强磁场中弱相互作用费米气体的热力学性质

基于赝势法和局域密度近似研究了强磁场中弱相互作用费米气体的热力学性质,得出化学势、总能和热容量的解析式,同时分析了磁场及相互作用对系统热力学性质的影响.研究表明,无论是高温情况还是低温情况下,磁场都能调节相互作用的影响.低温下,与无磁场的系统相比,磁场降低系统的化学势、总能和热容量;与无相互作用系统相比,排斥作用增加化学势而降低总能及热容量.高温下,磁场和排斥作用均可降低系统的总能而增加热容量,强磁场可以改变相互作用对总能及热容量的影响. 关键词： 强磁场 弱相互作用 费米气体 热力学性质     

弱磁场中弱相互作用费米气体的热力学性质

根据赝势法和系综理论导出弱磁场中弱相互作用费米气体的内能、化学势和热容量的小参数r的解析式.在此基础上给出高温和低温两种情况下弱磁场中弱相互作用费米气体的热力学性质,探讨磁场及粒子间相互作用对热力学性质的影响,分析磁场与三维谐振势两种约束对系统性质影响的不同及其原因. 关键词： 赝势法 费米气体 相互作用 热力学性质     

有限尺度下弱相互作用费米气体的热力学性质

基于巨正则系综理论和数值模拟方法,研究有限尺度下弱相互作用费米气体的热力学性质,给出系统低温下的化学势、能量及热容量的解析式,分析弱相互作用、有限尺度效应对系统热力学性质的影响.研究表明,有限尺度和排斥相互作用增大了系统的化学势、能量,吸引相互作用减小了系统的化学势、能量.相互作用受到尺度的调制,尺度变大,相互作用影响变小,相互作用和尺度效应都受到温度的调制,温度升高,相互作用和尺度的影响减小.尺度和相互作用的一级修正对热容量无影响.     

有限尺度下弱相互作用费米气体的热力学性质

基于巨正则系综理论和数值模拟方法，研究有限尺度下弱相互作用费米气体的热力学性质，给出系统低温下的化学势、能量及热容量的解析式，分析弱相互作用、有限尺度效应对系统热力学性质的影响.研究表明，有限尺度和排斥相互作用增大了系统的化学势、能量,吸引相互作用减小了系统的化学势、能量.相互作用受到尺度的调制，尺度变大，相互作用影响变小，相互作用和尺度效应都受到温度的调制，温度升高，相互作用和尺度的影响减小.尺度和相互作用的一级修正对热容量无影响.     

反常磁矩对弱磁场弱相互作用费米气体热力学性质的影响

考虑费米子的反常磁矩, 运用赝势法和热力学理论, 导出弱磁场中弱相互作用费米气体自由能的解析式, 以此为基础给出高温和低温情况下系统热力学性质, 分析反常磁矩对热力学性质的影响机理. 研究表明: 反常磁矩对热力学性质的影响与温度相关, 而且这种影响随温度的上升在低温区是增大的, 在高温区是减小的; 对于系统的化学势、内能, 反常磁矩加强了磁场的影响, 弱化了相互作用的影响; 对于系统的热容量, 反常磁矩在低温区使其减小, 在高温区使其增加.     

由N-E-V分布及赝势法研究弱磁场中弱相互作用费米子气体的热力学性质

基于低温下量子系统的相关实验多是在体积、能量和粒子数都可变的外场束缚下进行的事实, 由体积、能量和粒子数可变的完全开放系统的统计分布(N-E-V分布)研究了弱磁场中弱相互作用费米系统的热力学性质. 首先求出了一般情况下由费米积分表示的内能和热容的解析表达式. 在此基础上, 又给出了在低温极限条件下内能与热容的解析表达式和数值计算结果, 并将N-E-V分布(粒子数密度变化)的结果与赝势法(粒子数密度不变)的结果进行了比较. 结果表明: N-E-V分布方法的计算结果总是补偿赝势法计算结果的过度偏差. 由N-E-V 分布方法所得结果最特异之处在于: 在低温条件下, 弱磁场中弱相互作用费米系统存在一相变温度t_c, 其正处于费米系统发生玻色-爱因斯坦凝聚(BEC)和费米原子形成库珀对的超流状态(BCS)相变及BEC-BCS跨越的温度范围内, 且不随反映弱相互作用大小和特征的散射长度a (a<0引力, a>0斥力)变化, 但随弱磁场的加强而降低, 即弱磁场可调节该相变温度. 磁场为零时, 相变温度最高, 为费米温度的0.184倍.     

