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1.
The magnetoresistivities ρ22(H) and ρ32(H) and the Hall coefficient R 32.1 for single-crystal samples of the n-Bi0.93Sb0.07 semiconducting alloy have been measured at low temperatures in magnetic fields up to H=14 T at HC 2. The samples with three electron concentrations n 1=1.25 × 1016 cms-3, n 2=3.5×1016 cms-3, and n 3=1.6×1017 cms-3 have been studied. The strong anisotropy of the electron spectrum of the alloys has made it possible to observe quantum oscillations of the magnetoresistivity ρ22 (H) at HC 2 for electrons of the secondary ellipsoids with the transition to the quantum limit in high magnetic fields. However, in the same magnetic fields, the quantization condition for electrons of the main ellipsoid is not satisfied. An increase in the energy of electrons of the secondary ellipsoids in the magnetic fields of the quantum limit leads to their migration to the main ellipsoid. After the complete migration, the Fermi energy for the alloy samples with the electron concentrations n 1, n 2, and n 3 increases from 7.0 to 11.3 meV, from 11.0 to 17.1 meV, and from 20.2 to 30.6 meV, respectively. After the migration, the magnetoresistivity for electrons of the main ellipsoid increases with an increase in the magnetic field and the specific features in the behavior of the kinetic coefficients are observed in the vicinity of the magnetic field H=10 T. Therefore, the electronic topological transition from the three-valley electron spectrum to the single-valley electron spectrum occurs in the Bi0.93Sb0.07 single crystals for HC 2 at low temperatures in the range of magnetic fields of the quantum limit.  相似文献   

2.
The first thin La1?xAgyMnO3 epitaxial films (yx) were grown on SrTiO3 (110) substrates with silver present in the ionized state (Ag+) only. The Curie temperatures TC of the compositions with x = y = 0.05, x = y = 0.1, and x = 0.3 and y = 0.27 crystallizing in the hexagonal structure \(R\bar 3c\) above or close to room temperature. The temperature dependences of electrical resistivity ρ and of magnetoresistance ¦Δρ/ρ/¦ = ¦(ρH ? ρ H = 0)/ρH=0¦ pass through maxima near TC, with the magnetoresistance being negative and reaching colossal values of ~7–20% in a magnetic field H = 8.2 kOe not only at TC but also at room temperature. The magnetic moment per formula unit as derived from the saturation magnetization at T = 5 K is substantially smaller than expected for complete ferromagnetic ordering. The magnetization in fields of up to 6 kOe depends on the actual sample cooling conditions, and the hysteresis loop of a field-cooled sample is displaced along the H axis by ΔH. The above properties can be accounted for by the fact that the films are in a two-phase magnetic (ferromagnetic-antiferromagnetic) state induced by strong s-d exchange. The maximum value of Δ H was used to calculate the energy of exchange coupling between the ferromagnetic and antiferromagnetic parts of a sample.  相似文献   

3.
We report on large negative magnetoresistance observed in ferromagnetic thiospinel compound CuCrZrS4. The electrical resistivity increased with decreasing temperature according to the exp(T0/T)1/2, an expression derived from variable range hopping with strong electron-electron interaction. The resistivity under a magnetic field was expressed by the same form with the characteristic temperature T0 decreasing with increasing magnetic field. Magnetoresistance ratio ρ(T,0)/ρ(T,H) is 1.5 for H=90 kOe at 100 K and increases divergently with decreasing temperature reaching 80 at 16 K. Results of magnetization measurements are also presented. A possible mechanism of the large magnetoresistance is discussed.  相似文献   

