共查询到17条相似文献,搜索用时 78 毫秒
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在不同温度下,分别测量了掺杂偶氮材料、偶氮聚合物和偶氮液晶聚合物的光致双折射行为,并利用双e指数模型对光致双折射的动力学过程进行了拟合.实验结果表明,偶氮材料的光致双折射源于偶氮分子的光致异构和光致分子取向,光致双折射大小随温度的升高表现出先增大后减小的趋势.在抽运光的作用下,含偶氮材料的光致双折射包含一个由偶氮分子取向引起的快过程和一个由偶氮分子带动大分子取向引起的慢过程.关闭抽运光后,掺杂偶氮材料和偶氮聚合物表现为可逆的弛豫,而偶氮液晶聚合物则展现出长久光存储特性. 相似文献
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研究一种新型的并列式的高密度存储材料ADPA-PVK-PBA-TNF聚合物薄膜.在非吸收区用光抽运测试法研究了薄膜光致双折射,获得光致双折射变化值Δn=1.3×10-3,分析了该聚合物薄膜光致取向增强的物理和化学机理.探讨了抽运光对光致双折射的增强和抑制效应.在此基础上初步实现了多重角度复用信息存储、获得了较为清晰的全息存储图像.并讨论了图象存储的增强/抑制效应,利用这种效应可对存储图像处理或删除.
关键词:
掺杂偶氮苯聚合物薄膜
光致双折射
光全息存储
光致取向增强 相似文献
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不同生色团对聚合物薄膜全光开关效应的影响 总被引:6,自引:3,他引:3
在聚甲基丙烯酸甲酯(PMMA)中掺人不同的偶氮染料并制成薄膜样品,以调制的线偏振Ar^ 激光(514nrn,CW)作为控制光,He-Ne激光(632.8nm,CW)为信号光,研究了样品的光致双折射效应及全光开关效应。通过对样品的响应特性和全光开关效应进行比较,发现电子推拉势较强的生色团分子在控制光作用下,可以产生较大的光致双折射效应,但光响应速度较慢,其光致双折射效应以光致异构取向为主要机制;而对于具有较弱电子推拉势的生色团分子,其光致双折射效应则主要来自光致异构烧孔机制,虽然其光致双折射效应小,但光响应速度快。 相似文献
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介绍了在近代物理实验中开设偶氮染料甲基橙掺杂PVA薄膜的光致双折射特性实验.实验结果表明样品的光致双折射反应程度和激发光功率成正比例关系;在激发光功率一定的情况下,当激发光偏振方向与探测光偏振方向夹角为45°时样品的光致双折射反应程度达到最大. 相似文献
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偶氮苯侧链聚合物液晶薄膜的光致双折射和永久光学性存储研究 总被引:9,自引:8,他引:1
研究了一种含偶氮基侧链聚合物液晶薄膜,该液晶薄膜表现出显着的光致双折射(Δn~1.1×10-2).当关闭写光作用后,光致双折射的大小没有任何衰减,表现出永久光存储特性.光致双折射的擦除可通过将样品加热到接近其清亮点温度,或用一束圆偏振光照射来实现.分析了偶氮侧链聚合物永久性光学存储的物理机制. 相似文献
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The photoinduced birefringence in an azobenzene polymer is investigated at different temperatures between -20℃ to 50℃. It is found that there is a peak value of photoinduced birefringence in the temperature dependence of the photoinduced birefringence under a certain pumping intensity. With the pump light in 90mW/cm^2, the peak value of the photoinduced birefringence appeared at about 0℃ C. The effect of temperature on the photoinduced birefringence is discussed using the competition mechanism between the photoinduced reorientation and the thermal random motion. 相似文献
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Fuli Zhao Jun Wu Zhihua Pan Changshun Wang Jinwen Zhang Yi Zeng Xuemin Lu 《Optics Communications》2012,285(21-22):4180-4183
Photoinduced anisotropy and polarization holographic recording were investigated in an azobenzene-containing ionic self-assembly complex. The complex film was found to possess large photoinduced dichroism (D~0.36) and photoinduced birefringence (Δn~10?2). A noteworthy observation was that the photoinduced birefringence did not show any decay, but strongly increased after switching off the pump light at room temperature. The diffracted signals of the polarization holographic gratings, written by two orthogonally linear and circular polarized beams respectively, exhibited similar inverse relaxation behavior as the photoinduced birefringence after switching off the writing lights. A discussion about the mechanism accounting for the abnormal relaxation process of photoinduced birefringence is presented. 相似文献
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A. V. Trofimova A. I. Stankevich V. V. Mogil’nyi 《Journal of Applied Spectroscopy》2009,76(4):585-591
We present the results of an experimental study of photoanisotropy in polymethylmethacrylate layers containing phenanthrenequinone.