弱磁场中弱相互作用费米气体的有限粒子数效应(英文)

由弱磁场中弱相互作用费米气体的配分函数,导出有限粒子数条件下系统的配分函数G(β,N ).在此基础上,运用统计平均方法求解有限粒子数弱相互作用费米气体热力学量的解析表达式,给出各种温度条件下的热力学性质.研究结果表明,有限粒子数效应使各个热力学量都产生了一个修正项,除温度趋于0外,粒子数对化学势的修正项有直接影响,对内能和热容量的修正项并不产生直接影响.并且有限粒子数效应总是降低化学势,从而使化学势的0点向低温漂移,粒子数增大,会削弱这种效应,粒子间的相互排斥会加强这种效应.     

相互作用对玻色气体热力学性质及稳定性的影响

根据由赝势法得到的非理想玻色气体的自由能和状态方程，研究了相互作用对凝聚温度的影响.从热力学角度揭示了存在引力作用时定压热容量、等温压缩系数、定压膨胀系数的反常热力学特性.研究了引力作用下玻色气体系统的不稳定性，给出了不稳定性的温度判据和粒子数密度判据. 关键词： 相互作用 玻色气体 热力学性质 不稳定性判据     

非相对论弱相互作用玻色气体的有效场理论处理

采用有效场理论研究了非相对论弱相互作用玻色-爱因斯坦凝聚量子气体的一般性质.在分析了系统的不可重整化性质后,从有效拉氏量出发,计算了最低阶环路修正下拉氏量参量的运动耦合常数(running coupling constant)的形式,并且得到了相应的微分方程.研究结果表明,不同于相对论玻色气体的有效理论,对非相对论弱相互作用的玻色气体,可以移除该有效理论中的内禀能量尺度,即可令该有效理论的内禀能量尺度取无穷大值.所得的分析结果将有助于对玻色-爱因斯坦凝聚的临界性质和行为的深入研究.     

谐振子势阱囚禁玻色气体的玻色-爱因斯坦凝聚

基于Thomas-Fermi半经典近似研究了谐振子势阱约束下任意维理想玻色气体的玻色-爱因斯坦凝聚(BEC).导出了玻色气体的BEC转变温度、基态粒子占据比例、内能和热容量等物理量的解析表达式,讨论了空间维度和谐振子势阱的影响.以二维和三维玻色系统为例,数值计算了上述热力学量,并与解析结果进行了对比,二者获得了较好的吻合.     

Thermodynamic stability of a weakly interactingFermi gas trapped in a harmonic potential

Based on the theoretical results derived from pseudopotential method and local approximation, this paper studies the thermodynamic stability of a weakly interacting Fermi gas trapped in a harmonic potential by using analytical method of thermodynamics. The effects of the interparticle interactions as well as external potential on the thermodynamic stability of the system are discussed. It is shown that the system is stable as for the complete average, but as for local parts, the system is unstable anywhere. This instability shows that the stability conditions of mechanics cannot be satisfied anywhere, and the stability conditions of thermostatics cannot be satisfied somewhere. In addition, the interactions and external potential have direct effects on the local stability of the system.     

Finite-size effects in a D-dimensional ideal Fermi gas

By using the Euler-MacLaurin formula,this paper studies the thermodynamic properties of an ideal Fermi gas confined in a D-dimensional rectangular container.The general expressions of the thermodynamic quantities with the finite-size corrections are given explicitly and the effects of the size and shape of the container on the properties of the system are discussed.It is shown that the corrections of the thermodynamic quantities due to the finite-size effects are significant to be considered for the case of strong degeneracy but negligible for the case of weak degeneracy or non-degeneracy.It is important to find that some familiar conclusions under the thermodynamic limit are no longer valid for the finite-size systems and there are some novel characteristics resulting from the finite-size effects,such as the nonextensivity of the system,the anisotropy of the pressure,and so on.     

