共查询到16条相似文献,搜索用时 109 毫秒
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全息光致聚合物中光化学反应参数的理论拟合研究 总被引:1,自引:1,他引:0
结合光致聚合物中光化学反应的基本过程及其理论函数模型,对多种采用不同双染料敏化的光致聚合物的透射率曲线进行拟合,得到了光化学反应理论模型中的参数。依托于实验数据,分析了利用MATLAB实现曲线拟合并得到光致聚合物中各光化学参数的新方法。结果表明:当曝光波长为632.8nm,曝光强度为65mW/cm2时,3种光致聚合物的拟合统计指标R-Square值分别为0.9687,0.9958和0.9902,说明所使用的理论结合实验数据的拟合分析方法是成功的。 相似文献
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制备了一种三乙醇胺与N-苯基苷氨酸为共同引发剂的丙烯酰胺基光致聚合物全息存储材料,并用He-Ne 激光器633 nm波长的光对样品进行曝光测试.实验表明,与单引发剂的光致聚合物相比,薄膜的质量有一定的提高,在曝光灵敏度变化不大的情况下,衍射效率有很大提高.优化两种引发剂浓度后,此种共同引发的光致聚合物材料呈现的衍射效率达到54%,曝光灵敏度为1.85×10-2cm2/mJ.还研究了此种光致聚合物的透过率随曝光时间和曝光强度的变化,说明此种光致聚合物材料内部均匀性好,对光的散射小. 相似文献
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根据取向透射率变化研究了偶氮苯侧链液晶聚合物在不同光照功率条件下的取向,用锥光干涉法表征了侧链介晶基元的取向方向,并研究了升温对取向膜的稳定性影响.实验结果表明介晶基元的取向速度和取向度都随光照时间和光照功率增加而增加|超过一定阈值功率(20 mW/cm2)时,随着光照时间延长薄膜的透射率(取向度)反而降低.高功率光照使侧链介晶基元发生了面内和面外两种取向,面外取向使聚合物膜的透射率降低.面外倾斜取向的介晶基元不稳定,在取向未达到饱和时停止光照,倾斜取向的介晶基元容易发生解取向,而面内取向的介晶基元则能维持取向的状态.用不饱和取向的方法,在光照功率为 20 mW/cm2时,取向时间缩短为饱和取向的1/20,薄膜的取向度提高1.3倍.4 ms的一次曝光足以使聚合物膜产生可读出、稳定的面内取向,取向的结果能保持2年不发生变化. 相似文献
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用低折射率的含氟共聚物为光致聚合物全息材料的成膜物,以增加全息记录材料折射率的空间可调制程度。用溶液聚合法合成了低折射率的水溶性甲基丙烯酸2,2,3,3-四氟丙酯-甲基丙烯酸共聚物(折射率为1.441),以该共聚物为成膜物质,丙烯酰胺为单体、亚甲基蓝为光敏染料、三乙醇胺为引发剂配制了光致聚合物薄膜;经过对光致聚合物组成构成的优化,在空间分辨力为1580lp/mm时,光致聚合物薄膜的灵敏度约为19 mJ/cm2,衍射效率可达93%,两者均优于以聚乙烯醇(PVA)为成膜物质的光致聚合物材料。 相似文献
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A holographic photopolymer based on SU-8 epoxy resin as the binder and trimethylolpropane ethoxylate triacrylate as the monomer with an iodonium salt photoinitiator was studied. A diffraction efficiency of 93% and a refractive index modulation (Delta n) of 1.3 x 10(-2) were obtained from a 16 microm thick sample with write beam intensities of 50 mW/cm(2) at a wavelength of 514.5 nm, an exposure time of 60 s, and a postbaking at 65 degrees C for 1 h. The material exhibits good heat resistance in the range from 40 degrees C to 160 degrees C and long projected life. 相似文献
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利用双积分球-光电管系统,开展了不同厚度的芳纶纤维/环氧、碳纤维/环氧复合材料在不同强度(低于烧蚀阈值)的1.319 mm连续激光辐照下的能量耦合规律研究。结果表明:芳纶纤维/环氧复合材料的反射率、能量耦合率随材料厚度增加而增大,透射率随材料厚度增加而减小;在材料厚度一定时,反射率、透射率随激光强度增加而增大,能量耦合率随激光强度增加而减小;体吸收系数随材料厚度的增加而减小,激光强度的变化对其没有影响。碳纤维/环氧复合材料的反射率随激光强度增加而增大,能量耦合率随激光强度的增加而减小,材料厚度对反射率和能量耦合率的影响不大。 相似文献
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Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitia-tors are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence:Triethanolamine (TEA)> Diethanolamine (DEA)> Ethanolamine (EA)> Triethylamine (TETN)> Diethy-lamine (DETN). The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26%, sensitivity is 1.72 × 10 3 cm2/mJ, and the maximum refractive modulation index is 4.64×10 4. 相似文献
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Manuel Ortuño Andrés Márquez Sergi Gallego Inmaculada Pascual 《Optics Communications》2008,281(6):1354-1357
Unslanted diffraction gratings are recorded in a 900 μm thick acrylamide photopolymer by means of peristrophic multiplexing. A solid state Nd:YAG (λ = 532 nm) laser is used as the recording beam, with a total incident intensity of 5 mW/cm2, and a He-Ne laser as the reconstruction beam. The dye concentration in the photopolymer is optimized so that it does not limit the dynamic range. Nine holograms are recorded using constant exposure time scheduling and variable exposure time scheduling. From the results obtained it may be deduced that optimization of the dye allows us to work in the linear response region of the photopolymer and at the same time obtain high values of diffraction efficiency for each hologram. An exponential increase in exposure time as the number of holograms increases enables the values of diffraction efficiency to be homogenized with regard to the case of constant exposure scheduling. In this way, better use is made of the dynamic range of acrylamide hydrophilic photopolymer. 相似文献
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A novel wideband sensitive dry holographic photopolymer sensitized by rose bengal (RB) and methylene blue (MB) is fabricated, the holographic storage characteristics of which are investigated under different exposure wavelengths. The result shows that the sensitive spectral band exceeds 200 nm in visible light range, the maximum diffraction efficiency under different exposure wavelengths is more than 40% and decreases with the decrease of exposure wavelength, the exposure sensitivity is not change with the exposure wavelength.This photopolymer is appropriate for wavelength multiplexing or multi-wavelength recording in digital holographic storage. 相似文献