4.
The transport coefficients of tellurium-doped n-Bi1 ? x Sb x semiconducting alloys (0.07 ≤ x ≤ 0.15) are studied for single-crystal samples in the temperature range 1.5 ≤ T ≤ 40 K and in magnetic fields 0 ≤ H < 20 kOe. The theory developed in this study attributes the specific features in the behavior of the transport coefficients observed in a magnetic field to a strong anisotropy of the electron spectrum and anisotropy in the electron relaxation time. It is found that the dependences of the transport coefficients on the magnetic field for HC 3 can be theoretically expressed through one anisotropy parameter δ, and those for HC 2, by means of several anisotropy parameters, namely, γ, η, ζ, and m 3/m 1. It is established that the anisotropy parameter δ in the n-Bi-Sb semiconducting alloys can be estimated from measurements of the electrical resistivity ρ22(∞)/ρ22(0) ? δ and the Hall coefficient R 12.3(∞)/R 12.3(H → 0) ? δ in a magnetic field HC 3. It is shown that the observed increase in the thermoelectric efficiency by a factor of 1.5–2.0 in the transverse magnetic fields HC 3 and HC 2 originates from the nonmonotonic dependence of the diffusion component of the thermopower Δα22(H)(?TC 1) on the magnetic field. The nonmonotonic dependence of the diffusion thermopower in n-Bi-Sb semiconducting alloys is associated with the strong anisotropy of the electron spectrum, the anisotropy in the electron relaxation time, and the many-valley pattern of the spectrum.  相似文献   

5.
In samples of semiconductor alloys n-Bi0.93Sb0.07 with different electron concentrations (n 1 = 8 × 1015 cm?3, n 2 = 1.2 × 1017 cm?3, and n 3 = 1.9 × 1018 cm?3), dependences of the electrical resistivity on magnetic fields up to 45 T parallel to the current and the bisector axis (HC 1j) have been measured at temperatures of 1.5, 4.5, and 10 K. The obtained dependences ρ22(H) demonstrate quantum oscillations of the resistivity (Shubnikov-de Haas effect), and, in high magnetic fields, there is a resistivity maximum far away from other maxima. On assumption that this maximum is related to the spin-split Landau level N = 0? for electrons of the main ellipsoid, the spin-splitting parameters are calculated for electrons of the main ellipsoid: γ1 = 0.87, γ2 = 0.8, and γ3 = 0.73. Using these values, the oscillation maxima can be reliably related to the numbers of split Landau levels for electrons of the main and secondary ellipsoids. The dependences of the resistivity ρ11 and the Hall coefficient R 31.2 on magnetic field have been measured in a transverse magnetic field at HC 1 and jC 2 on the sample with the electron concentration n 4 = 1.4 × 1017 cm?3. Using similar analysis, the spin-splitting parameter is found to be γ4 = 0.85, which is close to the value of γ2 = 0.8 obtained for the sample with close electron concentration (n 2 = 1.2 × 1017 cm?3) during the measurements in a longitudinal magnetic field. The quantum oscillation maxima of Hall coefficient R 31.2 are shifted to the range of high magnetic fields as compared to the quantum oscillation maxima of resistivity ρ11.  相似文献   

6.
A method for analyzing data on Mott hopping conduction in a magnetic field, ρ ~ exp[(T 0/T)α], based on scaling relation ln[ρ(H)/ρ(0)] = (T 0/T)α F(H/T) for the spin-polarized contribution to the magnetore-sistance is proposed. This general approach is tested for a carbon nanomaterial synthesized from single-wall carbon nanotubes under high pressure (up to 7 GPa). The experiments confirmed the theoretical predictions over the temperature range 1.8–12.0 K in a magnetic field of up to 70 kOe and made it possible to correctly determine all parameters of the localized states involved in the model. The experimental data obtained for carbon nanomaterials synthesized from single-wall carbon nanotubes and a mixture of C2N fullerenes indicate the possible renormalization of the magnetic moment of electrons involved in hopping transport.  相似文献   

7.
The surface magnetic field intensity Hp(y) of low-carbon steel plate specimen was measured after tensile test and unloading; variation of Hp(y) was studied. It was found that Hp(y) signals first decreased with increase in stress, and then reversed to the initial field when the stress was greater than 160 MPa. Under yield stress, Hp(y) reached its maximum, and then decreased slightly with further increase in stress. The initial magnetic signals have great impact on the variation of magnetic field.  相似文献   

