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1.
Nylon 6/poly(acrylonitrile‐butadiene‐styrene)(ABS) blends were prepared in the molten state by a twin‐screw extruder. Maleic anhydride‐grafted polypropylene (MAP) and solid epoxy resin (bisphenol type‐A) were used as compatibilizers for these blends. The effects of compatibilizer addition to the blends were studied via tensile, torque, impact properties and morphology tests. The results showed that the additions of epoxy and MA copolymer to nylon 6/ABS blends enhanced the compatibility between nylon 6 and ABS, and this lead to improvement of mechanical properties of their blends and in a size decrease of the ABS domains.  相似文献   

2.
《Composite Interfaces》2013,20(5-7):603-614
In this study composites of high density polyethylene (HDPE) with various SiO2 content were prepared by melt compounding using maleic anhydride grafted polyethylene (PE-g-MAH) as a compatibilizer. The composites containing 2, 4 and 6% by weight of SiO2 particles were melt-blended in a co-rotating twin screw extruder. In all composites, polyethylene-graft-maleic anhydride copolymer (PE-g-MAH, with 0.85% maleic anhydride content) was added as a compatibilizer in the amount of 2% by weight. Morphology of inorganic silica filler precipitated from emulsion media was investigated. Mechanical properties and composite microstructure were determined by tensile tests and scanning electron microscopy technique (SEM). Tensile strength, yield stress, Young's modulus and elongation at break of PE/SiO2 composites were mainly discussed against the properties of PE/PE-g-MAH/SiO2 composites. The most pronounced increase in mechanical parameters was observed in Young's modulus for composites with polyethylene grafted with maleic anhydride. The increase in the E-modulus of PE/PE-g-MAH/SiO2composites was associated with the compatibility and improvement of interfacial adhesion between the polyethylene matrix and the nanoparticles, leading to an increased degree of particle dispersion. This finding was verified on the basis of SEM micrographs for composites of PE/PE-g-MAH/4% by weight of SiO2. The micrographs clearly documented that addition of only 2 wt% of the compatibilizer changed the composite morphology by reducing filler aggregates size as well as their number. Increased adhesion between the PE matrix and SiO2 particles was interpreted to be a result of interactions taking place between the polar groups of maleic anhydride and silanol groups on the silica surface. These interactions are responsible for reduction of the size of silica aggregates, leading to improved mechanical properties.  相似文献   

3.
为了解决周期性爆发的巢湖水华蓝藻难以处置的问题,同时改善低密度聚乙烯材料降解周期长的现状,以低密度聚乙烯(LDPE)为基体,以巢湖新鲜水华蓝藻制得的蓝藻粉为生物材料,以马来酸酐接枝聚乙烯 (PE-g-MAH)为增容剂,以聚乙烯蜡和白油为润滑剂制备复合材料。设置蓝藻粉含量和增容剂含量2个因素作为实验因素,实验材料按一定比例充分混合后,双螺杆挤出制得了复合材料颗粒,再经过注塑方式获得待测样条。通过紫外-可见光谱扫描(UV-VIS)联合傅里叶变换红外光谱扫描(FTIR)的光谱学方法了解水华蓝藻粉、增容剂和复合材料的光谱学特征,分析复合材料制备过程中的结构变化,能够先决性判断该种实验方法对制备新型生物材料的可行性。并以力学性能测试和扫描电镜(SEM)等方法作为辅助手段,与光谱分析的结果相互反馈,充分分析水华蓝藻粉、增容剂含量对复合材料结构与性能的影响。结果显示:通过紫外可见光谱分析,蓝藻初提液在260和620 nm处出现藻蛋白质的特征吸收峰,表明了蓝藻细胞液中藻蛋白的存在,具备作为生物反应材料的基本条件。红外光谱分析可知,蓝藻粉在1 630,1 540和1 440 cm-1附近出现特征吸收峰,符合酰胺键的出峰规律,在3 300 cm-1附近出现O-H的特征吸收峰,进一步验证了蓝藻粉活性位点的存在;马来酸酐的红外光谱图中,酸酐在1 850和1 740 cm-1处出现C═O基的特征峰,环状酸酐中C-O-C的伸缩振动特征峰出现在1 200 cm-1附近;而经过反应所得的复合材料红外光谱中,除聚乙烯的特征吸收峰以外,蓝藻粉中的酰胺键和O-H,以及马来酸酐对应得特征吸收峰都已减弱或消失了,基本可以推测马来酸酐与-OH发生了开环酯化反应,马来酸酐在生物复合材料的制备过程中起到了连接两个不同反应体系的作用。而且,通过扫描电镜可直观的看出,蓝藻粉含量增加将会导致复合体系中成团现象加剧,增容剂的加入增强了复合体系界面的粘结性;力学性能测试的结果为蓝藻粉含量的增加导致复合材料力学性能下降,尤其冲击性能下降显著降幅达54.10%;当蓝藻粉的添加量为15.00%时,随着增容剂用量的增加,材料的拉伸强度、弯曲性能和冲击性能均呈现先增大后减小的趋势。扫描电镜和力学性能的结果也从侧面验证了光谱分析结果的前瞻性和正确性,避免了盲目实验带来的资源浪费等问题。综合考虑,该生物复合材料可选取蓝藻粉含量15.00%,增容剂含量3.00%,聚乙烯蜡和白油用量3.00%和1.00%的配方,此时的力学性能为:拉伸强度为11.70 MPa,冲击强度为20.00 kJ·m-2,弯曲强度为8.80 MPa,弯曲模量为220.00 MPa。  相似文献   

