Jerks-and-jumps type electrode diagnostics in a DBD reactor by OES

This work reports on the successful measurement of the second-positive N₂(B ? C) and the first-negative N ₂ ⁺ (B ? X) band system emissions intensities for the transitions observed in the 337.1-and 391.4-nm wavelengths, respectively, by optical emission spectroscopy (OES). By determining the electron energy distribution function and the spectroscopy results, it is possible to obtain the average electron energy of the system. Two dielectric barrier discharge reactors of rectangular geometry have been used for this purpose: a first reactor, endowed with a single dielectric and a modified electrode, in which discontinuities of the jerks-and-jumps type were manufactured in order to confine the discharge, and a second reactor of conventional flat electrodes and a double dielectric. The final objective of this study is to ascertain which of the reactors provides a higher efficiency in the NO _x removal from a gas mixture. The results indicate that, for the first reactor, energies on the order of 11 eV were reached, while lower energies up to 8 eV were obtained in the second reactor. This indicates clearly that the first reactor is close to the corona discharge behavior. As to the removal efficiency, the first reactor showed a better performance with inferior concentrations around a 50-μmol/mol mixture.     

Spectroscopic diagnostics of barrier-discharge plasma in mixtures of cadmium diiodide vapor with gases

The spectral characteristics of the emission of atmospheric-pressure gas-discharge plasma in mixtures of cadmium diiodide vapor with gases (Ne, Ar, Kr, Xe, and N₂) were investigated along with the time characteristics of the voltage and current. The gas-discharge plasma was produced and excited by a barrier discharge at a repetition rate of sine voltage pulses of up to 140 kHz. The discharge emission was analyzed in the spectral range 200–900 nm with a high resolution (0.05 nm). Radiation from exciplex CdI(B-X) molecules and excimer I₂* molecules was revealed, as well as the atomic lines of cadmium, iodine, and inert gases. In a mixture with xenon, radiation from exciplex molecules XeI(B-X, B-A) was also found. This radiation prevailed in the spectra at mixture temperatures up to 150°C. The further increase of the temperature leads to the prevalence of the CdI(B-X) radiation. It was found that the most intense CdI(B-X) radiation is observed in mixtures CdI₂/Xe(N₂)/Ne. Regularities in the spectral characteristics of the emission of the gas-discharge plasma are discussed.     

Emission und Schwingungsverteilung der 1. neg. Gruppe und der 2. pos. Gruppe in einem Stickstoffplasma

The intensity of the first negative system ofN ₂ ⁺ (B ² Σ _u ⁺ -X ² Σ _g ⁺ and of the second positive system ofN ₂(C ³ Π _u -B ³ Π _g ) was observed in the discharge and in the afterglow as function of discharge current. An a. c. discharge in pure nitrogen was used at pressures of about 5 torr. The intensity of the first negative system ofN ₂ ⁺ — in the discharge and in the afterglow — rises to a maximum and decreases with further increase of the discharge current. The afterglow intensity of the second positive system ofN ₂ shows a maximum too. In the discharge, however, the intensity of the second positive system ofN ₂ increases with increasing discharge current. The relative population of the vibrational levelsN _v′ =i/N _v′ =0 (i=1,2,3,4) of theB ² Σ _u ⁺ state ofN ₂ ⁺ , in the discharge and in the afterglow, increases with increasing discharge current, while the relative population of the vibrational levelsN _v′ =i/N _v′ =0 (i=1, 2, 3, 4) of theC ³ Π _u state ofN ₂ reaches a maximum in the discharge. There seems to be evidence that the first negative system ofN ₂ ⁺ is not excited by electron impact withN ₂ molecules in ground state under the discharge conditions in question.     

Spectral characteristics of a barrier discharge in cadmium dihalide vapor-inert gas mixtures

Spectral characteristics of a barrier-discharge plasma produced in atmospheric-pressure mixtures of cadmium diiodide and cadmium dibromide vapors with neon, krypton, and xenon at a repetition rate of sine voltage pulses up to 130 kHz are studied. The emission from the discharge is studied within the spectral range 200–900 nm with a resolution of 0.05 nm. Emission of exciplex molecules CdI(B → X) and CdBr(C, B → X), and cadmium and inert gas atoms is revealed, as well as emission of exciplex molecules XeI(B → X, A) and XeBr(B → X, A) in xenon-containing mixtures. The emission of xenon halides prevails in the spectra at a mixture temperature up to 200°C. With a further temperature increase, the emission of cadmium halides becomes dominating. It is ascertained that the most intense emissions of CdI(B → X) and CdI₂/CdBr₂/Xe/Kr and CdBr(B → X) molecules are observed, respectively, in CdI₂/CdBr₂/Xe/Kr and CdI₂/CdBr₂/Xe mixtures. The cadmium dihalide-inert gas mixtures are of interest for the use as a radiating gas in a multiwavelength and broadband excilamp emitting in the UV and visible spectral ranges.     

