首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到19条相似文献,搜索用时 93 毫秒
1.
Zr-Ti-Cu-Ni-Be大块非晶低温比热   总被引:2,自引:0,他引:2       下载免费PDF全文
测量了Zr41Ti14Cu12.5Ni10Be22.5大块非晶及不同退火条件的样品在液氦温区的比热.低温下的比热数据可用电子比热和声子比热两部分的贡献来拟合,发现非晶的电子比热系数γ值比其他样品大,德拜温度从非晶到平衡相依次增大,并从电子态密度和德拜理论出发,初步解释了这种差异. 关键词: 低温比热 大块非晶  相似文献   

2.
常压和高压合成MgB2的低温比热及两个超导能隙研究   总被引:13,自引:0,他引:13       下载免费PDF全文
测量了常压和高压合成MgB2超导样品6K—80K的比热,并在数据拟合中考虑了爱因斯坦振动模的贡献,得到其电子比热数据.解释了超声测量得到的德拜温度和低温比热拟合结果之间的巨大差异.并且在12K附近观察到了异常的电子比热,此异常来源于MgB2的第二个能隙.此外,对高压和常压合成对样品的影响做了初步分析. 关键词: 低温比热 MgB2 能隙  相似文献   

3.
分形介质声子导热的频域问题   总被引:1,自引:0,他引:1  
本文论证了分形介质中声子导热的必要条件,给出了分形介质定容比热的频域。结果表明,同一材料的分形介质定容比热恒小于均匀介质的定容比热。  相似文献   

4.
吴子华  谢华清 《物理学报》2010,59(4):2703-2707
对电脉冲诱导的不同电阻态下La0.7Ca0.3MnO3样品的比热进行了研究.实验结果表明,电脉冲导致La0.7Ca0.3MnO3样品比热随电阻状态发生可逆变化.比热随电阻状态的减小而减小.低温比热拟合及不同电阻状态下的比热差与温度关系说明,声子对比热的贡献不随电阻状态变化,磁性和载流子对比热的贡献是导致La0.7Ca0.3MnO3样品比热变化的原因.电脉冲诱导O离子沿一维扩展性缺陷的电化学迁移,导致材料中局部区域的O离子浓度发生变化.O离子浓度的变化导致载流子浓度的变化,同时载流子浓度的变化将使得低温下磁性耦合强度发生变化,从而导致比热发生变化. 关键词: 0.7Ca0.3MnO3')" href="#">La0.7Ca0.3MnO3 比热 氧离子迁移  相似文献   

5.
吴子华  谢华清 《中国物理 B》2010,19(4):2703-2707
对电脉冲诱导的不同电阻态下La0.7Ca0.3MnO3样品的比热进行了研究.实验结果表明,电脉冲导致La0.7Ca0.3MnO3样品比热随电阻状态发生可逆变化.比热随电阻状态的减小而减小.低温比热拟合及不同电阻状态下的比热差与温度关系说明,声子对比热的贡献不随电阻状态变化,磁性和载流子对比热的贡献是导致La0.7Ca0.3MnO3样品比热变化的原因.电脉冲诱导O离子沿一维扩展性缺陷的电化学迁移,导致材料中局部区域的O离子浓度发生变化.O离子浓度的变化导致载流子浓度的变化,同时载流子浓度的变化将使得低温下磁性耦合强度发生变化,从而导致比热发生变化.  相似文献   

6.
以海森堡相互作用模型为基础,系统分析了铁砷超导体自旋密度波的反铁磁表现形态,计算了长波近似条件下的内能和比热等理论值,比较讨论了与实验结果的符合情况及其相应意义,表明自旋密度波理论在较低温度下基本能够描述铁砷超导体的有关特征.详细分析讨论了电子和声子在不同低温区对比热的贡献,与实验结果进行了比较.  相似文献   

7.
本文概述了低温量热的发展历史和基本原理.按照绝热、非绝热和半绝热的分类,介绍了低温量热技术近年来的发展.又较为系统地介绍了低温量热在固态研究中的应用.以最近的实验结果为例,讨论如何从测量数据进行各种模式比热贡献的分解.如何通过比热研究抽取物质内部相互作用的信息.其中较为详细地介绍了对钆镓石榴石的比热研究,利用能级图将比热和磁化强度测量所获得的似为矛盾的结果统一起来.  相似文献   

8.
Y_(0.9)Ba_(0.1)CuO_3超导体的低温比热   总被引:1,自引:0,他引:1  
测量了陶瓷超导体Y_(0.9)Ba_(0.1)CuO的低温比热,在Tc=90K附近未观察到比热跃变,而发现在12K附近存在典型的λ-相变,反映在样品中同时含有一个低Tc的超导相。从12K以上的低温比热数据计算出该超导体的德拜温度为400K左右,比热中线性项的系数较大,其中含有原子振动自由度的贡献。  相似文献   

9.
研究了低温下NdMnO3单晶的比热随温度和磁场的变化(2K≤T≤200K,0T≤H≤8T ).对应于 Mn磁矩亚晶格的A型反铁磁(A-AF)相变,零场下的比热曲线在85K附近出现尖锐的λ形峰,随 着磁场的增加,此λ峰降低展宽而且平滑变化,这与此温度附近磁化强度的变化规律一致. 与磁有序相变相关的熵变约为理论值的26%,这可能是由于磁有序涨落延续在较大温区造成 的.在20K以下,比热曲线出现了明显的肩膀形状的Schottky反常,其峰值随着磁场的增加而 逐渐向高温移动.考虑了低温下比热的各种贡献,根据Nd3+位有效分子场(H mf) 引起的Nd3+基态双重态(GSD)劈裂对上述现象进行了解释.通过对2K≤T≤2 0K,0T≤ H≤8T范围内比热数据的拟合,得到了样品的GSD劈裂,德拜温度和A-AF自旋波劲度系数以及 它们对磁场的依赖关系.发现GdFeO3型八面体旋转引起的A-AF结构中Mn磁矩亚晶 格的铁磁成分可能是Hmf的来源. 关键词: 比热 Schottky反常 反铁磁相变  相似文献   