4.
Halloysite nanotubes (HNTs) filled 80/20 (wt/wt) polypropylene (PP)/acrylonitrile butadiene styrene (ABS) blends and its composites in presence and absence of dual compatibilizer (polypropylene grafted maleic anhydride (PP-g-MA), and styrene-ethylene, butylene-styrene triblock copolymer grafted with maleic anhydrite (SEBS-g-MA)) have been prepared using twin screw extruder followed by injection moulding. Significant refinements in dispersed ABS droplets diameter and interparticle distance between dispersed ABS droplets were observed in case of HNTs filled 80/20 (wt/wt) PP/ABS blends and its composites in presence of PP-g-MA and SEBS-g-MA. This has resulted in significant enhancement in tensile and impact properties of HNTs filled 80/20 (wt/wt) PP/ABS blends and its composites in presence of PP-g-MA and SEBS-g-MA. Refinement in morphology of dispersed ABS phase results in decrease in crystallinity of HNTs filled 80/20 (wt/wt) PP/ABS blends and its composites in presence of PP-g-MA and SEBS-g-MA. In addition, HNTs act as heterogeneous nucleating agent for the growth of PP crystals, and hence crystallization rate of HNTs filled 80/20 (wt/wt) PP/ABS blends and its composites in presence and absence of PP-g-MA and SEBS-g-MA increases. Thermal stability also increases in case of HNTs filled 80/20 (wt/wt) PP/ABS blends and its composites in presence and absence of PP-g-MA and SEBS-g-MA.  相似文献   

5.
Long glass fiber (LGF)-reinforced polypropylene (PP) was prepared using a self-designed impregnation device. The effect of dicumyl peroxide (DCP) and maleic anhydride (MA) content on the compatibilizer, PP grafted with maleic anhydride (PP-g-MA), was investigated by means of scanning electron microscopy (SEM) and mechanical properties. The experimental results demonstrated that the increase of DCP and MA could effectively improve the interfacial interaction between PP and GF. Good interfacial adhesion between PP and GF in PP/ PP-g-MA /LGF composites was observed from SEM studies for the higher contents of MA. The best mechanical properties of PP/ PP-g-MA /LGF(30%) composites were obtained when the content of DCP and MA were 0.4 and 0.8 wt%, respectively. The storage modulus of the PP/PP-g-MA/LGF composites increased and then decreased with the content of MA. When the content of MA was 0.8 wt%, tan δ had the lowest value, indicating that the corresponding composites had the best compatibility.  相似文献   