Thermodynamic limit for classical systems with Coulomb interactions in a constant external field

We introduce a new method for studying the thermodynamic limit for systems of particles with Coulomb interactions. The method is based on calculating the potential energy of the Coulomb interactions from the electric or magnetic fields in the system rather than from the energy of the individual particle — particle interactions. We are able to include the effects of a constant external field being imposed at the boundary of the system. The difficulties associated with Coulomb potentials being not even weakly tempered are overcome by imposing the boundary condition that at the boundary of the region containing the particles, the electric or magnetic field has normal component equal to that of the applied field. We prove that the thermodynamic free energy density exists and is independent of the sequence of regions used to define the limit. We introduce sequences of regions all of the same shape and show that for these sequences of regions the thermodynamic free energy density is independent of shape. Finally, we prove that the thermodynamic free energy is a convex function of the density of particles and of the applied field.     

Unified properties of a weakly interacting Fermi gas in a weak magnetic field

When the orbital motion and the spin motion of particles were considered simultaneously, the thermodynamic potential function of a weakly interacting Fermi gas in a weak magnetic field was derived using the thermodynamics method. Based on the derived expression, the analytical expressions of energy, heat capacity, chemical potential, susceptibility and stability conditions of the system were given, and the effects of the interparticle interactions as well as the magnetic field on the properties of the system were analyzed. It was shown that the magnetic field always causes energy and stability to decrease, while the chemical potential of the system to increase. The repulsive (attractive) interactions always increase (decrease) energy and stability, but decrease (increase) the chemical potential and paramagnetism. The repulsive (attractive) interactions decrease (increase) heat capacity of the system at high temperatures but increase (decrease) it at low temperatures.     

Relativistic thermodynamic properties of a weakly interacting Fermi gas in a weak magnetic field

This paper derives the analytical expression of free energy for a weakly interacting Fermi gas in a weak magnetic field, by using the methods of quantum statistics as well as considering the relativistic effect. Based on the derived expression, the thermodynamic properties of the system at both high and low temperatures are given and the relativistic effect on the properties of the system is discussed. It shows that, in comparison with a nonrelativistic situation, the relativistic effect changes the influence of temperature on the thermodynamic properties of the system at high temperatures, and changes the influence of particle-number density on them at extremely low temperature. But the relativistic effect does not change the influence of the magnetic field and inter-particle interactions on the thermodynamic properties of the system at both high and extremely low temperatures.     

Statistic properties of Fermi gas in a strong magnetic field

Based on the thermodynamic potential function of Fermi gas in a strong magnetic field, using the thermodynamics method, the integrated analytical expressions of thermodynamic quantities of the system at low temperatures are derived, and the effects of the magnetic field on the statistic properties of the system are analysed. It is shown that, as long as the temperature is not zero, the effects of the magnetic field on the thermodynamic quantities of the system contain both oscillatory and non-oscillatory parts. For the non-oscillatory part, compared with the situation of Fermi gas in a weak magnetic field, the influence of the magnetic field on the thermodynamic quantities is not exactly the same. For the oscillatory part, the period and amplitude of the oscillation are all related to the magnetic field. Due to the oscillation, the chemical potential may be greater than Ferim energy of the system, but the oscillation does not affect the thermodynamic stability of the system.     

Effect of side by side interactions on the thermodynamic properties of adsorbed CO molecules on the Ni(111) surface: a cluster model study

The effect of electrostatic interactions on vibrational frequencies and thermodynamic properties of CO adsorbate on the Ni(111) surface is calculated by taking the first and second nearest-neighbour interactions into account. In order to obtain reasonable results, the cluster model of various surface adsorption sites with CO adsorbate is partially optimized, using Density Functional Theory and also the MP2 method for the hcp site. Comparison between DFT and MP2 results shows that DFT results are more reliable for this system. The stretching and bending frequencies of CO adsorbate are calculated using both Partial Hessian Analysis and Cluster–Adsorbate Coupling methods. Stretching and bending frequencies are both shifted by the side by side interactions. The coupling of surface phonons and adsorbate vibrations reduces the side effects. The largest side effects on the vibrational internal energy, isochoric heat capacity, entropy and total Helmholtz free energy of adsorbed CO molecule calculated using the CAC method are found for 0.5 ML coverage. The results of the CAC method are better, but the PHA method can be used as a simple upper bound estimation. The adsorptive phase acts as an intelligent material in such a way that it changes its configuration in order to reduce the side effects.