Investigation of Rust Formed on Steel Surfaces and Related Oxyhydroxides

In order to indentity the corrosion products formed on steel surfaces from ⁵⁷Fe Mössbauer spectroscopy, detailed Mössbauer parameters have been determined for various kinds of iron-oxyhydroxides: -FeOOH, -FeOOH, -FeOOH and -FeOOH. ⁵⁷Fe Mössbauer measurements of the iron oxyhydroxides indicate the following results. Fe occupies a single site in -FeOOH, but below the Néel temperature as at e.g., 300 K the Mössbauer spectrum is always broad, showing a distribution of the strength of the magnetic exchange interactions. Its shape depends on the grain-size and synthetic methods of the specimen. Fe occupies 3 sites in -FeOOH. High-purity reagents of -FeOOH always contain small amounts of -FeOOH and their Néel temperatures depend on the synthetic methods of the specimen. Mössbauer spectroscopy of the synthetic -FeOOH shows very broad distribution of the hyperfine magnetic fields.     

Corrections to cluster-radius scaling for branched polymers and percolation

We report analyses of series enumerations for the mean radius of gyration for isotropic and directed lattice animals and for percolation clusters, in two and three dimensions. We allow for the leading correction to the scaling behaviour and obtain estimates of the leading correction-to-scaling exponent . We find -0.640±0.004 and =0.87±0.07 for isotropic animals in 2d, and =0.64±0.06 in 3d. For directed lattice animals we argue that the leading correction has= or= ; we also estimate =0.82±0.01 and 0.69 ±0.01 ind=2, 3 respectively. For percolation clusters at and abovep _c, we find (p _c) =0.58±0.06 and (p>p _c)=0.84±0.09 in 2d, and (p _c)=0.42±0.11 and (p>p _c)=0.41 ±0.09 in 3d.     

Zeros of the finite-size scaling region partition function for a model with a wetting transition

We derive a finite-size scaling representation for the partition function for an Onsager-Temperley string model with a wetting transition, and analyze the zeros of this partition function in the complex scaled coupling parameter of relevance. The system models the one-dimensional interface between two phases in a rectangular two-dimensional region (x, y) ²,–L yL,oxN. The two phases are at coexistence. The string or interface has a surface tension 2KkT per unit length and an extra Boltzmann weighta per unit length if it touches the surfaces aty=±L. There is a critical valuea _c=1/2K and fora>a _c the string is confined to one of the surfaces, while fora a _c the string moves roughly in the rectangular region. The finite-size scaling parameters are =a _c ² N/L ² and =L(a–a _c)/a _c ² . We find that for || large, the zeros of the scaled partition function lie close to the lines arg()=±/4 with re()>0. We discuss the motion of all the zeros as changes by both analytic and numerical arguments.     

One-dimensional harmonic lattice caricature of hydrodynamics

We derive the hydrodynamic (Euler) approximation for the harmonic time evolution of infinite classical oscillator system on one-dimensional lattice ¹ It is known that equilibrium (i.e., time-invariant attractive) states for this model are translationally invariant Gaussian ones, with the mean 0, which satisfy some linear relations involving the interaction quadratic form. The natural parameter characterizing equilibrium states is the spectral density matrix function (SDMF)F(), [– , ). Time evolution of a space profile of local equilibrium parameters is described by a space-time SDMFF(t;x, ) t, xR ¹. The hydrodynamic equation forF(t; x, ) which we derive in this paper means that the normal mode profiles indexed by are moving according to linear laws and are mutually independent. The procedure of deriving the hydrodynamic equation is the following: We fix an initial SDMF profileF(x, ) and a familyP ,>0 of mean 0 states which satisfy the two conditions imposed on the covariance of spins at various lattice points: (a) the covariance at points close to the value ^–1 x in the stateP is approximately described by the SDMFF(x, ); (b) The covariance (on large distances) decreases with distance quickly enough and uniformly in. Given nonzerotR ¹, we consider the states P _–1 ,>0, describing the system at the time moments ^–1 t during its harmonic time evolution. We check that the covariance at lattice points close to ^–1 x in the state P _–1 is approximately described by a SDMFF(t;x, ) and establish the connection betweenF(t; x, ) andF(x,).     

