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1.
采用水雾化方法制备Fe74Al4Sn2P10C2B4Si4合金粉末,研究发现该合金具有强的非晶形成能力和高热稳定性,在粉末粒度小于400目时可以形成非晶态合金.采用该非晶粉末制备的磁粉芯在高频下品质因数显著高于MPP粉芯,说明该磁粉芯高频损耗较低.分析表明,非晶合金磁粉芯高频下损耗低的主要原因是电阻率较高. 关键词: 非晶合金 磁粉芯 玻璃形成能力 软磁性能  相似文献   

2.
中国科学技术大学磁学教研室有关同志为研制高密度记录用磁粉,从改进国内磁粉生产工艺着手,参考国外有关资料[1-4],并结合我国具体情况,于1979年下半年研制出包附SiO2的细微针状rFe2O3磁粉. 该磁粉研制的工艺特点是采用强碱法,在比常规反应温度和浓度均低的条件下制备铁黄(a-Fe  相似文献   

3.
方祺  王庆  赵哲龙  董远达 《物理学报》2007,56(3):1292-1296
采用铜模吸铸法制备出直径为2 mm的Cu50.3Zr49.7-xNbx(x=0,2)大块非晶合金,利用示差扫描量热分析(DSC)研究了2at%Nb元素添加对Cu-Zr非晶合金玻璃转变动力学和晶化动力学的影响,发现含Nb合金具有较低的脆性指数,和较高的晶化激活能.这表明微量Nb的添加提高了该二元Cu基非晶合金过冷金属液相的热稳定性,从而有利于其非晶合金的形成. 关键词: Cu-Zr非晶合金 Nb添加 玻璃转变动力学 晶化动力学  相似文献   

4.
国际应用磁学(INTERMAG)会议的三个卫星会仪之一──第一届国际磁性材料物理会议,于1987年4月8-11日在日本仙台市召开.我国有近20名代表参加,是外国代表中人数最多的. 会议共有138篇论文,分七类:1.稀上永磁材料及非晶材料的磁性;2.薄膜;3.细粉末;4.无序及亚稳系统;5.磁各向异性及磁致伸缩;6.高频磁损耗;7.磁光、磁弹性波及新实验技术.其中有关薄膜的论文有48篇,占35%。软磁硬磁大块材料包括非晶合金及稀土永磁合金的文章数与薄膜文章数相比显得少得多.从这里可以看出人们对薄膜的兴趣日益增长. 为了降低软磁薄膜的磁致伸缩以改善磁性,人…  相似文献   

5.
目前金属软磁粉芯材料在高频电感等电子元件的应用前景广阔,然而其主要的构成元素属于过渡金属,表面易形成致密的氧化层,影响其软磁性能的调控.为了解决这些问题,本文引入H2/Ar混合气体高温预处理工艺对FeNiMo原粉进行还原,证实了还原性气氛高温处理可以有效地去除材料表面的金属氧化物,增加金属单质的含量,进而显著提升FeNiMo原粉的有效磁导率.对预处理后的FeNiMo粉末进行SiO2绝缘包覆,所获得的FeNiMo/SiO2软磁复合材料表面包覆均匀;与未处理FeNiMo原粉包覆SiO2所形成的软磁复合粉芯相比, H2/Ar混合气体高温预处理后的FeNiMo/SiO2具有更高的有效磁导率、更低的损耗.与同类其他软磁复合粉芯相比,通过H2/Ar混合气体高温预处理工艺和绝缘包覆工艺的协同效应,所制备的FeNiMo/SiO2复合粉芯具有优异的软磁性能.因此经过还原性气氛高温预处理工艺后的绝缘包覆可以更大程度地提升软磁粉芯复合...  相似文献   

6.
采用固相反应法制备了Ni0.8Zn0.2Fe2O4和2wt% Co2Y添加Ni0.8Zn0.2Fe2O4铁氧体多晶样品,并对样品的磁性质进行了研究.实验发现,添加Co2Y后,铁氧体的磁损耗明显下降,相同条件下Q值增大到原来的3倍左右.对添加Co2Y引起铁氧体磁损耗下降的原因进行了讨论,认为主要是钴离子掺杂引起的铁氧体磁滞损耗明显降低所导致的.  相似文献   

7.
采用溶胶 凝胶法制备NiFe2 O4 纳米粉末 ,并经不同温度热处理 .测定了制备过程中各阶段的红外吸收光谱和不同温度处理样品的红外漫反射光谱 .结果表明 ,红外吸收光谱较好地反映了溶胶 凝胶法制备NiFe2 O4 纳米粉末过程中结构的变化 ,为确定热处理温度提供了实验依据 ,彻底消除有机物 ,热处理需在 40 0℃以上 ;红外漫反射谱可以较好地反映粉末的尺寸效应和形态效应 ,粉末粒径越小 ,漫反射函数 (K M)值越大 ;当粒径达到一定尺寸时 ,红外漫反射的尺寸效应消失  相似文献   

