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1.
用化学溶液法以醋酸锌和六亚甲基四胺为原料在玻璃衬底上生长出不同形貌的亚微米和微米ZnO棒。探讨了反应液的酸碱度和反应液浓度对生成的ZnO棒形貌的影响,并分析了其生长机制。通过控制一定的酸碱度和溶液浓度,可以得到规则的六角ZnO棒状阵列。这种规则的六角棒沿着[002]方向生长。测量了样品的XRD,扫描电镜像(SEM),并对其发光性能进行了测量分析。其中规则六角ZnO棒的光致发光光谱中有一很强的峰值650nm红色宽谱带和一峰值约387nm的激子发光峰。激子发光峰加宽,实际上是自由激子的发光峰(380nm)和Zni的发光峰(430nm)的叠加。而红色发光峰可能是Vo2+中的电子和价带中的空穴辐射复合所致。  相似文献   

2.
一步溶液法制备ZnO亚微米晶体棒及其发光性能   总被引:6,自引:3,他引:3       下载免费PDF全文
用硝酸锌(Zn(NO3)2·4H2O)或醋酸锌(Zn(CH3COO)2·2H2O)分别与六亚甲基四胺((CH2)6N4)以等浓度0.005mol/L配制成两种反应溶液,通过化学溶液法在玻璃衬底上生长出ZnO六角型亚微米棒(长5~8μm,直径300~700nm)。测量了样品的XRD和扫描电镜像。经XRD分析,所得样品均为纤锌矿的ZnO六角型晶体。扫描电镜(SEM)像表明,生长时间为3h或5h时,样品为细长条的棒状结构,长径比超过10:1;生长48h后的ZnO亚微米棒的一端被腐蚀成一定深度的ZnO亚微米管。用负离子配位四面体生长模型分析了ZnO亚微米棒的生长机理。ZnO亚微米棒退火前后的光致发光谱表明,退火处理后的发射谱中的紫外峰消失,而红色发光峰红移并且增强(峰值由630nm左右移到710nm),同时它的激发光谱中的室温激子激发峰也增强。  相似文献   

3.
两步溶液法制备亚微米ZnO棒阵列及其退火后的发光   总被引:1,自引:1,他引:0       下载免费PDF全文
通过改变溶液浓度、酸碱度等生长条件,用两步化学溶液沉积法在玻璃衬底上制备出有序排列的亚微米级ZnO棒阵列,棒的截面呈正六边形,直径约为200~500nm。测量了样品的XRD谱和扫描电镜像,证明这些样品都是六方纤锌矿结构的ZnO单晶,且以[002]方向择优生长。将样品退火前后的PL光谱进行比较分析,发现退火后样品的发射光谱中紫外峰消失而长波段的红色发光峰红移并且增强(峰位由630nm左右移到720nm),而其激发光谱中的室温激子激发峰也增强。当退火时间增加到6h后,出现了由430nm的蓝峰和505nm绿峰组成的宽谱带蓝绿色发射。并对发光机理进行了讨论。  相似文献   

4.
以ZnS和金属Zn粉末混合物为蒸发源以及金属Zn片为衬底,利用热蒸发气相沉积方法,在弯曲的金属Zn微球表面上,成功地获得了ZnO亚微米棒阵列结构。场发射扫描电镜研究表明:在弯曲的Zn微球表面,能自组织地生长出大量的截面为六边形的ZnO亚微米棒,这些亚微米棒的平均直径为500nm,长约1μm。棒的顶部是平滑的。能量散射X射线谱结果表明:合成的产品只存在Zn和O两种元素,其成分比例接近1∶1。没有观察到S元素。光致发射(PL)光谱显示:在387nm紫外波长处,出现一个强的半峰全宽为16nm的窄发光峰,可归属于ZnO的近带边发光,而509nm左右较弱的宽峰则源于界面缺陷态发光。这些研究结果说明我们所合成的这种ZnO亚微米棒阵列材料在紫外受激发射器件方面有着潜在的应用价值。  相似文献   

5.
MOCVD方法生长ZnO微米柱的结构与光学性质   总被引:2,自引:2,他引:0  
通过X射线衍射、扫描电子显微镜和变温光致发光光谱对MOCVD方法生长在蓝宝石衬底上的ZnO微米柱材料的结构及发光特性进行了表征.X射线衍射结果表明,ZnO具有良好的c轴择优取向,扫描电子显微镜图中可观察出ZnO微米在呈六角结构生长,半径约为0.5~1.5μm.样品的发光光谱通过He-Cd激光器的325nm线激发,从光谱中发现低温(81K)下出现极强的与激子相关的带边发光峰,温度升高到360K时与自由激子相关的紫外发射峰仍然是清晰可见.  相似文献   