6.
《Composite Interfaces》2013,20(8):553-573
Jute fiber-reinforced chemically functionalized polyethylene high density (JF/CF-HDPE) composites have been processed, by Palsule process without using any compatibilizer and without any fiber modification, by using chemically functionalized maleic anhydride grafted polyethylene (MAPE) as matrix, in place of polyethylene. Fiber/matrix interfacial adhesion generated in situ, due to interactions between jute fiber and the maleic anhydride of the CF-HDPE matrix, has been established by Fourier transform infrared spectroscopy and scanning electron microscope micrographs. Mechanical properties of the JF/CF-HDPE composites developed with in situ fiber/matrix interfacial adhesion in this study have been found to be higher than those of the CF-HDPE matrix and increase with increasing amounts of jute fibers in the JF/CF-HDPE composites, and are better than properties of literature reported and laboratory processed jute fiber/polyethylene composites with and without MAPE compatibilizer. Measured tensile modulus of JF/CF-HDPE composites compares well with values predicted by rule of mixtures, inverse rule of mixture, Hrisch Model, Halpin-Tsai equations, Nielsen equations, and with Palsule equation. The feasibility of developing natural fiber/maleic anhydride grafted polyolefin composites by Palsule process without using any compatibilizer and without any fiber treatment is demonstrated.  相似文献   

7.
Maleic anhydride grafted polypropylene (PP-g-MA) was employed as the compatibilizer and carbon nanotubes (CNTs) or hydroxylated CNTs as reinforcements for polypropylene/wood flour composites. The results showed that when the PP-g-MA loading level was 10 wt%, the bending strength, tensile strength, Izod notched impact strength, and elongation at break of PP-wood composites were enhanced by 85% (66.3 MPa), 93% (33.7 MPa), 5.8% (2.01 kJ/m2), and 64% (23%), respectively, relative to the uncompatibilized composites. The introduction of pristine CNTs only improved slightly the overall mechanical properties of the compatibilized composites due to poor interfacial compatibility. Unlike CNTs, incorporating hydroxylated CNTs (CNT-OH) could significantly improve all of the mechanical properties; for instance, at 0.5 wt% CNT-OH loading, the flexural strength and tensile strength reached 68.5 MPa, and 40.4 MPa about 6.6% higher than that for the composites with the same CNT loading. Furthermore, CNT-OH also remarkably enhanced the storage modulus. Contact angle and morphology observations indicated that the increases in mechanical properties could be attributed to the improvements of interfacial interactions and adhesions of CNTs with the matrix and fillers.  相似文献   

8.

Super‐tough nylon 6/ABS blends were prepared by using styrene/acrylonitrile/maleic anhydride co‐polymer (SAM) as a compatibilizer. The variations in morphology, mechanical behavior, and crystallinity associated with the reaction of the SAM with the nylon were characterized. The results showed that the addition of SAM to nylon 6/ABS blends enhanced the interfacial adhesion between nylon 6 and ABS, and this led to the decrease of ABS domain size and the improvement of mechanical properties of their blends. Moreover, it could be found that the crystallinity and phase morphology changed with the variation of SAM.  相似文献   

9.
High-density polyethylene/organoclay nanocomposites were prepared via melt intercalation in an internal mixer using both a direct mixing and master batching method. Two types of maleic anhydride grafted polyethylene, high-density polyethylene grafted maleic anhydride, and linear low-density polyethylene grafted maleic anhydride, (HDPE-g-MA, LLDPE-g-MA) were used as compatibilizers to enhance the dispersibility of nanoclay in HDPE. Dispersion of organoclay in the nanocomposites was characterized by using X-ray diffraction (XRD), transmission electron microscopy (TEM), and rheological mechanical spectroscopy (RMS). Effects of clay content and degree of clay dispersion on the rheological and tensile properties were also investigated. Furthermore, the effect of order of mixing on the dispersion and distribution of the clay layers was studied. The obtained results showed that organoclay in the nanocomposites were dispersed homogeneously and exfoliated better when HDPE-g-MA and the direct mixing route were used. Although in the master batching method clay intercalated better, clay layers chiefly remain in compatibilizer rich areas. On the other hand, direct mixing was observed to lead to clay particles being dispersed in the HDPE matrix or at the interface of the matrix and compatibilizer and, consequently, better improvement in the tensile modulus was achieved. It was determined that the compatibilizer with the higher miscibility with the matrix was the key factor for achieving better exfoliation of clay sheets.  相似文献   