On the invariant sets of a family of quadratic maps

The Julia setB for the mappingz (z–)² is considered, where is a complex parameter. For 2 a new upper bound for the Hausdorff dimension is given, and the monic polynomials orthogonal with respect to the equilibrium measure onB are introduced. A method for calculating all of the polynomials is provided, and certain identities which obtain among coefficients of the three-term recurrence relations are given. A unifying theme is the relationship betweenB and -chains ± (± (± ...), which is explored for –1/42 and for with ||1/4, with the aid of the Böttcher equation. ThenB is shown to be a Hölder continuous curve for ||<1/4.Supported by NSF Grant MCS-8104862Supported by NSF Grant MCS-8002731     

Nonstationary Markov chains and convergence of the annealing algorithm

We study the asymptotic behavior as timet + of certain nonstationary Markov chains, and prove the convergence of the annealing algorithm in Monte Carlo simulations. We find that in the limitt + , a nonstationary Markov chain may exhibit phase transitions. Nonstationary Markov chains in general, and the annealing algorithm in particular, lead to biased estimators for the expectation values of the process. We compute the leading terms in the bias and the variance of the sample-means estimator. We find that the annealing algorithm converges if the temperatureT(t) goes to zero no faster thanC/log(t/t ₀) ast+, with a computable constantC andt ₀ the initial time. The bias and the variance of the sample-means estimator in the annealing algorithm go to zero likeO(t^–1+) for some 0<1, with =0 only in very special circumstances. Our results concerning the convergence of the annealing algorithm, and the rate of convergence to zero of the bias and the variance of the sample-means estimator, provide a rigorous procedure for choosing the optimal annealing schedule. This optimal choice reflects the competition between two physical effects: (a) The adiabatic effect, whereby if the temperature is loweredtoo abruptly the system may end up not in a ground state but in a nearby metastable state, and (b) the super-cooling effect, whereby if the temperature is loweredtoo slowly the system will indeed approach the ground state(s) but may do so extremely slowly.     

Search for right-handed currents in muon decay

We report new limits on right-handed currents, based on precise measurements of the endpoint of the e⁺ spectrum from ⁺ decay. Highly polarized ⁺ from the TRIUMF surface beam were stopped in pure metal foils within either an 1.1-T spin-holding logitudinal field, or a 70-gauss spin-precessing transverse field. Decay e⁺ emitted within 200 mrad of the beam direction were momentum-analyzed to ±0.2%. For the spin-held data, decay via (V-A) currents requires the e⁺ rate to approach zero in the beam direction at the endpoint. Measurement of this rate sets the 90%-confidence limits P />0.9959 and M(W_R)>380 GeV, where W_R is the possible right-handed gauge boson. For the spin-precessed data we independently determine a 90% confidence limit P />0.9918.We are indebted to the entire TRIUMF management and staff for their splendid support of this experiment. In its early stages we benefited from discussion with J. Brewer, R. Cahn, K. Crowe, and W. Wenzel. Rapid commissioning of the polarimeter was made possible by the superb efforts of the LBL support staff. This research was supported in part by the U.S. Department of Energy, Division of Basic Energy Sciences, Office of Energy Research under contracts W-7405-ENG-48 and AC02-ER02289.     

The van der Waals limit for classical systems

For a -dimensional system of particles with the two-body potentialq(r)+ ^v K(r) and density , it is proved under fairly weak conditions onq andK that the canonical pressure (, ) and chemical potential (, ) tend to definite limits when 0. The limiting functions are absolutely continuous and are given in terms of the derivative of the limiting free energy density which was found in Part I.     

Comparison between static and adiabatic coupling mechanisms for nonradiative multiphonon transitions in semiclassical approximation

Semiclassical versions of the static (diabatic) and adiabatic coupling schemes are applied to a two-level-one-mode system at total energies above the cross-over level. The corresponding rates of nonradiative multiphonon transitions reduce to alternativemonotonous dependences on the usual Landau-Zener parameter. Static coupling gives an increasing transition probability (per oscillation) of the familiar formP ^st() = 4. Adiabatic coupling associated with a sufficiently low mechanism-specific potential barrier of Born's type produces a decreasing transition probability of the formP ^ad() exp (–2). The underlying Beyond-Non-Condon calculation procedure shows that (1) the weak dependence of the pre-exponential factorP ^ad is a consequence of the-independent normalization of the electronic matrix element governing the non-adiabaticity operator and (2) the occurrence of the mechanism-specific tunnelling factor exp(–2) is due to the avoided crossing of adiabatic oscillator potentials. Ranges of applicability of both alternative coupling schemes are limited by comparison with earlier non-perturbational results.     

A contribution to the theory of the triple crystal diffractometer

The first part of the paper gives a general equation for triple-crystal arrangement with perfect crystals on the assumption that the third crystal is rotated. It is shown that in the case of perfect crystals the shape of the reflection curve is practically independent of the vertical divergence. The case of mosaic crystals is also solved and the possibility of rotation by other than the third crystal is considered. A method is proposed for investigating the imperfection of a crystal which is different from methods used up to now. The paper is supplemented by some experimental results.

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