The change in primary extinction during decomposition of a super saturated solid solution 1. System Al-Ag

On the basis of the correlation of diffraction data (intensity and width) of a precipitate with the intensity of reflection of a matrix solid solution it is shown that the change in primary extinction during the decomposition of a solid solution of Agin Alis caused by the precipitation of the phase Ag₂Aland not by the production of lattice defects (zones, stacking faults).

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I. Al-Ag

( ) , Ag Al Ag₂Al, ( , ).

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Reported in part at the VIth Scientific Technical Conference on the Application of X-rays held in Leningrad in 1958.

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The author thanks M. Mikovský for preparing the single crystals of the alloy Al-Ag having a high primary extinction and J. Laek and Prof. J. Bedná for carefully checking their homogeneity and chemical composition.     

An attempt to relate area-preserving diffeomorphisms to Kac-Moody algebras

In the same way as the Virasoro algebra can be connected with Kac-Moody algebras defined on the S ¹ circle, the area-preserving diffeomorphism algebra SDiff(), where is a two-dimensional surface, acts as a derivation algebra on super Kac-Moody algebras with one or two supersymmetries. Then a Sugawara-like construction with fermions of the nonextended SDiff() algebra is discussed.     

Новый тип рентгеновс кого спектрографа

. 1', . . .     

The geometric equation of dislocation dynamics

Recent advances in the continuum theory of dislocations have been achieved mainly in two directions: (1) the differential geometric (non-linear) theory of stationary dislocations, and (2) the formal linear dislocation dynamics. These two are unified here to form a differential geometric dynamical theory of continuous distributions of dislocations. To begin with, the basic concepts of the geometric theory are briefly summed up. The fundamental geometric equation of time-dependent distortions is derived first in a physically instructive elementary way and afterwards by means of exact differential geometry. A symmetrized form of the equation is given in terms of deformations or the metric tensor. The physical meaning of a previously introduced dislocation current tensor is discussed. A general form of the continuity equation for the dislocation current is then given. Thereafter the forces acting on dislocations are dealt with in connection with energy dissipation during plastic deformation and Ohm's law for dislocations, which has been introduced recently. The dislocation conductivity in simple cubic crystals is discussed. Finally, an invariant partition of the torsion (or dislocation) tensor is introduced. The semi-symmetrical part of this tensor corresponds to volume deformations, while the remainder is associated with shape deformations only. The main unsolved problems are enumerated, and some concluding remarks, concerned with the correspondence between dislocation theory on the one hand and general relativity and differential geometry on the other, are added.

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, , : (1) - ( ) (2) . . . , . , . . . , , . . ( ). , . , , , .

     

ПРОВОДИМОСТЬ СРЕДНЕ Й ЧАСТИ КАНАЛА КОНДЕНСИРОВАННЫХ РА ЗРНДОВ

. , . . - , 500 10 000 30 500 . - , .     

ПРИБЛИЖЕННЫЙ МЕТОД УСТРАНЕНИЯ КОЛЛИМАЦИОННЫХ ИСКАЖЕНИЙ РЕНТГЕНОГРАММ МАЛОУГЛОВОГО РАССЕЯНИЯ В СЛУЧАЕ ПРИМЕНЕНИЯ ПЕРВИЧНОГО ПУЧКА С КРУГЛЫМ СЕЧЕНИЕМ

The exact method of eliminating collimation distortion of a diffraction small-angle image by Fourier inversion using a primary beam with circular cross-section is too complicated due to the need for lengthy calculations. The paper describes an approximate method for obtaining undistorted diffraction curves. Examples are given of its graphical use for some scattering functipns and an estimate of the approximation obtained.

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Double quantum transitions in paramagnetic resonance

The theory of double quantum transitions of the M=±2 type, with regard to inhomogeneously broadened spin systems is studied in this paper with the approximation ²T₂T₃ 1. We suppose that the inhomogeneous broadening is formed by an inhomogeneous crystal field. The obtained results describe the magnitude of absorption as a function of the h.f. power and also describe the shape of the absorption curve. It is demonstrated that in inhomogeneously broadened spin systems the absorption curve of double quantum transitions has the form of the difference of two different Lorentz's curves and that at the saturation ( ²T₂T₁ 1) the absorption increases with the cube of the h.f. field intensity. The shape of the curves is expressed by means of phenomenological relaxation constants of the system.