10.
设计了一套测量材料低温比热的装置,在13.81—273.15K范围内,先后用纯铋和无氧铜作为校验样品,测得的比热值与美国珀杜大学(Purdue University)热物理性能研究中心(TPRC)汇集的数据比对,偏差小于2.8%. 从简单固体原子比热的Debye模型出发,提出了低温比热测试中确定最佳温升△T的方程式.给出了误差分析及一些材料的比热测试结果.  相似文献   

11.
The specific heat of the layer compound semiconductor tin diselenide SnSe2 has been measured in the temperature range from 2.7 to 280 K. In this range, the overall temperature dependence of the specific heat is dominated by the lattice contribution, which yields a limiting Debye characteristic temperature at absolute zero θD (0) = 140 ± 2K. The increase in the specific heat at low temperatures is more gradual than what would be expected for a simple Debye solid, and reflects the quasi-two dimensional layer structure of this compound.  相似文献   

12.
The Morin transition in samples of natural haemitite has been examined by specific heat and Mössbauer measurements. Specific heat measurements on as-received samples reveal an anomaly at ~ 273.2 K and irregular behaviour at higher temperatures. However, heat treatment of samples demonstrated that these effects were due to water trapped inside the natural specimens.No anomaly due to the Morin transition was observed in the specific heat although the expected changes in the Mössbauer hyperfine parameters were observed for the different magnetic phases below and above the Morin transition. The results are consistent with a coexistence of the two phases and a spread of temperatures ~ 40 K over which the transitions take place throughout the material of purity 99.6 wt%.  相似文献   

13.
Adiabatic expansion of plasma behind the reflected shock front in an electromagnetic shock tube has been verified. Electron densities and temperatures have been measured spectroscopically. Assuming complete local thermal equilibrium, the specific heat ratios of hydrogen plasmas have been determined out of expansion rate per a heavy particle directly from the adiabatic expansion law. Noticeably lower values of the ratio are determined at temperatures where ionization and recombination processes are abundant. The ratios determined in this work are in excellent agreement with theoretical values determined in an earlier work.  相似文献   

14.
The specific heat at constant pressure of polycrystalline LiCuVO4 has been measured at temperatures of 80 to 310 K. The data obtained corroborate the earlier conclusion that this material is a superionic.  相似文献   

15.
The specific heat of rare earth nitrides has been measured at temperatures between 1.7 ans 270°K by means of an adiabatic calorimeter. The various terms contributing to the total specific heat have been separated. The total splitting of the ground-state multiplet of the trivalent RE-ions in the octahedral crystal field has been determined. The experimental values agree reasonably well with those calculated with the point charge model. The spontaneous magnetization and the magnetic specific heat below the ordering temperature are calculated with the molecular field theory by taking into account all the 2J+1 energy levels of the ground-state multiplet and including exchange interaction and crystal field splitting. Comparision is made with the experimental results, and the values obtained for the exchange energies are listed.  相似文献   

16.
Monte Carlo simulations of a binary alloy with impurity concentrations between 20 and 45 at.% have been carried out. The proportion of large clusters relative to that of small clusters increases with the number of MC diffusion steps as well as impurity concentration. Magnetic susceptibility peaks become more prominent and occur at higher temperatures with increasing impurity concentration. The different peaks in the susceptibility and specific heat curves seem to correspond to different sized clusters. A freezing model would explain the observed behaviour with the large clusters freezing first and the small clusters contributing to susceptibility (specific heat) peaks at lower temperatures.Contribution No. 153 from the Solid State and Structural Chemistry Unit  相似文献   

17.
An exact analytical expression for the specific heat jump at the critical temperature Tc has been obtained directly from the BCS gap equation for any shape of the energy dependent electronic density of states (DOS). We consider a model which takes into consideration electron-electron repulsion, formulated in the Hubbard model along with the electron-electron attraction due to electron-phonon interaction in the BCS formalism. We have analyzed this expression for constant as well as for the Lorentzian forms of DOS. It is shown that the constant DOS in the simple BCS theory cannot explain the large values of , found in some superconductors. The specific heat versus temperature curve has been found to have a peak, similar to that of Eliashberg theory of superconductivity. The influence of repulsive interaction is very small and occurs mainly at higher temperatures. Received: 26 January 1998  相似文献   

18.
The low temperature specific heat and thermal conductivity of (Cu50Zr50)94Al6 bulk metallic glass have been studied experimentally. A low temperature anomaly in the specific heat is observed in this alloy. It is also found that in addition to Debye oscillators, the localized vibration modes whose vibration density of state has a Gaussian distribution should be considered to explain the low temperature phonon specific heat anomaly. The phonon thermal conductivity dependence on temperature for the sample does not show apparent plateau characteristics as other glass materials do; however, the influence of the resonant scattering from the localized modes on the lattice thermal conductivity is prominent in the bulk metallic glass at low temperatures.  相似文献   

19.
The specific heat of an amorphous superconductor Zr3Rh (Tc = 4.3 K) has been measured in the temperature range from 0.35 K to 10 K and with an applied magnetic field of 75 kG. The high field suppresses superconductivity and allows accurate determination of the phonon (βT3) term for the lowest temperatures studied. A careful subtraction of the normal electronic specific heat (γT) and phonon terms reveals a well defined excess linear heat capacity γ'T at low temperature. This excess term is attributed to localized lattice excitations using the two-level tunneling defect model of Phillips.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号