8.
Calcium hydrogen phosphate dihydrate (CaHPO4·2H2O, brushite) crystals are grown in gel medium at physiological pH by single diffusion method in the presence of different magnetic field strengths, namely 0, 0.1 and 0.2 Tesla. The results indicate that in the presence of magnetic field, the number of brushite crystals formed at the gel-solution interface reduces and the average size of the crystals increases. This shows that the growth of brushite crystal was favored by magnetism. Vickers and Knoop microhardness studies were carried out on the crystals grown at various magnetic fields. The Vickers (HV) and Knoop (HK) microhardness numbers were found to increase with increasing load. The values of Meyer’s index number (n) decrease while the magnetic field strength increases. Nevertheless the n values are greater than 1.6, which shows that the brushite crystals grown under magnetic fields still fall in the soft material category. The brittle index (Bi), yield strength (σy) and elastic stiffness constant (c11) were calculated. The Young’s Modulus was calculated using the Knoop hardness value and found to decrease in higher magnetic field strengths.  相似文献   

9.
The dependences of the electrical resistivity ρ and the Hall coefficient R on the magnetic field have been measured for single-crystal samples of the n-Bi0.93Sb0.07 semiconductor alloys with electron concentrations in the range 1 × 1016 cm−3 < n < 2 × 1018 cm−3. It has been found that the measured dependences exhibit Shubnikov-de Haas quantum oscillations. The magnetic fields corresponding to the maxima of the quantum oscillations of the electrical resistivity are in good agreement with the calculated values of the magnetic fields in which the Landau quantum level with the number N intersects the Fermi level. The quantum oscillations of the Hall coefficient with small numbers are characterized by a significant spin splitting. In a magnetic field directed along the trigonal axis, the quantum oscillations of the resistivity ρ and the Hall coefficient R are associated with electrons of the three-valley semiconductor and are in phase with the magnetic field. In the case of a magnetic field directed parallel to the binary axis, the quantum oscillations associated both with electrons of the secondary ellipsoids in weaker magnetic fields and with electrons of the main ellipsoid in strong magnetic fields (after the overflow of electrons from the secondary ellipsoids to the main ellipsoid) are also in phase. In magnetic fields of the quantum limit ħω c /2 ≥ E F, the electrical conductivity increases with an increase in the magnetic field: σ22(H) ∼ H k . A theoretical evaluation of the exponent in this expression for a nonparabolic semiconductor leads to values of k close to the experimental values in the range 4 ≤ k ≤ 4.6, which were obtained for samples of the semiconductor alloys with different electron concentrations. A further increase in the magnetic field results in a decrease of the exponent k and in the transition to the inequality σ22(H) ≤ σ21(H).  相似文献   

10.
Gradient films of ferromagnetic 3d metals with prescribed magnetic potential profile along the film thickness are obtained. It is found that the spin-wave resonance spectrum in these films is characterized by anomalous dependences of resonance fields of spin-wave modes H r on the mode number: H r(n) ~ n, H r(n) ~ n 2/3.  相似文献   

11.
The upper critical fields (Hc2) of the single crystals (Sr,Na)Fe2As2 and Ba0.55K0.45Fe2As2 were determined by means of measuring the electrical resistivity, ρxx(μ0H), using the facilities of pulsed magnetic field at Los Alamos. In general, these compounds possess a very large upper critical field (Hc2(0)) with a weak anisotropic effect. The detailed curvature of Hc2(Tc) may depend on the magnetic field orientation and the sample compositions. We argue that such a difference mainly results from the multi-band effect, which might be modified via doping.  相似文献   

12.
In isotopically pure praseodymium hexaboride (Pr11B6) single-crystal samples, the transverse magnetoresistance Δρ/ρ has been measured in a temperature range of 2–20 K in magnetic fields up to 80 kOe. The field and angular dependences Δρ/ρ(H, ?, T 0) reveal a new magnetic phase in the AFM state of Pr11B6 which is observable only for the external magnetic field orientation in a narrow angular range near H ‖ 〈110〉. The data remove the previous contradictions in the Pr11B6 magnetic phase diagram representation and can be explained under the assumption that the spin-polarized regions (ferrons) are involved in the formation of the complex magnetic structure in the Pr11B6 AFM state in the 5d band in the vicinity of the rare-earth ions.  相似文献   

