏感特性,在此基础上提出在光纤SPR传感探针表面增覆不同厚度且具有水分子吸附功能的PVA薄膜来实现环境相对湿度的监测。研究结果表明,增覆双层PVA薄膜的光纤SPR传感探针在高湿区具有较好监测效果,其共振强度对应的相对湿度测量灵敏度达到1.59%/%RH,较光纤SPR探针呈现显著提高。而增覆单层PVA薄膜的光纤SPR传感探针在高湿区共振波长对应的相对湿度监测灵敏度达到2.411nm/%RH。此外所提出的新型光纤SPR湿敏探针在PVA薄膜失效后经过特殊工艺处理仍可重复镀膜使用。  相似文献   

18.
王海燕  李新建 《物理学报》2005,54(5):2220-2225
报道了硅纳米孔柱阵列(Si-NPA),Fe3O4复合的Si-NPA(Fe 3O4/Si-NPA)两种薄 膜材料的制备方法并对其形貌和结构进行了表征,研究了其电容湿度传感特性.结果表明,S i-NPA,Fe3O4/Si-NPA均为微米/纳米结构复合体系.当环境相对湿 度从11%上升到95% 时,采用100 Hz的信号频率进行测试,以Si-NPA和Fe3O4/Si-NPA 为电介质材料制成的湿 敏元件的电容增加值分别为起始值的1500%和5500%;采用1000 Hz的信号频率测试时,则 分别为起始值的800%和12000%,显示出两种材料较高的湿度灵敏性和较强的绝对电容输出 信号强度.同时,在升湿和降湿过程中,Si-NPA,Fe3O4/Si-NPA都 具有较快的响应速度 ,其响应时间分别为15 s,5 s和20 s,15 s.文章结合材料的形貌和结构特性对其物理机理 进行了分析.上述结果表明,Si-NPA无论是直接作为湿度薄膜传感材料还是作为复合薄膜湿 度传感材料的衬底都具有很好的前景. 关键词: 硅纳米孔柱阵列 3O4')" href="#">Fe3O4 湿度电容传感特性  相似文献   

19.
Sensitivity of zinc oxide film to humidity is studied using prism based opto-electronic sensor configuration. Film is deposited on the base of the prism by screen printing. The film is crystalline in nature and has micropores on its surface which is suitable for humidity sensing. The sensing mechanism, here, is the modulation in emergent light intensity with change in ambient humidity. Response of the sensor configuration is repeatable and the configuration is found to be sensitive to relative humidity (RH%) ranging from 5 to 90 RH%.  相似文献   

20.
提出了以聚酰亚胺(PI)为感湿材料的三耦合点单微环新型湿度传感器。外界湿度变化使得聚酰亚胺SOI微环谐振特性发生变化,最终通过谐振波长的漂移量确定湿度值。讨论了不同部位感湿时系统的传感特性,并且选择了最佳湿敏元件。数值模拟结果表明:与传统的单微环传感器相比,新型传感器具有较高灵敏度和测量范围,Through端口的自由频谱范围可提高3倍。三耦合点单微环谐振器整体结构可作为最佳湿敏元件,该传感器在10%RH~80%RH相对湿度范围内,灵敏度可达到0.98 nm/%RH,该结构为制备高灵敏度可集成微型湿度传感器件提供了一定的理论依据。  相似文献   

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