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M=±2 ²T₂T₃ 1. , - . . , ( ²T₂T₁ 1) . .

     

A remark on the third law of thermodynamics

It is shown that Falk's formulation of the third law of thermodynamics (when the energy has minimum value the entropy is also minimum) can be replaced by an equivalent assertion: the absolute minimum energy is unattainable with a finite number of processes.

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,

( , ) : .

     

Quantitative method for determination of fibre texture in wires I. Principle of method and analytical expression of absorption factor

An X-ray diffraction method is described for the quantitative determination of the fibre texture in cylindrical specimens (wires), which does not require specimen preparation. The integrated intensity of the diffracted radiation from a certain atomic plane is measured in the direction parallel to the plane determined by the axis of the wire and by the direct beam for different orientations of the axis of the wire. These measurements can be carried out in practice using an X-ray counter diffractometer or Weissenberg goniometer. The pole figure is determined from the dependence of the diffracted intensity on the orientation of the wire after correcting the intensities for the absorption of radiation in the specimen. The geometric arrangement enables the absorption factor to be calculated analytically. Its form was verified experimentally by measuring the dependence of the intensity of the 220 reflection on the orientation of the axis of a cylindrical specimen of Al containing randomly oriented crystals.

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I.

( ), . , , , . . , . . 220 .

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The author wishes to thank Z. iký for help in carrying out the measurements and calculations.     

The application of the thermodynamics of irreversible processes to welding arcs

The self-regulation of an inert gas shielded metal welding arc is dealt with briefly. A thermodynamic equation is derived for the self-regulation of such an arc.

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. .

     

THe mechanism of the amplification of moving striations in a d-c discharge

To determine the mechanism of the amplification of moving striations one starts out from the processes which [3] showed to be decisive for the production of stratification of the plasma of a positive column. An analysis of the influence of other processes shows that the main processes leading to the decay of space charges and thus to a smoothing out of the inhomogeneities and thereby to the attenuation of the periodic structure, cannot by overcome by ionization phenomena caused by changes in the concentration of electrons but only partially compensated.It was found that the process which can lead to the predomination of the processes of amplification over the attenuation is the process of the spatial shift of the temperature deflections of the electrons with respect to the additional electric field, which is expressed in a simplified way by Eq. (12).By solving the extremely simplified basic equations it is proved that under favourable conditions this displacement can lead to both a time and a spatial amplification of the striations. Such a possibility is also verified quantitatively by substituting numerical values into the formulae obtained.

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, [3] . , , , , , ., , (12). , , . .

     

КОРРЕКЦИОННЫЕ ФАКТО РЫ ПРИ АБСОЛЮТНОЙ ДОЗ ИМЕТРИИ ПЛОСКИХ ИСТОЧНИКОВβ-ИЗЛУЧЕНИЯ С ПОМОЩЬЮ СЧЕТЧИКА ГЕЙГЕРА-МЮЛ ЛЕРА

n n, n , .     

Polarization of photo-luminescence of ZnS: Cu monocrystals

Different models of luminescence centres are discussed on the basis of measurements of the composition of ZnS monocrystal photo-luminescence in different polarizations and temperature dependence of the degree of polarization. Those of the models submitted by Birman, which assume the polarization to be due to the different force of the oscillators for transitions withEc andEc, or models assuming luminescence polarization to be due to the orientation of the luminescence centres, agree with the results of experiments, i.e. the temperature independence of the degree of polarization and the conformable spectral composition of both polarizations. It is also shown that measurements made up to now of the degree of polarization must be taken as orientational as a consequence of the depolarizing influence of the diffused rays of luminescence on its value.

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ZnS: Cu

ZnS , . , . . , , , E E, , . , , - .

     

СЕРНИСТЫЙ ТЕЛЛУР — ПО ЛУПРОВОДИОЕ СОЕДИНЕ НИЕ

, , , , .     