13.
Mössbauer source experiments of dilute 153Eu and 57Fe in SmCo5 and 153Eu in Sm2(Co1-xFex)17 and Sm2 Cox My at 4.1 K were performed. After the 153Sm→β?153 decay the Eu ion is trivalent and exhibits extremely large hyperfine interactions due to strong exchange fields. Since the exchange interactions are comparable to the Eu3+ spin-orbit coupling, we calculated the expectation values of the Eu3+ spin, magnetic hyperfine field and electric field gradient as a function of exchange field and second order crystalline field, by diagonalization of the full Hamiltonian of spin orbit, exchange and crystalline field. For SmCo5 and Sm2(Co1-xFex)17 the exchange and crystalline fields are known and thus allow us to analyze our experimental results and obtain the polarized conduction electron contributions to the magnetic hyperfine field. The contribution due to magnetic neighbour polarization of conduction electrons is found to be linear in exchange field. The experimental results together with the theoretical analysis yield the Eu electric field gradient 4f Sternheimer shielding factor RQ to be 0.26±04. It is shown that Mössbauer studies of two probes (155Gd and Eu3+) in magnetic systems yield directly the second order crystalline field, the exchange field and the various contributions to the hyperfine field acting on the Eu nucleus. From the experimentally measured magnetic hyperfine fields alone, approximate values for the exchange fields in the mixed systems Sm2CoxMy were determined.  相似文献   

14.
If for a relativistic field theory the expectation values of the commutator (Ω|[A (x),A(y)]|Ω) vanish in space-like direction like exp {? const|(x-y 2|α/2#x007D; with α>1 for sufficiently many vectors Ω, it follows thatA(x) is a local field. Or more precisely: For a hermitean, scalar, tempered fieldA(x) the locality axiom can be replaced by the following conditions 1. For any natural numbern there exist a) a configurationX(n): $$X_1 ,...,X_{n - 1} X_1^i = \cdot \cdot \cdot = X_{n - 1}^i = 0i = 0,3$$ with \(\left[ {\sum\limits_{i = 1}^{n - 2} {\lambda _i } (X_i^1 - X_{i + 1}^1 )} \right]^2 + \left[ {\sum\limits_{i = 1}^{n - 2} {\lambda _i } (X_i^2 - X_{i + 1}^2 )} \right]^2 > 0\) for all λ i ≧0i=1,...,n?2, \(\sum\limits_{i = 1}^{n - 2} {\lambda _i > 0} \) , b) neighbourhoods of theX i 's:U i (X i )?R 4 i=1,...,n?1 (in the euclidean topology ofR 4) and c) a real number α>1 such that for all points (x):x 1, ...,x n?1:x i U i (X r ) there are positive constantsC (n){(x)},h (n){(x)} with: $$\left| {\left\langle {\left[ {A(x_1 )...A(x_{n - 1} ),A(x_n )} \right]} \right\rangle } \right|< C^{(n)} \left\{ {(x)} \right\}\exp \left\{ { - h^{(n)} \left\{ {(x)} \right\}r^\alpha } \right\}forx_n = \left( {\begin{array}{*{20}c} 0 \\ 0 \\ 0 \\ r \\ \end{array} } \right),r > 1.$$ 2. For any natural numbern there exist a) a configurationY(n): $$Y_2 ,Y_3 ,...,Y_n Y_3^i = \cdot \cdot \cdot = Y_n^i = 0i = 0,3$$ with \(\left[ {\sum\limits_{i = 3}^{n - 1} {\mu _i (Y_i^1 - Y_{i{\text{ + 1}}}^{\text{1}} } )} \right]^2 + \left[ {\sum\limits_{i = 3}^{n - 1} {\mu _i (Y_i^2 - Y_{i{\text{ + 1}}}^{\text{2}} } )} \right]^2 > 0\) for all μ i ≧0,i=3, ...,n?1, \(\sum\limits_{i = 3}^{n - 1} {\mu _i > 0} \) , b) neighbourhoods of theY i 's:V i(Y i )?R 4 i=2, ...,n (in the euclidean topology ofR 4) and c) a real number β>1 such that for all points (y):y 2, ...,y n y i V i (Y i there are positive constantsC (n){(y)},h (n){(y)} and a real number γ(n){(y)∈a closed subset ofR?{0}?{1} with: γ(n){(y)}\y 2,y 3, ...,y n totally space-like in the order 2, 3, ...,n and $$\left| {\left\langle {\left[ {A(x_1 ),A(x_2 )} \right]A(y_3 )...A(y_n )} \right\rangle } \right|< C_{(n)} \left\{ {(y)} \right\}\exp \left\{ { - h_{(n)} \left\{ {(y)} \right\}r^\beta } \right\}$$ for \(x_1 = \gamma _{(n)} \left\{ {(y)} \right\}r\left( {\begin{array}{*{20}c} 0 \\ 0 \\ 0 \\ 1 \\ \end{array} } \right),x_2 = y_2 - [1 - \gamma _{(n)} \{ (y)\} ]r\left( {\begin{array}{*{20}c} 0 \\ 0 \\ 0 \\ 1 \\ \end{array} } \right)\) and for sufficiently large values ofr.  相似文献   

