速度调制光谱技术在等离子体诊断中的应用

采用速度调制分子离子激光光谱技术,通过对CO+彗尾带系(A2Π-X2Σ+)(2,3)带转动光谱强度分布和谱线线宽的测量,不仅获得了CO+的转动温度,还获得了离子的漂移速度、迁移率、正柱区电场、热温度等等离子体参量,同时还测量得到速度调制的调制度为0372±0119. 关键词：     

差分浓度调制激光光谱技术

报道了在近红外波段的差分浓度调制激光光谱技术的研究工作,以N2^ 的浓度调制光谱为例,研究了浓度调制制激光光谱技术的特性。将浓度调制光谱与速度调制光谱相结合得到了速度调制光谱调制度与各因素的关系。同时展示的Ar激光发态的差分浓度调制光谱表明,差分浓度调制光谱技术在探测中性自由基分子和分子离子方面具有很大的应用潜力。     

激光诱导AlO自由基B2∑+–X2∑+跃迁光谱研究

基于激光诱导击穿光谱技术, 利用Nd:YAG脉冲激光激发Al₂O₃ (含量为99%)陶瓷片产生等离子体, 获得了AlO自由基B²∑⁺–X²∑⁺跃迁的33条发射谱线. 就AlO自由基光谱的时间演化规律和激光能量对谱线的影响规律进行了研究与分析. 结果表明, AlO自由基光谱出现在Al原子和Al离子光谱之后, 且持续时间较长. 当激光的脉冲能量由10 mJ起不断增加时, AlO自由基光谱强度逐渐减小, 且最大值出现时间随激光能量的增加而后移. 在此基础上, 进行了陶瓷等离子体在空气和氩气环境下的对比试验, 发现从Al₂O₃陶瓷片中激发所产生的AlO自由基必须有空气中O₂参与反应. 关键词： 激光诱导击穿光谱 AlO自由基 B²∑⁺–X²∑⁺跃迁光谱')" href="#">B²∑⁺–X²∑⁺跃迁光谱     

一种新型的分子离子吸收光谱技术

将频率调制和磁旋转 技术应用于速度调制激光光谱技术中,形成一种全新的具有高灵敏度的分子离子光谱测量技术,它不仅保留了速度调制光谱技术掏中性分子吸收信号的特点,同时使噪声达到散粒噪声的测量极限。     

Yb3+掺杂四磷酸盐玻璃光谱研究

制备了Yb³⁺掺杂四磷酸盐玻璃,以实测的吸收光谱及荧光光谱计算了Yb³⁺在四磷酸盐玻璃中各光谱性能参数和激光性能参数,以荧光捕获效应讨论了倒易法和Fuchtbaucr-Ladenbury公式之间的计算差异.此外,还进一步讨论了Yb³⁺在四磷酸盐玻璃中各性能参数的浓度效应以及OH基对Yb³⁺发光的影响.研究表明Yb³⁺掺杂四磷酸盐玻璃具有相当优良的光谱和激光性能参数. 关键词： 3+掺杂')" href="#">Yb³⁺掺杂 四磷酸盐玻璃 光谱性质     

等离子体参数的光谱测量法

通过对速度调制分子离子激光光谱技术中光谱信号的强度及线宽的测量，获得了辉光放电中等离子体的电子浓度、电子温度及德拜长度等主要参数。     

利用双光缔合光谱技术直接测量超冷铯分子0u+(6S1/2+6P1/2)长程态的转动常数的实验研究

实验获得了超冷铯分子6S_1/2+6P_1/2离解限下0_u⁺长程态振动能级v=187的转动常数. 首先利用调制的荧光光谱技术获得了高分辨的转动量子数J=0–6的超冷铯分子纯转动光谱. 利用双光缔合光谱技术, 构建了高精度的频率参考信号, 进而得到了相邻转动能级间的频率间隔. 最后通过非刚性转子模型拟合得到了转动常数和离心畸变常数.     

等离子体参数的光谱测量法

通过对速度调制分子离子激光光谱技术中光谱信号的强度及线宽的测量,获得了辉光放电中等离子体的电子浓度、电子温度及德拜长度等主要参数.     