6.
气相沉积法生长不同结构ZnO纳米线及其发光   总被引:6,自引:4,他引:2  
用Zn粉、Zn/In2O3/C粉作为不同锌源,通过气相沉积法在空气或N2/O2混合气氛下生长出多种形貌的ZnO纳米线(如:四脚状、多脚状、梳子状、绒棒状,以及纳米棒、纳米丝、纳米带等多种形貌),直径约为50-1000nm,长度约为1—20μm。测量了样品的XRD谱、扫描电镜、透射电镜和选区电子衍射像,证明这些样品都是六方纤锌矿结构的ZnO单晶。四脚状样品的PL光谱显示样品存在近紫外峰(380nm)和绿峰(500nm)两个发射带,半峰全宽分别约为15,90nm,其峰值强度比其他方法(如溶液法)制得样品的峰值强。样品的尺寸对光谱强度有一定影响,但对谱峰位置并无影响。用He-Cd激光器的325nm激光对四脚状样品进行发射光谱分析,发现其近紫外激子发光大大增强而绿色缺陷发光相对较弱,近紫外的峰值位于383nm,半峰全宽约为16nm;绿峰峰值位于515nm,半峰全宽约为76nm。  相似文献   

7.
利用水热法制备ZnO微米棒。醋酸镁[Mg(CH3COO)2.4H2O]、醋酸锌[Zn(CH3COO)2.2H2O]和六次甲基四胺(C6H12N4)以一定比例配置成反应溶液,把反应溶液加热到90℃,反应时间为24h,能够在硅衬底上生长高质量的ZnO微米棒。用扫描电镜(SEM)和X射线衍射仪对ZnO微米棒的晶体结构和表面形貌进行了分析,结果表明,样品为细长条棒状结构,呈现六方纤锌矿结构,长径比可达10∶1,并且在[002]方向择优生长。在样品中并未发现镁离子,它有可能扮演着催化剂的角色。对ZnO微米棒的光致发光性能进行测量,由PL光谱分析可知,样品在384nm处有一个紫外发光峰,半峰全宽为13nm,紫外发光峰强度比可见发光峰强度大的多,样品的质量较好。  相似文献   

8.
采用微乳液法制备了Fe掺杂ZnO纳米球材料(Zn1-xFexO,x=0.1),利用XRD和TEM对制备样品的结构、形貌进行了表征。在室温下,测得材料宽化的吸收光谱。用325nm的激光激发,测量了ZnO纳米球的光致发光光谱,低强度激发时观察到半峰全宽较窄、峰值波长为385nm的紫光峰和半峰全宽较宽、峰值波长约625nm的深能级发光峰;两峰的发光强度和峰位随着激发光功率密度的变化而变化,但变化规律不同。所合成材料的吸收和发光性质与Fe掺杂相关。  相似文献   

9.
秦莉  张喜田  梁瑶  张锷  高红  张治国 《物理学报》2006,55(6):3119-3123
利用化学气相沉积(CVD)的方法通过热氧化高纯锌粉在硅衬底上得到氧化锌微米花. X射线衍射(XRD)结果表明,其具有六角纤锌矿晶体结构.场发射扫描电子显微镜(FE-SEM)图像表明,合成的样品是由很多长且直的ZnO亚微米棒组成的微米花, 具有六角棱柱端面,棒的长度在30μm到50μm之间.在背向共振拉曼散射光谱测量中,观测到ZnO A1(LO)的五阶声子紫外共振拉曼散射,表明样品具有较高的晶体质量.在变温光致发光谱测量中,观察到明显的中性受主束缚激子(A0X)的 关键词: ZnO微米花 光致发光 共振拉曼 “负热淬灭”效应  相似文献   

10.
ZnO薄膜的光抽运紫外激射   总被引:3,自引:3,他引:0  
采用等离子体增强MOCVD方法生长出高质量的ZnO薄膜,并观察到了ZnO薄膜的光抽运紫外激射现象。在不同激发强度下进行了光荧光谱测量,发现紫外发光强度随着激发光强度的增加呈直线增强,证明此紫外发光峰来源于带边自由激子辐射复合。激发的激光器为3倍频YAG激光器,脉宽15ps,每秒10个脉冲。抽运光达到样品的光斑直径约为25μm,激射阈值为0.28μJ,利用光纤连接到CCD来探测接收激射光。在385~390nm之间的激射峰,其半峰全宽为0.03nm。所观察到的激射没有固定的方向,也就是说是往各个方向发射的。对于ZnO薄膜,由于我们并没有制作通常激光器的谐振腔,激射是通过晶粒强烈的散射导致的自形成谐振腔所产生的。  相似文献   