15.
We present a study of the structural and electrical behavior of nano-polycrystalline mixed barium and alkali substituted lanthanum-based manganite, (La1−yKy)0.7Ba0.3MnO3 with y=0.0-0.3. The samples were synthesized by the polymerization complex sol-gel method. The powder X-ray diffraction (XRD) data of the samples show a single-phase character with space group. The magnetic and electrical transport properties of the nano-polycrystalline samples have been investigated in the temperature range 50-300 K and a magnetic field up to 10 kOe. The metal-insulator transition temperature Tp of all the samples decreased with potassium doping, and also, it increased slightly with the application of magnetic field. The low field magnetoresistance, which is absent in the single-crystalline perovskite, was observed and increased with decreasing temperature. Comparing the experimental resistivity data with the theoretical models shows that the high temperature electrical behavior of these samples is in accordance with the adiabatic small polaron-hopping model. In the metal-ferromagnetic region the resistivity is found to be quite well described by ρ=ρ0+ρ2T2+ρ4.5T4.5.  相似文献   

16.
Polycrystalline La0.70Sr0.30Mn1−yFeyO3 (0.05?y?0.07) samples are prepared by the co-precipitation method and have been studied. The substitution of Mn3+ by Fe3+ reduces the number of available hopping sites for the Mn eg(↑) electron and suppresses the double exchange (DE), resulting in the reduction of the metal–semiconductor transition temperature (TP) and the flux density saturation (Bs). Low-temperature resistivity (ρ) data (below TP) well fit with the relation ρ(T)=ρ0+ρ2T2, indicating the importance of grain/domain boundary effects and electron–electron scattering processes in the conduction of these materials. On the other hand, at high temperature (TP<T<θD/2) conductivity data satisfy the variable range hopping (VRH) model. For T>θD/2 the small polaron hopping model is more appropriate than the VRH model.  相似文献   