10.
In order to prepare intumescent flame retardant acrylonitrile-butadiene-styrene (ABS) composites with only a small decrease in their mechanical properties, we investigated the effect of adding an elastomeric polyacrylate latex and the surfactant TX-10 phosphate to modify the ammonium polyphosphate, melamine, and calcium 3-hydroxy-2, 2-bis(hydroxymethyl) propyl phosphate normally used, which resulted in an intumescent flame retardant composite (IFRC) powder with the aim of improving compatibility. These ABS/IFRC composites were compared with standard material containing unmodified intumescent flame retardant (NIFR) by investigating their thermal properties, melt characteristics, mechanical properties, and microstructure. The data showed that the glass transition temperature of the ABS/IFRC composites decreased slightly in all cases, the complex viscosity of the ABS/IFRC composites was remarkably reduced, and the mechanical properties improved in comparison with the material containing NIFR. A slight increase in impact strength retention, as well as a remarkable increase in tensile and flexural strength retention of ABS/IFRC, was achieved due to superior compatibility between ABS and IFRC in comparison with ABS/NIFR.  相似文献   

11.
The preparation and properties of wood–plastic composites (WPCs) based on acrylonitrile–butadiene–styrene (ABS) and bamboo fibers (BFs) are described. The BFs were first modified by alkali treatment in order to improve their adhesion to an ABS matrix. The BF modifications were monitored by Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). Styrene–maleic anhydride (SMA) copolymer, as a compatibilizer, was added to both the untreated and alkali-treated composites. The changes in the structure and the properties resulting from these treatments were observed by the SEM and mechanical tests. The experimental results indicated that both the alkali treatment of the BF and the inclusion of the SMA copolymer improved the interactions between the BF and ABS matrix, and promoted better mechanical properties of the composites.  相似文献   

12.
The crystallinity, mechanical properties, and thermal stability of polypropylene (PP)/organic montmorillonite (OMMT) and PP/polyolefin elastomer (POE)/OMMT composites, with polypropylene-g-maleic anhydride/styrene (PPMS) as a compatibilizer for both, were compared. The results showed that the strong interaction between the clay platelets and compatibilizer, which were generated by the maleic anhydride (MAH), improved the compatibility of the polymer matrices with the OMMT. A unique lamellar, flocculated structure of OMMT was formed after introduction of the POE. The highly dispersed clay layers could act as nucleating agents, resulting in smaller spherulites and higher crystallization temperatures. Compared with pure PP, the PP/OMMT nanocomposite showed enhanced mechanical properties and thermal stability; however, the PP/POE/OMMT had the best impact toughness.  相似文献   

13.
The blends of polyamide 6/acrylonitrile-butadiene-styrene (PA6/ABS), with added styrene-maleic acid copolymer (SMA) compatibilizer, were prepared through melt mixing in an internal mixer. The effects of blend composition and various process conditions, as well as the addition of multi-wall carbon nanotubes (MWCNTs) to the blends, on the morphology and mechanical properties were investigated. The morphology of the blends and blend nanocomposites were observed by scanning electron microscopy (SEM) and analyzed using an image analysis technique. The mechanical behavior of the blends was investigated by tensile and also impact testing. The results showed that the blend composition as well as the processing conditions significantly affected the morphology and mechanical properties of the PA6/ABS blends. Among the various compositions, the blend with 36?wt.% of ABS and 4?wt.% of SMA compatibilizer exhibited the best mechanical properties. Comparing various speeds and times of mixing, it was found that less mixing speed and longer mixing times resulted in the favorable morphology and conditions for achievement of the desired toughness for the polyamide 6. By adding different amounts of MWCNTs to the blends, it was found that the presence of the carbon nanotubes changed the viscosity of the resulting nanocomposite and thus changed the morphology. These nanocomposites also showed an improvement in mechanical properties. The MWCNTs acted as a second compatibilizer, resulting in a synergistic effect on the mechanical properties of the PA6/ABS blend nanocomposites.  相似文献   