Plasma-volume generation of H<Superscript>−</Superscript> ions in a low-voltage xenon-hydrogen discharge. II

A low-voltage xenon-hydrogen discharge is considered theoretically at an interelectrode distance of L = 1 cm and cathode emission current densities of j _s = 2–20 A/cm². Basic parameters of the discharge plasma, in particular, the total hydrogen and xenon densities, are optimized to attain the maximum possible density of negative hydrogen ions \(N_{H^ - } (L)\) at the plasma-anode boundary. The distributions of the plasma parameters over the discharge gap are calculated for optimized regimes. According to calculations, at intermediate cathode emission current densities (j _s ≈ 5–10 A/cm²) in optimized discharge regimes, the density of negative hydrogen ions in the anode region of the plasma is \(N_{H^ - } (L)\) ≈ (1.5–2.5) × 10¹² cm^?3 and the total plasma pressure is p ₀ = 0.5–0.6 Torr.     

Using a chiral anomaly to determine the number of colors

The N_c dependence of PPPγ vertices, where P is a pseudoscalar meson and N_c is the number of colors, is analyzed with allowance for the N_c dependence of the quark charges. It is shown that the reactions Kγ → Kπ and π^±γ → π^±η and the decay η → π⁺π^?γ are the best processes for determining N_c. The cross section σ(π^?γ → π^?η) as measured by using the VES facility at IHEP agrees with the value of N_c=3.     

Photon distribution functions of the fluorescence photons from a single nanoparticle in various photon counting methods

Simple expressions have been derived for three photon distribution functions w _N ^M (T), w _N ^Z (T), and w _N ^O (T) corresponding to three different methods for counting fluorescence photons from a single nanoparticle excited by continuous laser radiation. In contrast to the previously derived expressions represented in the form of N multiple integrals, the new expressions contain only single or double integrals of Poisson functions, which makes it possible to easily perform the numerical calculation of the photon distribution. The simplest photon counting method corresponds to the lengthiest function w _N ^M (T); on the contrary, the simplest function w _N ^O (T) corresponds to the most complex photon counting method. The functions w _N ^M (T), w _N ^Z (T), and w _N ^O (T) are noticeably different in short time intervals T; however, the distributions calculated using these functions are almost indistinguishable from each other in long T intervals. This circumstance makes it possible to use the simplest function w _N ^O (T) to consider the photon statistics measured by the simplest method. This possibility is particularly important for investigating the fluorescence photon statistics, where the intensity fluctuates.     

Electric quadrupole moments of light nuclei and transition probabilities for them in the multiquantum approximation of the orthogonal scheme

A method for calculating electric quadrupole moments of light nuclei and probabilities of electric quadrupole transitions in them in the multiquantum approximation of the orthogonal scheme is proposed. Specific calculations of these quantities are performed for the ₄ ⁸ Be nucleus with allowance for all U(3(A ? 1)) states characterized by the λ = [44] Young diagram, the quantum numbers K _min and K _min + 2 of the O(3A ? 1)) group, and the number E = K + 2N (N = 0, 1, …, 9) of oscillator quanta. It is shown that an extension of the basis from the E = K _min to the E = K _min + 2 approximation leads to an increase of 15 to 45% in the electric quadrupole moments and to an increase in the transition probabilities B(E2) by a factor of 1.6 to 2.8. The inclusion of E = K + 2N (N = 0, 1, …), states involving multiquantum excitations (ρ excitations) increases additionally the results by 10 to 30%. The results of these calculations are compared with their counterparts obtained in the multiquantum approximation of the unitary scheme.     