固体介质中光速减慢现象的研究

利用均匀加宽介质中的光谱烧孔效应在红宝石晶体中观测到了最慢为27.55±0.05m/s的极慢光速. 且介质中光传输的群速度与激光的调制频率、激光光功率以及晶体的晶格方向有关. 调制频率越低、相互作用越强，介质中的光速越慢. 关键词： 光速减慢 光谱烧孔 红宝石     

边带非对称性对调制转移光谱中心频率的影响

调制转移光谱技术广泛应用于高精度激光稳频,而调制边带的非对称性会引起调制转移光谱谱线中心过零点的频移,从而影响稳频定性及复现性.从密度矩阵运动方程出发,导出非对称边带的调制转移光谱线型公式.以此线型公式为基础,从理论上举例讨论了几种因素对稳频的影响,并模拟计算了谱线中心频移与边带非对称程度的关系. 关键词：     

Vibrational transitions in 182W

Directional correlation measurements (e-e, e-γ) have been performed on ¹⁸²W. The multipole mixing ratios have been measured for the 2_γ⁺2?2_g⁺0 and 4_γ⁺2?4_g⁺0 transitions and a 6⁺6-6_g⁺0 transition in the decay of ¹⁸²Ta and ¹⁸²Re. The mixing ratio of the 2_β⁺0-2_g⁺0 transition is discussed. A strong mixing of the 4_β⁺ and 4_γ⁺ states is suggested.     

Quasi-gamma bands in even-mass Xe AND Ba nuclei

Low-lying excited states of ^124,126Xe and ¹³²Ba have been studied by means of in-beam γ-ray spectroscopy in (p, xny) reactions. Excitation functions, angular distributions and γ-γ coincidence spectra were obtained. The 2₂⁺ , 3⁺, 4₂⁺ and 5⁺ levels were observed at the following excitation energies in keV: 846.4(2₂⁺), 1247.5(3⁺), 1437.3 (4₂⁺), 1836.6(5⁺) in ¹²⁴Xe, 879.7(2₂⁺), 1317.3(3 ⁺), 1488.2(4₂⁺), 1903.1(5 ⁺) in ¹²⁶Xe and 1032.1(2₂⁺), 1511.3(3⁺), 1729.9(4₂⁺) in ¹³²Ba. The 2214.3 and 2561.7 keV levels in ¹²⁶Xe were tentatively assigned as the 6₂⁺ and 7⁺ levels, respectively. These 2₂⁺, 3 ⁺, 4₂⁺, 5⁺, 6₂⁺and 7⁺ levels are interpreted as members of a quasi-γ band. The E2/M1 mixing ratios of the 2₂⁺ → 2₁⁺ transitions in ^124,126Xe and ¹³²Ba were obtained as + 6.3^+5.3_?2.0 + 10.8^7.8_?3.2 and + 8.3^+4.9_?2.2, respectively.     

Spectroscopic properties, energy transfer and structural analysis of Sr2CeO4:M+ and Sr2CeO4:Eu3+, M+ (M+ = Li+, Na+, K+)

The room-temperature luminescent emission characteristics of Sr₂CeO₄:M⁺ and Sr₂CeO₄:Eu³⁺,M⁺ (M⁺ = Li⁺, Na⁺, K⁺) have been investigated under UV excitation. By introducing appropriate alkali metal cations dopants (Li⁺, Na⁺, K⁺) into the crystalline lattice, not only emission color of the blue-white-emitting Sr₂CeO₄ doped with low Eu³⁺ content can be tuned to green, but also the red emission intensity of Sr₂CeO₄ doped with high Eu³⁺ concentration is strengthened significantly. The relevant mechanisms have been elucidated in detail.     

Dissociative photoionization of l-menthone: An experimental and theoretical study

The dissociative photoionization mechanism of l-menthone has been investigated with photoionization mass spectrometry using synchrotron radiation. The adiabatic ionization energy (IE) of l-menthone and the appearance energies (AE) of its major fragment ions C₉H₁₅O⁺, C₉H₁₇⁺, C₈H₁₆⁺, C₇H₁₁O⁺, C₆H₁₀O⁺, C₆H₉O⁺, C₅H₈O⁺, C₅H₁₀⁺, C₄H₆O⁺, C₅H₉⁺, C₄H₈⁺, C₄H₇⁺, C₃H₇⁺, C₃H₆⁺, C₂H₂O⁺, and CH₃⁺ are determined with their photoionization efficiency (PIE) spectra in the photon energy region of ∼8−15.5 eV. Breakdown diagrams identifying the major products are presented. Dissociative photoionization channels for formation of these fragment ions are proposed based on comparison of determined experimental appearance energies and energies predicted with the DFT calculations. According to our results, the experimental dissociation energies are in fair agreement with the theoretical values of the possible photodissociation channels of C₁₀H₁₈O.     

Electron stimulated desorption of condensed,branched alkanes

Electron stimulated desorption of H⁺, CH₃⁺, H₂⁺ and D⁺ has been measured as a function of excitation energy for condensed phase neopentane, tetramethylsilane, 2-methylpropane-1-d₁, and 2-methylpropane-2-d₁. The data show that the processes which result in both H⁺ and CH₃⁺ production are initiated by the same excitation. The excitations which produce H⁺, CH₃⁺ and H₂⁺ appear to be largely localized on the methyl groups. The results indicate that multi-electron (hole) final states are responsible for H⁺ and CH₃⁺ desorption.     