14.
Vinyltriethoxysilane (VTES) was grafted onto natural rubber (NR) in latex form, using potassium persulfate (KPS) as initiator. The VTES grafted NR (NR-g-VTES) was then further reinforced with graphene oxide (GO) by a mechanical mixing method with different GO loadings to get the rubber composite (GO/NR-g-VTES). The NR-g-VTES was characterized and confirmed by attenuated total teflectance-Fourier transforms infrared spectroscopy (ATR-FTIR). The effect of GO content on the curing characteristics and resulting mechanical properties of the GO/NR-g-VTES were studied and compared with neat NR filled with GO (NR/GO). The maximum and minimum torque and the tensile and tear strength of the NR-g-VTES/GO composites were higher than that of NR/GO. The samples containing low GO concentration showed maximum torque and tensile and tear strength. Dynamic mechanical analysis showed that the interaction between GO and NR-g-VTES was better than that of the GO-reinforced NR.  相似文献   

15.
《Composite Interfaces》2013,20(5):309-329
Chemically functionalized maleic anhydride (MAH)-grafted polypropylene matrix has been used (in place of polypropylene as matrix with compatibilizer) to process banana fiber/chemically functionalized polypropylene (BF/CFPP) composites, without using any compatibilizer and without any fiber modification by Palsule process. Fiber/matrix interfacial adhesion generated, in-situ, due to interactions between BF and the MAH of the CFPP matrix has been established by Fourier transform infrared spectroscopy and scanning electron microscopy. Mechanical properties of the BF/CFPP composites developed by Palsule process with in-situ fiber/matrix interfacial adhesion in this study have been found to be higher than those of the matrix and it increases with increasing amounts of fibers in composites, and are better than properties of literature reported BF/polypropylene composites processed with compatibilizers. Measured modulus of BF/CFPP composites compares well with values predicted by rule of mixtures, Hrisch model, Halpin-Tsai equations and its modified Nielsen version, and with Palsule equation. The feasibility of developing natural fiber/MAH grafted polyolefin composites by Palsule process without using any compatibilizer and without any fiber treatment is demonstrated.  相似文献   

16.
《Composite Interfaces》2013,20(4):295-307
The paper reports some results of an experimental study on ethylene vinyl acetate (EVA) copolymer/olive husk flour (OHF) composites incorporated at various filler ratios (15, 30 and 45 wt%) in the absence and the presence of ethylene-butyl acrylate-glycidyl methacrylate (EBAGMA) terpolymer used as a compatibilizer. The composite samples have been prepared by melt blending and their chemical structure, as well as morphological, mechanical and water absorption properties investigated. It is shown that the compatibility of EVA/OHF composites is improved by the addition of EBAGMA terpolymer. Indeed, FT-IR analysis shows that chemical interactions have occurred between the compatibilizer and the base blend components. Morphological results from SEM shows better dispersion of the wood particles in the EVA matrix and the resulting composite samples exhibit better tensile properties at break and lower water absorption than the uncompatibilized ones. Moreover, the results indicate that the loading concentrations of both OHF and EBAGMA have an effect on the composite properties.  相似文献   

