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1.
三环已基羧酸锡的13C和119Sn NMR研究   总被引:2,自引:2,他引:0  
测定了33个三环己基脂肪族和芳香族羧酸锡在非配位溶剂(CDCl3)中的13C和119Sn NMR谱。结果表明:化学位移δ(119Sn)值主要由锡原子的配位数决定,结构上微小的变化。都能在δ(119Sn)值上明显地表现出来。讨论了不同类型化合物间NMR参数间的关系。  相似文献   

2.
以苯并[1,2-b∶4,5-b´]二噻吩-4,8-二酮为原料合成了一种聚合物太阳能电池材料的单体2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩. 通过多核1D和2D NMR技术(包括1D 1H、13C、119Sn、117Sn NMR、DEPT、选择性1D TOCSY及2D1H-1H COSY、gHSQC、gHMBC)表征了目标分子结构,完成了 1H、13C、119Sn 与117Sn NMR化学位移归属,并探讨了该化合物的NMR谱线特征.  相似文献   

3.
报道了四种新的萘酰亚胺衍生物的13C NMR谱. 应用1H、13C、DEPT、HMQC、HMBC 等谱确定了这四种化合物的分子结构,并对全部谱峰进行了归属,探讨了分子结构对13C NMR化学位移的影响.  相似文献   

4.
二正丁基锡(IV)基羧酸酯的谱学表征   总被引:10,自引:0,他引:10  
合成了10个二正丁基锡(IV)基羧酸酯化合物{[nBu2Sn (O2CR)]2O}2(A1~A5)和nBu2Sn (O2CR)2(B1~B5)(R=1:CCl3;2:CHCl2;3:CH2Cl;4:PhCH=CH;5:2,2,3,3-四甲基环丙基),其中A4、A5和B5为新化合物,对它们进行了元素分析和IR及、1H、13C、119Sn NMR谱表征,重点讨论了13C和119Sn NMR谱的谱学特征及化学位移值与母体酸的PKa值大小的关系,并在此基础上推测了它们分子结构。  相似文献   

5.
1H, 13C NMR及多种二维核磁共振谱进一步确定了本系列化合物5,10-二氢磷杂吖嗪衍生物的结构,完成了1H和13C NMR 谱峰的全归属,探讨了影响偶合常数大小的因素.  相似文献   

6.
以邻苯二胺和丙炔酸酯为原料,Ga(OTf)3催化一锅法合成了一类新型的1,5-苯并二氮杂卓衍生物,超声波辅助加快了反应的进行,该反应条件温和,反应时间短. 利用1H NMR、13C NMR 确定了该产物的结构,并通过DEPT、1H-1H COSY、HMQC、HMBC等2D NMR谱,对化合物的1H NMR和13C NMR数据进行了详细的归属,讨论了化合物的质谱裂解规律,进一步确证了该化合物的结构.  相似文献   

7.
苯基哌嗪衍生物的NMR波谱研究   总被引:2,自引:0,他引:2  
通过1H NMR、13C NMR、及HMBC、HSQC、1H-1H DQFCOSY等2D NMR方法对新合成的10个苯基哌嗪衍生物类抗高血压药物进行结构鉴定, 并对这些化合物的1H NMR和13C NMR信号进行了全归属. 初步探讨了取代基对分子13C化学位移的影响.   相似文献   

8.
7-氧代-3-苯基香豆素的NMR谱研究   总被引:1,自引:0,他引:1  
详细归属了三个7-氧代-3-苯基香豆素类衍生物的核磁共振谱(11H、13C NMR).除7-甲氧基-3-苯基香豆素的13C NMR谱外,上述化合物的核磁共振谱均未见报道.  相似文献   

9.
1H, 13C NMR及多种二维核磁共振谱确定了一系列新合成的二氮杂萘酮衍生物的结构,完成了1H和13C NMR 谱的归属,给出了该系列衍生物的氢、碳原子的准
确化学位移.  相似文献   

10.
本文用1H、13C NMR及UV对六个莰烯衍生物进行了研究,给出了全部13C谱线和部分1H谱线的归属。对13C、1H化学位移进行了关联,获得了近乎直线的13C-1H相关图。结果表明,13C化学位移与UV λmax无必然联系,而与电荷密度密切相关。本文对此进行了讨论。  相似文献   

11.
Solid-state 119Sn and 195Pt magic-angle spinning (MAS) NMR spectra are reported on a series of MPtSn compounds (M = Ti, Zr, Hf, Th). In favorable cases (TiPtSn and ZrPtSn) the spectra reveal expected J-coupling patterns originating from indirect spin coupling between Pt and Sn nuclei. MAS has no effect on the broad and asymmetric spectra of either 119Sn and 195Pt nuclei in HfPtSn.  相似文献   

12.
The solvolysis of hexphenylditin by a variety of inorganic acids leads to the formation of compounds having the empirical formula SnX3. Tin-119 Mössbauer spectroscopy shows that these compounds should be formulated as Sn(II)Sn(IV)X6: in some of these compounds the non-bonding electron pair of the Sn(II) is stereochemically inactive.  相似文献   

13.
本文测定了二十个含有烷基、苯基、烯丙基、五元杂环基及其它极性基团的Sn(Ⅳ)化合物的~(119)Sn、~(117)Sn-NMR谱,讨论了各种取代基对Sn核电子云密度及磁屏蔽的影响,考察了~(119)Sn谱峰随溶剂、浓度、温度的变化,研究了Ph_3SnCl化合物与DMSO配位生成配合物的过程,测出了平衡常数和自由能的变化。  相似文献   