Charge transfer over localized states in a TlS single crystal

It is revealed that TlS single crystals exhibit a variable range hopping conduction along a normal to their natural layers at temperatures T ≤ 230 K in a dc electric field and a nonactivated hopping conduction at low temperatures in strong electric fields. Estimates are made for the density of states near the Fermi level (N _F = 2.8 × 10²⁰ eV^?1 cm^?3 and their energy spread (ΔW = 0.02 eV), the localization radius (a = 33 Å), the average jump distance in the region of activated (R _av(T) = 40 Å) and nonactivated (R _av(F) = 78 Å) hopping conduction, and also the drop in the charge carrier potential energy along the jump distance in an electric field F: eFR = 0.006 and 0.009 eV at F = 7.50 × 10³ and 1.25 × 10⁴ V/cm, respectively.     

Optical characteristics of radiation from N<Stack><Subscript>2</Subscript><Superscript>*</Superscript></Stack> dimers in a barrier discharge

The spectral and power characteristics of radiation of the second positive system of nitrogen (C ³Π _u → B ³Π _g ) in Ar-N₂ and Ar-N₂-Cl₂ mixtures excited by barrier discharge have been studied experimentally. Addition of argon to N₂ increased the radiation power by sixfold. In the triple mixture Ar-N₂-Cl₂ = 210/0.5/0.005, minor chlorine additions increased the intensity of the C ³Π _u → _B ³Π _g transition by 26% compared to Ar-N₂ mixtures. Radiation power density of 2.7 mW/cm² has been achieved. In both binary and triple mixtures, the second positive system of nitrogen was the major contributor to radiation, while the contributions of the fourth positive system of N ₂ ^* (D ³Σ _u ⁺ → B ³Π _g ), the Vegard-Kaplan transition of N ₂ ^* (A ³Σ _u ⁺ → X ¹Σ _g ⁺ ), and the D′ → A′ band of Cl ₂ ^* were negligibly small.     

Parametric study of radiofrequency helium discharge under atmospheric pressure

The parameters of radiofrequency helium discharge under atmospheric pressure were studied by electrical and optical measurements using high voltage probe, current probe and optical emission spectroscopy. Two discharge modes α and γ were observed within certain limits. During α to γ mode transition, a decrease in voltage (280–168 V), current (2.05–1.61 A) and phase angle (76^°–56^°) occurred. The discharge parameters such as resistance, reactance, sheath thickness, electron density, excitation temperature and gas temperature were assessed by electrical measurements using equivalent circuit model and optical emission spectroscopy. In α mode, the discharge current increased from 1.17 to 2.05 A, electron density increased from 0.19 × 10¹² to 0.47 × 10¹² cm^?3 while sheath thickness decreased from 0.40 to 0.25 mm. The excitation temperatures in the α and γ modes were 3266 and 4500 K respectively, evaluated by Boltzmann’s plot method. The estimated gas temperature increased from 335 K in the α mode to 485 K in the γ mode, suggesting that the radiofrequency atmospheric pressure helium discharge can be used for surface treatment applications.     

On the theory of the resonant interaction of electrons with a high-frequency electric field in one-dimensional two-barrier nanostructures with symmetric barriers of finite height and width

The theory of the interaction of electrons with a high-frequency electric field in one-dimensional two-barrier nanostructures with symmetric barriers of finite height and widths was developed. An exact solution to the Schrödinger equation was found for electrons in this nanostructure in the absence of high-frequency electric field. An analytical expression for the direct current I ₀ induced in this structure by an incident electron flux with energy ε differing slightly from the resonant level energy ε _r (|ε ? ε _r | << ε _r ) was derived. In the small-signal approximation, the active (field-phased) component I _c of the alternating electric current was calculated. At ε > ε _r , the current I _c is negative in the entire frequency range, which suggests the possibility of ac electric field amplification and generation in the two-barrier resonant-tunneling structure with the barriers of finite height and width. Within the applicability of the theory (?ω << ε _r ), the frequency at which amplification and generation of the ac electric field are possible reaches ω ? 10¹³ s ^?1; the power transferred by electrons to the field is ～1 W/cm².     