17.
The water desorption kinetics of polymer composite systems with hydrophilic cellulose fibers from recycled paper (PSP) filler embedded in various polymer matrices (hydrophobic thermoset epoxy resin [EP] and thermoplastic polypropylene [PP], and hydrophilic thermoplastic poly[vinyl alcohol] [PVA]) was studied. Polymer composites test pieces containing 0, 3, 6, 9, and 30 wt. % of fibers were prepared. Adhesion between fibers and polymer matrices was improved by utilization of maleic anhydride grafted polypropylene (MAPP) coupling agent in the case of thermoplastic matrices (both PP and PVA). Water desorption tests were conducted after immersing test pieces in a distilled water bath at room temperature for 24 h. Study of the water desorption kinetics proved the expected enhanced absorption of the resulting composites after incorporation of cellulose fibers. A difference between two similar types of PVA by measurement of the desorption kinetics was found.  相似文献   

18.
The effect of an ultrahigh rubber acrylonitrile-butadiene-styrene (ABS) impact modifier resin (UHR-ABS) on the mechanical properties of an intumescent flame-retardant ABS composite was characterized. Samples were obtained by compounding ABS and an intumescent flame-retardant master batch that was prepared using an intumescent flame-retardant composite (IFRC) with ABS and/or UHR-ABS as well as by direct compounding IFRC, UHR-ABS, and ABS. The incorporation of UHR-ABS resulted in reduction in the storage modulus, damping behavior and glass transition temperature, as evidenced by dynamic mechanical analysis. With increasing mass fraction of the UHR-ABS, the tensile strength and the flexural strength decreased gradually, and the notched impact strength increased, but the increase was more significant for compounding IFRC, UHR-ABS, and ABS than for compounding ABS and IFRC master batches. SEM micrographs of the fresh fracture surface of the composites were used to estimate the mechanism of the increased notched impact strength owing to the incorporation of UHR-ABS.  相似文献   

19.
High‐density polyethylene (HDPE) and maleic anhydride grafted HDPE (HDPE‐g‐MA) were selected as lubricant and compatibilizer, respectively, for improving the tribological and mechanical properties of polycarbonate (PC). The morphology of worn surfaces and debris was observed by means of scanning electron microscopy (SEM). The mated steel ring surface was analyzed by using SEM combined with energy dispersive spectroscopy (EDS). Both HDPE and HDPE‐g‐MA reduced the friction and wear of pure PC. HDPE‐g‐MA, which had a better compatibility with PC than HDPE, resulted in better improvement of the mechanical and tribological properties of the PC matrix. A 10 vol. % HDPE‐g‐MA reduced the wear of pure PC by 4 orders of magnitude, and the friction coefficient was reduced from 0.86 to 0.22. Such improvements in the tribological behavior resulted from the good self lubrication of HDPE and HDPE‐g‐MA. The PC/HDPE‐g‐MA (S90‐0‐10) polyblend also showed higher notched impact strength than pure PC. It may be a useful material for application in tribological fields.  相似文献   

20.
《Composite Interfaces》2013,20(2-3):175-196
The morphology of blends of poly(acrylonitrile-co-butadiene-co-styrene) (ABS) and poly(ethylene terephthalate glycol) (PET-G) has been investigated with special reference to the effect of blend ratio and compatibilization. Scanning electron microscopy (SEM) examination revealed different morphologies such as dispersed, cocontinuous and phase inverted depending on the composition, which indicates that the binary blends are immiscible and form a two-phase structure. Tensile properties decreased with increase in the ABS content while the impact strength reached an optimum at ca. 70% ABS. Influence of a triblock co-polymer based on styrene and butadiene (SBS) on morphology, mechanical measurements and failure topography was used as criterion of the compatibilization effect. The compatiblizing action of SBS was evidenced by the sharp decrease in domain size of the dispersed phase followed by an increase at higher concentrations. The conformation of the compatibilizer at the interface was further analyzed based on the area occupied by the compatibilizer at the blend interface. The results were in agreement with the theoretical predictions of Noolandi and Hong. The extent of interface adhesion in these blends was analyzed by examination of the fracture-surface morphology. Addition of SBS also improved notched impact, elongation-at-break, tensile strength and modulus of elasticity. These results confirm that SBS is an effective compatibilizer for ABS/PET-G blends.  相似文献   

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