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为了提高LED光源色温和亮度的调节精度和准确度,结合色温由低向高变化时光色所呈现的渐变特点,提出了一种低色温白光LED灯珠、高色温白光LED灯珠加红绿蓝光LED灯珠补偿式调光的方法.将色温分成三个部分进行调节,每个部分选用不同的LED灯珠组合来进行调光.实验结果表明:不同组合情况下的LED光源的初始输出色温相对于目标值的偏差范围在1%以内;亮度可以在保证色温不变的情况下独立进行调节,初始输出值与目标值的偏差范围在1%以内;经过微调之后可以达到目标值;达到了色温和亮度独立调节的要求;光源发光稳定,不会因为长时间工作而影响调节精度.  相似文献   

13.
Muonic and pionic X-rays of the L- and M-series in C and O have been measured with a Si(Li) detector in the energy range between 7 keV and 60 keV. The target consisted of mylar (C5H4O2). Energies and intensities of 21 transitions have been determined. The strong interaction shift of the pionic 2p level in O was measured and found to be +4.1 ±2.3 eV. The measured width of this level is 11±6 eV. The measured yields have been compared with cascade calculations.  相似文献   

14.
This is a further development of the author's paper A Unified Theory of Biology and Physics. It is found that male and female in biology, as well as particle and antiparticle in physics, are analogues of symmetrical sideband pairs in communication theory. This gives a new point of view from which to investigate the significance and characteristics of these different paired entities.These findings are intimately related to the fact that there are two transform domains of representation of entities in all the cases involved. They are the somatic and the genetic domains in biology, the configuration domain and the domain of conserved observables in physics, and the time and frequency domains in communication.  相似文献   

15.
A technique combining image processing and laser interferometry for visualizing and detecting the deformation of transparent cylindrical and spherical sample is proposed. This deformation includes geometric deformation such as volume transition in profilometry and physical deformation such as refractive index change in tomography. Phase contour lines are used for quantitative analysis and graphical representation of the deformation. This method allows us to visually detect the spatial variation of the deformation field and to evaluate the test quality such as misalignment of optical system. A theoretical analysis using phase contour map to characterize the deformation field is described in detail. A method using phase contour map to qualify the interferometric test is proposed. Analysis of test examples is carried out. Suggestions on using phase contour line method to ameliorate test system design are finally discussed.  相似文献   

16.
We show that good approximations to the exact equivalent local potential (ELP) and damping factor of a nonlocal Perey-Buck potential can be calculated in the partial wave WKB approximation of Horiuchi. The exact ELP and damping factor are obtained by means of a method previously given by one of us. We also confirm that an approximate ELP proposed by Bauhoff et al. is of comparable accuracy as the Horiuchi approximation. Thesel-dependent ELP's exhibit reduced attraction in the interior and provide a test for higher order WKB approximations. We subsequently obtain an equivalent velocity dependent potential (EVDP) which is even exactly wave function equivalent to the original nonlocal potential. This almost local potential, unlike the trivial equivalent local potential, is smooth and well-behaved and is therefore particularly useful in nuclear reactions where the off-shell behaviour of the potential is important.  相似文献   

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The relative stability of alternative carbon nanoparticles with icosahedral symmetry, such as diamond-like nanocrystallites and multiwalled fullerenes (onions), is investigated using the parametric model and the density functional tight-binding (DFTB) method. It is demonstrated that an increase in the size of particles and their hydrogenation favor the stabilization of diamond-like nanocrystallites. The formation of “intermediate” nanostructures consisting of diamond-like nanocrystallites inside the fullerene cage is revealed. The electronic spectra of icosahedral carbon nanoparticles are calculated.  相似文献   

20.
Discrepancies and accords between quantum (QM) and classical mechanics (CM) related to expectation values and periods are generally found for both the harmonic oscillator (SHO) and a free particle in a box (FPB), which may apply generally. These indicate non-locality is expected throughout QM. The FPB energy states violate the Correspondence Principle. Previously unexpected accords are found and proven that 〈x 2 CM =〈x 2 QM and τ CM =τ QMb (beat period i.e. beats between the phases for adjoining energy states) for the SHO for all quantum numbers, n. However, for the FPB the beat periods differ at small n. It is shown that a particle’s velocity in an infinite square well varies, no matter how wide the box, nor how far the particle is from the walls. The quantum free particle variances share an indirect commonality with the Aharonov-Bohm and Aharonov-Casher effects in that there is a quantum action in the absence of a force. The concept of an “Expectation Value over a Partial Well Width” is introduced. This paper raises the question as to whether these inconsistencies are undetectable, or can be empirically ascertained. These inherent variances may need to be fixed, or nature is manifestly more non-classical than expected.  相似文献   

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