8.
张媛媛  林鑫  杨海欧  李加强  任永明 《物理学报》2015,64(16):166402-166402
基于金属熔体结构的遗传性, 激光熔池的快速熔凝导致粉末的晶化状态可能会对最终成形件的晶化产生重要影响, 理清其影响规律对于制备大块非晶合金具有重要意义. 本文选取等离子旋转电极法所制粉末和1000 K退火态粉末为沉积材料, 采用激光立体成形技术沉积Zr55Cu30Al10Ni5块体非晶合金, 考察了粉末中已有晶化相对熔池及热影响区晶化行为的影响. 结果发现, 原始粉末组织由非晶相及粗大的Al5Ni3Zr2相组成; 当激光线能量较低时, 相应熔覆层的熔池和热影响区皆含有Al5Ni3Zr2相; 随着线能量的提高, 熔池中Al5Ni3Zr2相消失, 保持了非晶态, 但热影响区晶化加重, 并有大量Al5Ni3Zr2相析出; 当采用退火态粉末时, 即使线能量较小, 相应熔覆层仍主要由非晶构成, 几乎无Al5Ni3Zr2相析出. 这是由于原始粉末在退火时其微观结构发生重排, 与Al5Ni3Zr2相关的原子短程/中程有序结构减少, 导致已沉积层非晶区的热稳定性提高, 不利于Al5Ni3Zr2相析出. 可见, 提高线能量将会加剧非晶沉积体的晶化, 而粉末中的Al5Ni3Zr2团簇相状态对Zr55Cu30Al10Ni5合金沉积层的晶化有重要影响.  相似文献   

9.
非晶合金因具有独特的无序结构、优异或独特的各种性能以及良好的应用前景,而受到专家学者的广泛关注.其中,制备过程中的冷却速率对非晶的结构与性能起着非常重要的调控作用.本文采用分子动力学的模拟方法,分别以4种冷却速率获得相同尺寸的Zr_(48)Cu_(45)Al_7三元非晶合金的制备态原子结构模型,并模拟了各制备态模型的压缩变形过程.在此基础上系统地研究冷却速率对非晶微观结构及其变形行为的影响.研究表明:在施加大冷却速率时,非晶合金保留更多高温液态的结构特征,如五次对称性低的团簇数量较多,原子堆积较为松散,自由体积含量更多,并存在更多的"类液区".上述大冷却速率所对应的结构特征导致了非晶发生变形时,屈服强度降低,表现出软化行为,同时降低了剪切带形成与发生局域化变形的概率,从而提高了非晶的塑性.  相似文献   

10.
未经均匀化热处理的纯三元及含Zr,Ga元素的SC合金铸片经优化的HDDR工艺处理都可以制备各向异性Nd Fe B磁粉.这表明:元素的添加及SC铸片是否进行了均匀化热处理都不是HDDR磁粉各向异性形成的必要条件.磁粉各向异性形成的关键因素在于HDDR工艺的调节,即适当地加快歧化反应过程,减缓脱氢再结合过程以及控制脱氢再结合时的合适氢气压强均有利于磁粉各向异性的形成.本文将为制备低成本高各向异性磁粉提供重要的指导.  相似文献   

11.
The structural and magnetic properties of the synthesized pure and functionalized CoFe_2O_4 magnetic nanoparticles(NPs) are studied by analyzing the results from the x-ray diffraction(XRD), transmission electron microscopy(TEM), FT–IR spectroscopy, thermogravimetry(TG), and vibrating sample magnetometer(VSM). To extract the structure and lattice parameters from the XRD analysis results, we first apply the pseudo-Voigt model function to the experimental data obtained from XRD analysis and then the Rietveld algorithm is used in order to optimize the model function to estimate the true intensity values. Our simulated intensities are in good agreement with the experimental peaks, therefore, all structural parameters such as crystallite size and lattice constant are achieved through this simulation. Magnetic analysis reveals that the synthesized functionalized NPs have a saturation magnetization almost equal to that of pure nanoparticles(PNPs). It is also found that the presence of the turmeric causes a small reduction in coercivity of the functionalized NPs in comparison with PNP. Our TGA and FTIR results show that the turmeric is bonded very well to the surface of the NPs. So it can be inferred that a nancomposite(NC) powder of turmeric and nanoparticles is produced. As an application, the anti-arsenic characteristic of turmeric makes the synthesized functionalized NPs or NC powder a good candidate for arsenic removal from polluted industrial waste water.  相似文献   

12.
The photoluminescent (PL) emission and excitation behaviour of green-emitting CaAl2S4:Eu2+ powder phosphor is reported in detail. CaAl2S4:Eu2+ emission provides good CIE colour coordinates (x=0.141; y=0.721) for the green component in display applications. Powder with a dopant concentration of 8.5 mol% shows the highest luminescence efficiency. Temperature dependence of the radiative properties, such as luminescence intensity and decay time, was investigated. In particular, the Stokes shift, the mean phonon energy, the redshift, the energy of the f→d and d→f transition and the crystal field splitting of the CaAl2S4:Eu2+ emission were determined. The thermal quenching of the emission was examined.  相似文献   