17.
The structural, electronic, and magnetic phase transitions induced by the isovalent substitution of the rare-earth Nd3+ ion for the La3+ ion with a larger radius have been investigated in the system of self-doped manganites La1 ? y Nd y MnO3 + δ (0 ≤ y ≤ 1; δ ~ 0.1). For the average radius of the ions in A-sites of the lattice 〈r A 〉 〈 1.19 Å (y 〉 0.5), the phenomena revealed in the manganites are as follows: the ordering of Mn e g orbitals, the transition from the pseudocubic O* phase to the orthorhombic O’ phase, the opening of the dielectric Jahn-Teller gap, the frustration of the collinear ferromagnetic (FM) state, and the transition from the lowtemperature canted FM to canted antiferromagnetic (AFM) state of Mn spins. It is assumed that, in samples with neodymium concentrations y = 0.9 and 1.0 (〈r A 〉 ≈ 1.16 Å) at temperatures T < 12 K, there coexist A- and E-type modulated AFM states similar to the sinusoidal and helical structures of Mn spins, which were previously studied in RMnO3 multiferroics. The magnetic T-H phase diagrams of these samples are characteristic of quasi-two-dimensional antiferromagnets with a very low (zero) magnetic anisotropy in the ab planes. Under these conditions, the phase transition from the A-type AFM phase to the spin-flop state occurs in a relatively weak magnetic field. The AFM ordering of the Nd magnetic moments with a critical phase transition temperature T Nd ≌ 6 K is induced in magnetic fields with a strength H ≥ 3.5 kOe. For the NdMnO3 + δ manganite in a magnetic field H = 10.7 kOe, the curves M(T) are characterized by additional very narrow peaks near temperatures T 1 ≌ 4.5 K and T 2 ≌ 5 K. The additional features revealed for the first time in the magnetization near T = 0 are assumed to be caused by the quantization of the spectrum of free holes in the ab planes by a strong magnetic field.  相似文献   

18.
We report the transport studies of YBa2Cu3Oy/YxPr1−xBa2Cu3Oy and YBa2Cu3Oy/R1−xMxMnO3 superlattices in magnetic fields in which R=La or Nd, and M=Ca or Sr. The X-ray diffraction of samples shows superlattice structure. The resistive transition in a magnetic field shows thermal activated behavior. The flux pinning is reduced when the coupling strength between YBCO layers is decreased. The angular dependence of the critical current of YBa2Cu3Oy/PrBa2Cu3Oy superlattices reveals the dimensionality of superlattices. The magnetoresistance ratio (MR), |Δρ(H=7 T)−Δρ(H=0)|/Δρ(H=7 T), of YBa2Cu3Oy/R1−xMxMnO3 superlattices is affected by the layer coupling of R1−xMxMnO3 layers. The enhancement of the MR ratio in the tri-layer YBa2Cu3Oy/La0.7M0.3MnO3/YBa2Cu3Oy film in the low temperature regime is significant and has a value of 33650% at T=75 K. We attribute this enhancement of the MR to the ordering of magnetic moment in ferromagnetic layers in magnetic fields. The results are discussed in terms of existing theories.  相似文献   

19.
To detect scattering by magnetic correlations and to estimate their characteristic space scale, YBa2(Cu1?x Fex)3O7+y ceramic with x=0.13 and y=0.4 is investigated by the small-angle scattering of polarized neutrons. The measurements are carried out in the range of temperatures 15 K?T?315 K and magnetic fields 0<H?4500 Oe. Anomalies in the temperature curves of the intensity I(T,q) (where q is the momentum transfer) and the polarization P(T,q) are observed in the temperature range T<40 K. Interference between nuclear and magnetic scattering is also observed in this temperature range. The observed phenomena are interpreted as scattering by magnetic correlations having a scale 70 Å<R<370 Å. Irreversible effects and the type of magnetic ordering are discussed.  相似文献   

20.
The electron paramagnetic resonance (EPR) spectra of mixed crystals (BaF2)1?x? y(LaF3)x(CeF3)y (y = 0.001 = 0.1%, x = 0–0.02) are investigated in a magnetic field H‖C4 at a frequency of 9.5 GHz. The angular dependence of the EPR spectrum is measured for the sample with x = 0.02. The lines attributed to Ce3+ impurity centers with tetragonal symmetry and g factors (g = 0.75, g = 2.4) close to those measured for the KY3F10: Ce3+ compound are separated in the complex EPR spectrum. The assumption is made that the aforementioned impurity centers are cubooctahedral clusters of the La6F37 type in which one of the La3+ ions is replaced by the Ce3+ ion.  相似文献   

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