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1.
High resolution absorption spectra of the (4, 20) band in the second negative system (A2ΠuX2Πg) of O2+ cation were measured and analyzed in the range of 11 900–12 300 cm–1 via optical heterodyne velocity modulation spectroscopy. Precise molecular constants of the levels involved were obtained by a nonlinear least-squares fitting procedure combining with our previous spectra of the (4, 19) and (6, 20) bands.  相似文献   

2.
The infrared spectrum of yttrium monoiodide has been excited in an electrodeless microwave discharge and explored between 2500 and 12 000cm−1 with a high-resolution Fourier transform spectrometer. A unique system is observed (ν00 = 9905.520 cm−1), which we attribute to a 1Π → 1Σ transition and an extensive analysis is made. Rovibrational constants are obtained for both states mainly from a simultaneous multiband fitting. This procedure is applied to the whole set of 2231 observed line wavenumbers in the 1-0, 0-0, and 0–1 bands, yielding a final weighted standard deviation of 0.0038 cm−1. Furthermore, a partial analysis of the 2-0 and 3-1 bands is performed. The following equilibrium constants are derived (cm−1): ω′e=192.210 ω′exe=0.463Be=0.0399133 α′e=0.0001150ω″e=215.815 ω″exe=0.514Be=0.0422163 α″e=0.0001125 High-order constants Dv and Hv are also calculated for the various vibrational levels (v′ = 0, 1, 2, 3; v″ = 0, 1).  相似文献   

3.
This paper describes invariance of the normalized optical spectrum for a particular class of optical fields propagated in the far zone from a secondary, spatially, partially coherent source. The optical field across the secondary planar source is inhomogeneous to give the complex degree of spectral coherence such that μ = h(αω(ρ1–ρ2))exp(iɛω(ρ12–ρ22)), where α, ɛ are constants, ω is optical frequency, and ρ1, ρ2 denote two points in the secondary source. This expression for μ is the same as obtained in the Fresnel zone from a primary, spatially incoherent source. The invariance law does not hold for the spectrum of the light propagated from the primary source.  相似文献   

4.
Measurements of the electron paramagnetic resonance (EPR) of Fe3+ ion pairs in InBO3 crystals are conducted. Some parts of the procedure of spectrum identification without measuring the temperature dependence of the resonant line intensities have been developed. Experimental curves of the second- and fourth-order axial Hamiltonian constants D S and (aF)S, respectively, of the total spin number S are constructed. The single-ion second-order axial constant D c is well described by a linear dependence on S. The constant (aF)S has a quadratic dependence.  相似文献   

5.
Far-infrared reflectivity spectra of Pb1−xMnxTe (0.0001x0.1) single crystals were measured in the 10–250 cm−1 range at room temperature. The analysis of the far-infrared spectra was made by a fitting procedure based on the model of coupled oscillators. In spite of the strong plasmon–LO phonon interaction, we found that the long wavelength optical phonon modes of these mixed crystals showed an intermediate one–two mode behavior.  相似文献   

6.
Magnetotransport at fields up to 500 mT and LF-noise characteristics are reported for miniature magnetoresistors with ferrite concentrators based on Sn-doped n-InSb/i-GaAs heterostructures grown by MBE. The thickness of the InSb epilayers lie in the range 0.55–1.5 μm giving room temperature mobilities of 2.5–5.5 m2 V−1 s−1 with carrier densities of (0.5–1.5)×1017 cm−3. The room temperature magnetoresistance (MR) for our two terminal devices could be as high as 115% at 50 mT which is comparable to the extraordinary MR (ExMR) recently reported in microscopic composite van der Pauw disks four terminal devices [Science 289 (2000) 1530]. In addition, a high signal-to-noise ratio and a good temperature stability of R(B)/R0=0.5–0.83% K−1 was observed for B<60 mT (below the saturation field Bsat for ferrite). Device resistance stability R0(T) was equal to 0.27–0.66% K−1 in zero field with a nominal device resistance R0=197–224 Ω for DC currents in the range I=0.01–1.0 mA. The minimum detectable magnetic field is estimated from the reduced differential MR (∂R/∂B)/R=2000% T−1 at B=31 mT and normalised 1/f current noise power spectral density measured at the same field. The resolution limit Bmin=2.6 nT at 102 Hz and Bmin=0.82 nT at 103 Hz. These resolution limits are seven times better than those recently reported for the same material n-InSb/i-GaAs and ferrite fabricated Hall sensors [Magnetotransport and Raman characterization of n-InSb/i-GaAs epilayers, for Hall sensors applications over extremely wide ranges of temperature and magnetic field, Proceedings NGS 10, IPAP Conference Series 2, IPAP, Tokyo, 2001, pp. 151–154].  相似文献   

7.
We analyse in detail the behaviour of supersymmetric QCD with a number of flavours M smaller than the number of colours N, for quark masses smaller than the dynamically generated scale Λ. In this regime, we find it useful to move from meson superfields to Nambu–Goldstone-like variables. In particular we work out the mass spectrum and the set of decay constants that specify the interactions of the low-energy theory. We explicitly check that masses and decay constants have a consistent behaviour under decoupling and that they satisfy current algebra requirements. Finally we speculate about the massless limit. For vanishing quark masses, and only in this case, the relation between mesons and Nambu–Goldstone variables becomes singular. When analysed in terms of the Nambu–Goldstone superfields, the massless limit exhibits a spontaneous breaking of the flavour symmetry, with massless Goldstone modes embedded in an M2-dimensional complex moduli space. The symmetry-breaking order parameter is formally infinite, but this has the only effect of turning off the interactions between the chiral superfields. The massive case, for masses smaller than Λ, can be thought of as a perturbation around the massless case, with corrections that can be systematically computed in the effective theory.  相似文献   

8.
High-resolution infrared spectra of the low-lying ν3, ν4, and ν5 fundamentals of the transient molecule DCOCl are reported. These type-A/B hybrid bands have been analyzed in detail, providing extensive rotational assignments for the DCO35Cl and DCO37Cl isotopomers. The ground state constants have been refined by a simultaneous fit of the available microwave data and FTIR combination differences from the three bands. The excited state constants have been determined by fitting assignments over a wide range of J and Ka values. A small perturbation was found at high Ka values in the ν4 band and determined to be due to a ΔKa = −2 interaction with the rotational levels of the 61 vibrational state.  相似文献   

9.
The ν3 mode of T2O, observed at 0.04 cm−1, has been analyzed. By an iterative process of fitting and assignment 210 lines were assigned; 167 of these were used in the final fitting. The standard deviation of the fit is 0.023 cm−1. The rotational constants, A, B, and C, as well as the quartic distortion constants, have been evaluated for the excited state.  相似文献   

10.
The dependence of the electrostatic energy of closely packed structures of metals on the kind of crystalline lattice is investigated in this paper. The fact of a reciprocal dependence of the Ewald constants is noted in different closely packed structures. On this basis, computational formulas are proposed for the Ewald constants, different from those currently used. It is clarified that the error in a linear approximation does not exceed 9·10–8 and 2·10–8 for a quadratic approximation. This permits their application for specific computations. Structures obtained from closely packed ones by axial compression or tension also possess the same property.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 78–81, March, 1987.The author is grateful to Z. A. Matysina for aid in preparing the paper.  相似文献   

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