13.
《中国物理 B》2021,30(7):78202-078202
Electron density plays an important role in determining the properties of functional materials. Revealing the electron density distribution experimentally in real space can help to tune the properties of materials. Spinel Li Mn2 O4 is one of the most promising cathode candidates because of its high voltage, low cost, and non-toxicity, but suffers severe capacity fading during electrochemical cycling due to the Mn dissolution. Real-space measurement of electron distribution of Li Mn2 O4 experimentally can provide direct evaluation on the strength of Mn–O bond and give an explanation of the structure stability.Here, through high energy synchrotron powder x-ray diffraction(SPXRD), accurate electron density distribution in spinel Li Mn2 O4 has been investigated based on the multipole model. The electron accumulation between Mn and O atoms in deformation density map indicates the shared interaction of Mn–O bond. The quantitative topological analysis at bond critical points shows that the Mn–O bond is relatively weak covalent interaction due to the oxygen loss. These findings suggest that oxygen stoichiometry is the key factor for preventing the Mn dissolution and capacity fading.  相似文献   

14.
This paper reports the emission analysis of green-emitting Tb3+-doped MgAl2O4 phosphors. Uniformity of the phase of the Tb3+-doped MgAl2O4 phosphor has been checked by X-ray diffraction (XRD) technique and show common bands existing in the results of Fourier transform infrared (FT-IR). This phosphor exhibits weak blue, orange emissions and a strong emission at λexci=350 nm. The blue and green-orange emissions are ascribed to 5D37FJ and 5D47FJ (where J=3-6) transitions of Tb3+ ions, respectively. These phosphors have shown a strong, more prominent green emission from 5D47F5 at 543 nm. The results have indicated that MgAl2O4:Tb3+ could be a potential candidate as agreen-emitting powder phosphor.  相似文献   

15.
Lit-doped Ho PO4 powders with a pure tetragonal phase are successfully synthesized by the co-precipitation method. It exhibits an obvious color change under sunlight and tri-phosphor fluorescent light illumination.The introduction of Litions into Ho PO4 can further enhance its photochromic property effectively. The doped Litions induce changes in the crystal structure. The spectral characteristics and thus photochromic properties of Ho PO4 are explored. The improved Ho PO4 powder, when used as a photochromic material, has wide-ranging prospects in security, decoration, and other applications.  相似文献   

16.
Submicron-sized NiAl2+X O4 fragments and nanocondensates of Ni-doped γ-Al2O3, Al-doped NiO and β-Ni(OH)2 were synthesized simultaneously by pulsed laser ablation of NiAl2O4 powder in water and characterized using X-ray/electron diffraction and optical spectroscopy. The NiAl2+X O4 is Al-enriched spinel with dislocations and subgrains. The Ni-doped γ-Al2O3 spinel has paracrystalline distribution (i.e., with fair constant longitudinal spacing, but variable relative lateral translations) of defect clusters and intimate intergrowth of θ-Al2O3 and 2x( \( \overline{1} \) 3 \( \overline{1} \) ) commensurate superstructure. The Al-doped NiO has perfect cubo-octahedron shape and as small as 5 nm in size. The β-Ni(OH)2 and 1-D turbostratic hydroxide lamellae occurred as a matrix of these oxide nanoparticles. The colloidal suspension containing the composite phases has a minimum band gap of 5.3 eV for potential photocatalytic applications.  相似文献   

17.
18.
 对采用自悬浮定向流法制备的Cu4Al纳米微粉进行了差热分析(DTA),发现在258,423和537 ℃存在不同量值的吸热峰。参照DTA曲线上吸热峰所对应的温度,分别对粉末样品进行了模拟退火实验,热处理后样品的X射线衍射(XRD)分析证实258和423 ℃处无结构相变发生,537 ℃处的吸热峰则对应于从Cu4Al向Cu3Al的相转变,并且伴随着Cu3Al晶粒的长大。对比实验结果表明,Cu4Al纳米微粉在440 ℃以下具有非常好的热稳定性,超过537 ℃将发生结构相变。  相似文献   

19.
The hyperfine splitting of Mu in evacuated SiO2 powder has been measured over the temperature range 17–300 K using the two frequency method. Above 100 K it is consistent with the vacuum value (4463.3 MHz) indicating the Mu atoms are moving freely between the particle grains. At lower temperatures it drops rapidly to 4437±4 MHz at 17 K. The effect is attributed to thermal adsorption on the SiO2 surface. Measurements were also made on an Ar coated powder between 7–62 K. The hyperfine splitting is consistent with the vacuum value over this range.  相似文献   

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