We consider the characteristic features of inducing birefringence for different contents of the photosensitive molecules and
temperatures of the layer. We propose a mechanism for appearance of photoinduced birefringence; we explain the concentration
and temperature dependences of its magnitude based on the dimerization of phenanthrenequinone, established from the IR spectra.
We have observed stability of the photoinduced birefringence relative to subsequent exposure to optical radiation, which can
be used to improve contrast when converting polarization phase images to amplitude images. 相似文献
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Two-photon absorption and photoinduced anistropy of a methyl orange/Au nanoparticles composite system were investigated. Open aperture Z-scan measurements demonstrated that the absorption cross section of methyl orange in an Au colloid solution can increase 42-fold compared to purified that of a methyl orange aqueous solution. Meanwhile, a 2.6-fold enhancement of the photoinduced birefringence of methyl orange in the presence of Au was also observed. The mechanism accounting for the enhancement of two-photon absorption coefficient and photoinduced birefringence was discussed in terms of the localized field effect via surface plasmon resonance of Au nanoparticles, which was further confirmed using the fluorescence spectrum technique. 相似文献
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对6-(4-((4-(十八烷氧基-)苯基)二氮烯基)苯氧基)-1-己醇(E-1-ol)的光致变色、双折射和全息光存储特性进行了研究.以488 nm的氩离子(Ar+)激光为抽运光,632.8 nm 的氦氖(He-Ne)激光为探测光,研究了透射信号强度随时间的变化关系;在10 mW~160 mW的范围内,研究了透射信号强度的最大值随抽运光功率的变化;经计算,在各抽运光功率下,获得的光致双折射值(δn)达10-2量级,最大激光功率下,获得的δn为2.8×10-2.对透射信号强度随时间的变化曲线进行了理论拟合,得出曲线的上升和下降符合双指数增长和衰减,时间响应常量分别是:上升阶段:t1=4.8 s,t2=85.8 s;下降阶段:t1=1.9 s,t2=27.6 s.用等强度s偏振的两束Ar+激光为写入光, He-Ne光为读出光,研究了衍射信号强度随时间的变化及写入光功率改变时,衍射信号强度最大值与写入光功率的变化关系;对衍射信号强度随时间变化的动力学过程进行了理论拟合,得出光栅生长和衰减也有快和慢两个过程,光栅生长时间响应常量为:t1=3.9 s,t2=33.9 s,光栅衰减时间响应常量为 t1=1.8 s,t2=60.1 s. 相似文献
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Bassam Abbas Yousef T. Salman Moustafa S. El-Daher 《Journal of Macromolecular Science: Physics》2015,54(12):1457-1465
Photoinduced birefringence in poly(methyl methacrylate) (PMMA), polymeric thin films doped with di-azo Sudan G was investigated. A pump-probe method was used to study the dynamic behavior of the birefringence. The mechanism for the inducement of birefringence is discussed in terms of the photoisomerization of the di-azo Sudan G molecules. The results showed that the dynamic evolution of the photoinduced birefringence was such that the average birefringence increased, saturated, and then decreased with respect to the laser pump intensity. Also, an exponential-like relationship was observed between both the saturation and the isotropic states of the averaged transmitted probe beam (expressing the residual anisotropy) and the birefringence on one hand, and the intensity amplitudes of the pumping powers on the other hand. 相似文献