Photoluminescence in germanium with a quasi-equilibrium dislocation structure

The dislocation-related photoluminescence of n-Ge single crystals with a quasi-equilibrium structure of 60° dislocations is investigated at a temperature of 4.2 K. It is shown that the dislocation-related photoluminescence spectra are described by a set involving from 8 to 13 Gaussian lines with a width of less than 15 meV. With due regard for the data available in the literature, the Gaussian lines with maxima at energies in the range 0.47 < E _m ≤ 0.55 eV are assigned to the emission of 90° Shockley partial dislocations involved in quasiequilibrium segments of 60° dislocations with different values of the stacking fault width Δ (Δ = Δ₀, Δ < Δ₀, and Δ > Δ₀). It is revealed that the d8 line at the energy E _m = 0.513 eV, which corresponds to the emission of straight segments with the equilibrium stacking fault width Δ₀, dominates in the photoluminescence spectra only at dislocation densities N _D < 10⁶ cm^?2. As the dislocation density N _D increases, the intensity of the d8 line decreases with the d7 line (E _m ≈ 0.507 eV) initially and the d7 and d6 lines (E _m ≈ 0.501 eV) then becoming dominant in the photoluminescence spectrum. The d7 and d6 lines are attributed to the emission of segments with stacking fault widths Δ < Δ₀. Possible factors responsible for the formation of stacking faults with particular widths Δ ≠ Δ₀ for quasi-equilibrium dislocations are discussed.     

Energy and momentum losses of a magnetized plasma via familon emission

Familon emission from a dense magnetized plasma in the processes e^? → e^?φ and e^? → μ^?φ is investigated. The contribution of these processes to the energy losses of a supernova remnant is calculated. It is shown that, at a late stage of the cooling of a supernova remnant, the energy loss of a plasma via familon emission may become commensurate with the loss via neutrino emission. It is found that, because of asymmetry of familon emission in the process e^? → gm^?φ, there arises a force acting on the plasma.     

Quark microscopic picture for vector and pseudoscalar mesons in the nucleon and their quasielastic knockout by high-energy electrons

A technique for projecting a multiquark wave function in the microscopic model of a ³P⁰ scalar fluctuation onto the virtual-decay channels N → N + ρ and N → N + π is formulated (at a more general level for the latter than previously). The amplitude for the electromagnetic transition ρ + γ _T ^* → π in electron-induced quasielastic rho-meson knockout followed by rho-meson conversion to a pion is considered. Theoretical results obtained in this way are contrasted against available experimental data, and reasonable agreement is found for cross-section values. This confirms a universal character of the ³P₀ model. The precision of relevant experiments is as yet insufficient for comparing the momentum distribution of the rho meson from the channel N → N + ρ with its theoretical counterpart.     

High-field autosolitons in an electron-hole plasma in <Emphasis Type="Italic">p</Emphasis>-Ge

The formation of high-field thermodiffusion autosolitons was studied experimentally in a photogenerated electron-hole plasma heated up by an electric field in p-Ge samples oriented along the 〈111〉 axis at T=77 K. Measurements of the current-voltage characteristics, electric field distributions along the samples, and IR emission in the wavelength range λ=1.65–10 μm showed that the arising of an autosoliton was accompanied by the appearance of N-shaped current-voltage characteristic regions. Autosolitons were formed at electron-hole plasma concentrations n≥1×10¹⁴ cm^?3 and field strengths E≥500 V/cm. They manifested themselves as static, moving, and pulsating strata with field strengths E _as =1000–20000 V/cm and carrier temperatures T _e ≥1000 K. We also observed a turbulent electron-hole plasma state when autosolitons chaotically appeared and disappeared in the samples. The multivalley band structure of germanium influenced the dynamics of autosoliton formation; intervalley transfer of electrons in the strong field of autosolitons caused a three-step autosoliton field growth.     

Density functional study of $$\hbox {AgScO}_2$$: Electronic and optical properties

Dielectric relaxation studies of binary (jk) polar mixtures of tetrahydrofuran with N-methyl acetamide, N,N-dimethyl acetamide, N-methyl formamide and N,N-dimethyl formamide dissolved in benzene(i) for different weight fractions (w _{j k} ’s) of the polar solutes and mole fractions (x _j ’s) of tetrahydrofuran at 25 ^°C are attempted by measuring the conductivity of the solution under 9.90 GHz electric field using Debye theory. The estimated relaxation time (τ _{j k} ’s) and dipole moment (μ _{j k} ’s) agree well with the reported values signifying the validity of the proposed methods. Structural and associational aspects are predicted from the plot of τ _{j k} and μ _{j k} against x _j of tetrahydrofuran to arrive at solute–solute (dimer) molecular association upto x _j =0.3 of tetrahydrofuran and thereafter solute–solvent (monomer) molecular association upto x _j =1.0 for all systems except tetrahydrofuran + N,N-dimethyl acetamide.