14.
The variations of the 119Sn Mössbauer isomer shift δ are interpreted for tin compounds from a semi-empirical tight-binding calculation of the electronic density at the nucleus ρ(0). A molecular model is proposed in order to relate the variations of ρ(0) for the Sn(IV) chalcogenides to the changes in the Sn environment. The variations of the experimental values of the quadrupole splitting δ are linearly correlated to the values of the electric field gradients (EFG) calculated by the full-potential linearized-augmented-plane-wave (FP-LAPW) method. The value of the 119Sn nuclear quadrupole moment is found to be |Q| = 10.5 ± 0.2 fm2. Finally, the relation between the EFG and the Sn environment is discussed for SnO.  相似文献   

15.
The perturbed angular correlation technique and Mössbauer spectroscopy were applied to study the electric field gradient on 111Cd and 119Sn probe atoms in isostructural NiIn and CoSn compounds. The 111Cd PAC measurements performed in the temperature range 80--1100 K demonstrated the existence of two axially symmetric EFG's in each of the investigated compounds, related to the 2(d) and 1(a) probe sites in the B35 structure. A 1(a)-site preference for Cd probes in CoSn compound was observed. The temperature dependence of the quadrupole frequencies for 111Cd in both compounds, interpreted in terms of the empirical model proposed by Christiansen et al.[1], follows a T3/2 relation with different slope parameters for each of the observed frequencies. These results are combined with the data from the Mössbauer experiment. The 119Sn Mössbauer spectra taken at liquid nitrogen and at room temperatures showed two quadrupole split doublets with the intensity ratio 2:1 for CoSn and 8:1 for NiIn0.99Sn0.01sample, giving an evidence of 2(d)-site preference for tin atoms in NiIn. The EFG values measured on 119Sn are 2.5 to 4 times larger than those on 111Cd nuclei, while the ratio of the respective Sternheimer antishielding factors is equal to 0.77. Within the limits of errors no differences were observed in the magnitude and temperature dependence of Debye--Waller factors for 2(d) and 1(a) 119Sn positions in CoSn and NiIn lattices.  相似文献   

16.
High-resolution NMR spectra of [Formula: see text] nuclei, particularly (119)Sn and (31)P, in solid tin(II) phosphite, SnHPO(3), and tin(II) phosphate, SnHPO(4), are presented. The results are discussed in relation to the crystal structures. Spinning sideband analysis has been carried out for both nuclei, giving information on the shielding tensors. Satellite peaks allow the indirect Sn,Sn coupling constants to be determined. Surprisingly large values of 2600+/-200Hz and 4150+/-200Hz are reported for SnHPO(3) and SnHPO(4) respectively. The satellite peaks were investigated by using a single Hahn echo for each refocusing time, which showed that the observed splittings result from (119)Sn, (117)Sn coupling. For SnHPO(3), the calculated relative intensities of the satellites for six intra-layer coupling interactions are in agreement with the experiment values, but for SnHPO(4) the coupling appears to be inter-layer in nature. Tin-119 (and in one case phosphorus-31) shielding tensor data derived from MAS NMR are also reported for four other crystalline tin(II) compounds, namely tin diphosphate, tin oxalate, tin sulphate and calcium tin ethylenediamine tetraacetate.  相似文献   

17.
119Sn Mössbauer spectroscopy studies were performed on 12 uranium intermetallic compounds in order to investigate correlations between the formation of the magnetic moment on the U atom and the magnetic hyperfine field transferred to 119Sn nuclei in magnetically ordered materials. The measured hyperfine fields (Hhf) are related to the values of the ordered U magnetic moments (UB) by UoHhf/n=A UU. The parameter A varies between 0.73 (UGa2) and 1.55 (UGe2). It seems to correlate with the extent of the hybridization of the 5f states with the conduction electron states.  相似文献   

18.
The hyperfine fields acting on119Sn nuclei in the RT2 (R=Sm?Lu; T=Fe, Co, Ni) have been measured by Mössbauer spectroscopy. It has been found that the hyperfine fields acting on119Sn nuclei in the RT2 compounds are changed at some electronic occupation of the 4f shell of the R-component. The occupation of 4f shell is varied with the T-component. The sharp change of the hyperfine fields are connected with the change of the electronic band structure.  相似文献   

19.
We have carried out measurements on the decay of 119In isomers and the 118Sn(n, γ) reaction to supplement Coulomb excitation measurements on 119Sn. In addition to the 311.39 keV isomeric transition in 119In, we observed 13 γ-rays in 119Sn from the decay of the 2 min and 18 min 119In isomers. These γ-rays have been incorporated into a level scheme of 119Sn with levels at 0, 23.867, 89.54, 787.01, 920.5, 921.4, 1089.5, 1187.76, 1249.67, 1304.44 and 1354 keV. Conclusive evidence for the existence of a 920.5–921.4 keV, 32+-52+ level doublet was obtained from capture γ-ray measurements of resonance energy neutrons.  相似文献   

20.
The 119Sn Mössbauer spectroscopy has been applied to investigate the magnetic behaviour of the UCoAll-xSnx compounds, in which the graduring transition from paramagnetism (UCoAl) to ferromagnetism (UCoSn) reflects the reduced 5f-ligand hybridization. The influence the Al?Sn local surrounding of U atoms on the U magnetic moments has been observed for the concentrations near to the onset of magnetic ordering.  相似文献   

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