Production and loss of N 2 + , Ne+ and Ne 2 + during the decay period of plasmas produced in neon-nitrogen mixtures

Studies of the time dependencies of the number density of N ₂ ⁺ , Ne⁺ and Ne ₂ ⁺ ions have been made during the decay period of plasmas produced in neon containing various concentrations of nitrogen molecules. Reaction rate constants were obtained for N ₂ ⁺ +N₂+Ne→N ₄ ⁺ +Ne((1.2±0.2)×10^?29 cm⁶ sec^?1) and Ne⁺+N₂→N ₂ ⁺ + Ne ((2.9±0.3) × 10^?12 cm³ sec^?1). The ambipolar diffusion coefficient of N ₂ ⁺ in neon was found to beD _a p _o =350±20 cm² sec^?1 Torr.     

小尺寸VmOn+团簇的激光光解和密度泛函计算

通过激光溅射法产生了V₂O_n⁺ (n=1, 2), V₃O_n⁺ (n=1, 2, 3)和V₄O₃⁺等缺氧的钒氧团簇,并采用532和266 nm波长的激光对它们进行了光解研究. 利用密度泛函理论计算与激光光解实验相结合确定了这些团簇的几何结构和可能的光解通道. 激光光解实验表明V相似文献   

Assessment of the nature of interactions of cations with cycloheptatriene derivatives using change in the aromaticity: Comparison with electron density and NBO results

ABSTRACT

Interactions of cycloheptatriene derivatives, C₇H₆X, (X?=?NH, PH, AsH, O, S, Se) with the cations H⁺, CH₃⁺, Cu⁺, Al⁺, Li⁺, Na⁺, and K⁺ are studied using B3LYP functional and 6-311++G(d,p) basis set. The calculated gas-phase cation affinities (CA) and cation basicities (CB) for all molecules decrease as H⁺ > CH₃⁺ > Cu⁺ > Al⁺ > Li⁺ > Na⁺ > K⁺. We used the induced aromaticity in the 7-membered ring of C₇H₆X upon interaction with the cations, M⁺, as a measure of C₇H₆X/M⁺ interaction. Nucleus-independent chemical shift (NICS) and harmonic oscillator model of aromaticity (HOMA) were used as two indices of aromaticity. The highest and lowest induced aromaticities were observed for interactions of H⁺ and K⁺, respectively. Also, the aromaticity induced by interaction with a cation in C₇H₆AsH and C₇H₆PH was larger than that in C₇H₆NH and C₇H₆O. Hence, the aromaticity was considered as a measure of covalency for the C₇H₆X/M⁺ interactions showing a rational dependence on both the molecule and cation. The nature of the interactions was also assessed using electron density, charge distribution analysis and NBO calculations. The results of the aromaticity indices, NICS and HOMA, were compared with the electron density and NBO results.     

Molecular pseudopotential calculations V

The equilibrium geometries, nuclear distances, wave functions and energies for the XY ²₊ , X₂Y⁺, Y₂H⁺ (X=Li, Na, K; Y=Rb, Cs), resp. the X₂H⁺, X₂Y⁺ (X, Y=Cu, Ag, Au) triatomic alkali ions, resp. noble metal ions, further the dissociation energies for the X₂Y⁺→X⁺+XY; XY ²₊ →Y⁺+XY and Y₂H⁺→Y⁺+YH processes are determined with the pseudopotential method. The calculations were performed using the Hellmann-type analytical potential with simple floating-type one-centre wave function.

     

Studies on the analytical potential energy function of diatomic molecular ion XY<Superscript>+</Superscript> using variational method

A new analytical potential energy function for diatomic molecular ion XY⁺ is proposed based on the energy consistent method (ECM). The Coulomb potential included in the new ionic potential contains multipole corrections, converges quickly and is variationally, changeable. The new potential and the ECM are applied to variationally studying the potential energies of eight electronic states of several diatomic molecular ions: the A²π state of CO⁺, the X²∑_g⁺ state of Li₂⁺, the X²∑_g⁺ state of He₂⁺, the 1²∏_u state of Na₂⁺, the A²∏_u state of N₂⁺, the X¹∑⁺ state of KrH⁺, the X²∑⁺ state of SiO⁺ and the A²π state of SO⁺ ion. The present results agree excellently with the experiment-based Rydberg-Klein-Rees (RKR) potentials, and are superior to the commonly used Huxley-Murrell-Sorbie (HMS) analytical potentials, and are better in some cases than some quantum mechanicalab initio potentials in the ionic asymptotic and dissociation regions.