The internal friction of longitudinal oscillations in ferromagnetic materials

The paper deals with the theory of the new magnetomechanical phenomenon in an alternating field [6, 7]. The first part concerns the internal friction of longitudinal oscillations of a ferromagnetic material in the shape of a wire in a constant magnetic field. It is assumed that the medium in which the sample oscillates is conducting and has a certain permeability. Equations defining the magnetic field in the oscillating material are derived from the basic thermodynamic relations. The term describing the non-conservative force component in a complex formulation is used to determine the internal friction. A general relation between the internal friction and the magnetic field is derived, as well as other expressions, which are a simplification of it. The second part of the paper deals with internal friction in an alternating field. It is shown that the solution can be transformed to the sum of the internal frictions of the different harmonic oscillations, which are obtained as a partial solution of the problem on the assumption that the elastic oscillations in interaction with the field oscillations are separated into their harmonic components. The calculation then becomes that of the internal friction considered in the first part of the paper. In this case the internal friction significantly depends on the field amplitude. The functional dependence of the internal friction peak on the frequency of the mechanical oscillations is also calculated. The agreement of the theory with experiment is satisfactory.

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e . , , , . , . , . , , , . , , , . , . . . .

     

Summation formulae in the theory of thin films

On the basis of general summation formulae for light reflected and transmitted by a thin film the author derives formulae for a thin dielectric film, for a thin metallic film and for a system of thin dielectric films. This solution is based on Stokes's principle of reversibility, which is the idea unifying the cases into one theory. In conclusion he gives the solution of a general case, dealing with light reflected and transmitted by a system of thin dielectric and metallic films.

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, . , , . , .

     

The influence of elastic deformation on the magnetostriction constant of nickel and iron-nickel alloys

The dependence of the magnetostriction constant of different materials in the form of a wire on the elastic elongation was measured. With pure nickel the magnetostriction constant is independent of the elastic deformation. All three alloys of iron and nickel and the triple alloy Fe-Ni-Co exhibit a linear dependence on the deformation, which differs for different crystallographic texture. In two iron-nickel alloys the dependence of the magnetostriction constants of the single crystal on the elastic deformation was calculated from measurements on polycrystals having different crystallographic textures. In the triple alloy Fe-Ni -Co a considerable linear decrease in the volume magnetostriction with the elastic elongation was also found. The observed changes can be explained by assuming the influence of the lattice deformation on the spinorbital interaction in alloys.

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. . - Fe-Ni-Co , . - . , Fe-Ni-Co . - .

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A preliminary report on some of the results of this paper was given at the conference on magnetism in Kyoto (Japan) in September 1961.

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In conclusion the authors thank Z. Frait C. Sc. and S. Libovický for remarks, J. Míová for help in the measurements, members of the chemical department of our institute for annealing and analyzing the samples and members of the Metal Research Institute in Panenské Beany for their exceptional helpfulness in preparing the wires.     

The distribution of ions and their valencies in magnesium manganese ferrites

A model of the distribution of cations and valencies in non-stoichiometric magnesium manganese ferrites was proposed and its validity verified by measuring the saturation magnetic moments. The results of measuring the moment in stoichiometric ferrites to a certain extent confirms the correctness of the proposed model for this type of magnesium manganese ferrites, too. In a discussion of the distribution coefficient for manganese ions the close connection between this coefficient and the average valency of the manganese was pointed out. The question of the dependence of the distribution coefficient of magnesium ions on the composition is solved by introducing the maximum values of this coefficient and assuming that a simple proportionality holds for all compositions between the actual value of this coefficient and its maximum value.

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e - . - . ] . , .

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In conclusion the author thanks Dr. S. Krupika and K. Závta for valuable discussions.     

ВлИьНИЕ Cd НА пОглОЩЕН ИЕ NaCl

NaCl Cd , .

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The influence of Cd on the absorption of NaCl

Absorption measurements on uncoloured and X-rayed crystals of NaCl with different Cd-concentrations were made to show under what conditions the non-active form of this impurity may become the active form.

     

ЛОКАЛЬНЫЕ КОЛЕБАНлЯ ДВУХАТОМНОЙ ЛлНЕЙНО Й ЦЕПОЧКл С ДЕФЕКТАМл

. n : , . npou u , n . n n npocm .